313 results about "Tungsten oxide" patented technology

The invention relates to the technical field of functional materials, in particular to a polyvinyl butyral flexible material as well as a preparation method and application thereof. The molecular chain regularity is destroyed through an isobutyraldehyde branched chain, the crystallinity is reduced, and the flexibility is improved; cesium-tin co-doped tungsten oxide has high infrared rejection rate and good dispersity, and the influence on the flexibility of the material is reduced; magnesium salicylate and magnesium formate are compounded, so that the reaction activity with resin is reduced, and the bonding stability in the bending process is ensured; the flexibility and migration resistance of the material are synergistically improved through the flexible plasticizer, and the interlayer sheet is prevented from being sticky; the flexible reinforcing agent polycaprolactone micro powder is used for forming an elastic node, bending stress is absorbed, and the recovery performance is improved. The polyvinyl butyral flexible material provided by the invention has flexible bending performance, an efficient infrared barrier function and stable bonding performance, is suitable for scenes such as curved building curtain walls, special-shaped automobile sunroofs or arc-shaped rail traffic windows, and has a wide application prospect.

The invention discloses a full-spectrum protective anti-fingerprint resin lens and a preparation method thereof. The full-spectrum protective anti-fingerprint resin lens comprises a functionalized resin base material and a gradient composite functional coating. The base material takes polyurethane acrylate as a matrix, and nano cerium oxide, nano barium titanate and nano tungsten oxide functional particles are uniformly dispersed through in-situ polymerization, so that base material intrinsic protection on ultraviolet rays, harmful blue light and near-infrared light is realized. The gradient coating comprises an adhesion promoting layer, a full-spectrum repairing and protecting layer and an anti-fingerprint layer from inside to outside, a stable composite system is formed through chemical bonding, protection is further reinforced, and the lens is endowed with super-hydrophobic and oleophobic anti-fingerprint characteristics. Through the integrated design of base material modification and coating compounding, the technical problems that an existing lens is single in protection wave band, not lasting in performance and prone to being stained with fingerprints are solved, and meanwhile the lens has high light transmittance, low reflection, excellent wear resistance and impact resistance and excellent comprehensive performance.

The invention belongs to the technical field of functional materials, and particularly relates to ultra-thick tabular tungsten oxide and a preparation method thereof.The preparation method of the ultra-thick tabular tungsten oxide comprises the following steps that S1, ammonium tungstate is added into deionized water and stirred to be dissolved at the temperature of 70-90 DEG C, and a clarified ammonium tungstate solution is obtained; s2, cooling the clarified ammonium tungstate solution to normal temperature at a cooling rate of 0.5-2 DEG C / h, and then carrying out suction filtration to obtain plate-shaped ammonium tungstate crystals; s3, calcining the tabular ammonium tungstate crystal to obtain ultra-thick tabular tungsten oxide; ammonium tungstate is adopted as a raw material, controllability is high, tungsten oxide which is uniform in particle size and complete in plate shape is obtained through optimized crystallization and calcination, the purity is larger than or equal to 99%, the problems that traditional tungsten oxide is agglomerated and disordered in shape are solved, functional adaptability is high, the plate-shaped structure can be directionally oriented, the dielectric performance, the breakdown performance and other performance are improved, and the method is suitable for multiple high-end scenes; parameters are easy to control, and operation is simple, green and safe.

The invention belongs to the technical field of water environment detection, and particularly relates to a heavy metal concentration and water body flow velocity synchronous detection method for a dispersed drain outlet, which is used for synchronously detecting the heavy metal cadmium concentration and the water body flow velocity. The core of the method comprises a three-electrode sensing system consisting of a working electrode coated with a tungsten oxide film, a reference electrode and a counter electrode, and is assisted by an electrochemical workstation, a peristaltic pump, a flow cell and a signal processing module. The cadmium concentration is accurately measured through the square wave anodic stripping voltammetry, the flow velocity is synchronously detected through the open circuit potentiometry, dual-function detection is achieved through integration of the square wave anodic stripping voltammetry and the open circuit potentiometry, synchronous in-situ detection of the cadmium concentration and the water body flow velocity is achieved, and errors caused by measurement position differences are effectively eliminated. The result shows that the cadmium concentration and the dissolution peak current are in a linear relationship, and the water flow velocity logarithm and the open-circuit potential are in a linear relationship. The method designed by the invention is suitable for scattered and small sewage draining exit scenes, and effectively solves the problems of time consumption and equipment redundancy of traditional step-by-step detection. In an actual water sample test, the cadmium recovery rate is 80%-120%, the flow velocity measurement RSD is smaller than or equal to 5.0%, high reproducibility, stability and anti-interference performance are achieved, technical support is provided for real-time online evaluation of the total heavy metal emission amount, and the method has remarkable environmental monitoring application potential.

The application discloses a physical vapor deposition device, an electrochromic device and a preparation method thereof, and relates to the technical field of electrochromic devices. The preparation method comprises the following steps: sputtering and depositing an electrochromic layer of WO3 on the surface of a first ITO layer, and the oxygen content is any value in the range of 42.5% to 52.5%; sputtering and depositing a pre-set thickness of a tungsten oxide ion conduction layer on the electrochromic layer, and the oxygen content of the corresponding chamber is any value in the range of 35% to 45%; sputtering and depositing an ion storage layer containing lithium ions on the ion conduction layer; depositing a second ITO layer on the ion storage layer, and obtaining the electrochromic device after vacuum annealing treatment and cooling treatment; wherein the deposition temperature of the second ITO layer is any value in the range of 350 DEG C to 400 DEG C, and the annealing temperature of the vacuum annealing treatment is any value in the range of 450 DEG C to 500 DEG C. The electrochromic device prepared by the application has the characteristics of high transmittance and low sheet resistance.

The application belongs to the technical field of metallurgy, and particularly relates to medium-granularity tungsten carbide powder and a preparation method and application thereof. The preparation method comprises the following steps: S1, obtaining high-purity ammonium paratungstate, and calcining the high-purity ammonium paratungstate to obtain tungsten oxide, wherein K in the high-purity ammonium paratungstate is less than or equal to 1 ppm, Na in the high-purity ammonium paratungstate is less than or equal to 1 ppm, and the specific surface area of the tungsten oxide is 0.3-1.0 m 2 / g; S2, first hydrogen reduction, second hydrogen reduction and third hydrogen reduction are performed on the tungsten oxide to obtain tungsten powder; S3, the tungsten powder is sieved and carbon is added to obtain a tungsten-carbon mixture, carbonization, crushing and sieving are performed on the tungsten-carbon mixture to obtain medium-granularity tungsten carbide powder. The application selects high-purity ammonium paratungstate with less than 1 ppm of impurity elements such as potassium and sodium as raw material, which can effectively reduce abnormal growth of tungsten powder particles caused by impurity elements in the reduction process, tungsten powder particles are developed completely by adopting three-stage hydrogen reduction, the powder activity is low, and the particle size increase is small in the subsequent carbonization process.

The invention belongs to the technical field of polymeric membrane composite glass, and discloses a preparation method and application of polymeric membrane composite glass, the polymeric membrane composite glass comprises a first glass layer, a second glass layer and an EVA composite membrane located between the two glass layers, the EVA composite membrane contains nano metal oxide particles, and the nano metal oxide particles contain nano metal oxide particles. The nano metal oxide particles comprise cerium oxide, tungsten oxide, titanium oxide and yttrium oxide. The middle layer of the EVA composite film of the polymeric film composite glass additionally comprises nano metal oxide particles, tungsten oxide absorbs near-infrared heat radiation, titanium oxide reflects infrared light, cerium oxide and yttrium oxide can absorb ultraviolet light, and the heat insulation performance is excellent; according to the present invention, with the nano-metal oxide particles, the tungsten oxide, the tin oxide and other nano-oxide particles, the elastic modulus, the density and the viscosity of the EVA are increased, the sound wave conduction path is effectively blocked, the sound insulation and noise reduction performance is excellent, the nano-metal oxide particles can improve the interface bonding strength of the EVA composite film and the glass layer, and the safety performance is high.

The application discloses an oxide-sulfide S-type heterojunction composite photocatalyst as well as a preparation method and application thereof. x The oxide-sulfide S-type heterojunction composite photocatalyst is prepared by adding WO x into ethanol, uniformly ultrasonic dispersing, and then performing heating and dry distillation. The application successfully constructs a tungsten oxide and cadmium sulfide heterojunction, has good light response, utilizes a heterojunction interface formed by the two catalysts and having a synergistic effect, improves the photocatalytic hydrogen production capacity, and promotes selective oxidation of benzyl alcohol. The application has simple operation and good repeatability.

The application discloses a method for preparing high-purity superfine tungsten powder by series impurity removal and microwave calcination, and relates to the technical field of refractory metal powder metallurgy. The method uses 99% and below industrial-grade ammonium paratungstate as raw material, and sequentially performs pyrolysis, two-stage physical purification, ultrasonic synergic acidolysis deep purification, microwave uniform calcination and sectional reduction. Firstly, the ammonia solution-evaporation crystallization method and the chemical precipitation method are connected in series to realize deep impurity removal, and the chemical precipitation method is used to directly obtain a nano tungsten oxide precursor, so that the morphology of the tungsten powder is guaranteed for subsequent reduction; secondly, the microwave calcination process is introduced to realize fast and green and environment-friendly uniform heating, and the hard agglomeration of the precursor is significantly reduced; finally, the sectional reduction method is adopted to effectively block the CVT effect in the reduction process, and abnormal grain growth is avoided. The method solves the problems of incomplete purification, sintering agglomeration of the precursor during reduction and out-of-control reduction particle size in the prior art, and the prepared tungsten powder has high purity and small average particle size.

The invention relates to the field of catalysts. The invention relates to a catalyst for catalytic oxidation of carbon monoxide in industrial sulfur-containing flue gas. A carrier is a cordierite honeycomb ceramic carrier coated with activated aluminum oxide (Al2O3), silicon oxide (SiO2) or titanium oxide (TiO2), or a honeycomb carrier with titanium oxide as a skeleton; the noble metal active component is selected from one or a combination of more of palladium (Pd), platinum (Pt) and rhodium (Rh), the total loading capacity accounts for 0.05-0.4 wt% of the mass of the carrier, and the noble metal component is loaded on the surface layer of the carrier at the depth of 10-300 microns and is of an eggshell type distribution structure; the cocatalyst component is selected from one or a combination of more of vanadium oxide (VO), tungsten oxide (WO), cerium oxide (CeO), molybdenum oxide (MoO) and lanthanum oxide (La2O3) and is uniformly distributed on the carrier. Unification of activity, stability and economical efficiency of the catalyst is achieved, the problems that a catalytic oxidation catalyst is prone to inactivation, low in activity and high in cost in complex sulfur-containing flue gas are solved, and the industrial application value is remarkable.

The invention relates to a method for preparing a rapid hydrochromic mesoporous tungsten oxide film based on a plasma etching technology. The preparation method comprises the following steps: mixing an amphoteric block copolymer template agent with a tungsten source precursor, and coating the surface of a substrate with obtained sol to construct an organic-inorganic hybrid film; then introducing oxygen-containing plasma to etch the hybrid film; and finally loading a catalyst layer on the surface of the film. By utilizing the synergistic effect of high-energy active particles and active oxygen species in the plasma, through coupling of physical bombardment and chemical oxidation / volatilization reaction, the rapid removal of the organic template is realized under a low-temperature condition, meanwhile, the structural integrity of a mesoporous skeleton is kept, and the pore collapse and the specific surface area loss caused by traditional high-temperature calcination are avoided. The obtained mesoporous WO3 thin film has a high specific surface area and abundant surface active sites, and hydrogen diffusion and interface reaction kinetics can be effectively improved, so that the coloring / fading response is remarkably accelerated, and the hydrogen-induced discoloration performance is improved.

This invention belongs to the field of target material preparation technology, and discloses a sintering method for a yellow tungsten oxide titanium target and the yellow tungsten oxide titanium target itself. The sintering method for the yellow tungsten oxide titanium target includes the following steps: Step 1: Heating the tungsten oxide titanium target blank to 800℃ at a heating rate of 0.5-1℃ / min, with continuous oxygen flow during the process at an oxygen flow rate of 15-20L / min; Step 2: Heating from 800℃ to 1150℃-1200℃ at a heating rate of 2-3℃ / min, holding at this temperature for 1-3 hours, with continuous oxygen flow during the process at an oxygen flow rate of 40-60L / min. This invention discloses a sintering method for a yellow tungsten oxide titanium target, employing a two-stage heating approach. In the first stage of heating, a lower heating rate and lower oxygen flow rate are used to improve the density of the target material; in the second stage of heating, a higher heating rate and higher oxygen flow rate are used to avoid deactivation of tungsten trioxide, which could lead to a change in the valence of tungsten.

The invention discloses physical vapor deposition equipment, an electrochromic device and a preparation method of the electrochromic device, and relates to the technical field of electrochromic devices. The preparation method comprises the following steps: sputtering and depositing the WO3 electrochromic layer on the surface of the first ITO layer, wherein the oxygen content is any one of 42.5-52.5%; sputtering and depositing a tungsten oxide ion conducting layer with a preset thickness on the electrochromic layer, wherein the oxygen content of the corresponding chamber is any one of 35%-45%; sputtering and depositing an ion storage layer containing lithium ions on the ion conduction layer; a second ITO layer is deposited on the ion storage layer, and the electrochromic device is prepared after vacuum annealing treatment and cooling treatment; wherein the deposition temperature of the second ITO layer is any one value from 350 DEG C to 400 DEG C, and the annealing temperature of the vacuum annealing treatment is any one value from 450 DEG C to 500 DEG C. The electrochromic device prepared by the invention has the characteristics of high transmittance and low sheet resistance.

A tungsten oxide coating material for an electrochromic device that is a coating material for forming a tungsten oxide thin film having electrochromic characteristics, the coating material comprising: a solvent; tungsten oxide nanoparticles dispersed in the solvent; and a binder, wherein in the tungsten oxide nanoparticles, a half-value width of a peak detected at 29° ±1° in X-ray diffraction analysis (2θ) is 2° or less, and a primary particle size is 5 to 25 nm.

The invention relates to the technical field of beneficiation, and particularly provides a beneficiation process for tungsten-molybdenum ore with calcium and magnesium ions easy to separate out. According to the beneficiation process disclosed by the invention, the iron ore concentrate, the molybdenum sulfide concentrate and the tungsten molybdenum oxide concentrate can be comprehensively obtained by improving the magnetic separation process, the flotation reagent combination, the desliming, the ore washing and other operation procedures; the problem of loss of tungsten and molybdenum metal along with magnetic concentrate due to the existence of a large amount of magnetite-molybdenite and magnetite-tungsten-molybdenum oxide ore intergrowth of the ore is effectively solved, and the problem of low molybdenum sulfide flotation index due to mismatching of a sulfuration flotation process is solved; the core problem that a large number of calcium and magnesium ions are separated out and react with a fatty acid collecting agent to cause heating flotation failure is solved, the technical bottleneck troubling the type of mine for more than ten years is successfully overcome, and the tungsten and molybdenum resource comprehensive recovery competitiveness of related enterprises can be remarkably improved.

A heat ray shielding film comprising a glass substrate, a first layer, and a second layer, wherein: the first layer contains at least one substance selected from tungsten oxides represented by general formula WO3-x (0≤x≤0.28), silicon oxynitrides represented by general formula SiOaNb, and aluminum oxide; the second layer contains tungsten bronze; and the layers are arranged in the order of the first layer and the second layer, with the first layer being closest to the glass substrate.

The application discloses a nickel-based flux-cored wire and a preparation method and application thereof. The nano tungsten trioxide is introduced into the nickel-based flux-cored wire, the high-temperature strength and hot strength of the nickel-based alloy are improved, meanwhile, the hardness, friction performance and corrosion resistance of the alloy are improved, and the problems of low high-temperature corrosion strength, hot strength and mechanical performance of the nickel-based flux-cored wire are solved.

The invention relates to the field of composite materials, and discloses a composite material, a preparation method and application thereof, and a catalytic oxidation treatment method of organic wastewater. The composite material comprises the following components in 100 parts by weight: (a) 0.5-15 parts of cerium tungsten oxide; (b) 3.5 to 25 parts of manganese titanium oxide; and (c) 60-96 parts of a carrier. The preparation method of the composite material comprises the step of loading the cerium tungsten oxide and the manganese titanium oxide on the carrier. The composite material is suitable for treating organic wastewater, COD and total cyanogen in the wastewater can be effectively removed after treatment, the biotoxicity of the wastewater is reduced, and the biodegradability of the wastewater is improved.

This invention provides a quasi-two-dimensional / two-dimensional van der Waals heterojunction based on SOI and Si / WS2, its preparation method, and its application. The method includes the following steps: cleaning the SOI substrate; using sulfur powder, tungsten oxide powder, sodium chloride powder as a catalyst, and erbium chloride and ytterbium chloride powder as dopants, chemical vapor deposition is performed on the SOI substrate to prepare an erbium- and ytterbium-doped monolayer WS2 material; the top silicon layer of the SOI substrate is an n-type silicon layer. This invention, employing the above-mentioned quasi-two-dimensional / two-dimensional van der Waals heterojunction based on SOI and Si / WS2, its preparation method, and its application, effectively reduces the defect density during material synthesis while significantly increasing the carrier concentration in the material. The prepared photodetector exhibits good photoelectric response performance, providing a simple and efficient new method for the preparation of high-performance heterojunction photodetectors.

The objective is to provide a heat-shielding composition that includes a dispersion powder that can be converted into an aqueous dispersion using water as a dispersion medium by adding water. [Solution] A nonionic polymer dispersant and A crystal with a hexagonal crystal structure, general formula M x WO y (However, element M includes one or more elements selected from Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, and satisfies 0.1 ≤ x ≤ 1.0 and 2.0 ≤ y < 4.0) Composite tungsten oxide particles containing composite tungsten oxide, A heat-shielding composition comprising polycarbonate resin or acrylic resin.

The present invention developed a composite having a novel structure containing, in a high content, a powder having a radiation-shielding function.　Provided is a composite having a radiation-shielding function and a method for producing the same. The composite comprises a preform made from a mixture containing a liquid silica-based binder and one or more radiation-shielding powders selected from gadolinium oxide, boron carbide, boron oxide, boron, barium sulfate, strontium oxide, tungsten, tungsten oxide, tungsten carbide, molybdenum, molybdenum oxide, iron powder, iron oxide powder, and ferrite powder, the radiation-shielding powder(s) being contained in the range from 3% to 85% in total. All of the voids in the preform are impregnated and filled with molten aluminum and solidification is allowed to occur to form a composite, or 25% or more of the voids in the preform are impregnated with a liquid organic / inorganic sealing agent and solidification is allowed to occur to form a composite. The liquid silica-based binder has properties that allow the preform to be formed at a temperature at which the radiation-shielding powder(s) does not decompose.

This invention discloses a tungsten oxide-supported carbon-coated nickel catalyst, its preparation method, and its application. The catalyst includes a support and an active component supported on the support. The support is tungsten oxide containing both pentavalent and hexavalent tungsten ions, and the active component is nickel coated with a carbon layer. This catalyst can be applied to the catalytic conversion of cellulose to ethylene glycol. In an aqueous solvent, only an initial hydrogen atmosphere is required to achieve 100% conversion of cellulose, with an ethylene glycol monomer yield reaching 75%. This completes the one-step conversion of cellulose into a high-value fuel. The catalyst preparation and reaction process are characterized by high efficiency, greenness, economy, and renewability, showing broad prospects for industrial application.

The embodiment of the invention relates to an electrochromic device and a preparation method and application thereof, and the electrochromic device comprises a heat sealing film frame body, first indium tin oxide (ITO) conductive glass, an electron blocking layer, second indium tin oxide (ITO) conductive glass and an electrochromic layer; a solution injection hole is reserved in the heat sealing film frame body; the first indium tin oxide (ITO) conductive glass is positioned on one side of the heat-sealing film frame body; the electron blocking layer and the second indium tin oxide I-TO conductive glass are located on the other side of the heat sealing film frame, and the electron blocking layer and the first indium tin oxide I-TO conductive glass are oppositely arranged, so that a containing cavity is formed between the electron blocking layer and the first indium tin oxide I-TO conductive glass; the component of the electrochromic layer is a tungsten oxide quantum dot solution of metal perchlorate, and the solution is injected into the containing cavity through the solution injection hole.

The present application relates to a kind of tungsten oxide-based super-amphiphobic photochromic coating material preparation method, application, in the preparation process, zinc ion and sodium dodecyl benzene sulfonate are introduced to the morphology of WO3 / ZnO powder is doubly regulated.In the low surface energy treatment of WO3 / ZnO powder after improvement method, finally obtainable reentrant micro / nano structure of flower-like.The prepared super-amphiphobic photochromic coating is blue within 3min under ultraviolet irradiation, fade after heating 90min in air, photochromism obtains great promotion.The contact angle of the coating to water and edible oil is all greater than 150°.In addition, when facing sand impact, water impact, corrosive solution, long-term ultraviolet irradiation, still maintain super-amphiphobicity, and also have antifouling and self-cleaning ability.The present application provides new insights for developing super-amphiphobic photochromic material with good stability and high repeatability, and has good application prospect in the field of optical information storage, anti-fake and rewritable material.

Various embodiments herein relate to electrochromic devices and electrochromic device precursors, as well as methods and apparatus for fabricating such electrochromic devices and electrochromic device precursors. In certain embodiments, the electrochromic device or precursor may include one or more particular materials such as a particular electrochromic material and / or a particular counter electrode material. In various implementations, the electrochromic material includes tungsten molybdenum oxide. In these or other implementation, the counter electrode material may include nickel tungsten oxide, nickel tungsten tantalum oxide, nickel tungsten niobium oxide, nickel tungsten tin oxide, or another material.

The application relates to a preparation method of a nano WC-Co-based composite powder with inhibitor uniform distribution, and belongs to the technical field of powder preparation. In the application, tungsten oxide and cobalt oxide with large brittleness are used as raw materials, the raw materials are easily broken in a ball milling process, the superfine and nano particle size of a precursor mixed powder containing an inhibitor and the uniform distribution of the raw materials are ensured, the precursor of the inhibitor is dissolved in anhydrous ethanol, a solution is formed, and the solution is mixed with other raw materials, so that the uniform distribution of the component of the inhibitor element in the precursor mixed powder containing the inhibitor is ensured. Polyethylene glycol is added in the ball milling process, the agglomeration of powder particles is reduced, the friction between the powder particles is reduced, and the flowability of the particles is increased. Through the matching of precursor components, the density of the mixed powder of the inhibitor-containing compact and a stage-by-stage heating process, the full reaction of the compact is ensured, the rapid discharge of generated gas is ensured, and through the further ball milling treatment of the prepared powder, the powder is ensured to have the characteristics of pure phase, small WC particle size and uniform component distribution.

The invention belongs to the technical field of hydrogen-sensitive materials, and particularly relates to a preparation method of a vanadium-containing modified tungsten oxide-titanium dioxide composite hydrogen-sensitive color-changing material, which comprises the following steps: S1, selecting ammonium metatungstate and ammonium metavanadate as raw materials, adding deionized water, stirring and dissolving, adding titanium dioxide, and carrying out ultrasonic dispersion and magnetic stirring for 30 minutes to form a uniform suspension; s2, drying the mixed solution obtained in the step S1 in a drying oven until the weight is constant, and calcining the dry powder in a muffle furnace; s3, weighing chloroplatinic acid, dissolving the chloroplatinic acid in deionized water, adding the dry powder obtained in S2 into the solution, uniformly stirring, drying, and calcining in a muffle furnace to form a Pt-loaded composite material; the color of the material prepared in the S3 turns into dark blue from light grey after meeting hydrogen. The whole preparation and detection process is high in efficiency, quick in response, simple in technological process and free of secondary pollution.

The application discloses a kind of titanium modified molybdenum-doped tungsten oxide nanoparticles, electrochromic film, electrochromic device and preparation method.Nanoparticle chemical composition is, x=0.05~0.15, y=0.05~0.15, x+y=0.10~0.20, with Porous or mesoporous structure, specific surface area 50~150 m² / g.Sol-gel method is used to prepare, and is obtained by heat treatment at 400~600 DEG C.Electrochromic film is made by the nanoparticle by spraying method, thickness 200~800 nm, porosity 20%~50%.All-solid-state electrochromic device includes transparent conductive substrate, the electrochromic film, solid electrolyte layer, ion storage layer and second transparent conductive substrate, and is assembled by hot-pressing composite.The application widens lithium ion transmission channel by Ti-Mo binary synergic doping, electrochromic film optical modulation range 4%~75%, response time ≤60 seconds, cycle life ≥50,000 times, and suitable for large-area production.

The application relates to a ruthenium-tungsten oxide material and a preparation method and application thereof, and the preparation method comprises the following steps: (1) uniformly stirring water, glucose, urea, ruthenium chloride and cetyltrimethylammonium bromide to obtain solution A, and the solution is transparent, and then the solution is prepared; (2) adding tungsten chloride into ethanol and stirring to obtain solution B; (3) slowly adding solution B into solution A and uniformly stirring; (4) standing the mixed solution obtained above; (5) transferring the mixed solution obtained above into a drying box and drying; (6) calcining the dried product under an air atmosphere, annealing and cooling to room temperature to obtain the target product, i.e. the ruthenium-tungsten oxide material. Compared with the prior art, the application has the advantages of good chemical stability, excellent anti-physical structure deterioration and high tolerance to impurity ions.

This invention discloses a terahertz band optical comb frequency converter, belonging to the field of frequency conversion technology. The frequency converter includes an optical fiber interface, an optical fiber focusing lens, a frequency converter chip, a hemispherical silicon lens, and an electrical interface. The frequency converter chip includes antenna electrodes, a photoconductor, and an InP substrate. An external 1560nm femtosecond optical comb signal sequentially passes through the optical fiber interface and the optical fiber focusing lens onto the frequency converter chip; simultaneously, an external terahertz signal under test passes through the hemispherical silicon lens onto the frequency converter chip. The antenna electrodes and the electrical interface are connected by a circuit. This invention offers a wider response bandwidth: the response bandwidth is increased through the design of internal defects in the photoconductor; higher sensitivity: the sensitivity of the frequency converter is improved through antimony doping and tungsten oxide thin film design; and higher reliability: the tungsten oxide thin film design and special protection design of the antenna electrodes can respectively avoid damage to the frequency converter caused by optical and electrical signals, thereby improving reliability and service life.