This invention discloses a Z-type ZnTCPP / ZIS
heterojunction catalyst, its preparation method, and its application, belonging to the field of
photocatalysis technology. The process includes the following steps: Step S1, synthesizing a
zinc porphyrin metal-organic framework (Zn-TCPP); Step S2, dissolving Zn-TCPP,
zinc salt,
indium salt, and a
sulfur source in water, stirring until homogeneous, and then performing a
solvothermal reaction; Step S3, after the reaction is complete, cooling to
room temperature, centrifuging, washing, and
drying to obtain the Z-type ZnTCPP / ZIS
heterojunction catalyst. Photogenerated electrons on the ZnIn2S4
conduction band recombine with photogenerated holes on the ZnTCPP
valence band at the interface, while the electrons retained on the ZnTCPP
conduction band and the holes on the ZnIn2S4
valence band possess strong reducing and oxidizing abilities, respectively. This forms a built-in
electric field from ZnTCPP to ZnIn2S4, and the unique charge transfer path promotes the spatial separation of photogenerated carriers, effectively suppressing bulk recombination of
electron-hole pairs, and significantly improving
charge separation efficiency and photocatalytic activity.