The invention discloses a craft for producing
pyromellitic dianhydride catalyzed by a carrier-type poly-oxometalate, including melting the
pyromellitic dianhydride by the groove, feeding to the mixing
machine for evapouration after pre-heating with a feed concentration of 15.0-19.5g / m3, mixing with the air, entering into the
fixed bed reactor for a oxidation, oxidating with an
airspeed of 4500-6500 h-1, cooling the produced air, then condensing in the collector, getting coarse
pyromellitic dianhydride. At 300-340 DEG C, the catalyzer is mostly poly-oxometalate which is fixed on the catalyst
bed after loading. The
mass ratio of the catalyzer to pyromellitic dianhydride is 0.2-1%. The invention has the
durene in the C10 heavy aromatics as
raw material, produces the pyromellitic dianhydride by oxidation in air, makes the C10 heavy aromatics be with a higher added value, uses the current resource and industrial equipments as more as possible, exploits the
catalysis and synthesis path of the pyromellitic dianhydride. The invention has a low
pollution and production cost, a wide development prospect and is suitable for commercial process.