3441 results about "Electrochromism" patented technology

The invention relates to electro-optic displays and methods for driving such displays. The invention provides (i) electrochromic displays with solid charge transport layers; (ii) apparatus and methods for improving the contrast and reducing the cost of electrochromic displays; (iii) apparatus and methods for sealing electrochromic displays from the outside environment and preventing ingress of contaminants into such a display; and (iv) methods for adjusting the driving of electro-optic displays to allow for environmental and operating parameters.

An improved electrochromic device, the device incorporating an electrochromic medium that comprises at least three electroactive materials having absorption spectra that add together such that the color of the electrochromic medium can be pre-selected by individually choosing the concentrations of the at least three electroactive materials. The electrochromic medium generally maintains the pre-selected perceived color throughout its normal range of voltages when used in an electrochromic device. The at least three electroactive materials include at least one electrochemically reducible material (cathodic material), at least one electrochemically oxidizable material (anodic material) and at least one additional electroactive material which may be either an anodic or cathodic material. Thus, there are always three electroactive materials present in the medium, with at least two either being anodic or cathodic materials. The pre-selected color may be chosen from a wide variety of colors and may be, for example, red, orange, yellow, green, blue, purple. For electrochromic mirrors for motor vehicles, a presently preferred color is gray.

Electrochromic compounds capable of reversibly attenuating the transmittance of the near infrared portion of the electromagnetic spectrum are provided. These compounds exhibit an energy difference between the singly occupied molecular orbital (SOMO) energy and the highest doubly occupied molecular orbital (HDOMO) energy (ESOMO-EHDOMO) of less than about 3.6 eV. In addition, these compounds have a transition moment of the configuration made up of the HDOMO and SOMO that is "long axis polarized".

Methods of manufacturing electrochromic windows are described. An electrochromic device is fabricated to substantially cover a glass sheet, for example float glass, and a cutting pattern is defined based on one or more low-defectivity areas in the device from which one or more electrochromic panes are cut. Laser scribes and / or bus bars may be added prior to cutting the panes or after. Edge deletion can also be performed prior to or after cutting the electrochromic panes from the glass sheet. Insulated glass units (IGUs) are fabricated from the electrochromic panes and optionally one or more of the panes of the IGU are strengthened.

An electrochromic variable reflectance mirror for a vehicle includes a reflector / electrode on the third surface of the mirror. This reflector / electrode forms an integral electrode in contact with the electrochromic media, and may be a single layer of a highly reflective material or may comprise a series of coatings. When a series of coatings is used for the reflector / electrode, there should be a base coating which bonds to the glass surface and resists any adverse interaction, e.g., corrosive action, with the constituents comprising the electrochromic media, an optional intermediate layer (or layers) which bonds well to the base coating and resists any adverse interaction with the electrochromic media, and at least one highly reflective layer which directly contacts the electrochromic media and which is chosen primarily for its high reflectance, stable behavior as an electrode, resistance to adverse interaction with the materials of the electrochromic media, resistance to atmospheric corrosion, resistance to electrical contact corrosion, the ability to adhere to the base or intermediate layer(s) (if present) and to the epoxy seal, and ease of cleaning. If a base layer is deposited it preferably covers the entire third surface; however, when this is done the highly reflective layer may optionally only coat the central portion of the third surface and not the perimeter edge portion. The third surface reflector / electrode provides of improved electrical interconnection techniques used to impart a voltage drive potential to a transparent conductor on the mirror's second surface.

Electrochromic rearview mirrors having reduced apparent size bezels are disclosed. Visual characteristics of the bezel, such as lightness value, are controlled in order to reduce the apparent size of the bezel. The lightness value of the bezel is preferably matched to the lightness value of the electrochromic mirror. In addition, the color value of the bezel may also be controlled. The electrochromic rearview mirrors may be mounted in the interior or on the exterior of vehicles.

Window units, for example insulating glass units (IGU's), that have at least two panes, each pane having an electrochromic device thereon, are described. Two optical state devices on each pane of a dual-pane window unit provide window units having four optical states. Window units described allow the end user a greater choice of how much light is transmitted through the electrochromic window. Also, by using two or more window panes, each with its own electrochromic device, registered in a window unit, visual defects in any of the individual devices are negated by virtue of the extremely small likelihood that any of the visual defects will align perfectly and thus be observable to the user.

Electrochromic windows powered by wireless power transmission are described, particularly, the combination of low-defectivity, highly-reliable solid state electrochromic windows with wireless power transmission. Wireless power transmission networks which incorporate electrochromic windows are described.

This invention relates to processes for the assembly of three-dimensional structures having periodicities on the scale of optical wavelengths, and at both smaller and larger dimensions, as well as compositions and applications therefore. Invention embodiments involve the self assembly of three-dimensionally periodic arrays of spherical particles, the processing of these arrays so that both infiltration and extraction processes can occur, one or more infiltration steps for these periodic arrays, and, in some instances, extraction steps. The product articles are three-dimensionally periodic on a scale where conventional processing methods cannot be used. Articles and materials made by these processes are useful as thermoelectrics and thermionics, electrochromic display elements, low dielectric constant electronic substrate materials, electron emitters (particularly for displays), piezoelectric sensors and actuators, electrostrictive actuators, piezochromic rubbers, gas storage materials, chromatographic separation materials, catalyst support materials, photonic bandgap materials for optical circuitry, and opalescent colorants for the ultraviolet, visible, and infrared regions.

A display comprises spaced first and second electrodes, and a plurality of electrochromic nanoparticles disposed between the electrodes, each of the nanoparticles having an electron-rich state and an electron-depleted state, the two states differing in at least one optical characteristic. Upon injection of charge from one of the electrodes, the nanoparticles switch between their electron-rich and electron-depleted states, thus changing an optical characteristic of the display.

The inventive electrochromic mirror may be used in a vehicle rearview mirror assembly having a light source positioned behind the electrochromic mirror for selectively projecting light through the mirror. The electrochromic mirror includes front and rear spaced elements each having front and rear surfaces and being sealably bonded together in a spaced-apart relationship to define a chamber, a layer of transparent conductive material disposed on the rear surface of the front element, an electrochromic material is contained within the chamber, and a second electrode overlies the front surface of the rear element in contact with the electrochromic material. The second electrode includes a layer of reflective material and a partially transmissive coating of and is disposed over substantially all of the front surface of the rear element. The second electrode further includes a region in front of the light source that is at least partially transmissive.

Variable transmittance optical filters capable of transitioning from a light state to a dark state on exposure to UV radiation and from a dark state to a light state with application of an electric voltage are provided. The optical filters comprise a switching material that comprises one or more chromophores that have electrochromic and photochromic properties.

The invention relates to electro-optic displays and methods for driving such displays. The invention provides (i) electrochromic displays with solid charge transport layers; (ii) apparatus and methods for improving the contrast and reducing the cost of electrochromic displays; (iii) apparatus and methods for sealing electrochromic displays from the outside environment and preventing ingress of contaminants into such a display; and (iv) methods for adjusting the driving of electro-optic displays to allow for environmental and operating parameters.

According to one embodiment of the present invention, an electrochromic rearview mirror assembly for a vehicle includes an electrochromic mirror having a variable reflectivity, a glare sensor for sensing levels of light directed towards the front element from the rear of the vehicle, an ambient sensor for sensing levels of ambient light, a display positioned behind the partially transmissive, partially reflective portion of the reflector for displaying information therethrough; and a control circuit coupled to the sensors and the display. The control circuit determines whether daytime or nighttime conditions are present as a function of the ambient light level sensed by the ambient sensor. During daytime conditions, the control circuit responds to light levels sensed by the glare sensor to control a contrast ratio of light originating from the display and light reflecting from the partially transmissive, partially reflective area of the reflector.

A multi-layer device comprising a first substrate and a first electrically conductive layer on a surface thereof, the first electrically conductive layer having a sheet resistance to the flow of electrical current through the first electrically conductive layer that varies as a function of position.

There is disclosed an automatic electronic window shading (tinting) system for houses and transport vehicles such as automobiles, RV's, trains, boats and the like, to provide shading for people to protect them from exposure to harmful direct sunlight, by providing the windows of said houses and transport vehicles with display elements and light (photocell / photovoltaic) sensors. The system comprises liquid crystal, electrochromic, suspended particle device (SPD), or NanoChromics display (NCD) element attached to a part of a transparent body (such as the windows) and a liquid crystal, electrochromic, suspended particle device (SPD), or NanoChromics display (NCD) controlling semiconductor element controlling the operation of the display element.

A self-powered variable transmittance optical device, such as a smart window or other device, and associated method are provided. The device comprises one or more transparent substrates, with a switching material disposed thereon or therebetween. The switching material may be a hybrid photochromic / electrochromic material capable of transitioning from a first transmittance state to a second transmittance state with application of electricity, and from second state to first state due to another stimulus, such as UV radiation. Electrodes are coupled to the switching material for applying electricity. An electrical system provides for controllable application of the electricity, and may store energy. Energy is provided by an energy-harvesting power source such as a solar cell or other photovoltaic source, or array thereof, or another device for harvesting vibrational or thermal energy. Energy harvesting, energy storage capacity and / or switching material may be configured to provide at least a predetermined level of device operability.

A vehicular video mirror system comprises an interior electrochromic mirror having a transflective mirror reflector and a video screen disposed behind the mirror reflector so that its presence is substantially unobservable to a driver of the vehicle until the video screen is actuated to emit light that passes through the electrochromic reflective element to be viewed by the driver of the vehicle. Common control circuit circuitry may control dimming of the electrochromic medium and actuation of the video screen. The control circuitry may receive a signal indicative of selection of a reverse gear of the vehicle by the driver and actuates the video screen in order to display video images captured by a video imaging device disposed to the rear of the vehicle and having a field of view rearward of and external to the vehicle.

The present invention is directed to electrochromic systems comprising an electrochromic glazing or insulated glazing unit, a photovoltaic module for supplying power to the electrochromic glazing or IGU, and an electronics module in communication either the electrochromic glazing and / or photovoltaic module.

A vehicular rearview mirror assembly (600) includes an electrochromic (EC) glass element (303) and a printed circuit board (603) for mounting electrical components. A liquid crystal display (LCD) (615) is mounted to the printed circuit board (603), while a plurality of light emitting diodes (LEDs) (608) are also mounted to the same printed circuit board below the LCD (603) for providing backlighting.

An electrochromic element comprises a first substrate having a first surface and a second surface opposite the first surface, a second substrate in spaced-apart relationship to the first substrate and having a third surface facing the second surface and a fourth surface opposite the third surface, and an electrochromic medium located between the first and second substrates, wherein the electrochromic medium has a light transmittance that is variable upon application of an electric field thereto. The electrochromic element further comprises a transparent electrode layer covering at least a portion of at least a select one of the first surface, the second surface, the third surface, and the fourth surface, wherein the transparent electrode layer comprises an insulator / metal / insulator stack. The materials utilized to construct the insulator / metal / insulator stack are selected to optimize optical and physical properties of the electrochromic element such as reflectivity, color, electrical switch stability, and environmental durability.

An electrical control system is disclosed for controlling a plurality of variable transmittance windows. The electrical control system comprises a master control circuit and user input circuits for supplying control signals representing transmittance levels for the variable transmission windows, and a plurality of slave window control circuits coupled to the master control circuit, user input circuits and the variable transmittance windows. Each slave window control circuit controls the transmittance of at least one of the variable transmission windows in response to control signals received from the master control circuit and / or user input circuits. Also disclosed are novel methods for the manufacture of an electrochromic device used in variable transmittance windows. Novel structural features for improving heat transfer away from the windows, shielding the window from external loads, and improving the electrical performance of the windows are also disclosed.

Window units, for example insulating glass units (IGU's), that have at least two panes, each pane having an electrochromic device thereon, are described. Two optical state devices on each pane of a dual-pane window unit provide window units having four optical states. Window units described allow the end user a greater choice of how much light is transmitted through the electrochromic window. Also, by using two or more window panes, each with its own electrochromic device, registered in a window unit, visual defects in any of the individual devices are negated by virtue of the extremely small likelihood that any of the visual defects will align perfectly and thus be observable to the user.

According to the present invention, a rearview mirror comprises a first substrate having a front surface and a rear surface, a reflective coating disposed on a surface of the first substrate, and an electronic circuit component secured to the rear surface of the first substrate. The mirror element may be an electrochromic mirror element comprising a transparent second substrate positioned in front of the first substrate. The electronic component secured to the rear surface may be a component of a drive circuit for the electrochromic mirror element. The rearview mirror element may further comprise electrically conductive tracings provided on the rear surface of the first substrate electrically coupled to the electrical component. The tracings may be used to electrically couple the drive circuit to the electrodes of the electrochromic mirror element. The tracings may be deposited on the rear surface using numerous methods including inkjet printing techniques.

There is disclosed an automatic electronic window shading (tinting) system for houses and transport vehicles such as automobiles, RV's, trains, boats and the like, to provide shading for people to protect them from exposure to harmful direct sunlight, by providing the windows of said houses and transport vehicles with display elements and light (photocell / photovoltaic) sensors. The system comprises liquid crystal, electrochromic, suspended particle device (SPD), or NanoChromics display (NCD) element attached to a part of a transparent body (such as the windows) and a liquid crystal, electrochromic, suspended particle device (SPD), or NanoChromics display (NCD) controlling semiconductor element controlling the operation of the display element.

A vehicular rearview mirror assembly (600) includes an electrochromic (EC) glass element (303) and a printed circuit board (603) for mounting electrical components. A liquid crystal display (LCD) (615) is mounted to the printed circuit board (603), while a plurality of light emitting diodes (LEDs) (608) are also mounted to the same printed circuit board below the LCD (603) for providing backlighting.

The inventive electrochromic mirror may be used in a vehicle rearview mirror assembly having a light source positioned behind the electrochromic mirror for selectively projecting light through the mirror. The electrochromic mirror includes front and rear spaced elements each having front and rear surfaces and being sealably bonded together in a spaced-apart relationship to define a chamber, a layer of transparent conductive material disposed on the rear surface of the front element, an electrochromic material is contained within the chamber, and a second electrode overlies the front surface of the rear element in contact with the electrochromic material. The second electrode includes a layer of reflective material and a partially transmissive coating of and is disposed over substantially all of the front surface of the rear element. The second electrode further includes a region in front of the light source that is at least partially transmissive.

A vehicular video mirror system comprises an interior electrochromic mirror having a transflective mirror reflector and a video screen disposed behind the mirror reflector so that the presence of the video screen is substantially unobservable to a driver of the vehicle until the video screen is actuated to emit light that passes through the electrochromic reflective element to be viewed by the driver of the vehicle. Control circuitry receives a signal indicative of selection of a reverse gear of the vehicle by the driver and actuates the video screen in order to display video images captured by a video imaging device disposed to the rear of the vehicle and having a field of view rearward of and external to the vehicle.

An electrical control system is disclosed for controlling a plurality of variable transmittance windows. The electrical control system comprises a master control circuit and user input circuits for supplying control signals representing transmittance levels for the variable transmission windows, and a plurality of slave window control circuits coupled to the master control circuit, user input circuits and the variable transmittance windows. Each slave window control circuit controls the transmittance of at least one of the variable transmission windows in response to control signals received from the master control circuit and / or user input circuits. Also disclosed are novel methods for the manufacture of an electrochromic device used in variable transmittance windows. Novel structural features for improving heat transfer away from the windows, shielding the window from external loads, and improving the electrical performance of the windows are also disclosed.