6970results about How to "High selectivity" patented technology

Provided are compounds of Formula I:nucleosides, nucleoside phosphates and prodrugs thereof, wherein R6 is CN, ethenyl, 2-haloethen-1-yl, or (C2-C8)-alkyn-1-yl. The compounds, compositions, and methods provided are useful for the treatment of Flaviviridae virus infections.

The invention relates to the technical field of sensor detection, and discloses a detection method and device based on a multi-mode gas sensor, and the method comprises the following steps: carrying out blending processing on a metal oxide semiconductor and a conductive material to obtain a bimodal nano composite material, and creating a multi-mode gas detection module, the preprocessed multi-mode signal data is acquired and obtained; acquiring and analyzing data of the temperature sensor and the humidity sensor to obtain environmental factor compensation parameters; performing adaptive calibration processing on the preprocessed multi-modal signal data according to the environmental factor compensation parameters to obtain calibrated multi-modal signal data; constructing a multi-input neural network model based on the calibrated multi-modal signal data, and training to obtain a gas recognition model; multi-mode signals collected and calibrated in real time are analyzed and judged based on the gas recognition model, gas type and concentration information is obtained, and high-precision and high-reliability gas detection is achieved.

The invention discloses a catalyst used for preparing acrylic acid and butyl ester by the dehydration of butyl lactate and a preparation method thereof. The catalyst is a composite catalyst, comprising a main catalyst A and auxiliary catalysts B, C, D and E, wherein, A is calcium sulphate, B is sulphuric acid, C is phosphate, D is alkaline matter and E is promoter. The preparation method comprises the steps as follows: five compositions A, B, C, D and E are sufficiently mixed, baked for 2-10 hours at the temperature of 200-800DEG C and formed for standby. The catalyst has high catalytic activation; under the catalysis of the catalyst, the molar yield reaches 75.1 percent and the molar selectivity of the acrylic acid and butyl ester reaches 71.5 percent. The preparation method has the advantages that the crystal structure of the main catalyst can be improved so as to be beneficial for carrying out the reaction; and the introduction of different auxiliary catalysts and quantities is helpful to improve the conversion ratio of the raw material and the product selectivity and is beneficial for improving the strength of the catalyst.

The invention relates to the technical field of subgrade settlement prediction, in particular to a subgrade settlement prediction method based on deep learning, electronic equipment and a medium, the subgrade settlement prediction method provided by the invention adopts a subgrade settlement prediction model for prediction, and the model adopts the combination of a convolutional neural network and a bidirectional long-short term memory network. Spatio-temporal features are effectively captured, and the prediction precision and stability of the model are improved; by introducing a channel attention enhancement mechanism module, dynamic weighting is performed on different feature channels, the selection ability of the model to key features is improved, and the sensitivity of the model to subtle changes in data and the capture ability of the model to global features are enhanced; the model is trained through the genetic algorithm, the efficiency is improved, and the genetic algorithm can automatically find an optimal combination in a complex hyper-parameter space, so that the model can show good generalization ability on different roadbed settlement data sets, and the prediction precision of the model is improved.

The invention discloses an improved efficient turbulent flow microbubble flotation device for feeding and discharging materials. Comprising an outer cylinder, an inner cylinder arranged in the outer cylinder, a stirring mechanism arranged in the outer cylinder, a feeding mechanism used for conveying raw materials into the inner cylinder, a concentrate tank located on the upper portion of the outer cylinder, a countercurrent mineralization mechanism arranged in the inner cylinder and a tailing separation mechanism connected to the bottom of the inner cylinder. Through cooperation of the sawtooth disc self-suction dispersion impeller and the false bottom structure, local area circulation can be formed, the elution effect on the surfaces of coarse particles can be enhanced, meanwhile, dispersion of heterogeneous fine silt is facilitated, and the purity of tailings is further ensured; according to the method, the flotation efficiency can be improved, and the energy consumption is greatly reduced; due to the design of the sawtooth disc self-suction dispersion impeller, gas is allowed to enter in a self-suction mode, and energy consumption of traditional air compression equipment is avoided. According to the sawtooth disc self-suction dispersion impeller, suction force brought by the vacuum effect generated by rotation of the impeller can be improved, and suction of more air is promoted.

The invention provides a continuous preparation system and method of pyroxasulfone. The continuous preparation system comprises a mixing device, a continuous oxidation reaction device, a continuous quenching device, a continuous devitrification device, a continuous solid-liquid separation device and a continuous drying device. Compared with intermittent preparation of pyroxasulfone, the continuous preparation system disclosed by the invention has the advantages that the reaction can be more stable, and the reaction temperature can be more accurately controlled, so that the problems of large heat release and high process risk in batch reaction can be effectively solved. Moreover, compared with a tank reactor, the continuous oxidation reaction device filled with the catalyst bed layer can improve the oxidation reaction rate, shorten the oxidation reaction time and improve the yield and selectivity of oxidation products.

The invention discloses a p-methyl benzyl chloride production process and a production system thereof, p-xylene side chains and chlorine are subjected to a gas phase substitution reaction under micro negative pressure and visible light catalysis to generate crude methyl benzyl chloride and hydrogen chloride, and 99.0% methyl benzyl chloride, a small amount of benzyl dichloride and 31% hydrochloric acid are respectively generated through rectification and absorption; the device consists of four working sections of chlorination, rectification, hydrochloric acid absorption and distillation. According to the method, the defects in the prior art are overcome, on one hand, chlorine is introduced, and an aromatic ring chlorination reaction is carried out under visible light catalysis; on one hand, a supported catalyst filler is arranged at the bottom of a chlorination tower, and a zeolite molecular sieve modified by long-chain alkylsilane and supported by metal salt is used as a catalyst to catalyze chloromethylation reaction, on the other hand, the hydrophobicity of the modified catalyst is obviously enhanced, and meanwhile, the density of acidic sites is not reduced; the contact opportunity of the catalyst and a reaction substrate is greatly increased, and the catalytic efficiency of the catalyst is improved.

The invention discloses a city planning information display method and system based on digital twinning, and relates to the technical field of city planning. Static data and dynamic data of a city are collected, a three-dimensional model of the city is constructed through the static data, and the dynamic data and the three-dimensional model are combined to construct a digital twinning model of the city; the method comprises the following steps: setting a random data generation pool to generate random data, importing the random data into a digital twinborn model, and monitoring and optimizing a chaos current situation in the digital twinborn model to obtain an optimization scheme; by constructing a public voting platform, public opinions are imported into city planning to obtain a final optimization scheme; according to the method, the digital twinborn model of the city is constructed, more random scenes are provided for city planning by using the random data generation pool, potential changes and uncertainty of the city are fully simulated, and in combination with public opinions, the perspectiveness and flexibility of the digital twinborn technology in the city planning are improved, and a new direction is brought to the city planning.

The invention discloses an infrared image super-resolution reconstruction method based on comparative learning, and relates to the technical field of image processing. Comprising the following steps: preparing a data set; constructing a degradation pool; training a comparison encoder; constructing a network model; and training the network model. According to the technical scheme of the invention, the structure and the training mode of a comparison encoder are designed, discriminative feature representations are generated from the two dimensions of structure and degradation respectively, and the modulation infrared super-resolution network is represented to realize a specific super-resolution task according to the feature representations. The capabilities of the existing super-division network in the aspects of degradation adaptability, structural detail recovery, generated image quality and feature expression discrimination can be effectively improved, and the bottleneck of the traditional super-division network in the aspects of coping with complex degradation and insufficient detail recovery is solved; according to the method and the device, super-division of a real-world low-quality infrared image is realized, so that the quality of the infrared image is improved, and particularly, the details and the contrast ratio of the infrared image are enhanced.

The invention discloses a colorimetric and fluorescent dual-mode nano-enzyme sensor. The colorimetric and fluorescent dual-mode nano-enzyme sensor comprises nano-enzyme, hydrogen peroxide and a colorimetric probe, wherein the nano-enzyme is prepared from ZrCl4, 2-aminobiphenyl dicarboxylic acid and Cu (NO3) 2 by a one-pot method; the colorimetric probe is TMB, can oxidize colorless TMB into blue oxTMB, generates an ultraviolet absorption peak at 652 nm, and has a strong fluorescence emission peak at 405 + / -5 nm. The zirconium-based metal organic framework UiO-67-NH2 with high stability is used as a carrier, Zr < 4 + > sites are replaced by part of Cu < 2 + >, the fluorescent nano-enzyme with peroxidase activity is formed, and the problems that free enzyme is difficult to recover, the stability is low and the like are solved.

The invention relates to the technical field of chemical degradation of waste polyester, and discloses a titanium-silicon compound catalyst, a preparation method thereof and a method for depolymerizing polyethylene glycol terephthalate. The preparation method of the titanium-silicon compound catalyst comprises the following steps: (1) preparing a titanium compound, an orthosilicate compound and a solvent, and reacting with an organic acid solution to obtain a solution; and (2) carrying out post-treatment on the solution to obtain the titanium-silicon compound catalyst. The catalyst has the characteristics of high PET depolymerization rate, low polymerization degree in a depolymerization product, high purity of a depolymerization product bis (2-hydroxyethyl) terephthalate (BHET) and low titanium residue in a target product in a PET degradation reaction. The BHET obtained by the method disclosed by the invention can be directly used for preparing PET polyester products or other high-added-value products, and closed-loop cyclic utilization of PET is realized.

The invention relates to a preparation method and application of an organosilicon / MOF-303 mixed matrix membrane, a silicon source precursor is uniformly dissolved in an ethanol solvent, then a mixture of water and hydrochloric acid is added according to a certain proportion, a water bath heating reaction is carried out for a period of time to obtain an organosilicon sol, prepared MOF-303 powder is added into the organosilicon sol according to a certain proportion, and the organosilicon / MOF-303 mixed matrix membrane is obtained. The preparation method comprises the following steps: uniformly mixing the raw materials through ultrasound to obtain a separation layer sol, coating the prepared separation layer sol on a ceramic support body through a hot coating method, and calcining in an air atmosphere for a period of time to obtain the MOF-303 / mixed matrix membrane. An organic silicon substance BTESA with a rigid acetylene bridge structure is preferably selected as a precursor, an MOF-303 material with a high specific surface area is doped into the precursor, the pore channel structure of the membrane is modified, more adsorption sites are provided for water molecules, and the composite membrane material with the optimal separation performance is obtained by optimizing the composite proportion.

The invention provides an intelligent routing control method and system based on a dual-mode communication terminal and a medium. The method comprises the following steps: acquiring an ad-hoc network state flag bit of a dual-mode communication terminal, comparing the ad-hoc network state flag bit with a preset ad-hoc network state flag bit set value, if the ad-hoc network state flag bit is consistent with the preset ad-hoc network state flag bit set value, processing according to communication quality monitoring data and node load data of each communication link of an ad-hoc network to obtain a link state evaluation index, and if the link state evaluation index is consistent with the preset ad-hoc network state flag bit if the Ad hoc network state flag bits are inconsistent, channel monitoring data corresponding to all channels of the low-orbit satellite are acquired, a target channel is determined, further processing is carried out to generate flow prediction data, flow distribution is carried out on the target channel according to the flow prediction data, and service data transmission is carried out; therefore, intelligent routing control of the dual-mode communication terminal is realized.

The invention relates to a catalyst for ethylene oxide ring-opening polymerization and a preparation method thereof, and belongs to the technical field of high polymer material synthesis, and the catalyst is a composite structure based on a silicon dioxide nanoparticle loaded bimetal organic complex; a modified nitrogen-containing polydentate ligand is prepared by adopting a special method, is coordinated with metal ions through covalent bonds and is loaded on silicon dioxide nanoparticles; by utilizing the high dispersity and stability of the silicon dioxide nanoparticles and the synergistic catalytic effect of the bimetal organic complex, the catalytic effect is effectively improved, the polymerization process is accelerated, the polymerization stability is enhanced, the polymerization molecular weight is improved, and the distribution is narrow.

The invention belongs to the technical field of magnetic confinement controllable thermonuclear fusion, and particularly relates to an in-situ laser diagnosis system and method for plasma fuel thermal desorption / impurity deposition in a wall material. The long-pulse laser module emits a long-pulse laser beam, and the long-pulse laser beam sequentially passes through the dichroscope I, the convex lens, the dichroscope II and quartz glass on the vacuum chamber and is irradiated to the surface of the sample to be detected; the short-pulse laser module emits a short-pulse laser beam, and the short-pulse laser beam sequentially passes through the dichroscope I, the convex lens, the dichroscope II and quartz glass on the vacuum chamber of the fusion device and is irradiated to the surface of the sample to be detected; the irradiated radiation light of the to-be-detected sample sequentially passes through the focusing lens, and a spectral signal is transmitted to the spectrum acquisition system. According to the system, high-efficiency in-situ laser thermal desorption can be carried out on fuel gas retained in a wall material, in-situ laser diagnosis of impurity deposition can also be carried out, the two methods are flexibly coupled into one set of system and can be independently used or simultaneously carried out, and a reference basis is provided for fusion reactor divertor operation control and wall material research and development in the future.

The invention provides lithium sulfide as well as a preparation method and application thereof. The preparation method of the lithium sulfide comprises the following steps: providing a mixed solution containing a lithium-containing compound and liquid sulfur which are uniformly mixed, and enabling the mixed solution to be in contact with a reducing gas so as to carry out a lithium sulfide synthesis reaction, after the synthesis reaction of the lithium sulfide is finished, at least removing part of sulfur in the obtained reaction mixture to obtain a crude finished product; and calcining the crude finished product to convert lithium polysulfide in the crude finished product into lithium sulfide to obtain a lithium sulfide product. According to the preparation method provided by the invention, the high-purity lithium sulfide is prepared by a one-pot method, the liquid sulfur is used as a reaction raw material and a reaction solvent, and the whole reaction process does not need to use an organic solvent; according to the method, the lithium salt conversion rate can reach 99% or above, and the purity of the obtained lithium sulfide can reach 99.99% or above; compared with the prior art, the reaction temperature is lower, and low energy consumption and high conversion rate are both considered.

The invention provides a knowledge graph completion method, and aims to improve the accuracy and effectiveness of knowledge graph completion. The method comprises the following steps: firstly, obtaining and expanding triple data of a knowledge graph, and supplementing a data set by generating an inverse triple; in combination with various negative sample generation technologies, the recognition capability of the model on error links is improved, and text embedding learning is performed on entities and relationships in a triple by using a double-text encoder. A deformable adaptive attention module is provided, and potential feature capture is carried out on text features. And calculating a cosine similarity score of text embedding and adding a path reasoning gain score to obtain a triple similarity score. And text embedding is optimized by comparing and estimating a loss function by using information noise with margin, so that the complementation effect is effectively improved. And finally, completing the model by using the trained knowledge graph, and completing triple maximum similarity matching. According to the method, complex semantic association can be captured, and the accuracy and robustness of knowledge graph completion are enhanced.

The invention discloses a preparation method of a reverse osmosis membrane and the reverse osmosis membrane. The preparation method comprises the following steps: (1) adding polyethersulfone into N, N-dimethylacetamide in a heating and stirring state, and stirring for a period of time after charging is completed, so as to obtain a mixed solution; (2) cooling the mixed solution, continuing to add a pore-foaming agent, and stirring for a period of time after charging is completed to obtain a precursor solution; (3) performing vacuum defoaming treatment on the precursor solution to obtain a membrane casting solution; (4) loading the membrane casting solution on a carrier, and then carrying out gel bath treatment to obtain a base membrane; and (5) performing polyamide treatment on the surface of the base membrane to obtain the reverse osmosis membrane. The preparation method disclosed by the invention is simple in process and low in material cost, and the obtained reverse osmosis membrane has more uniform and more through-type pore structures, higher separation efficiency, more excellent chemical stability and better mechanical properties, can adapt to higher operation pressure, and can continuously and stably operate at higher flux under high pressure.

The invention discloses industrial-grade mixed oil produced by utilizing kitchen waste oil and a preparation method of the industrial-grade mixed oil, and belongs to the technical field of recycling of the kitchen waste oil. The invention relates to industrial-grade mixed oil produced by using kitchen waste oil and a preparation method thereof, and the preparation method comprises the following steps: firstly collecting kitchen waste containing the waste oil, and storing the kitchen waste in a container through special equipment; carrying out screen solid-liquid separation, cleaning grease on the surface of the solid waste, and then carrying out precipitation separation; then carrying out centrifugal separation, chemical cleaning, water washing, acid treatment, dehydration, degumming and metal ion removal on the separated grease and oil-containing liquid; carrying out ultrasonic-assisted multistage ester exchange after enzymolysis optimization, carrying out membrane separation on glycerol and fatty acid methyl ester, and carrying out reduced pressure distillation to obtain a high-purity fraction; carrying out adsorption refining, plasma treatment and supercritical fluid extraction; finally, nano particles are added and blended with additives, efficient recycling of the kitchen waste oil is achieved, and then high-purity industrial-grade mixed oil is prepared.

The invention discloses a seed layer induced FeCoNiCuMo high-entropy alloy nanocage electrocatalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing and reacting iron, cobalt and nickel precursors to prepare a FeCoNi nanocage catalyst as a seed layer; adding copper salt and molybdate into the seed layer solution, carrying out ultrasonic mixing, adding a pH regulator and a reducing agent, carrying out ultrasonic treatment, putting the mixed solution into liquid nitrogen, cooling, carrying out primary nucleation, naturally unfreezing, standing for nucleation, cleaning, and freeze-drying to obtain the high-entropy alloy nanocage electrocatalyst. The catalyst is used for preparing urea through CO2 and NO3 <-> electro-catalysis, can effectively adjust the matching of CO2 and NO3 <-> reaction kinetics, and has extremely high Faraday efficiency and yield for synthesizing urea through C-N coupling.

The invention relates to an isoterpinene 4, 8-epoxide synthesis method, which comprises: blending an isoterpinene raw material, a catalyst, a catalyst auxiliary agent and a solvent, stirring to form a mixture solution, carrying out a mixing reaction on the mixture solution and an oxidizing agent in a reactor, purifying, and drying to obtain the isoterpinene 4, 8-epoxide. And 2, 8-epoxide. According to the synthesis method of the isoterpinene 4, 8-epoxide, an adopted reaction system is moderate in oxidability and mild in reaction condition, double bonds at the fourth position can be directionally oxidized, high oxidation selectivity is achieved, and finally the highest selectivity of the isoterpinene 4, 8-epoxide can reach 95% or above; meanwhile, the method overcomes the defect that the existence of water in a catalytic system in the prior art easily causes ring-opening hydrolysis of epoxidation reaction, accelerates the epoxidation reaction process, shortens the reaction time, and increases the yield of the product, and the highest yield can reach 88% or above.

The invention discloses a carbon dioxide adsorbent and a preparation method and application thereof.The preparation method comprises the following steps that a biological shell material is cleaned and then dried, the pretreated biological shell material is ground, and coarse shell powder is obtained; sequentially calcining and grinding the coarse shell powder in a protective atmosphere to obtain shell micro powder; mixing the shell micro powder with a magnesium oxide solid phase, calcining in a protective atmosphere, and grinding to obtain the carbon dioxide adsorbent. According to the invention, a solid-phase mixing method is adopted, and the marine biological waste with specific content and magnesium oxide are mixed, so that the mutual cooperation and mutual synergism among the raw material components can be fully exerted, the element composition and microstructure of the adsorbent material can be effectively regulated and controlled, and by virtue of the preparation method which is easy to operate and low in cost, the adsorbent material can be prepared. The obtained novel carbon dioxide adsorbent can improve the CO2 adsorption capacity and cycle stability of MgO, and can stably maintain high carbon dioxide adsorption rate and adsorption capacity for a long time.

The invention discloses a preparation method and application of a ternary multifunctional three-dimensional framework mediated high ammonia nitrogen selectivity polyamide reverse osmosis membrane, and belongs to the technical field of membrane separation. The method comprises the following steps: 1, preparing a high-molecular copolymer; 2, preparing a polysulfone support layer by adopting a non-solvent induced phase inversion method; 3, preparing a polyamide reverse osmosis membrane by adopting an interfacial polymerization method; and 4, preparing the polyamide reverse osmosis membrane with high ammonia nitrogen selectivity. Through reasonable design of the structure and distribution of the group of the ternary multifunctional three-dimensional structure high-molecular copolymer, the copolymer can react with the acyl chloride group on the surface of the polyamide active layer to form a covalent amido bond, and the covalent amido bond is anchored on the surface of the polyamide layer in situ to construct the functional layer. The functional layer not only can significantly improve the surface potential of the membrane, but also can increase the inherent concentration of ammonia nitrogen on the surface of the membrane, thereby increasing the diffusion resistance, finally realizing the repulsive force to the ammonia nitrogen, and improving the interception capability of the grafted membrane to the ammonia nitrogen. The operation process is simple and mild, the whole membrane preparation process is not changed, and industrialization is easy.

The invention relates to the technical field of all-vanadium redox flow batteries, in particular to a sulfonated polybenzimidazole proton exchange membrane as well as a preparation method and application thereof. The proton exchange membrane structurally comprises a polybenzimidazole polymer main chain and a sulfonic acid group, the free volume of the polybenzimidazole polymer is regulated and controlled by synthesizing raw materials with different structures, and the polybenzimidazole proton exchange membrane is obtained by sulfonating the polybenzimidazole polymer. Aiming at the problems of cross permeation of vanadium ion electrolyte of a positive electrode and a negative electrode of the all-vanadium redox flow battery, capacity attenuation of the all-vanadium redox flow battery and low energy conversion efficiency, the preparation method comprises the following steps: constructing a polybenzimidazole polymer main chain by selecting raw materials with high rigidity and high free volume; the mechanical property of the polybenzimidazole membrane is improved while a rapid ion channel is constructed in the polymer membrane, and water molecules can be contained to limit swelling of a membrane material.

The invention discloses a conformal antenna component manufacturing system and method based on cross-scale space-time frequency shaping femtosecond laser, and belongs to the technical field of micro-nano machining. The system comprises an ultrafast laser excitation module, a laser pulse time / frequency shaping module, a pulse detection module, an online monitoring module and a focusing high-speed scanning galvanometer module. By means of the system, high-selectivity, large-breadth and three-dimensional precision machining of conformal antenna circuit patterns is achieved, and it is ensured that a substrate is not damaged. The femtosecond laser time-frequency shaping technology is combined in the machining process, layered scanning and accurate removal of the heterogeneous multilayer structure are achieved through an adjustable pulse sequence and a high-speed galvanometer system, and the problems that in the prior art, materials are damaged, and the size precision is low are solved. The device further integrates an on-line depth monitoring function, the machining efficiency and the forming quality are remarkably improved, and the device is suitable for high-precision patterning machining of complex curved surface heterogeneous thin film materials.

The invention relates to the technical field of chemical degradation of waste polyester, and discloses a titanium-rare earth compound catalyst which comprises a titanium-containing compound and a rare earth catalyst, wherein the titanium-containing compound is selected from at least one of dihydric alcohol modified alkyl titanate, alkyl titanate, dihydric alcohol titanium, titanium phosphate and organic-inorganic hybrid titanium; wherein the rare earth catalyst is selected from acetylacetone rare earth catalysts. The titanium-rare earth compound catalyst has the characteristics of high PET depolymerization rate, low polymerization degree in a depolymerization product, small catalyst dosage, high catalyst selectivity and high yield and purity of a depolymerization product bis (2-hydroxyethyl) terephthalate (BHET) in a degradation reaction of polyethylene glycol terephthalate (PET). The BHET obtained by the method disclosed by the invention can be directly used for preparing PET polyester products or other high-added-value products, and closed-loop cyclic utilization of PET is realized.

The invention belongs to the technical field of ethylene oligomerization catalysis, and discloses a catalytic system for ethylene selective oligomerization and a preparation method and application thereof, and the catalytic system comprises a carbon bridge bidentate phosphine chromium catalyst, an organic boron auxiliary agent and an aluminum-containing activator in a molar ratio of 1: (1-50): (100-1500). The carbon-chromium catalyst is prepared by the following steps: reacting CrCl3 (THF) 3, a ligand and CH2Cl2 under stirring, filtering, and carrying out post-treatment to obtain the catalyst, the catalyst and the aluminum-containing activating agent are uniformly mixed, and then the organic boron auxiliary agent is added and stirred. The catalyst system constructed by the carbon bridge bidentate phosphine chromium catalyst, the organic boron auxiliary agent and the aluminum-containing activating agent realizes ethylene selective oligomerization. The catalytic system can realize high-efficiency and high-selectivity preparation of 1-hexene and 1-octene under the condition that aluminoxane co-catalysts such as MAO and MMAO are not adopted, the catalytic activity is high, the reaction initiation is rapid, the operation is stable, and the repeatability is good.

The invention discloses a method for simultaneously detecting ergothioneine, ergosterol, ergosterol peroxide and lentinine in lentinus edodes, and belongs to the technical field of measurement of active ingredients of the lentinus edodes. The method comprises the following steps: detecting a shiitake mushroom extracting solution by adopting an ultra-high performance liquid chromatography-tandem mass spectrometry mode, wherein a chromatographic column is an HILIC or C18 chromatographic column; the mobile phase A and the mobile phase B are an aqueous solution containing formic acid and a methanol or acetonitrile solution containing formic acid respectively; the mass spectrum conditions comprise an electrospray ionization source; a positive ion multiple reaction monitoring mode; the ion spraying temperature is 315-325 DEG C; the temperature of the ion transmission tube is 320-330 DEG C; and the ion spraying voltage is 3500 V to 3700 V. The method has the characteristics of high sensitivity, high selectivity and high accuracy, and is suitable for quantitative detection of ergothioneine, lentinine, ergosterol peroxide and ergosterol compounds in shiitake mushrooms.

The invention discloses a synthesis method and application of a Cu / Ni and Cu / Zn bimetallic conductive MOF-based catalyst for enhancing reduction of nitrate into ammonia, and relates to MOF catalyst preparation, and the synthesis method is characterized by comprising the following steps: S1, dissolving cupric acetate monohydrate and nickel acetate tetrahydrate or zinc acetate dihydrate in ultrapure water to prepare a solution A; s2, dissolving 2, 3, 6, 7, 10, 11-hexahydroxy tribenzene and ammonia water into N, N-dimethylformamide (DMF), so as to obtain a solution B; s3, mixing the solution A and the solution B, and performing ultrasonic treatment for 10-30 minutes to prepare a solution C; and S4, heating the solution C in an isothermal oven at 85 DEG C for 1-3 hours, naturally cooling to room temperature, respectively washing with deionized water and acetone for 6 times, and finally drying in a vacuum oven at 60 DEG C to obtain a dark blue crystal. The Cu / Zn and Cu / Ni bimetallic conductive MOF prepared by the method has high specific surface area, and the prepared electrode has high responsivity to nitrate ions, has a remarkable nitrate removal effect, has high removal efficiency and has high ammonia selectivity.

The invention relates to a method for preparing methanol based on carbon dioxide capture, and a method for preparing ethylene glycol and environment-friendly polyester. The method comprises the following steps: capturing and purifying a byproduct high-concentration carbon dioxide gas flow in a petroleum refining process into high-purity carbon dioxide, and sequentially carrying out hydrogenation reaction and preparation of green methanol in three stages of fixed bed reactors, a copper-zinc-calcium-magnesium-aluminum hydrogenation catalyst is adopted in the first-stage reactor and the third-stage reactor, and the copper-zinc-calcium-magnesium-aluminum hydrogenation catalyst is adopted in the second-stage reactor and the third-stage reactor. And a copper-zirconium-titanium-vanadium deposition type hydrogenation catalyst is adopted in the second-stage reactor. The green ethylene glycol can be prepared from the green methanol through an MTO process, ethylene oxidation and ethylene oxide hydrolysis. The environment-friendly carbon-reducing polyester can be prepared from the green ethylene glycol and terephthalic acid PTA through slurry preparation, esterification reaction and polymerization reaction; in the esterification and polymerization process, by adding a specific esterification catalyst and a compound stabilizer, the performance of the environment-friendly carbon-reducing polyester can be improved, and the performance of the environment-friendly carbon-reducing polyester is equivalent to that of a polyester product corresponding to petrochemical method ethylene glycol.