The invention relates to the technical field of
precious metal recovery, in particular to a method and
system for recovering gold, silver,
palladium and
platinum from silver
anode slime. S2,
palladium precipitation: adding a
potassium-
magnesium mixture and
sodium chlorate into the pre-impregnation liquid obtained in S1 to obtain
palladium precipitation residues and
platinum precipitation liquid; s3, separating gold; s4,
platinum and palladium precipitation: adding a
potassium-
magnesium mixture and
sodium chlorate into the gold separation liquid obtained in S3 to obtain platinum and palladium precipitation residues and platinum and palladium precipitation post-liquid; s5, gold is reduced; s6, platinum and palladium separation, wherein
hydroxylamine hydrochloride is added into the platinum and palladium precipitation residues obtained in the step S4, and palladium separation liquid and platinum precipitation residues are obtained; 7, platinum purification, wherein
hydroxylamine hydrochloride is added into the platinum precipitation residues obtained in the step 6, and platinum separation liquid is obtained; s8, carrying out primary palladium deposition; s9, carrying out secondary palladium deposition; and S10, palladium is reduced. The
recovery rate of palladium is 99% or above, the
recovery rate of platinum is 99% or above, the purity of platinum is 99.9%, the purity of palladium is 99.95%, the recovery rate of silver is 98.5% or above, and the recovery rate of gold is 99% or above.