38 results about "Nitrogen trifluoride" patented technology

The invention relates to a preparation method of antimony pentafluoride, which comprises the following steps: preheating raw material gas nitrogen trifluoride, placing nitrogen trifluoride and antimony powder in a tubular furnace reactor made of a specific material, carrying out gradient heating reaction at 300-400 DEG C under the condition that the antimony powder is distributed by adopting a multi-layer nickel plate tiled structure, carrying out reaction for 10-40 seconds, and carrying out solid filtration through a filter after the reaction is completed, so as to obtain the antimony pentafluoride. And carrying out cold trap collection to obtain an antimony pentafluoride product. The diameter of the reactor is made of a nickel material or Monel to prevent corrosion of antimony pentafluoride, the number of tiled layers of nickel plates is r / 5-r / 10, the contact area is increased, the reaction yield is increased, and the utilization rate of the raw material nitrogen trifluoride is increased.

The invention provides a process for purifying nickel from electrolytic waste for preparing nitrogen trifluoride, which comprises the following steps: after a nitrogen trifluoride electrolytic cell stops electrolysis, transferring the electrolytic waste into a first batching kettle, adding anhydrous hydrogen fluoride, dissolving ammonium bifluoride mixed in the electrolytic waste into a molten state, and adding a second batching kettle; then solid-liquid separation is achieved in a centrifugal mode, and the liquid part is molten liquid to be reused as electrolyte; ammonia water is added into a second batching kettle to adjust the pH value, solid-liquid separation is achieved in a centrifugal mode, the liquid part is transferred into an intermediate tank, potassium hydroxide is added to continue to adjust the pH value, nickel in the solution is precipitated out, ammonia escapes and is prepared into dilute ammonia water in a falling film absorption mode, and the dilute ammonia water can return to a system to be reused; the solid part directly enters a smelting furnace, the temperature is gradually increased until nickel is smelted into a liquid state, then cooling is conducted, and the nickel purity can reach 99% or above. According to the method, the nickel in the electrolytic waste mixed with the sediments in the nitrogen trifluoride electrolytic cell is purified, and appreciation is achieved.

The application belongs to the field of chemical purification, and discloses a method for separating carbon tetrafluoride in nitrogen trifluoride by using a eutectic solvent under pressure and an equipment thereof, which comprises the following steps: (1) increasing the pressure of crude nitrogen trifluoride gas to more than 0.5 MPa; (2) cooling the temperature of the crude gas to below 40 DEG C through a crude gas feeding heat exchanger; (3) reducing the content of carbon tetrafluoride in the crude gas to below 5 ppm by countercurrent contact between the crude gas entering the tower kettle and the eutectic solvent entering the top of the absorption tower through the absorption tower; (4) reducing the content of carbon tetrafluoride in the eutectic solvent to below 1 ppm through two-stage flash tanks; and (5) reducing the temperature of the eutectic solvent to below 30 DEG C through a eutectic solvent discharging heat exchanger and a eutectic solvent cooler, and circulating the eutectic solvent from the bottom of the absorption tower back to the absorption tower. The method can improve the quality of the nitrogen trifluoride product, and the content of carbon tetrafluoride impurities in the nitrogen trifluoride product can be reduced to 5 ppm, and the cost is low.

Provided is a plasma processing method capable of achieving flat etching process while suppressing vertical etching.The plasma processing method for plasma-etching a titanium nitride (TiN) film that forms a metal gate and contacts an insulating film on both sides includes the step of etching the titanium nitride (TiN) film by using plasmas that are generated by using a mixed gas of boron trichloride (BCl3) gas, nitrogen (N2) gas, and nitrogen trifluoride (NF3) gas and are generated by radio-frequency power modulated by a pulse, wherein the pulse has a first period with a first amplitude as its amplitude and a second period with a second amplitude as its amplitude and wherein the second amplitude is greater than 0 and less than the first amplitude.

The invention discloses a production method of high-purity fluorine-nitrogen mixed gas, and belongs to the technical field of fluorine chemical industry. The method comprises the following steps: mixing high-purity nitrogen trifluoride and high-purity nitrogen according to a molar ratio of 1: (5.5-10), introducing the mixture into a cracker, reacting at the reaction temperature of 1000-1250 DEG C under the pressure of 0.2-0.7 Mpa until the pressure is not changed any more, cooling the reacted gas through a condenser, introducing the cooled gas into a buffer tank 1, compressing the cooled gas through a compressor, introducing the compressed gas into a de-heavy rectifying tower to remove heavy component impurities, and recovering the heavy component impurities to obtain the high-purity nitrogen trifluoride. And gas extracted from the top of the rectifying tower is introduced into the buffer tank 2, compressed by the compressor and then filled into a steel cylinder. The nitrogen is introduced into the cracking reaction, so that the safety of the reaction can be ensured, meanwhile, the production links of purifying fluorine gas and removing nitrogen impurities after the nitrogen trifluoride is cracked are reduced, the fluorine-nitrogen mixed gas with the preset concentration can be directly produced, the production cost is reduced, the production links are reduced, and the 20% fluorine-nitrogen mixed gas can be directly prepared.

The invention provides a catalyst for nitrogen trifluoride decomposition and a preparation method thereof, and a decomposer, the catalyst comprises a bearing table and a catalyst layer; the bearing table is of a porous structure; the catalyst layer comprises a carrier and an active component, the active component is loaded on the carrier to form catalyst particles with the particle size being smaller than 100 nm, and the surface of the porous structure is coated with the catalyst particles to form the catalyst layer; wherein the carrier is doped with a transition metal oxide or a rare earth metal oxide; and the active component is a noble metal bimetallic composite material. According to the catalytic layer provided by the invention, the hydrogen fluoride corrosion resistance of the carrier is improved by adopting the transition metal oxide or the rare earth metal oxide, and the decomposition rate of nitrogen trifluoride on the surface of the catalytic layer is promoted and the reaction temperature of complete decomposition of nitrogen trifluoride is reduced by utilizing the effect of a noble metal bimetallic composite material, so that the catalytic activity is ensured.

There is provided a method for producing trifluoroamine oxide. The method includes a step of preparing an intermediate product by simultaneously providing and reacting nitrogen trifluoride and nitrous oxide under the presence of a SbF5 reaction activator; and a step of producing trifluoroamine oxide by reacting the intermediate product with potassium fluoride. The step of reacting the intermediate product with potassium fluoride is performed under atmospheric pressure and room temperature.

The application discloses a production method of high-purity fluorine-nitrogen mixed gas and belongs to the technical field of fluorine chemical industry. The method is characterized by mixing high-purity nitrogen trifluoride and high-purity nitrogen gas according to a 1:5.5-10 molar ratio, introducing the mixture into a cracking device, setting the reaction temperature to 1000-1250 DEG C, setting the pressure to 0.2-0.7 Mpa, reacting until the pressure does not change any more, cooling the reacted gas by a condenser and introducing the gas into a buffer tank 1, compressing the gas by a compressor, removing heavy component impurities in a heavy-removing rectifying tower, introducing the gas collected from the top of the rectifying tower into a buffer tank 2, compressing the gas by a compressor and filling the gas into a steel cylinder. The method can ensure the safety of the reaction, reduce the production steps of fluorine gas purification and nitrogen impurity removal after cracking of the nitrogen trifluoride, directly produce fluorine-nitrogen mixed gas with a predetermined concentration, reduce the production cost, reduce the production steps and directly prepare 20% fluorine-nitrogen mixed gas.

The utility model relates to the field of high-purity gas recycling, in particular to a reusable high-purity helium recovery device. Comprising a pneumatic diaphragm valve, a filter, a recovery tank, a one-way reciprocating pump and a helium tank which are arranged along the flow direction of high-purity helium, the pneumatic diaphragm valve is used for controlling the pressure of the recovery tank; the filter is used for filtering solid particles in high-purity helium; the recovery tank is used for recovering high-purity helium, and the one-way reciprocating pump is used for compressing and pressurizing the high-purity helium in the recovery tank and filling the high-purity helium into a helium bottle. According to the nitrogen trifluoride production pipeline recycling device, the recycling device capable of recycling the high-purity helium is connected in the nitrogen trifluoride production pipeline, waste of the high-purity helium is reduced through repeated use, the production cost requirement can be lowered, the cleanliness of the production pipeline can be guaranteed through the recycled high-purity helium, and the production quality is improved.

The invention provides a lithium battery electrolyte as well as a preparation method and application thereof. The lithium battery electrolyte is prepared from the following raw materials: thionyl chloride, lithium tetrachloroaluminate, sulfur dioxide and nitrogen trifluoride. Nitrogen trifluoride is added into the electrolyte, the nitrogen trifluoride reacts with a metal lithium negative electrode to generate a lithium fluoride enriched solid electrolyte interface with high ionic conductivity on the surface of the electrode in situ, so that the lithium ion transmission efficiency is remarkably improved, and the voltage hysteresis phenomenon is effectively improved. The preparation method is simple in process and remarkable in effect, and a new solution is provided for development of high-performance lithium thionyl chloride batteries.

The utility model discloses an energy-saving efficient evaporation system for nitrogen trifluoride production sewage. The energy-saving efficient evaporation system comprises a potassium fluoride waste liquid treatment unit, a sodium sulfate waste liquid treatment unit, a calcium chloride waste liquid treatment unit, a salt-rich water waste liquid treatment unit, a crystal evaporation separation unit, a crystal collection unit and a backwashing unit. The system disclosed by the utility model is used for separately treating four kinds of sewage, namely potassium fluoride waste liquid, sodium sulfate waste liquid, calcium chloride waste liquid and salt-rich water waste liquid generated in a nitrogen trifluoride production process to obtain multiple crystal products with single components, so that hazardous wastes and solid wastes are separately recycled, and the quantity of hazardous waste products and the treatment cost are reduced; one set of evaporation system is shared for intermittent treatment, so that the product production cost is reduced, the energy is saved, the consumption is reduced, the equipment production allowance is reasonably used, and the equipment utilization rate is improved.

An apparatus includes a body configured to support a substrate, a first coating, conformal on a surface of the body, that is corrosion resistant to at least one of: boron trichloride, nitrogen trifluoride, hafnium tetrachloride, aluminum trichloride, oxygen gas, chlorine gas, fluorine gas, chlorine trifluoride, hydrogen fluoride, hydrogen gas, ammonia, tungsten hexafluoride, tetrafluoromethane, titanium tetrachloride, molybdenum pentachloride, ozone, tetrafluorosilane, or hexafluoroethane, and a second coating, on the first coating, having a hardness that greater than or equal to about 8 gigapascals.

The invention relates to a method and a device for purifying crude nitrogen trifluoride gas, and belongs to the technical field of nitrogen trifluoride gas purification, and the method comprises the following steps: sequentially carrying out preheating, cracking, hydrogen fluoride washing, reduction, alkali washing, water ring pressurization, water removal and secondary rectification on nitrogen trifluoride electrolytic gas prepared by adopting an electrolytic method. According to the method, the high-purity nitrogen trifluoride gas with the purity of 99.995 vol% or above can be obtained, and the method is safe to operate, low in cooling medium consumption and low in energy consumption; the device comprises a preheater, a cracking tower, a buffer tank, a hydrogen fluoride washing tower, a reduction tower, an alkaline washing tower, a water ring compressor, water removal equipment, a rectification system and a filling system, and the method and the device are simple in structure, high in operation safety, strong in operability, low in operation cost, suitable for large-scale production and wide in application prospect.

The application discloses a method for adsorbing and purifying nitrogen trifluoride gas and relates to the technical field of nitrogen trifluoride adsorption and purification. The method comprises the following steps: uniformly mixing 3A molecular sieve, a modifier and anhydrous ethanol, and performing a temperature rising reaction to obtain an adsorbent; the adsorbent is filled into an adsorption device, activated under a nitrogen atmosphere, and then cooled to room temperature; crude nitrogen trifluoride is subjected to adsorption in the adsorption device filled with the adsorbent under the conditions that the temperature is-25-10 DEG C, the pressure is 0.1-0.5 MPa, and the flow rate is 0.25-0.70 m 3 / h, and nitrogen trifluoride from which HF is removed is obtained. The method can effectively reduce the acidity of HF, and the adsorbent used has excellent compressive strength.

This invention relates to a method for preparing manganese trifluoride catalyst and its application, belonging to the field of chemical technology. The method includes the following steps: S1, adding manganese powder to a reactor and preheating the reactor; S2, adding nitrogen trifluoride to the reactor and maintaining the reactor temperature until the reaction is complete; S3, the manganese powder and nitrogen trifluoride react to generate manganese trifluoride and nitrogen gas. After the reaction is complete, excess fluorine gas and the nitrogen gas produced in the reaction are removed for tail gas treatment, and the product manganese trifluoride is collected; S4, the prepared manganese trifluoride is added to an octafluoropropane synthesis reactor for use as a catalyst. This invention utilizes the decomposition of nitrogen trifluoride at a certain temperature to generate free fluoride ions, which react completely with manganese powder to generate manganese trifluoride. The reaction process is stable and can achieve continuous industrial production. The conversion rate of octafluoropropane synthesis can be effectively improved through the catalysis of manganese trifluoride.

The invention particularly relates to a nitrogen trifluoride raw material electrolyte preparation device and method.The device comprises an HF storage tank, an ammonia conveying unit, an electrolyte preparation unit and an electrolyte storage tank, the HF storage tank and the ammonia conveying unit communicate with the electrolyte preparation unit through pipelines, and the electrolyte preparation unit communicates with the electrolyte storage unit through a pipeline; the ammonia gas conveying unit comprises a liquid ammonia storage tank, a liquid ammonia conveying pump, an ammonia vaporizer and an adsorption tower which are sequentially communicated along the material flow direction; and the electrolyte preparation unit comprises a mixing reaction kettle and an electrolyte heat exchanger. According to the method, liquid hydrogen fluoride and liquid ammonia are pumped from a storage tank to a mixing reaction kettle, hydrogen fluoride reacts with ammonia gas to generate a molten electrolyte of NH4HF2 and HF, the electrolyte is conveyed through a circulating pump after the reaction, one part of the electrolyte is stored in an electrolyte storage tank, and the other part of the electrolyte is cooled by a heat exchanger and then returns to the reaction kettle to maintain the temperature stable. The method has the advantages of energy conservation, high product purity, high yield and the like.

1. The name of the design product: remote plasma source cavity (45L). 2. The use of the design product: used for dissociating nitrogen trifluoride gas into fluoride ion pairs for chamber cleaning, surface treatment, material modification, film deposition and other processes in a vacuum environment. 3. The design points of the design product: in shape. 4. The picture or photo that best shows the design points: perspective view.

The invention discloses a cathode structure for preparing nitrogen trifluoride gas, which comprises a conductive shell, two tubular conductive binding posts fixedly arranged outside the shell at an interval and a heat exchange tube arranged in the shell, the two binding posts are both electrically connected with the shell, two ports of the heat exchange tube are respectively and fixedly communicated with the two binding posts, and the heat exchange tube is arranged in the shell. An insulated heat exchange medium circulates in the heat exchange tube, and the heat exchange medium flows in from one binding post and flows out from the other binding post to heat or cool the electrolyte, so that the heat exchange tube does not need to be independently arranged in the electrolyte. Due to the fact that the heat exchange tube does not make contact with the electrolyte, the heat exchange tube is not corroded by the electrolyte, the risk that the heat exchange tube leaks is avoided, and the situation that the heat-conducting medium leaks from the heat exchange tube and enters the electrolyte, and then normal electrolysis operation is affected is avoided.

The application discloses a production device for preparing nitrogen trifluoride gas by long-term continuous electrolysis, which comprises a raw material tank, a first pump body, an electrolytic tank, a sedimentation tank, a second pump body, a filter and a collection tank which are sequentially connected through pipelines, and a third pump body is further connected with the top of the raw material tank; the electrolytic tank comprises a tank body, a cathode cover is installed on the upper end of the tank body, an anode cover is installed in the middle of the cathode cover, and the anode cover and the cathode cover are in sealing connection; a gas outlet pipe is arranged at one end of the anode cover, an anode inert gas inlet is arranged at the other end of the anode cover, a cathode gas outlet and a cathode inert gas inlet are arranged through the cathode cover. The application utilizes electrolyte circulation to achieve self-purification effect, solves the problem that electrolysis is terminated due to deposition of electrolytic solid waste in traditional electrolytic tanks, and can directly replace the anode to solve the problem that electrolysis is terminated due to expiration of the anode in traditional electrolytic tanks.

The invention relates to the technical field of chemical engineering, in particular to a gas-liquid phase HF comprehensive recovery system in nitrogen trifluoride preparation through electrolysis, which comprises a buffer tower, the buffer tower is provided with a buffer tower liquid inlet and a buffer tower liquid outlet, the buffer tower liquid inlet is connected with a cold trap liquid phase pollution discharge outlet and a cooler pollution discharge outlet, and the buffer tower liquid outlet is connected with a cold trap liquid phase pollution discharge outlet and a cooler pollution discharge outlet. A liquid outlet of the buffer tower is communicated with a first-stage acid tank, the first-stage acid tank is communicated with a first-stage spray absorber, the first-stage acid tank is further communicated with a finished product acid tank, the first-stage spray absorber is communicated with a second-stage spray absorber, the bottom of the second-stage spray absorber is communicated with a second-stage acid tank, and the upper part of the second-stage spray absorber is communicated with a waste gas treatment device; and the first-stage spray absorber and / or the second-stage spray absorber are / is communicated with cold trap vacuum tail gas. The invention further relates to a comprehensive recovery method for gas-phase and liquid-phase HF in nitrogen trifluoride prepared through electrolysis. The comprehensive recovery method comprises the comprehensive recovery method for the gas-phase HF and the comprehensive recovery method for the liquid-phase HF. Waste utilization is achieved, and the cost is reduced.

The utility model belongs to a device for synthesizing and purifying high-purity antimony pentafluoride. Comprising a raw material adding unit, the raw material adding unit is connected with a high-purity antimony pentafluoride purification unit through an antimony pentafluoride synthesis unit, and the high-purity antimony pentafluoride purification unit is connected with a high-purity antimony pentafluoride filling steel cylinder; the raw material adding unit comprises a nitrogen trifluoride steel cylinder for storing nitrogen trifluoride and a storage tank for storing metal antimony powder; the method has the advantages that equipment investment and personnel operation skill requirements can be reduced, life safety of field personnel is guaranteed, combustion-supporting gas is not generated in the reaction process of nitrogen trifluoride and metal antimony, the reaction is mild, and the method has the advantages of being high in safety and not prone to generating explosion risks.

The application belongs to the technical field of electrolytic equipment and electrolytic process, and particularly relates to an electrolytic equipment and process method for producing nitrogen trifluoride gas. The electrolytic equipment for producing nitrogen trifluoride gas comprises an electrolytic tank body, which is divided into a cathode chamber and an anode chamber by a baffle; a cathode plate is arranged in the electrolytic tank body; a cathode connecting post, an anode gas outlet and a cathode gas outlet are arranged on the electrolytic tank body; a cathode rod is connected to the cathode connecting post; an anode connecting post is arranged on the electrolytic tank body and connected to an anode plate; the cathode plate comprises blades arranged in a 'wiFi' signal shape from bottom to top; the blades are arc-shaped; and the blades are provided with cathode plate air holes. The electrolytic equipment for producing nitrogen trifluoride gas provided by the application replaces the traditional plate-shaped and louver-shaped cathode plate with a wiFi-shaped cathode plate, increases the effective use area of the electrode, improves the electronic conversion efficiency and reduces the production cost.

The application relates to the technical field of material preparation, and particularly relates to a method for preparing fluorobenzene through photocatalytic fluorination based on nitrogen trifluoride. The method for preparing fluorobenzene through photocatalytic fluorination based on nitrogen trifluoride provided by the application adds pretreated benzoyl chloride into a closed pressure-resistant quartz photo-reactor, replaces the air in the reactor with high-purity argon to form an oxygen-free inert atmosphere, adds pretreated nitrogen trifluoride into the reactor, and stirs the reaction under the conditions that the temperature is 60-150 DEG C, the pressure is 0.1-0.4 MPa, and the molar ratio of benzoyl chloride to nitrogen trifluoride is 1:0.5-6; a UV light source module is started, and the reaction system is irradiated with UV light with a wavelength of 200-300 nm to perform photocatalytic reaction, so that fluorobenzene is obtained, one-step efficient synthesis of fluorobenzene is realized, traditional high-toxicity fluorine sources are replaced by nitrogen trifluoride, the safety is high, the reaction conditions are mild, the process steps are simplified, the product has high purity and good yield, the amount of waste is small, and the product is easy to be industrially produced.

The invention belongs to the technical field of fluorine-containing fine chemical synthesis, and particularly relates to a method and device for preparing octafluoropropane through plasma cracking. The method comprises the following steps: S1, introducing nitrogen trifluoride and hexafluoropropylene into a reactor according to a flow ratio of (0.2-3.2): 1, after electrifying, cracking the nitrogen trifluoride, and reacting with the hexafluoropropylene to generate reaction products octafluoropropane and nitrogen; and S2, condensing and separating the reaction product octafluoropropane from nitrogen, and finally collecting the octafluoropropane in a liquid form. The device comprises a plasma reactor, a cold trap and an octafluoropropane storage tank which are arranged in the material flow direction, the cold trap is further communicated with a vacuum pump, and a hexafluoropropylene gas inlet is formed in the plasma reactor. According to the method, hexafluoropropylene and NF3 directly react, NF3 is cracked into free fluorine ions in a plasma reactor, and the free fluorine ions and hexafluoropropylene react to generate octafluoropropane. The reaction process is mild, and continuous production can be realized.

The invention belongs to the technical field of positive electrode materials, and relates to a high-air-stability ternary positive electrode material based on a two-step plasma technology and a preparation method and application thereof. The ternary positive electrode material and a zirconium source are sintered in an oxygen plasma atmosphere under a normal pressure condition, efficient and uniform doping of Zr elements into material bulk phase crystal lattices is promoted, the crystallization process of the material is synchronously completed, and bulk phase strengthening of the crystal lattice structure is achieved. Then, the obtained Zr-doped ternary material is placed in a vacuum environment, fluorine source gas such as nitrogen trifluoride is introduced, and plasma is generated through excitation for surface lithium fluoride (LiF) coating; through the two-step plasma technology, synergistic modification of bulk phase doping and surface coating is achieved. After the prepared ternary positive electrode material is exposed to humid air, the capacity retention ratio, the cycle life and the rate capability of the ternary positive electrode material are remarkably improved, and the performance of the ternary positive electrode material is far better than that of an unmodified material and a single modified sample. And the method has a wide industrial application prospect.

This invention discloses an optical material and its preparation method based on plasma-assisted PVD evaporation, belonging to the field of glass surface treatment technology. This invention employs a plasma-assisted PVD evaporation process to treat fused silica, obtaining an optical material suitable for deep ultraviolet optics. Through a sol-gel method and solid-phase fluorination conversion process, a modified coating material with a calcium fluoride@aluminum fluoride core-shell structure was successfully prepared, integrating the two fluorides into a single coating material. During evaporation, in-situ fluorine replenishment is achieved using nitrogen trifluoride plasma, preventing fluorine loss from the fluorides at high temperatures, which would otherwise affect the material's optical properties. This invention, through its core-shell structure design, mitigates the fractionation effect during multi-component evaporation. Combined with plasma-induced ion beam-assisted deposition, a uniform coating is deposited on the surface of fused silica, enabling its use as a deep ultraviolet optical material.

The invention provides a composite anode for molten salt electrolysis as well as a preparation method and application of the composite anode. The composite anode comprises the following components in percentage by mass: 0.01%-10% of metal magnesium, 0.1%-6% of metal fluoride, 0-3% of metal oxide and the balance of nickel. The preparation method comprises the steps that nickel and magnesium are subjected to vacuum melting to form nickel-magnesium alloy and pulverized; carrying out ball-milling mixing on the alloy powder, metal fluoride and metal oxide; the mixed powder is subjected to hot press molding at the temperature of 600-1500 DEG C and the pressure of 50-60 MPa; processing into an anode profile; and immersing into a hydrofluoric acid solution with the concentration of 10%-45% to carry out surface passivation treatment. The composite anode is suitable for preparing fluorine gas or nitrogen trifluoride through electrolysis. Through the synergistic effect of magnesium alloying and fluoride / oxide, the corrosion resistance and structural compactness of the anode are remarkably improved, the anode effect approaches to zero, the service life is prolonged to 300 days or above, the current efficiency is high, and the technical problems that an existing carbon anode and an existing nickel anode are short in service life, rapid in dissolution and serious in pollution are effectively solved.

The invention discloses a method for improving the content stability of nitrogen trifluoride prepared through fusion electrolysis, and belongs to the technical field of nitrogen trifluoride electrolysis. Prepared metal powder is attached to the surface of a substrate in a high-temperature spray melting mode to obtain a coating electrode, and the coating electrode is used for electrolysis to prepare nitrogen trifluoride; the substrate is made of nickel metal. At different electrolysis temperatures, the stability of the anode material is better than that of nitrogen trifluoride prepared through electrolysis by taking pure nickel as the anode material. The coating alloy material used in the invention is lower in price than pure nickel, and has a wide development prospect in the aspect of industrial production.

The invention discloses a device and method for preparing rhenium hexafluoride. A reactor is of a vertical cylindrical structure, an upper-layer mesh cage structure and a lower-layer mesh cage structure are arranged in the reactor and used for being filled with raw material metal rhenium, the aperture of the upper-layer mesh cage is larger than that of the lower-layer mesh cage, a heating mechanism is arranged outside the reactor, and a gas inlet pipe and a gas distributor are arranged at the bottom of the reactor. A gas outlet pipe at the top of the reactor is sequentially connected with the first-stage freezing collector, the second-stage freezing collector and the washing tank; a communicating pipeline is arranged between the top and the bottom of the reactor. The preparation method comprises the following steps: (1) drying metal rhenium and then placing the metal rhenium on an upper-layer mesh cage and a lower-layer mesh cage; (2) introducing nitrogen / nitrogen trifluoride mixed gas into the reactor, raising the temperature to 300-350 DEG C, and maintaining the temperature for 4-6 hours; and (3) condensing and collecting the gas generated by the reaction to obtain rhenium hexafluoride. The reaction conditions are controllable, the process is simple, and efficient and oriented conversion of ReF6 is realized.

The invention discloses an anode material for preparing nitrogen trifluoride through electrolysis, the anode material is a nickel-based alloy doped with various metals, the invention further discloses application of the anode material for preparing nitrogen trifluoride through electrolysis, the metal-doped nickel-based alloy material is used as an electrolytic anode, and hydrogen fluoride and ammonium bifluoride are used as electrolytic raw materials for electrolysis, so that the anode material for preparing nitrogen trifluoride through electrolysis is obtained. In the electrolysis process, the temperature is controlled, the nitrogen trifluoride product is prepared through electrolysis under the constant voltage, and in the electrolysis period, the anode material is more resistant to corrosion than a nickel material with the purity of 99.96%. The anode material contains part of metal copper, compared with a pure nickel anode, the anode material is resistant to corrosion and lower in price, the amount of bottom slag of an electrolytic bath is smaller, and industrial production has wide development prospects.