617 results about "Gallium" patented technology

The invention provides a metal gallium extraction device and an extraction method thereof. The gallium extraction device comprises an extraction tank, a base and an extraction mechanism, a top plate is hermetically mounted at the top of the extraction tank through bolts, a mounting cover is mounted at the top of the top plate through bolts, a feeding pipe is mounted on the inner wall of the mounting cover, a recycling pipe is mounted at the bottom end of the extraction tank, a suction pipe is fixedly arranged on the side wall of the extraction tank, and the extraction mechanism comprises a mounting plate fixedly arranged on the inner wall of the extraction tank; according to the scheme, the cleaning plate designed in a special shape is used for controlling the screw rod to rotate in a linkage manner, so that water-phase clarified matters are synchronously treated in the process of discharging a water phase, the interior of the extraction tank can be well and finely cleaned, and meanwhile, the clarified matters are centrally treated, so that the blockage of a recovery pipe can be avoided; therefore, the top plate does not need to be opened for washing, clarified impurities in the extraction tank can be effectively reduced, and the subsequent extraction effect and the extraction stability are ensured.

The invention relates to the technical field of metal material processing. The invention provides an impurity removing and charging method, system and equipment for metal gallium production and a storage medium. The method comprises the following steps: inputting a production task through an intelligent control system, and presetting a material addition amount and process parameters; the remaining amount of the material storage bin is detected through a material level monitoring sensor, and the materials are conveyed to an adding actuator through a conveying device after it is confirmed that the remaining amount is sufficient; scanning a feeding area by means of a visual identification system and a laser scanner, obtaining coordinate data of a target feeding point, planning a motion path of the robot, and controlling the robot to accurately position; material adding is executed in stages, the concentration or liquid level change is monitored in real time so as to dynamically adjust the adding amount, meanwhile, the feeding state is continuously monitored through visual recognition, and the posture and parameters of the robot are corrected in real time for deviation or abnormity. The problems that in the impurity removal process of metal gallium production, the precision of traditional manual feeding is greatly influenced by operation experience, material proportion deviation is likely to be caused, the labor intensity of workers is high, and safety risks exist are solved.

The invention provides a flexible electromagnetic shielding film and a preparation method thereof. The preparation method comprises the following steps: mixing metal gallium and metal indium in a preset proportion to prepare a gallium-indium alloy; the preparation method comprises the following steps: putting a preset mass of gallium-indium alloy into an isopropanol solution, and treating through an ultrasonic cell disruption system to obtain a liquid metal particle suspension; stirring magnetic functional nanoparticles, an electrostatic spinning high-molecular elastomer and a solvent at normal temperature for a preset time to obtain an electrostatic spinning homogeneous solution; treating the electrostatic spinning homogeneous solution by adopting an electrostatic spinning process to obtain a magnetic nanofiber membrane; and spraying the liquid metal particle suspension onto the magnetic nanofiber membrane by adopting an electrostatic spraying process to obtain the flexible electromagnetic shielding film. According to the flexible electromagnetic shielding film and the preparation method thereof, the problem that the stability of an existing shielding material is reduced under the stretching effect can be solved.

The method comprises the following steps: weighing an oxide precursor of metal indium, an oxide precursor of metal M, an ammonium salt and a lithium salt according to a chemical formula of indium-based halide, fully mixing, and calcining in an inert atmosphere to obtain the indium-based halide solid electrolyte. Forming an indium-based halide solid electrolyte through a solid-phase reaction; wherein M is selected from at least one of magnesium, calcium, strontium, barium, aluminum, gallium, indium, bismuth, scandium, yttrium, zinc, germanium, tin, lanthanum, cerium, samarium, gadolinium, holmium, erbium and ytterbium. The method can greatly simplify the synthesis process, reduce the raw material cost and realize industrial batch preparation.

The invention relates to a catalyst for preparing methanol through hydrogenation of carbon dioxide. The catalyst comprises a hydroxide compound with a core-shell structure, the hydroxide compound with the core-shell structure is formed by taking a lamellar hydroxide as a core and coating the lamellar hydroxide with a granular hydroxide to form a shell; wherein the lamellar hydroxide and the granular hydroxide respectively and independently comprise one or more of hydroxides of copper, manganese, nickel, indium, zinc, aluminum, cerium, zirconium, cobalt, gallium and silicon, and the lamellar hydroxide and the granular hydroxide in the hydroxide compound with the same core-shell structure are different. Lamellar hydroxides in the hydroxide compounds with different core-shell structures are different. The invention further provides a preparation method of the catalyst, the preparation method is simple in process and low in cost, and the prepared catalyst is high in active element content, high in catalytic activity, high in carbon dioxide conversion rate and high in methanol yield.

The invention discloses a method for preparing a transdermal microneedle based on gallium-based liquid metal, which comprises the following steps: (1) heating the gallium-based liquid metal at a temperature higher than the melting point of the liquid metal, so that the gallium-based liquid metal is completely molten into a liquid state; (2) sucking the liquid metal preheated in the step (1) by using a microsyringe or a pipettor, and quickly injecting the liquid metal into a microneedle mold, so that the liquid metal is spread and completely covers a cavity of a needle tip in the mold; (3) transferring the mold in the step (2) into a constant-temperature vacuum box, and decompressing and degassing under vacuum; in the degassing process, the degassing temperature enables the liquid metal to be kept in a flowing liquid state all the time, and vacuumizing is conducted till the pressure is not higher than 10 Pa; the degassing time is not less than 5 hours; (4) continuously injecting the preheated gallium-based liquid metal or a degradable polymer solution into the mold to form a substrate of the microneedle; and (5) transferring the mold in the step (4) to a temperature far lower than the melting point of the liquid metal, and freezing and forming to obtain the transdermal microneedle.

The invention discloses an extraction method for extracting gallium from waste residues of coal gangue and bauxite, which is characterized in that metal elements such as gallium and aluminum in the waste residues can be uniformly distributed through powdering and proper mixing, ammonium sulfate is added in the roasting process, so that not only is the separation and release of gallium and aluminum realized, but also the generated ammonium sulfate gas is cooled, crystallized and recycled, and the production cost is reduced. According to the method, the process cost is reduced, acid leaching, alkaline leaching and composite extraction are adopted step by step, it is ensured that gallium is efficiently enriched and separated in all procedures, gallium oxide with the purity larger than or equal to 99.5% is finally obtained, meanwhile, residual silicon-rich residues and bauxite residues are subjected to hydrothermal crystallization to prepare molecular sieves, comprehensive utilization of waste residues is achieved, and obvious economic and environment-friendly benefits are achieved.

The invention discloses a gallium-based liquid metal composite material, which is prepared from the following components in parts by weight: 10 to 30 parts of elastomer, 65 to 95 parts of oxidized gallium-based liquid metal and 1 to 5 parts of Ti < 3 > C < 2 > T < x > MXene. By controlling the oxidation rate of the gallium-based liquid metal, the mobility of the gallium-based liquid metal can be effectively reduced, the gallium-based liquid metal is prevented from leaking in the composite material, and the flexibility is improved.

The invention relates to a colored radiation refrigeration coating and a colored cooling coating, the colored radiation refrigeration coating comprises a white prime coating and a colored surface coating which are matched for use, the sunlight reflectivity of a white bottom layer formed by the white prime coating at the wave band of 0.3-2.5 microns is greater than or equal to 95%, and the sunlight reflectivity of the colored surface coating at the wave band of 0.3-2.5 microns is greater than or equal to 95%. The atmospheric window emissivity at the wave band of 8-13 [mu] m is greater than or equal to 95%; the colored surface coating comprises a first filler, yttrium gallium garnet and first resin, the yttrium gallium garnet is doped with chromium, and the mass fraction of the chromium in the yttrium gallium garnet is 5%-15%. A color cooling coating formed by the color radiation refrigeration coating is bright in color, the sunlight reflectivity at the wave band of 0.3-2.5 microns is larger than or equal to 82%, the atmospheric window emissivity at the wave band of 8-13 microns is larger than or equal to 95%, and the color radiation refrigeration coating has an excellent cooling effect.

The invention discloses a method for improving performance of rare earth permanent magnet sintered neodymium iron boron grain boundary diffusion, and belongs to the technical field of rare earth permanent magnet materials. The method comprises the steps that a low-melting-point metal layer and a diffusion layer containing heavy rare earth elements are sequentially formed on the surface of a clean sintered neodymium-iron-boron magnet, and then vacuum diffusion heat treatment and tempering treatment are conducted. Wherein the low-melting-point metal layer comprises at least one of copper, aluminum, gallium and tin or an alloy of the copper, the aluminum, the gallium and the tin; the heavy rare earth element comprises at least one of dysprosium, terbium, holmium and gadolinium. The low-melting-point metal layer is preferentially diffused and wets the grain boundary in the heat treatment process, heavy rare earth elements are promoted to be deeply and uniformly diffused towards the interior of the magnet along the grain boundary, so that a heavy rare earth-rich shell layer is formed outside main phase grains of the magnet, and the intrinsic coercive force is improved; meanwhile, the low-melting-point metal forms a strengthening phase at the grain boundary, the brittleness of the magnet after diffusion is improved, the surface corrosion phenomenon is restrained, and collaborative optimization of the comprehensive performance of the magnet is achieved.

The present invention provides a dendrite-free zinc-based flow battery. The flow battery includes an anode integrated with a first collector, a cathode integrated with a second collector, a first storage tank comprising catholyte, a first pump connects the cathode and the first storage tank, a second storage tank comprising anolyte and liquid eutectic alloys, a second pump connects the anode and the second storage tank, and a separator to prevent direct contact between the anolyte and the catholyte. The room-temperature gallium-based liquid metals (Ga-LM) alloys enable zinc-based flow batteries (Zn-FBs) to achieve unparalleled areal capacity and exceptionally long cycle life.

The invention relates to the technical field of hydrometallurgy production, and particularly discloses a method for synergistically extracting gallium and scandium by coupling titanium white waste acid with vanadium extraction converter sludge, which comprises the following steps: mixing titanium white waste acid and vanadium extraction converter sludge in proportion, stirring and leaching to obtain a leaching solution; adding an extraction agent and a diluent into the leaching solution for extraction, and washing to obtain a gallium and scandium loaded organic phase; a first stripping agent is added into the loaded organic phase of gallium and scandium for stripping treatment, and a gallium stripping solution and a loaded organic phase of scandium are obtained; sequentially carrying out alkali precipitation, alkali dissolution and electrolytic treatment on the gallium reverse extraction solution to obtain crude gallium; a second stripping agent is added into the scandium-loaded organic phase for stripping treatment, and a scandium precipitation solution and an organic phase solution are obtained; and the scandium precipitation solution is filtered, washed and subjected to acid dissolution, and a scandium-containing solution is obtained. According to the method, the titanium white waste acid is effectively recycled, rare and precious metals in the vanadium extraction converter sludge are efficiently and synergistically extracted, and the method has a relatively good popularization prospect.

The invention provides an impurity removal method of a gallium-rich solution for a gallium-based fluorescent powder precursor, and belongs to the field of preparation of gallium-based fluorescent powder precursors. The method comprises the following steps: adding an oxidizing agent into an initial gallium-rich solution to carry out a first reaction so as to remove organic impurities in the initial gallium-rich solution and obtain a first gallium-rich solution; adding a composite impurity removal reagent into the first gallium-rich solution to carry out a second reaction to remove impurity elements such as calcium, silicon and vanadium in the first gallium-rich solution so as to obtain a second gallium-rich solution; and adding a sulfide type reagent into the second gallium-rich solution to carry out a third reaction so as to remove copper and iron impurity elements in the second gallium-rich solution, thereby obtaining the gallium-rich solution for the gallium-based fluorescent powder precursor. According to the method, various key impurity elements such as organic matters, alkaline earth metals, metalloids and heavy metals are directionally and efficiently removed through the impurity removal logic of oxidation impurity breaking, synergistic precipitation and deep vulcanization, so that the total content of the key impurity elements in the gallium-rich solution is remarkably reduced.

The invention belongs to the field of metallurgy, and particularly relates to a method for comprehensively recovering iron, vanadium, titanium, scandium and gallium through cooperation of vanadium titano-magnetite and red mud, which comprises the following steps: a) mixing vanadium titano-magnetite concentrate powder and red mud powder, roasting, leaching in water, and carrying out solid-liquid separation to obtain leached residues and leached liquid; b) mixing the leachate with a precipitant to precipitate vanadium, and carrying out solid-liquid separation to obtain vanadium-rich slag and vanadium-precipitated clear liquid; dissolving the vanadium-rich slag in a sulfuric acid solution, mixing the vanadium-rich slag with ammonium salt to react, carrying out solid-liquid separation, and roasting the obtained solid product ammonium polyvanadate to obtain V2O5; resin is used for adsorbing and desorbing gallium ions in the vanadium precipitation clear liquid, the pH of desorption liquid is adjusted to be alkaline, then electrolysis is conducted, and crude gallium is obtained; c) washing and drying the leaching residues to prepare pellets; after the pellets are pre-reduced, a carbonaceous reducing agent is mixed, melt separation treatment is carried out, and scandium-containing high-titanium slag and molten iron are obtained; and Ti and Sc in the scandium-containing high titanium slag are recycled. The method has the advantages of simple process, cleanness, high efficiency and the like.

The invention relates to an electrochemical induced metal oriented growth method based on a gallium-based liquid metal substrate, and belongs to the technical field of electrochemical materials. According to the present invention, the dynamic smooth interface and the low lattice mismatch characteristic of the liquid metal are utilized, the reduction kinetics of the metal ions is regulated and controlled through the constant current mode, the high orientation degree growth of the crystal along the specific crystal face (such as Zn (002) and In (111)) is achieved, and the prepared deposited metal dominant crystal face has the high orientation degree. The problems of stress accumulation and dendritic crystals of a traditional solid substrate can be solved, and the method is suitable for green preparation of nanowire arrays and functional coatings; and the process is simple and convenient to operate, easy in control of process parameters and suitable for batch production.

The invention discloses automatic quantitative high-precision filling equipment for heating refined gallium in an air environment, which comprises an automatic filling assembly, an automatic receiving assembly, an outer cover feeding assembly, an inner cover feeding assembly and an automatic bottle feeding assembly, gallium has certain corrosivity, and in order to ensure the purity of the gallium, a peristaltic pump is adopted to directly suck and convey the gallium; a refined gallium heating unit; the refined gallium is heated, so that the condition that filling is blocked due to solidification of the refined gallium in the filling process due to too low room temperature is avoided; a quantitative filling unit; and a five-layer sealing filling gun is adopted to ensure that no leakage phenomenon is generated after filling is finished. According to the automatic quantitative high-precision filling equipment for heating the refined gallium in the air environment, a method for precisely filling the refined gallium through the high-speed quantitative filling gun is adopted, the other high-precision liquid supplementing filling gun is used for filling the final refined gallium, and the precision of a final product is guaranteed.

The invention discloses a platinum-based high-entropy intermetallic compound electrocatalyst and a preparation method thereof, the electrocatalyst is carbon material loaded platinum-based high-entropy intermetallic compound nanoparticles, and comprises 1-6 of six metal elements of platinum, manganese, iron, cobalt, nickel, zinc and copper, and 1-3 of three metal elements of gallium, indium and tin; in the nano-particles, platinum atoms account for 40%-60% of atoms, the platinum atoms and other metal atoms are orderly and regularly arranged, and the phase structure is an L10 phase. The preparation method of the platinum-based high-entropy intermetallic compound electrocatalyst is simple in process, and the metal loading capacity can be effectively controlled. Due to the introduction of the low-melting-point gallium / indium / tin metal, the high-entropy intermetallic compound can be prepared at a relatively low temperature, the agglomeration / sintering phenomenon is effectively avoided, and the platinum-based high-entropy intermetallic compound electrocatalyst with uniform size and adjustable components can be obtained. The electrocatalyst can be used for a fuel cell cathode material, and has important significance for improving the performance of a fuel cell.

The invention belongs to the technical field of tin plating materials, and relates to a tin plating plate with high sulfur resistance and a preparation method and application thereof. The tin-plated plate with high sulfur resistance comprises a first passivation layer, a first tin-plated layer, a first multi-component alloy layer, a tin-plated substrate layer, a second multi-component alloy layer, a second tin-plated layer and a second passivation layer which are arranged in sequence, the surface, away from the first tin plating layer, of the first passivation layer is an inner coating surface; the surface, away from the second tin plating layer, of the second passivation layer is an outer coating surface; the arithmetic mean roughness of the inner coating surface is 0.4-0.5 [mu] m, the profile skewness is 0-0.3, and the profile kurtosis is 2.5-3; the arithmetic mean roughness of the outer coating surface is 0.6-0.7 [mu] m, the profile skewness is 0-0.3, and the profile kurtosis is 2.5-3; the first multi-component alloy layer and the second multi-component alloy layer respectively and independently comprise gallium; according to the tin plate with the high sulfur resistance, the binding force between the film layers is high, and the deformation resistance and the sulfur resistance of the film layers are excellent.

The invention provides a method for growing a (310) oriented beta-Ga2O3 single crystal thick film on a sapphire substrate. The method comprises the following steps: cleaning the sapphire substrate and then carrying out annealing treatment; and with hydrogen chloride gas, gallium metal and oxygen as reaction sources, epitaxially growing a (310) oriented beta-Ga2O3 single crystal thick film on the treated sapphire substrate by using a hydride vapor phase epitaxy method. According to the method for growing the (310) oriented beta-Ga2O3 single crystal thick film on the sapphire substrate, the process is simple, operation is easy, controllability is high, the obtained (310) oriented beta-Ga2O3 single crystal thick film is smooth in surface, compact and uniform in thickness, the crystallinity of the single crystal film layer is high, and the growth requirement of a single crystal epitaxial film layer of tens of micrometers can be met; in addition, the method provided by the invention can realize large-batch and large-scale production of the (310) oriented beta-Ga2O3 single crystal thick film, and meets the device preparation requirements.

The invention discloses a comprehensive recovery method of a low-grade multi-metal material. The comprehensive recovery method comprises the following steps: smelting the low-grade multi-metal material in a reinforced smelting furnace; smelting slag enters the echelon reduction volatilization furnace to be smelted; mixing soot obtained by smelting with the waste zinc electrolyte to obtain pulpified liquid; flue gas obtained by smelting and pulpified liquid are subjected to a contact reaction, and the reacted liquid is subjected to gas-liquid separation; carrying out contact reaction on the flue gas obtained after gas-liquid separation and the liquid again; extracting indium from the obtained lixivium by adopting P2O4; adding tannin into liquid after indium extraction to precipitate germanium; and adding alkali liquor into the germanium-deposited solution to neutralize and recover gallium. According to the method, the low-grade multi-metal material is sequentially subjected to echelon oxygen-enriched enhanced reaction smelting, continuous oxidation desulfurization leaching and scattered metal wet recovery by adopting an efficient smelting method, so that the energy consumption is reduced, the smelting efficiency is improved, the recovery rate of metals such as germanium is improved, the resource recovery rate is improved under the condition of relatively low energy consumption, and the economic benefit is increased. And the method has good social and economic benefits.

The invention discloses a neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and a preparation method thereof, and relates to the technical field of neodymium-iron-boron magnet preparation, and the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet comprises the following preparation raw materials: 170-175 kg of PrNd (praseodymium-neodymium alloy), 25-30 kg of BFe (iron white copper), 1-5 kg of Co (cobalt), 0.1-2 kg of Cu (copper), 1-5 kg of Zr (zirconium), 0.1-1 kg of Ga (gallium) and 380-420 kg of Fe (iron). According to the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and the preparation method thereof, the 54H sintered neodymium-iron-boron magnet is prepared through a double-alloy technology with neodymium, iron and gallium as auxiliary alloy without adding dysprosium, terbium and other scarce type heavy rare earth elements, and performance optimization and cost optimization of the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet are achieved.

The application discloses a low-driving-potential aluminum alloy sacrificial anode for a seawater cooling water system, which comprises a sacrificial anode body and a core, the core is wrapped in the sacrificial anode body, the sacrificial anode body is mainly composed of aluminum, and gallium, tin, antimony and copper are added, the weight percentage of each component is as follows: 0.3-0.5% of gallium, 0.01-0.1% of tin, 0.005-0.02% of antimony, 0.01-0.1% of copper, less than or equal to 0.06% of impurity iron, and the balance of aluminum. The working potential of the low-driving-potential aluminum alloy sacrificial anode for the seawater cooling water system is-0.75V to-0.90V (relative to a saturated calomel electrode), the electric capacity is greater than or equal to 2300 Ah / kg, the sacrificial anode surface dissolves uniformly, the corrosion product is easy to fall off, and the low-driving-potential aluminum alloy sacrificial anode is suitable for cathode protection of high-strength steel, titanium-steel composite structure, stainless steel and other materials in a seawater environment. The application further discloses a preparation method of the low-driving-potential aluminum alloy sacrificial anode for the seawater cooling water system.

The invention discloses a method for deeply separating and extracting gallium, and belongs to the technical field of non-ferrous metallurgy. According to the method for deeply separating and extracting gallium, the problems that an existing adsorption material is generally poor in chemical stability, insufficient in selectivity and adsorption capacity and the like in a gallium-containing solution with high alkalinity and coexistence of multiple components are solved, and the gallium is deeply separated and extracted on the basis of the coordination characteristic of gallate ions. A covalent organic framework adsorption material with a directional recognition site and an ordered pore channel structure is designed and constructed. According to the material, an organic porous framework with high crystallinity and large specific surface area is constructed through dynamic covalent chemistry, and efficient and high-selectivity adsorption of gallate ions can be realized. The method is suitable for efficiently capturing and enriching gallium from a high-alkalinity complex solution, and a reliable technical solution with application prospects is provided for efficient recycling of gallium resources.

The invention discloses a preparation method and application of a high-thermal-conductivity liquid metal gallium-indium-tin alloy, and relates to the technical field of gallium-indium-tin alloys, the high-thermal-conductivity liquid metal gallium-indium-tin alloy is prepared by weighing the following components in percentage by weight: 65-80% of gallium, 15-25% of indium, 3-10% of tin, 0.1-2% of trace element combination X and 0.05-1% of Y, and the purity of the gallium, the purity of the indium and the purity of the tin are greater than or equal to 99.99%, and the X is one or two of antimony and bismuth; y is one or two of zinc and copper; the raw materials are heated to 120-200 DEG C, so that the raw materials are completely molten into a liquid state; the molten liquid metal is subjected to magnetic field auxiliary stirring, and evenly-mixed alloy liquid is formed; and cooling the alloy liquid to room temperature in a vacuum or inert gas environment. The temperature sensing medium has the advantages that by synergistically adding antimony, bismuth, zinc, copper and other trace elements, the temperature sensing medium can be simultaneously used as a core temperature sensing medium of an expansion type thermometer and a resistance type thermometer, and the temperature sensing medium has high precision, wide temperature range and environmental friendliness.

A method may include contacting a hydrocarbon-containing feed with a catalyst in a reactor to form an olefin-containing effluent, then at least partially separating the olefin-containing effluent from the catalyst. Passing the catalyst to a combustor and heating the catalyst by combusting a supplemental fuel. The supplemental fuel includes methane in an amount greater than or equal to 1 mol. %. Passing the catalyst from the combustor to the reactor, such that at least a portion of the catalyst continuously cycles between the reactor and the combustor. The catalyst includes from 0.1 wt. % to 10 wt. % of one or more metals chosen from gallium, indium, thallium or combinations thereof, from 5 ppmw to 1000 ppmw of one or more metals chosen from platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof, from 100 ppmw to 30000 ppmw of chromium, and at least 85 wt. % support.

The invention discloses a device and a method for inhibiting crucible oxidation and raw material decomposition in gallium oxide single crystal growth, the device comprises a furnace body, an iraurita crucible, a thermal insulation layer, an induction coil, a lifting mechanism and the like, a temperature dynamic regulation and control system is arranged between the iraurita crucible and the thermal insulation layer; the temperature dynamic regulation and control system is used for monitoring the temperature distribution of the iridium crucible and the inner cavity in real time and regulating the heating frequency of the induction coil through feedback temperature; a melt decomposition monitoring system is arranged in the inner cavity close to the iraurita crucible and is used for detecting the gallium atom concentration and oxygen partial pressure change in the inner cavity in real time; and an atmosphere active adjusting system is also arranged in the furnace body. According to the device, the gallium oxide single crystal can be obtained, and the problems of crucible oxidation, melt decomposition and unstable crystal quality caused by a high-temperature environment can be solved; through dynamic monitoring and regulation, the oxidation and corrosion loss of the iraurita crucible is reduced, and meanwhile, the large-size and high-quality beta-Ga2O3 single crystal is obtained.

The invention discloses a gallium-cerium co-doped ITO target material and a preparation method thereof, and belongs to the field of transparent conductive oxide ceramic target materials, and the preparation method comprises the following steps: weighing indium oxide powder raw materials, tin oxide powder raw materials, gallium oxide powder raw materials and cerium oxide powder raw materials in proportion, and performing pretreatment; the raw material powder is subjected to independent ball milling till the raw materials reach the preset particle size; mixing the four kinds of slurry, and continuously performing ball milling to obtain uniform mixed slurry; adding a binder into the mixed slurry, and carrying out ball milling and mixing to form stable formed slurry; carrying out spray granulation on the formed slurry to obtain spherical precursor powder; pressing and forming the precursor powder to obtain a biscuit, then putting the biscuit into a sintering furnace, carrying out stepped sintering in an oxygen atmosphere, and naturally cooling to obtain the gallium-cerium co-doped ITO target material. According to the gallium-cerium co-doped ITO target material prepared by the method, the relative density is greater than or equal to 99.4%, the resistivity is less than or equal to 99.4%, and the three-point bending strength is greater than or equal to 230MPa.

The present application provides a kind of method for extracting metal gallium by vanadium extraction converter sludge, comprising the following steps: S1: vanadium extraction converter sludge is leached with leaching agent, and gallium leaching solution is obtained;S2: the gallium leaching solution of step S1 is extracted, and gallium-containing organic phase is obtained;S3: the gallium-containing organic phase of step S2 is back-extracted, and gallium-containing aqueous phase is obtained;S4: the gallium-containing aqueous phase of step S3 is treated to obtain gallium-containing precipitate, and the gallium-containing precipitate is dissolved in alkali to obtain gallium-containing alkali solution, which is treated by electrolysis to obtain metal gallium.The raw material for extracting gallium is unique, the gallium content is high, the gallium extraction process is short, the impurity removal effect is good, and the by-product produced has higher purity and better economic value.

The invention discloses a metalized diamond particle, a diamond / gallium-based liquid metal composite material and a preparation method thereof, and belongs to the field of composite thermal interface materials. The metallized diamond particle comprises a diamond particle, the surface of the diamond particle is coated with an immiscible alloy layer, the immiscible alloy layer contains a diffusion barrier component and a reaction wetting component, and the content of the diffusion barrier component in the immiscible alloy layer is not higher than 15 at% of the total content of the diffusion barrier component and the reaction wetting component; wherein the diffusion barrier component is one or more of tungsten, molybdenum and tantalum, and the reaction wetting component is one or more of silver and copper. The metallized diamond particles and the gallium-based liquid metal are combined to form the composite material, so that the diamond / gallium-based liquid metal composite material has more excellent thermal conductivity.

The invention discloses a green resource extraction method of metal gallium in coal-series solid waste, gallium element in waste is fully released through high-temperature activation and acid leaching dissolution, efficient selective enrichment of gallium is realized by adopting an ion imprinting modified persimmon peel adsorbent, high recovery rate in subsequent procedures is ensured, and the method is suitable for industrial production. And the high-purity metal gallium is recovered by utilizing a resin secondary enrichment and electrolytic refining technology, so that the process complexity and the equipment cost are reduced, the acid leaching residues can be converted into silica powder and aluminum oxide after being processed and treated, the resource utilization of wastes is realized, and the environmental pollution is reduced.