897 results about "Tungsten oxide" patented technology

The invention belongs to the technical field of powder metallurgy, and particularly relates to high-performance tungsten carbide and a preparation method thereof. A preparation method of medium-coarse tungsten carbide comprises the following steps that tungsten oxide is subjected to high-temperature reduction through a reverse hydrogen reduction method, and tungsten powder is obtained; and the tungsten powder is subjected to carbon blending, uniform mixing and high-temperature carbonization in a reducing atmosphere, a product is pre-crushed and then subjected to airflow crushing, and the tungsten carbide is obtained. According to the preparation method of the medium-coarse tungsten carbide, the particle size of the prepared tungsten carbide is 1-3 microns, the total carbon content is 6.12-6.18%, the combined carbon content is larger than or equal to 6.10%, the free carbon content is smaller than or equal to 0.06%, the oxygen content is smaller than or equal to 0.12%, and the impurity content is smaller than 0.5%; the particle size distribution is narrow, the particles are uniform, and the performance of the tungsten carbide powder is greatly improved.

The invention relates to the technical field of powder metallurgy, in particular to a tungsten-copper alloy preparation method and a tungsten-copper alloy. The preparation method of the tungsten-copper alloy comprises the following steps: mixing double-scale compound tungsten powder containing nanocrystals and ultra-fine grains or double-scale compound tungsten-tungsten oxide powder containing nanocrystals and ultra-fine grains with copper oxide powder to obtain precursor slurry; drying the precursor slurry to obtain precursor composite powder; the precursor composite powder is subjected to segmented reduction, tungsten-copper composite powder is obtained, and tungsten crystal grains in the tungsten-copper composite powder are distributed in a double-scale mode of nanocrystals and ultra-fine crystals; and the tungsten-copper composite powder is prepared into a blank and sintered, and the tungsten-copper alloy is obtained. The heat conductivity and density of the tungsten-copper alloy can be improved.

The invention relates to the field of optical protection materials, and provides a transparent film with laser eavesdropping prevention performance and a preparation method thereof.The transparent film is composed of surface-modified doped tungsten oxide nanosheets, amino-isocyanate bifunctional lithium niobate nanowires, urethane acrylate, an ultraviolet light absorber, a silane coupling agent, a dispersing agent and a flatting agent; the molybdenum-doped tungsten oxide nanosheets are obtained through silane coupling modification after hydrothermal synthesis, and the lithium niobate nanowires are prepared through a gradient modification process of hydrothermal synthesis-silane coupling-isocyanate grafting-phenol end capping. A modified nano material is uniformly dispersed in a resin matrix through an ultrasonic dispersion composite technology, and through blade coating forming, ultraviolet curing and constant-temperature and constant-humidity post-treatment, compared with the prior art, the scheme overcomes the problems that a traditional protective film is insufficient in optical transparency, laser eavesdropping prevention function and dynamic viscoelasticity, and is suitable for the field of high-end security and protection.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PVB (Polyvinyl Butyral) film and a preparation method thereof. The PVB film provided by the invention is prepared from the following components in parts by mass: 100 parts of PVB resin, 33 to 36 parts of triethylene glycol di-2-ethylhexoate, 7 to 9 parts of integrated anti-radiation toughening filler, 1 to 2 parts of organic montmorillonite, 0.8 to 1.2 parts of composite coupling agent, 0.5 to 1 part of ultraviolet light absorber, 0.6 to 0.8 part of antioxidant and 0.8 to 1 part of heat stabilizer. The integrated anti-radiation toughening filler adopts a core-shell structure, the anti-radiation core is composed of bismuth oxide and tungsten oxide according to the mass ratio of 3: 1, and the elastic coating layer is maleic anhydride grafted modified POE. The preparation method comprises the steps of pre-dispersion treatment, component mixing, melt extrusion, film casting, graded cooling, two-way stretching and the like. Through the core-shell structure design of the integrated anti-radiation toughening filler and the optimized processing technology, the anti-radiation performance and the toughening performance are synergistically improved, and the prepared film has the advantages of excellent anti-radiation effect, high toughness and good transparency.

The invention provides conductive paste, a solar cell, a preparation method of the solar cell and a photovoltaic module. The conductive paste comprises the following components in parts by weight: 70-85 parts of silver powder, 3-8 parts of glass powder, 0.1-2 parts of an additive and 12-25 parts of an organic carrier, wherein the silver powder comprises spherical silver powder and flaky silver powder; the glass powder is prepared from the following components in parts by weight: 65 to 75 parts of Bi2O3, 18 to 25 parts of TeO2 and 8 to 12 parts of V2O5; the additive is a carbon material and / or conductive metal oxide nanoparticles; the organic carrier comprises an infrared absorbing material; the infrared absorption material is selected from any one or more of copper phthalocyanine, a polyaniline-carbon nanotube compound and a tungsten oxide nanowire. The conductive paste can improve the conductivity of the conductive paste and improve the efficiency of the conductive paste in a laser sintering process, so that the contact resistivity is reduced, and the photoelectric conversion efficiency of a photovoltaic solar cell is improved.

The invention belongs to the technical field of superfine tungsten powder, and particularly relates to superfine tungsten powder and a preparation method thereof.The preparation method includes the steps that an ammonium tungstate solution, hydrochloric acid and carbon black serve as raw materials to prepare a mixture of tungstic acid and a carbon precursor; calcining the tungstic acid and carbon precursor mixture in a nitrogen atmosphere to obtain a tungsten oxide and carbon mixture; a tungsten oxide and carbon mixture is calcined in an argon atmosphere, the argon atmosphere is kept for natural cooling, the superfine tungsten powder is obtained, the superfine tungsten powder is uniform in dispersion, complete in grain development, smooth in surface, free of pores and complex in morphology, the crystal structure of the superfine tungsten powder is a body-centered cube, the average particle size is smaller than or equal to 0.7 micrometer, and the specific surface area is smaller than or equal to 1.0 m < 2 > / g.

The invention discloses a novel photocatalyst for producing hydrogen from organic matter wastewater and a preparation method of the novel photocatalyst, and relates to the technical field of photocatalysis. The photocatalyst disclosed by the invention is combined with oxidation-reduction capability, and can effectively degrade and produce hydrogen under the irradiation of sunlight. Through combination of quaternized porous tungsten oxide and vanadate radicals, silver vanadate load growth is promoted, the sunlight utilization rate is increased, and the electron-hole recombination rate is reduced. Reduced graphene oxide is used for pretreatment, active groups are introduced, the reduced graphene oxide is compounded with tungsten oxide / silver vanadate, the binding force is enhanced through heat treatment, photo-induced electron-hole pair compounding is inhibited through the conductivity, and the visible light catalytic performance is improved. The adsorption effect of porous tungsten trioxide and reduced graphene oxide can accelerate the degradation of organic matters. By optimizing the proportion of silver vanadate, tungsten oxide and reduced graphene oxide, the visible light response and charge separation efficiency are enhanced, the degradation and hydrogen production performance is improved, and light corrosion is reduced.

The invention relates to the technical field of electrochromism coating, in particular to an electrochromism device coating process and method, and the electrochromism device coating process comprises the following steps: step 1, substrate pretreatment: cleaning attachments on the surface of a flexible substrate through ultrasonic cleaning and plasma treatment; step 2, conducting layer deposition treatment: depositing an indium tin oxide (ITO) conducting layer on the substrate at the deposition temperature of 100-380 DEG C, the thickness of 200-350 nm and the vacuum degree of less than or equal to 10 <-5 > Pa; step 3, electrochromic layer deposition treatment: sequentially depositing a tungsten oxide (WO3) layer and a nickel oxide (NiO) layer through a magnetron sputtering process, and controlling the film thickness ratio of NiO to WO3 to enable the ratio of NiO / W to be 0.25-0.357; 4, annealing treatment is conducted, specifically, annealing is conducted for the first time at the temperature of 200-500 DEG C, and the annealing time is 200-300 seconds; and secondary annealing is conducted, specifically, annealing is conducted at the temperature of 400 DEG C, and the annealing time ranges from 200 seconds to 800 seconds. The effect of improving the yellow ground color of the electrochromic device is achieved.

The invention relates to the technical field of semiconductor manufacturing, and discloses a tungsten oxide etching method, a semiconductor structure and a chip, and the method comprises the steps: forming a tungsten oxide thin film on a substrate; forming a mask layer with a target pattern on the tungsten oxide thin film; etching the tungsten oxide thin film with the mask layer by adopting mixed gas in ICP etching equipment; in the ICP etching equipment, the mixed gas comprises trifluoromethane and argon, the ratio range of the trifluoromethane in the mixed gas is 22.5%-74.1%, the flow rate of the mixed gas is 135-155 sccm, the ratio range of ICP power to bias power is 1.53: 1-3.3: 1, the depth-to-width ratio range of the tungsten oxide etching structure is 10: 1-23: 1, the inclination angle of the side wall of the tungsten oxide etching structure is 40-90 degrees, and the width of the tungsten oxide etching structure is 20-30 degrees. The technical problem that it is difficult to achieve a tungsten oxide etching structure with the nanoscale line width and the high aspect ratio in the prior art is solved.

The invention relates to the technical field of functional materials, in particular to a polyvinyl butyral flexible material as well as a preparation method and application thereof. The molecular chain regularity is destroyed through an isobutyraldehyde branched chain, the crystallinity is reduced, and the flexibility is improved; cesium-tin co-doped tungsten oxide has high infrared rejection rate and good dispersity, and the influence on the flexibility of the material is reduced; magnesium salicylate and magnesium formate are compounded, so that the reaction activity with resin is reduced, and the bonding stability in the bending process is ensured; the flexibility and migration resistance of the material are synergistically improved through the flexible plasticizer, and the interlayer sheet is prevented from being sticky; the flexible reinforcing agent polycaprolactone micro powder is used for forming an elastic node, bending stress is absorbed, and the recovery performance is improved. The polyvinyl butyral flexible material provided by the invention has flexible bending performance, an efficient infrared barrier function and stable bonding performance, is suitable for scenes such as curved building curtain walls, special-shaped automobile sunroofs or arc-shaped rail traffic windows, and has a wide application prospect.

The invention provides a photoresponse water photovoltaic power generation device based on nano tungsten oxide and a preparation method of the photoresponse water photovoltaic power generation device, and relates to the field of water evaporation induced new energy power generation and novel photoelectric detection. The water photovoltaic power generation device is composed of a substrate, a positive electrode, a negative electrode and a slurry layer, wherein the slurry layer is obtained by drying slurry formed by mixing tungsten oxide, a Nafion solution and deionized water; the water photovoltaic power generation device can generate an open-circuit voltage of 1.4-1.8 V and a short-circuit current of 100-140 nA under the evaporation induction of deionized water. Under the illumination with the wavelength of 435 nm, the output voltage and current change along with the illumination intensity, and the material has the obvious light response characteristic and is expected to be used for optical detection and hydrovolt generator theory research.

The invention discloses a preparation method of a high-strength molybdenum alloy wire and the high-strength molybdenum alloy wire. The technical problem that in the prior art, a molybdenum alloy wire is small in tensile strength is solved. The preparation method of the high-strength molybdenum alloy wire comprises the following steps that molybdenum oxide, rhenium oxide, ruthenium oxide and tungsten oxide are subjected to ball milling and mixing; adding a mixed solution containing cerium ions, yttrium ions and lanthanum ions into the ball-milled and mixed slurry, and continuing ball-milling and mixing; carrying out spray drying on the slurry to obtain composite powder; performing high-temperature hydrogen reduction treatment to obtain multi-component doped molybdenum powder; and the high-strength molybdenum alloy wire is obtained through compression molding treatment, high-temperature sintering treatment, high-temperature rotary swaging and wire drawing treatment.

The embodiment of the invention provides a preparation method of a tungsten-copper alloy and the tungsten-copper alloy, and relates to the technical field of alloy preparation.The method comprises the steps that superfine tungsten oxide powder, tungsten salt, copper salt and a polymer additive are added into deionized water to be evenly mixed, and a precursor mixed solution is obtained; carrying out spray granulation on the precursor mixed solution by adopting a spray dryer to obtain spherical tungsten-copper precursor composite powder; roasting the spherical tungsten-copper precursor composite powder to obtain tungsten-copper oxide composite powder, and carrying out segmented reduction on the tungsten-copper oxide composite powder to obtain tungsten-copper composite powder with tungsten grains having a nanocrystalline / ultra-fine grain bimodal distribution characteristic; and the tungsten-copper composite powder is pressed to obtain an alloy blank, the alloy blank is sintered, and the tungsten-copper alloy is prepared. According to the double-peak distribution tungsten-copper composite powder, full densification of the alloy can be promoted through coupling rearrangement of large and small tungsten particles in the sintering process, and the compactness, the heat conductivity and the electric conductivity of the tungsten-copper alloy can be improved.

The invention provides a rapid preparation method of tungsten trioxide, which specifically comprises the following steps: step 1, weighing crude tungstic acid, dissolving in ammonia water, heating and stirring to obtain an ammonium tungstate solution; step 2, slowly dropwise adding the ammonium tungstate solution in the step 1 into a poor solvent to obtain an ammonium paratungstate suspension, and step 3, filtering the ammonium paratungstate suspension in the step 2 to obtain an ammonium paratungstate filter cake, and leaching the ammonium paratungstate filter cake with the poor solvent; 4, the ammonium paratungstate filter cake in the step 3 is placed in a drying oven to be dried; and (5) roasting the ammonium paratungstate filter cake in the step (4) at high temperature to obtain a faint yellow irregular flaky tungsten trioxide product. According to the preparation method, a mixed solvent crystallization and high-temperature roasting two-step process is adopted, the solubility of ammonium tungstate in water is reduced by adding a poor solvent, so that an ammonium tungstate solution rapidly reaches a saturated state and is separated out, the crystallization process of ammonium paratungstate is accelerated, and the preparation speed and the crystallization rate of a tungsten trioxide product are high.

The invention provides an organic phosphoric acid molecule modified tungsten oxide ammonia gas sensor as well as a preparation method and application thereof, and belongs to the field of nanostructure materials and ammonia gas detection. According to the invention, the catalytic decomposition capability of organic phosphoric acid molecules on ammonia gas is utilized, so that the adsorption and catalytic oxidation of ammonia gas molecules on the surface of tungsten trioxide are promoted, and the sensitivity and selectivity of tungsten trioxide on ammonia gas are enhanced; on the other hand, phosphorus-oxygen groups in organic phosphoric acid molecules can be bonded with Lewis reaction active sites (uncoordinated W < 6 + >) on the surface of tungsten trioxide in a covalent form, so that the surface activity of tungsten trioxide is protected, and the service life of the sensor is prolonged. The result of the embodiment shows that the sensitivity of the prepared organic phosphoric acid molecule modified tungsten oxide ammonia gas sensor to ammonia gas is remarkably improved, the organic phosphoric acid molecule modified tungsten oxide ammonia gas sensor has good selectivity to ammonia gas, the performance is not obviously attenuated after 5-month test, and the service life is long.

The present invention discloses a heat-insulating, sun-proof and self-cleaning multifunctional glass and a preparation method thereof, wherein the multifunctional glass comprises a modified glass substrate and a photochromic heat-insulating layer and a surface functional protective layer sequentially compounded on the surface of the modified glass substrate; the surface functional protective layer comprises a super-hydrophobic nanostructure layer and a self-cleaning functional layer sequentially arranged from the inside to the outside; the photochromic heat-insulating layer is a photothermal response layer with a gradient doping distribution of tungsten oxide nanoparticles, wherein the doping density of the tungsten oxide nanoparticles close to the side of the modified glass substrate is low, and the doping density of the tungsten oxide nanoparticles far from the side of the modified glass substrate is high; the super-hydrophobic nanostructure layer is mainly composed of fluorosilane-modified SiO2 nanoparticles; the self-cleaning functional layer is a TiO2 film deposited on the surface of the super-hydrophobic nanostructure layer by plasma enhanced chemical vapor deposition. Compared with the prior art, the glass of the present invention has multiple functions such as excellent heat insulation, sun protection and self-cleaning.

The invention provides a titanium-based ceramic target material and a preparation method and application thereof.The titanium-based ceramic target material is prepared from, by mass, 96.4 wt%-98.3 wt% of titanium oxide and 1.7 wt%-3.6 wt% of doped oxide, and the doped oxide is prepared from, by mass, 0.8 wt%-1.5 wt% of niobium oxide, 0.5 wt%-1.0 wt% of tantalum oxide, 0.3 wt%-0.8 wt% of tungsten oxide and 0.1 wt%-0.3 wt% of aluminum oxide. According to the method, the high-performance titanium-based ceramic target material is prepared by adopting a normal-pressure sintering method through multi-element synergistic doping and dynamic regulation and control of the sintering atmosphere, the titanium-based thin film prepared by sputtering the titanium-based ceramic target material can form a laminated thin film structure with an indium tin oxide (ITO) thin film, and high conductivity, high visible light transmittance and high electron mobility are achieved; and the actual requirements in the field of silicon-based and perovskite solar cells are met.

The invention discloses a full-spectrum protective anti-fingerprint resin lens and a preparation method thereof. The full-spectrum protective anti-fingerprint resin lens comprises a functionalized resin base material and a gradient composite functional coating. The base material takes polyurethane acrylate as a matrix, and nano cerium oxide, nano barium titanate and nano tungsten oxide functional particles are uniformly dispersed through in-situ polymerization, so that base material intrinsic protection on ultraviolet rays, harmful blue light and near-infrared light is realized. The gradient coating comprises an adhesion promoting layer, a full-spectrum repairing and protecting layer and an anti-fingerprint layer from inside to outside, a stable composite system is formed through chemical bonding, protection is further reinforced, and the lens is endowed with super-hydrophobic and oleophobic anti-fingerprint characteristics. Through the integrated design of base material modification and coating compounding, the technical problems that an existing lens is single in protection wave band, not lasting in performance and prone to being stained with fingerprints are solved, and meanwhile the lens has high light transmittance, low reflection, excellent wear resistance and impact resistance and excellent comprehensive performance.

The invention discloses a high-strength tungsten-boron silicone rubber radiation shielding material, which is prepared from the following ingredients in parts by weight: 100 parts of methyl vinyl silicone rubber raw rubber, 30 to 50 parts of white carbon black, 90 to 240 parts of tungsten oxide coated boron carbide heterostructure particles, 4 to 10 parts of hydroxyl silicone oil and 1 to 2.5 parts of 2, 5-dimethyl-2, 5-bis-(tert-butylperoxy) hexane. The preparation method comprises the following steps: 1, surface modification of tungsten oxide particles; 2, boron carbide surface modification; 3, grafting the surfaces of the two; and 4, mixing and vulcanizing the raw materials. White carbon black and tungsten oxide coated boron carbide heterostructure particles are introduced into the material, so that the dispersity of tungsten oxide particles in a silicon rubber matrix is improved, the interface interaction between boron carbide and the silicon rubber matrix is enhanced, the high strength of the material is ensured, and the material has excellent mechanical strength and neutron / gamma ray comprehensive shielding performance; the method is easy for mass production and can be used in the field of radiation protection.

[Problem] To provide an organic-inorganic hybrid coating film which contains a large amount of silver ions, copper ions, and zinc ions, which has an excellent antibacterial / antiviral function, antifungal function, and a deodorization function, which makes it possible to reliably eliminate germs, various viruses, various mold fungi and which makes it possible to reliably remove unpleasant odors. [Solution] A organic-inorganic hybrid coating film that is a glass coating film which contains silicon oxide (SiO2) as a base, wherein in the coating film, glass particles are electrically conductive glass which includes at least one type of ion from among silver ions (Ag+), copper ions (Cu2+), and zinc ions (Zn2+), and the glass particles include glass which contains, as a base, at least one oxide from among vanadium oxide (V2O5), tungsten oxide (WO3), and molybdenum oxide (MoO3), and phosphorus oxide (P2O5).

The invention belongs to the technical field of functional materials, and particularly relates to ultra-thick tabular tungsten oxide and a preparation method thereof.The preparation method of the ultra-thick tabular tungsten oxide comprises the following steps that S1, ammonium tungstate is added into deionized water and stirred to be dissolved at the temperature of 70-90 DEG C, and a clarified ammonium tungstate solution is obtained; s2, cooling the clarified ammonium tungstate solution to normal temperature at a cooling rate of 0.5-2 DEG C / h, and then carrying out suction filtration to obtain plate-shaped ammonium tungstate crystals; s3, calcining the tabular ammonium tungstate crystal to obtain ultra-thick tabular tungsten oxide; ammonium tungstate is adopted as a raw material, controllability is high, tungsten oxide which is uniform in particle size and complete in plate shape is obtained through optimized crystallization and calcination, the purity is larger than or equal to 99%, the problems that traditional tungsten oxide is agglomerated and disordered in shape are solved, functional adaptability is high, the plate-shaped structure can be directionally oriented, the dielectric performance, the breakdown performance and other performance are improved, and the method is suitable for multiple high-end scenes; parameters are easy to control, and operation is simple, green and safe.

The invention relates to the technical field of catalysts, and discloses a foam structure catalyst and a preparation method and application thereof. The foam structure catalyst comprises a foam structure, metal M2, metal oxide M2Ox, heteropolyacid salt of the metal M2, optional tungsten oxide WOz1 and optional molybdenum oxide MoOz2, the metal M2, the metal oxide M2Ox and the heteropolyacid salt of the metal M2 grow on the foam structure, z1 is equal to 2-3, and z2 is equal to 2-3; wherein the heteropolyacid salt is selected from one or more of tungstate and molybdate, M2 is selected from one or more of Cu, Ni, Fe, Zn and Co, and x is equal to 0.5 to 1.5; the foam structure contains metals M1 and M1Oy, M1 is selected from one or more of foam iron, foam nickel and foam cobalt, and y is equal to 1-1.5. The foam structure catalyst can be used for stable hydrogenolysis of glucose, the glucose conversion rate stably reaches 100% in a continuous fixed bed reactor, and the selectivity of 1, 3-propylene glycol is larger than or equal to 55%, and the selectivity of ethyl alcohol is larger than or equal to 48%.

The invention discloses a high-strength antioxidant tungsten-copper-chromium composite material and a preparation method thereof, and belongs to the technical field of tungsten-copper composite materials. The mass of the required tungsten metal powder, the mass of the required copper metal powder and the mass of the required chromium metal powder are calculated according to the mass fractions of the designed components, and then weighing and proportioning are conducted for standby application; tungsten metal powder and chromium metal powder are subjected to mechanical alloying through a planetary ball mill to obtain tungsten-chromium alloy powder, then copper metal powder is added, ball milling continues to be conducted, and tungsten-copper-chromium composite powder is obtained; and the obtained tungsten-copper-chromium composite powder is subjected to cold pressing, and then the high-strength anti-oxidation tungsten-copper-chromium composite material is prepared through liquid-phase sintering. According to the preparation method of the high-strength anti-oxidation tungsten-copper-chromium composite material, compared with a tungsten-copper composite material under the same preparation condition, the tensile strength and the oxidation resistance of the prepared tungsten-copper-chromium composite material are synergistically improved.

This invention proposes a tapered fiber optic hydrogen sensor and its fabrication method, belonging to the field of hydrogen sensors. The sensor includes a tapered section in the middle of an optical fiber; a sensing element tightly fitted around the tapered section; a light source inputting an optical signal into the optical fiber; a spectrometer measuring the position of characteristic peaks in the optical fiber's spectrum; and a three-layer thin-film structure comprising the sensing element from the inside out: an excitation layer that excites the optical fiber surface to generate a plasmon resonance effect; a reaction layer made of a gas-sensitive material that reacts with hydrogen; and a catalytic layer that catalyzes the reaction between the gas-sensitive material and hydrogen. This invention employs a tapering method to fabricate the fiber optic sensor, significantly improving its sensitivity. Using tungsten oxide and gold co-sputtering material as the gas-sensitive material greatly improves the response and recovery times compared to using only tungsten oxide.

The invention discloses a sodium metavanadate-based catalyst activity gradient regulation and regeneration system and method, and relates to the technical field of industrial catalyst regeneration, the sodium metavanadate-based catalyst is of a unique layered structure, the sodium metavanadate-based catalyst comprises an outer layer, a middle layer and an inner layer from the surface to the interior in sequence, and active components and doping elements of all the layers are different; the outer layer is doped with high-content sodium metavanadate and manganese oxide, reactant molecules can be quickly adsorbed and activated in the initial stage of the reaction, the manganese oxide can provide additional active sites, reduce reaction activation energy and promote quick start of the reaction, and the middle layer is doped with a proper amount of sodium metavanadate and cerium oxide, so that the reaction is more stable in the process of the reaction. The cerium oxide can adjust migration and conversion of oxygen species on the surface of the catalyst, optimize the reaction path, improve the selectivity of a target product and reduce side reactions, the inner layer is doped with the low-content sodium metavanadate and tungsten oxide, and the structural stability of the catalyst under high-temperature and long-time reaction is maintained by means of the high stability of the tungsten oxide.

The invention relates to a multi-element synergistic doped ATO target material and a preparation method thereof. Comprising the following steps: 1) uniformly mixing water and a powder dispersant, then adding an oxide 1 (at least one of tantalum pentoxide, niobium pentoxide, vanadium pentoxide, gallium oxide and tungsten trioxide), an oxide 2 (at least one of zinc oxide, copper oxide, cobalt oxide, manganese oxide and cerium oxide) and ATO raw material powder, and mixing and homogenizing to prepare slurry; 2) grinding the slurry and adding a powder forming adhesive; 3) carrying out spray drying granulation on the ground slurry; according to the preparation method, the ATO target material with high compactness (relative density gt, 98.5%) and low resistance (resistivity lt, 5 * 10 <-3 > omega.cm) is prepared through multi-element synergistic doping of the oxide, and the problem that compactness and conductivity of the ATO target material are difficult to consider at the same time in the prior art is solved.

The invention relates to an improvement method of a tungsten trioxide reduction process, which comprises the following steps: putting tungsten trioxide into a tubular furnace, and then introducing hydrogen to carry out reduction reaction to obtain tungsten powder; the reduction reaction comprises a first heating section, a first heat preservation section, a second heating section and a second heat preservation section which are sequentially carried out. The reduction reaction is carried out in multiple stages, the temperature gradient of the reduction reaction is controlled, the reduction efficiency is enhanced, and the situation that excessive condensate water is generated due to the fact that the temperature is directly increased to the highest temperature, and normal reaction is affected is avoided; according to the improvement method, a high-performance condenser does not need to be introduced, the equipment cost is reduced, and the performance of the obtained tungsten powder can also be guaranteed.

To provide a method and an apparatus of a deposition of tungsten having a small coarseness.SOLUTION: In some embodiments, a method has a step of flowing nitrogen together with hydrogen in an atomic layer deposition treatment for depositing tungsten by using hydrogen as a reducer. In some embodiments, the method has a step of depositing a cap layer such as a tungsten oxide layer or an amorphous tungsten layer on a side wall surface of a 3D NAND structure. An embodiment disclosed herein includes a wide variety of applications including making the 3D NAND structure by depositing a tungsten.SELECTED DRAWING: Figure 3

The invention provides a long-circulation high-rate negative electrode material as well as a preparation method and application thereof, and belongs to the technical field of negative electrode materials. Silicon powder, tin powder and graphene are compounded and subjected to carbon coating, a three-dimensional conductive network is constructed, volume expansion is relieved, and conductivity, cycling stability and rate capability are improved; tungsten oxide serves as an interface stabilizer to form a protective layer, side reaction is inhibited, interface impedance is reduced, and a conductive network is enhanced; metaphosphoric acid is decomposed to generate an inorganic phosphate protective film, and nitrogen-doped carbon generated by urea decomposition is combined, so that the interface stability and conductivity are remarkably improved, and the cycle life is remarkably prolonged; lithium carbide reacts with vinylidene fluoride to generate a lithium fluorocarbon additive, and lithium ions are released in stages to reduce the first lithium loss and stabilize an interface; a vanadium-based metal-organic framework prepared from ammonium metavanadate and terephthalic acid is combined with pre-embedded lithium and graphitized carbon coating, so that a lithium ion transmission path is optimized, and the performance of the lithium ion battery is improved. The synergistic modification measures improve the long cycle stability and high rate performance of the negative electrode material.

The invention discloses a tungsten trioxide electrochromic film for multi-tungsten oxygen cluster induced in-situ crystallization as well as a preparation method and application of the tungsten trioxide electrochromic film. The preparation method comprises the following steps: S1, adding hydrochloric acid into a sodium tungstate dihydrate aqueous solution to obtain a precipitate; washing the precipitate until the pH value of the supernate is greater than 3, and then drying the precipitate to obtain hydrated tungstic acid powder; dissolving the hydrated tungstic acid powder in a hydrogen peroxide solution to obtain a peroxy tungstic acid solution; s2, heating, evaporating and concentrating the peroxy tungstic acid solution to obtain a precursor solution containing multi-tungsten-oxygen clusters; and transferring the precursor solution containing the multi-tungsten-oxygen cluster to a substrate by adopting a film coating process, and annealing to obtain the tungsten trioxide electrochromic film with multi-tungsten-oxygen cluster induced in-situ crystallization, a matrix of the tungsten trioxide electrochromic film for multi-tungsten-oxygen cluster induced in-situ crystallization is amorphous tungsten trioxide, and hexagonal-phase tungsten trioxide nanocrystals are dispersed and distributed in the amorphous tungsten trioxide.