1112 results about "Sulfide" patented technology

The invention belongs to the field of photocatalytic materials, and particularly relates to a high-entropy sulfide and a preparation method and application thereof. The high-entropy sulfide is granular, the molecular general formula is (MnaFebCocCudZe) xS, x is equal to 1, and the atomic ratio of Mn to Fe to Co to Cu to Zn is a: b: c: d: e of (1-2): (1-2): (1-2): (1-2): (1-2): (1-2): (1-2). The preparation method comprises the following steps: S1, dissolving metal salt in a mixed solvent of isopropanol and glycerol according to the atomic ratio of metal elements, and carrying out solvothermal reaction to obtain a precursor; and S2, dispersing the precursor in ethanol, adding thioacetamide as a sulfur source, and carrying out solvothermal reaction to obtain the high-entropy sulfide. The high-entropy sulfide disclosed by the invention is used as a photocatalytic material and shows excellent photocatalytic performance.

The invention provides a wastewater advanced oxidation catalyst and a preparation method and application thereof, the wastewater advanced oxidation catalyst is of a core-shell structure, the core is activated carbon containing copper oxide and optional ferrous sulfide, and the shell is a silicon oxide-aluminum oxide compound containing nano ferrous sulfide. The invention further provides a preparation method of the wastewater advanced oxidation catalyst and application of the wastewater advanced oxidation catalyst in organic wastewater treatment. The wastewater advanced oxidation catalyst has the characteristics of high catalytic degradation capability on organic pollutants and the like, solves the problem of copper dissolution, and improves the long-term effectiveness of the catalyst.

The invention relates to the technical field of waste gas treatment, and discloses a desulfurization purification device and process based on industrial waste gas treatment.The desulfurization purification device comprises a desulfurization tower, a rotational flow mechanism, a transmission mechanism and a solid-liquid separation mechanism and further comprises a collection box fixedly installed at the bottom of the desulfurization tower and a dust removal mechanism fixedly installed on one side of the desulfurization tower; according to the technical scheme, through the combined action of spiral blades in the rotational flow mechanism and the transmission mechanism, an efficient rotating flow field is formed, the retention time of waste gas in the tower is prolonged, sulfide and atomized reaction liquid are more fully contacted, chemical reaction of the reaction liquid on the sulfide is promoted, and therefore efficient sulfide removal and purification are achieved; wherein the rotational flow mechanism endows the waste gas with tangential speed through inclined blades in the rotational flow mechanism, so that the waste gas rotates, a spiral ascending flow field is formed in the desulfurization tower, the retention time of the waste gas is prolonged, the contact opportunity of the waste gas and atomized reaction liquid is increased, sulfide absorption is facilitated, and the desulfurization purification effect is improved.

The invention relates to the technical field of mineralogy, and provides a prediction method for mineral flotation yield. According to the method, the content and dissociation degree of the target minerals under different size fractions are accurately obtained through the technologies of ore grinding, system screening and automatic mineralogy analysis, the yield prediction method based on the mineral selectability physical model is established, the crossing from elements to minerals and from the whole to the size fractions can be achieved, and the yield prediction accuracy is improved. And a brand-new, scientific and reliable technical reference is provided for precise prediction and process optimization of the sulfide ore flotation yield.

The invention relates to the technical field of lithium ion batteries, in particular to a preparation method of an interface-modified high-rate lithium iron phosphate positive electrode material, which is used for solving the problems of low interface impedance, low rate capability and low energy density of the existing lithium iron phosphate. According to the preparation method, zirconium-niobium co-doped iron phosphate is used as a precursor of the lithium iron phosphate positive electrode material, a lithium ion diffusion channel is widened, the lithium ion diffusion coefficient is improved, meanwhile, an olivine structure framework is provided, a wider tunnel space is provided for lithium ion migration, zirconium-niobium provides additional electrons, and the electron conductivity is improved through cooperation of the zirconium-niobium co-doped iron phosphate and the olivine structure framework; li2ZrCl6-LiCl interface modification can isolate sulfide electrolyte from being in direct contact with a positive electrode material, and interface side reaction is inhibited; carbon nanotube coating can enhance the conductivity, reduce erosion, improve the diffusion coefficient of Li < + > and the stability of the material structure, and improve the charge-discharge rate.

The invention provides a method and a device for recovering valuable metals from copper smelting slag, and the method for recovering valuable metals from copper smelting slag comprises the following steps: before molten copper smelting slag is transferred into a slag ladle for cooling, adding first gas, gypsum slag and nitrogen into the molten copper smelting slag in a plasma injection mode, and after injection is completed, adding second gas into the slag ladle for cooling; and metal gaseous substances and copper slag are obtained. Carrying out post-treatment and flotation on the copper slag to obtain a valuable metal sulfonium phase and depleted slag; wherein the first gas is one or more of CO, H2, CO2 and CH4; and the metal gaseous substances comprise gaseous lead and gaseous zinc. And the valuable metal sulfonium phase is sulfides of copper, iron, lead and zinc. The process method and device are simple, the production time is shortened, CO2 emission can be reduced, secondary pollution caused by waste water and waste residues is avoided, and the green metallurgy requirement is met.

This invention relates to a method for the combined leaching of high-silicon zinc roasted ore and high-sulfur zinc oxide powder, belonging to the field of hydrometallurgical technology. The high-sulfur zinc oxide powder is leached neutrally to obtain zinc oxide leaching residue and zinc powder leaching solution. The zinc powder leaching solution is then mixed with high-silicon zinc roasted ore slurry for controlled silica leaching of the high-silicon zinc roasted ore to obtain zinc ore leaching residue and zinc ore leaching solution. The zinc powder leaching residue and zinc ore leaching residue are mixed and then subjected to low-acid leaching to obtain low-leaching residue and low-leaching solution. The low-leaching residue is then subjected to hot acid leaching to obtain hot-leaching residue and hot-leaching solution. The hot-acid residue is then subjected to high-acid leaching to obtain lead-silver slag product and high-leaching solution. The hot-leaching solution is neutralized and reduced by high-sulfur zinc oxide powder to obtain neutralized solution and neutralized residue. The neutralized solution is then subjected to mineralization and iron precipitation to obtain hematite product and iron-removed solution. This invention can effectively control the leaching of silicon in the high-silicon zinc roasted ore leaching process, and simultaneously realize the oxidative leaching of sulfides in zinc oxide powder and the reductive leaching of zinc ferrite in zinc roasted ore, thus simplifying the leaching process of zinc roasted ore and zinc oxide powder.

An electrode composite material and a method of making same are disclosed. A mixture that includes lithium sulfide (Li2S) particles containing a Li2S compound, carbon particles, and halogenated lithium phosphorous sulfide (LPS-X) particles containing an LPS-X (X is F, Cl, Br, and / or I) compound are provided. The LPS-X particles have crystallinity which can be confirmed with XRD of the LPS-X particles or the mixture showing XRD peaks indicative of crystalline LPS-X. The mixture does not include lithium phosphorous sulfide (LPS) particles made of an LPS compound. The mixture is ball-milled to provide a ball-milled composite material. At least part of the LPS-X compound contained in at least part of the LPS-X particles is converted to the LPS compound. XRD of the ball-milled composite material shows none of the XRD peaks indicative of crystalline LPS-X.

The invention provides a sulfide solid electrolyte and a preparation method of the sulfide solid electrolyte. The sulfide solid electrolyte is a phosphorus-free solid electrolyte, and has a chemical general formula as shown in a formula I: Li < 7-m > MS < 6-m-n > OnXm, wherein M comprises at least one of As, Sb and Bi, and X comprises at least one of F, Cl, Br and I and 1lt; mlt; mlt; 2, 0.5 < = nlt; and 3, the sulfur-oxygen ratio S / O in the formula I is greater than 1. The sulfide solid electrolyte has excellent ionic conductivity and air stability.

The invention provides a sulfide solid electrolyte with an MOF structure, and a preparation method and application thereof, the process is designed from a molecular level, and lithium ions and sulfur elements are used as basic components for constructing an MOF skeleton through in-situ combination of excellent ion conduction capability of the sulfide electrolyte and structural advantages of an MOF material; the bulk sulfide electrolyte with a regular three-dimensional multi-channel crystalline MOF structure is directly synthesized and constructed by taking a sulfur element as an inherent component of an MOF skeleton in a breakthrough manner, so that the intrinsic design of the sulfide MOF skeleton electrolyte is realized, and the problems of interface bonding, performance stability and ion transmission path are fundamentally solved; a sulfur element in the electrolyte is derived from sulfur atoms (such as-SH and-S-) of a ligand and participates in construction of an MOF skeleton, the electrolyte has the advantages of good interface stability, regular ion transmission channels, adjustable mechanical properties and the like, and the problems of poor interface stability, irregular ion transmission paths and the like of a sulfide electrolyte in the prior art are solved.

The invention provides an impurity removal method of a gallium-rich solution for a gallium-based fluorescent powder precursor, and belongs to the field of preparation of gallium-based fluorescent powder precursors. The method comprises the following steps: adding an oxidizing agent into an initial gallium-rich solution to carry out a first reaction so as to remove organic impurities in the initial gallium-rich solution and obtain a first gallium-rich solution; adding a composite impurity removal reagent into the first gallium-rich solution to carry out a second reaction to remove impurity elements such as calcium, silicon and vanadium in the first gallium-rich solution so as to obtain a second gallium-rich solution; and adding a sulfide type reagent into the second gallium-rich solution to carry out a third reaction so as to remove copper and iron impurity elements in the second gallium-rich solution, thereby obtaining the gallium-rich solution for the gallium-based fluorescent powder precursor. According to the method, various key impurity elements such as organic matters, alkaline earth metals, metalloids and heavy metals are directionally and efficiently removed through the impurity removal logic of oxidation impurity breaking, synergistic precipitation and deep vulcanization, so that the total content of the key impurity elements in the gallium-rich solution is remarkably reduced.

The invention discloses asphalt-based hard carbon, a preparation method thereof and a sodium-ion battery negative electrode material, and relates to the technical field of sodium-ion batteries. The preparation method of the asphalt-based hard carbon comprises the following steps: S1, mixing an asphalt precursor, a sulfur source and a cross-linking agent, and performing cross-linking vulcanization treatment at a first temperature to obtain a primary product; s2, performing carbonization treatment on the primary product at a second temperature to obtain asphalt-based hard carbon; the sulfur source is any one of elemental sulfur, thiourea, dimethyl sulfide and sulfide, or any two of elemental sulfur, concentrated sulfuric acid, thiourea, dimethyl sulfide and sulfide. By adopting the method, the type of the sulfur source is controlled, and the sulfur source and the cross-linking agent are added, so that the reversible capacity and the rate capability of the asphalt-based negative electrode material can be effectively improved, and the application field of the asphalt-based negative electrode material is widened.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for enhancing peroxide to improve the leaching rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; an oxidizing agent is added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore under the catalytic action of ultraviolet light, and ore pulp activation liquid is formed; and the pH of the ore pulp activating solution is adjusted to 9-12, a gold leaching agent is added into the ore pulp complexing solution, and stirring gold leaching treatment is conducted. According to the method, efficient oxidation of sulfide and arsenide is achieved under the mild condition through the synergistic effect of photocatalysis and chemical oxidation, the leaching rate of gold is remarkably increased, compared with a conventional peroxide oxidation method for pretreatment, the leaching rate can be increased by 10%-35%, and meanwhile the agent use amount and environmental pollution are reduced.

The invention discloses a method for separating valuable metal in a waste photovoltaic welding strip through reduction smelting-vacuum gasification-vulcanization, and belongs to the technical field of resource recycling. The method comprises the steps that the waste photovoltaic welding strip is placed in a reducing atmosphere and heated for reduction smelting, so that carbon impurities on the surface of the waste photovoltaic welding strip are removed, tin, lead, silver and copper oxides on the surface are reduced, and a copper-tin-lead-silver alloy is obtained; then, heating the decarbonized and deoxidized photovoltaic welding strip under a vacuum condition, and carrying out vacuum gasification separation to obtain condensed metal lead and a copper-tin-silver alloy; and finally, sulfur is added into the copper-tin-silver alloy for vacuum vulcanization-separation, and volatile matter stannous sulfide and residual copper-silver alloy are obtained. According to the method, valuable metals in the waste photovoltaic solder strip can be efficiently separated, and the method has the advantages of being green and economical.

The invention relates to preparation and application of a substituted alkyl sulfide (sulfoxide) arylamine derivative. Specifically, the invention relates to a compound as shown in a formula (I), or an isotope labeled compound thereof, or an optical isomer, a geometric isomer, a tautomer or an isomer mixture thereof, or a pharmaceutically acceptable salt thereof, and an application of the compound in preparation of an acaricide for preventing and controlling pest mites, wherein the compound is used as a substituted alkyl sulfide (sulfoxide)-based arylamine derivative. The compound can achieve a better pest mite control effect at a lower dosage.

The invention relates to the technical field of mineral resource prospecting exploration, in particular to a prospecting prediction method based on a compound rock mass anatomy porphyry-skarn composite mineralization system. The control factors and formation mechanism of the ore deposit are clarified, and the deep earth dynamics process of porphyry mineralization development is disclosed. Through typical ore deposit fine dissection, the space-time structure characteristics of mineralization in different structural evolution stages are discussed; according to the method, mineral in-situ micro-area surface scanning and sulfide isotope in-situ tracing technologies are utilized to determine occurrence forms of metallogenic elements, restrain activation migration behaviors of microelements, find out sources of metallogenic metal substances, reveal a superposition metallogenic development mechanism and provide theoretical basis and technical support for prospecting exploration.

Provided is a composite active material that is capable of more suppressing deterioration of an active material caused by the moisture of the composite active material than a conventional composite active material by increasing a permissible water content of a layer of the composite active material. The composite active material that is used for solid-state batteries includes: an active material; a first coat layer that contains a fluoride-containing first solid electrolyte, the first coat layer coating at least part of a surface of the active material; and a second coat layer that contains a sulfide-containing second solid electrolyte, and a solvent, the second coat layer coating at least part of the first coat layer, wherein a water content of the composite active material at 200° C. measures at most 823 ppm on a Karl Fischer titrator.

The invention relates to the field of sewage treatment, and discloses a sewage treatment method based on desulfurization and denitrification, which comprises the following steps: S1, magnetic flocculation-electro-catalysis pretreatment: adding a polyaluminum chloride-magnetic powder composite flocculant into sewage through a magnetic flocculation reactor to form a magnetic floc, removing suspended matters through a permanent magnetic separation device, and then entering an electro-catalysis oxidation pond, carrying out electrolysis by taking titanium-based lead dioxide as an anode and active carbon fiber as a cathode; and S2, performing synchronous desulfurization and denitrification on the three-dimensional electrode fluidized bed, feeding pretreated effluent into a three-dimensional electrode fluidized bed reactor, filling activated carbon particles as a third electrode, and adding a composite flora of thiobacillus and denitrifying bacteria. The efficient removal of sulfides, total nitrogen, total phosphorus and chemical oxygen demand in the sewage is realized through a multi-stage synergistic process of magnetic flocculation-electrocatalysis pretreatment, synchronous desulfurization and denitrification of a three-dimensional electrode fluidized bed, deep denitrification and dephosphorization of a denitrification filter tank and catalytic ozonation-membrane separation combined deep treatment.

The invention provides the preparation method of the efficient photocatalyst which is simple and convenient, does not contain noble metals or toxic metals and does not need a cocatalyst. In the invention, a strategy for synergistically improving the catalytic performance by regulating and controlling sulfur vacancies and doping copper ions is provided, zinc indium sulfide (ZIS) is selected as a substrate material, the content of sulfur atoms is increased in the synthesis process through a solvothermal method to introduce the vacancies, and Cu (NO) is synchronously added to introduce Cu, so that the catalytic performance is improved. The Cin-VZIS catalyst is successfully prepared (n is a doping proportion relative to Zn). A TEOA aqueous solution is used as a sacrificial agent to carry out photocatalytic hydrogen production reaction, the synergistic effect of the two modification modes can significantly improve the performance of the catalyst, and when the copper doping ratio is 1.5%, the catalytic activity reaches the highest and is 1.799 mmol.g.h, which is 7.5 times of that of an original ZIS catalyst. The prepared catalyst is high in activity and good in stability, and a new way is provided for developing efficient and stable solar hydrogen production materials.

The invention relates to the technical field of preparation of high-entropy alloy materials, in particular to a C / S / HES composite electrode material based on high-entropy sulfides and a preparation method and application thereof.The preparation method comprises the following steps that a carbon material is dispersed in N, N-dimethylformamide to obtain a carbon material dispersion liquid, an iron source, soluble metal salt and sublimed sulfur are mixed with a carbon source solution, and the carbon material dispersion liquid is obtained; carrying out hydrothermal reaction to obtain high-entropy sulfide; mixing a carbon source with sublimed sulfur, and carrying out hot melting treatment to obtain a carbon / sulfur positive electrode material; the preparation method comprises the following steps: taking a high-entropy sulfide as an electrocatalyst, mixing and grinding the high-entropy sulfide and a carbon / sulfur positive electrode material, and carrying out hot melting treatment to obtain the C / S / HES composite electrode material based on the high-entropy sulfide. The electrochemical kinetics of soluble NaPSs in the sodium-sulfur battery is accelerated by screening a proper high-entropy sulfide catalytic host, and the electrochemical behavior is improved.

The present invention relates to the technical field of metal production or refining, and provides a non-ferrous metal smelting slag recovery and treatment system and method, the method comprising: performing reduction activation treatment on the molten slag, cutting the slag flow by a guide plate and combining mechanical vibration to strengthen the reduction reaction; using ultrasound and gradient magnetic fields to collaboratively sort metal particles; forming a vortex flow field by a rotating spray gun to achieve directional alloy precipitation, and continuously discharging the alloy melt; converting the tailings into glassy building aggregates; recovering the waste heat and quenching the flue gas, using a high-temperature resistant filter bag to capture zinc-containing dust, and then removing sulfides and heavy metals through a graded absorption process. The system comprises an activation reactor, a sorting tower, a precipitation furnace, and a flue gas treatment unit, and each device realizes the collaborative treatment of molten materials through a sealed conveying structure. The present invention realizes the efficient dissociation and recovery of valuable metals, the full-quantity resource utilization of tailings, and the control of the depth of flue gas pollution, significantly improving the resource circulation efficiency and environmental friendliness.

The invention relates to the technical field of high-temperature experiment earth science, in particular to a sulfide standard sample and a preparation method thereof. The method comprises the following steps: preparing a raw material of a sulfide standard sample based on a target element component in a target natural sulfide and the content of the target element component; a quartz tube with one open end and one closed end is filled with first predetermined height quartz powder, a raw material of a sulfide standard sample, second predetermined height quartz powder or a quartz column, elemental sulfur, and third predetermined height quartz powder and / or a quartz column in sequence; sealing the filled quartz tube; and performing heat treatment on the raw materials of the sulfide standard sample in the sealed quartz tube to obtain the sulfide standard sample. According to the method, high-resolution analysis of micro-area information can be realized by utilizing the in-situ standard sample, so that irreplaceability is realized, in-situ analysis does not need a complicated pretreatment process, and a solid sample can be directly analyzed and measured.

The invention relates to the technical field of lubricating materials, and provides a super-lubricating amorphous carbon-based thin film as well as a preparation method and application thereof. The super-lubricating amorphous carbon-based thin film comprises a bonding transition layer, a carbide gradient layer and a composite hydrogen-containing amorphous carbon-based film layer which are sequentially arranged from bottom to top, the composite hydrogen-containing amorphous carbon-based film layer is a sulfide-doped hydrogen-containing amorphous carbon thin film, and sulfide is one or two of tungsten sulfide and molybdenum sulfide. The structure of the carbon-based thin film is regulated and controlled by doping a small amount of sulfide, compared with a traditional hydrogen-containing amorphous carbon-based thin film, the obtained super-lubricating amorphous carbon-based thin film shows more stable super-lubricating performance and more excellent wear resistance, a new solution is provided for surface protection of tribological parts, and the method is suitable for popularization and application. The method has important industrial application value.

The invention discloses a preparation method of a biomass-based activated carbon desulfurizer. The method comprises the following steps: 1, crushing, cleaning and drying a biomass raw material to obtain a pretreated material; 2, pre-carbonizing and carbonizing to obtain charcoal particles; 3, introducing water vapor to activate the biochar particles to prepare activated carbon particles; 4, mixing and kneading the activated carbon particles and an additive, extruding into strips, and drying to obtain an activated carbon carrier; 5, dipping the activated carbon carrier with alkali to obtain a desulfurizer; the desulfurizer is applied to removal of sulfides in industrial feed gas. According to the desulfurizer, the biomass raw material serves as a carbon source, sufficient adsorption sites and alkaline catalysis sites are provided through water vapor activation pore forming and impregnation loading of alkali components, the desulfurization performance of the biomass-based activated carbon desulfurizer is improved, and the desulfurizer is suitable for deep desulfurization of industrial gas with high CO2 content and containing organic sulfur and inorganic sulfur; the raw materials are renewable, the desulfurization performance is excellent, the application range is wide, the precision is high, and the preparation process is green and environment-friendly.

The invention discloses an acidified soil conditioner and a preparation method thereof. The preparation method of the conditioner comprises the following steps: preparing a nano composite material: drying and crushing oyster shells, sieving and calcining to obtain oyster shell powder, namely the nano composite material; the preparation method comprises the following steps: preparing composite biochar powder: drying and grinding cleaned agricultural waste rice straws into powder, and carrying out sieving and calcining treatment to obtain straw biochar; mixing alkaline phosphate, sulfide, hemi-ferrite, manganese salt, clay, a microbial agent and straw charcoal in proportion to obtain composite charcoal powder; and preparing the acidified soil conditioner: compounding the nano composite material and the composite charcoal powder in proportion, and carrying out molding treatment on the complexing agent powder to obtain the acidified soil conditioner. The method has the beneficial effects that the available heavy metals in the soil can be reduced, the cation exchange capacity of the soil is enhanced, the acidification is neutralized, the soil fertility is improved, and the heavy metal pollution of the acidified farmland is repaired.

Disclosed is a method of synthesizing a compound selected from the group consisting of C-alkyl glycosides, C-alkenyl glycosides, C-heteroaryl glycosides, Se-glycosides and S-glycosides, the method comprising: a. Reacting a natural unprotected sugar with a 2-chloro-1, 1, 1, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3 The method comprises the following steps: reacting 1, 3-dimethylimidazoline chloride (DMC) and a mixture of heteroaryl mercaptan and trimethylamine (Et3N) in a mixture of water and dialkane to generate heteroaryl glycosyl thioether; b, under the irradiation of a blue light LED, in the presence of Hantzsch ester (HE), 1, 4-diazabicyclo [2.2. 2] octane (DABCO) and DMSO, heteroaryl glycosyl thioether and a reagent are subjected to light-induced cross coupling, and the compound is generated.

The invention provides a chromium-titanium bimetallic layered sulfide positive electrode material and a preparation method and application thereof, and belongs to the technical field of lithium ion battery materials. The chemical general formula of the material is LiCrxTiyS2, x + y = 1, the material belongs to a hexagonal crystal system O1 type structure, and the space group is Pm1. Microtopography analysis shows that the material is granular, the particle size distribution is 2-15 [mu] m, the particle surface has a layered structure characteristic, and each element is uniformly distributed on the particle surface and in a bulk phase. The capacity of the material mainly comes from oxidation reduction between titanium and sulfur, and chromium has the effect of stabilizing a structural framework and does not participate in the charge compensation process. Electrochemical analysis shows that the reversible capacity of the LiCr2 / 3Ti1 / 3S2 positive electrode material reaches up to 223 mAh g <-1 > and is close to the theoretical value of the positive electrode material of the system. In addition, the material shows excellent rate capability and cycling stability, and still keeps the capacity retention ratio of 80% after 330 times of cycling.

The invention relates to the technical field of organic sulfide preparation, in particular to a method for synthesizing and refining dimethyl sulfide (DMS) and dimethyl sulfoxide (DMSO) embedded into a methanol plant, which mainly utilizes high-purity oxygen of an air separation unit of the methanol plant, a high-concentration hydrogen sulfide product of low-temperature methanol washing and part of top gas-phase refined methanol of a pressurizing tower of a methanol rectification device. The production cost of the product is reduced, the added value of the product is improved, and the hydrogen sulfide product of a methanol plant is effectively utilized.

The invention belongs to the marine electromagnetic exploration technology, and relates to a deep-sea hydrothermal sulfide anisotropy detection system and method, and the system comprises a transmitting system which comprises an X-axis coil whose normal direction is located at an X axis, a Y-axis coil whose normal direction is located at a Y axis, and a Z-axis coil whose normal direction is located at a Z axis, and forms an orthogonal structure; the three-component synchronous receiving system comprises a three-axis receiving coil located in a seabed hole, and the three-axis receiving coil continuously collects the magnetic field intensity, the polarization direction and the three-dimensional space coordinates at each receiving node; the three-axis synchronous control system adopts a multi-frequency orthogonal current signal with a phase difference of 90 degrees; and the processor is used for performing spectral analysis on the signal received by the three-component synchronous receiving system, calculating an anisotropic response ratio in each polarization direction in a horizontal plane according to the complex amplitude response, and determining a superior principal axis direction of conductivity anisotropy according to the anisotropic response ratio. According to the invention, full-angle scanning excitation is realized, and the detection capability of the anisotropic structure of the hydrothermal sulfide is remarkably improved.

The invention relates to a water treatment agent for advanced treatment of thallium-containing wastewater in nonferrous metallurgy. The water treatment agent is prepared by fully mixing and uniformly stirring the following raw materials in parts by weight: 50-80 parts of a sodium diethyldithiocarbamate aqueous solution with the mass concentration of 5%-15%, 10-40 parts of sulfide or polysulfide and 10-40 parts of sodium thiosulfate. The water treatment agent provided by the invention can realize efficient removal of heavy metal ions, does not need a subsequent treatment process, not only simplifies the treatment process, but also reduces the treatment cost.