3922 results about "Inert gas" patented technology

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

The invention discloses a method for synthesizing electronic-grade ethyl acetate through catalytic esterification of acidic ion exchange resin, and belongs to the technical field of ethyl acetate preparation. The method comprises the following steps: mixing crosslinked polystyrene white balls and a swelling agent, and dropwise adding concentrated sulfuric acid for reaction to obtain S-PS resin; mixing an EDTA disodium salt saturated solution and a polyacrylic acid solution, adding a cross-linking agent and an emulsifier, and carrying out a cross-linking curing reaction to obtain EDTA microcapsules; the preparation method comprises the following steps: dispersing S-PS resin in a solvent, adding EDTA microcapsules, a dehydration condensation agent and a catalyst, reacting under the protection of inert gas, and filtering and recovering after the reaction is finished to obtain S-PS-EDTA resin; mixing glacial acetic acid, absolute ethyl alcohol and S-PS (at) EDTA resin for reaction, and filtering and collecting liquid after the reaction is finished; and rectifying the collected liquid to obtain the product. According to the method provided by the invention, metal impurities can be chelated in the synthesis process, and the electronic-grade ethyl acetate with high purity and low impurity content is produced.

The invention discloses a double-push-plate type nitrogen protection resistance furnace and an atmosphere circulation purification control assembly, relates to the technical field of resistance furnaces, and aims at solving the problems that when cavities of the double-push-plate type nitrogen protection resistance furnace are communicated, temperatures interfere with one another, and the temperature of a furnace chamber is influenced by supplementing a protective atmosphere. The furnace body assembly is formed by connecting a plurality of independent cavities in series, the adjacent cavities are provided with openable isolation doors, and each cavity is provided with a nitrogen inlet / outlet, a temperature and pressure sensor and a heating assembly; the inert gas circulation structure achieves circulation supply and purification of protective gas, the gas supply amount of a single cavity can be adjusted, the atmosphere temperature and pressure cooperative control system integrates a parameter collection module, a temperature and pressure reference setting module, a temperature recovery compensation module, a pressure balance adjustment module and a closed-loop control module, and a gas purity monitoring module is additionally arranged. And a temperature and pressure cooperative control closed loop is formed through secondary feedback control, so that accurate regulation and control of the temperature and pressure of each cavity, recycling and reusing of waste heat of protective gas and dynamic maintenance of purity are realized.

The utility model discloses an inerting and discharging combined safety protection device for a solid hydrogen storage tank, and belongs to the technical field of hydrogen storage and supply. The device comprises a solid hydrogen storage tank main body, a pressure and temperature sensing module, an inert gas injection system, a flameless relief device and a hydrogen treatment unit, the pressure and temperature sensing module monitors parameters in the tank in real time, when the parameters exceed a preset threshold value, the inert gas injection system injects inert gas from the lower portion of the tank body at constant pressure, the air pressure is stabilized through flow control, and meanwhile hydrogen is pumped out of an opening in the upper portion of the tank body to the processing unit; and a discharge port is formed in the side surface of the tank body and is linked with the flameless discharge device. According to the device, through the design of inerting inhibition and safe release, the potential safety hazard of overtemperature and overpressure in the solid hydrogen storage process is solved, the stability and safety of a hydrogen storage system are improved, and the device is convenient to operate and adapts to transformation of an existing solid hydrogen storage tank.

Systems, assemblies, and methods to enhance extraction of pyrophoric materials from a refinery apparatus may include supplying a pressurized fluid to a plurality of vacuum generators, and generating, via the plurality of vacuum generators using the pressurized fluid, a vacuum flow. A manifold may provide a flow path for the vacuum flow, and pyrophoric material may be extracted from the refinery apparatus via the vacuum flow to a material collector through which the vacuum flow passes, depositing at least a portion of the extracted pyrophoric material in the material collector. One or more of inert gas or a cooling medium may be supplied to the material collector.

The invention belongs to the field of thin films, and particularly discloses an atomic layer deposition method and a thin film prepared through the atomic layer deposition method. According to the deposition method, the reaction cavity, the two input pipeline systems, the outlet valve and the vacuum pump in the atomic layer deposition system are used for controlling precursor pulse deposition and inert gas purging conditions in the atomic deposition process, and the film deposition state is improved; the efficiency of purging and removing substances and impurity residues such as a precursor and a reaction product thereof is improved, the problem that the quality of a deposited film is affected by the impurity residues in a reaction system or on the surface of a sample in the film deposition process is avoided, the uniformity and compactness of film deposition and the coverage rate and conformal rate of a film on the surface of a base material hole are improved, the defects of the film are reduced, and the yield is improved. And the method can be applied to a substrate with a high aspect ratio structure to deposit the film, so that the purpose of manufacturing a large-size complicated special-shaped structure device is achieved.

The invention discloses a preparation method and application of a bimetallic sulfide / three-dimensional porous carbon catalyst, and relates to the technical field of electrolyzed water catalysts.The preparation method comprises the following steps that melamine sponge is cleaned, and the clean melamine sponge is obtained; the preparation method comprises the following steps: dissolving metal salt 1 and metal salt 2 in an ethanol aqueous solution, and adding alkali and an aniline monomer to obtain a precursor solution; completely soaking the clean melamine sponge in a precursor solution, carrying out constant-temperature hydrothermal reaction, and sequentially washing and drying to obtain the melamine sponge anchored with bimetal ions; introducing inert gas for protection, and performing high-temperature vulcanization treatment to obtain the three-dimensional porous carbon catalyst embedded with the bimetallic sulfide heterostructure. The catalyst comprises uniformly dispersed bimetallic sulfide nanoparticles and a spongy three-dimensional porous carbon carrier, shows excellent bifunctional catalytic activity and stability when being applied to an electro-catalytic water decomposition reaction, and has a wide application prospect.

The invention discloses an intelligent preparation system and process for a composite antibacterial material with synergistic interaction of nanoparticles, and relates to the field of preparation of composite antibacterial materials. The raw material pretreatment module integrates a nano particle purification unit, a base material modification unit and an antibacterial agent dispersion unit, so that the purity and the dispersity are improved; the intelligent proportioning and mixing module consists of a five-channel metering pump, a dynamic mixer and a concentration monitoring device and is used for accurately controlling the component proportion; the reaction synthesis module comprises a constant-temperature reaction kettle, a pressure control system and an inert gas protection unit, and stable reaction is guaranteed; the performance online detection module is used for testing the antibacterial property, the mechanical property and the microstructure; the intelligent regulation and control module optimizes process parameters through an algorithm; the product post-processing module comprises a filtering unit, a drying unit and a sterile packaging unit to ensure the product quality. The antibacterial performance and stability are improved, the antibacterial aging is prolonged, energy consumption is reduced, efficient, green and intelligent preparation of the composite antibacterial material is achieved, and industrial technology upgrading is promoted.

A method for preparing a positive electrode material and an energy storage battery are provided. The method includes: preparing an Fe-MOF, including: dispersing a first iron source in a solvent, adding the cyanamide organic ligands into the solvent to perform reflux reaction to obtain a reaction solution, and performing cooling, filtering, and cleaning on the reaction solution to obtain the Fe-MOF; grinding and blending the Fe-MOF with a second iron source, a lithium source, and a phosphorus source to obtain a premix; and performing a sintering treatment on the premix under an atmosphere of an inert gas to obtain a composite lithium iron phosphate positive electrode material. The composite lithium iron phosphate positive electrode material includes lithium iron phosphate particles and carbon nanotubes, the lithium iron phosphate particles are attached to a surface of the carbon nanotubes, and there is iron wrapped by each of the carbon nanotubes.

The synthesis process comprises the following steps: (1) introducing inert gas into a reactor, adding a solvent, a Lewis acid catalyst and diphenyl ether, then dropwise adding an acyl chloride monomer solution, and synthesizing an intermediate M with a short-chain small molecular structure; (2) continuously dropwise adding an acyl chloride monomer solution into the reactor for reaction, and then adding an end-capping reagent for reaction; and (3) quenching, washing and drying the reaction product in the step (2) to obtain the product. Under the condition that only the Lewis acid is used as the catalyst, the one-pot method is adopted for synthesizing PEKK in two steps, side reactions can be reduced, meanwhile, the dosage of the catalyst is reduced, the production cost is reduced, the post-treatment process is simplified, and the obtained polyether ketone ketone is high in molecular weight and good in heat resistance and mechanical performance.

The invention discloses a catalytic method for converting alpha-olefin in an alkane-olefin mixture into internal olefin and application, raw materials and a solid acid catalyst are carried out in a fixed bed or a reaction kettle, the reaction temperature is 50-150 DEG C, the reaction pressure is 15-400 psi, and the reaction environment is an inert gas atmosphere; when the reaction is carried out on the fixed bed, the mass space velocity of the solid acid catalyst is 1h <-1 >-20h <-1 >; when the reaction is carried out in the reaction kettle, the conversion frequency of the raw materials is 5000 mol substrate mol acid site density <-1 > h <-1 > to 50000 mol substrate mol acid site density <-1 > h <-1 >; wherein the raw material is an alkane-alkene mixture; the solid acid catalyst comprises an active component and a carrier, wherein the carrier contains at least one inorganic oxide; the active component has a structure as shown in a formula (1) and / or a formula (2), in the formula (1) and the formula (2), R is alkyl or phenyl, and n is greater than or equal to 1. According to the catalysis method provided by the invention, the conversion rate of alpha-olefin can be increased, and the proportion of skeleton isomerization products and oligomers in internal olefin products can be reduced.

The application provides an aluminum alloy, which comprises the following components in percentage by mass: Zn 4.0-5.0%, Mg 1.2-1.8%, Cu 0.1-0.3%, Zr 0.08-0.12%, Ti 0.02-0.06%, Fe less than or equal to 0.25%, and the balance of Al. The alloy elements containing Zn 4.0-5.0%, Mg 1.2-1.8%, Cu 0.1-0.3%, Zr 0.08-0.12%, Ti 0.02-0.06% and Fe less than or equal to 0.25% are added into a smelting furnace together with pure aluminum, smelted at 700-750 DEG C to form a melt, refined by blowing in inert gas or adding a refining agent, and the gas and inclusions are removed. The application utilizes the shearing force generated by the different rotating speeds of the upper and lower rollers of a differential rolling mill to break the coarse structure, refine the grains, and increase the dislocation density. The aluminum alloy is rolled at 480-500 DEG C to reduce the deformation resistance, promote dynamic recrystallization, maintain the processing performance, and further enhance the performance by 60-70% of the total deformation. After rolling, the aluminum alloy is subjected to multi-directional forging, the strain direction is changed multiple times, the grains are broken, the structure is homogenized, and anisotropy is eliminated, so that the comprehensive performance and application range of the aluminum alloy profile are improved. The problem that the structure cannot be refined and the dislocation density cannot be increased during the rolling process is solved.

The invention discloses a pyrochlore structure high-entropy ceramic solidified body material as well as a preparation method and application thereof, and belongs to the technical field of nuclear waste solidification. The preparation method of the high-entropy ceramic solidified body material with the pyrochlore structure comprises the following steps: weighing raw material powder of La2O3, Nd2O3, Sm2O3, Gd2O3, Eu2O3 and ZrO2 according to the proportion in (La0. 2Nd0. 2Sm0. 2Gd0. 2Eu0. 2) 2Zr2O7; the weighed raw material powder is subjected to ball milling treatment, and ball-milled powder is obtained; under the inert gas atmosphere, the ball-milled powder is subjected to heat treatment, and heat-treated powder is obtained; and carrying out spark plasma sintering on the heat treatment powder to obtain the pyrochlore structure high-entropy ceramic solidified body material. The powder is treated by using a heat treatment technology, so that the powder is homogenized, a pyrochlore phase is formed, grain growth is more favorably inhibited, a fine grain structure is obtained, and the irradiation stability and the mechanical property of the pyrochlore material are improved.

The invention relates to the technical field of new energy, in particular to a negative pole piece for a battery without a negative active material, a preparation method and application. The preparation method comprises the following steps: under the protection of inert gas, dissolving a fluoroborate-containing oxalate material in an in-situ polymerization monomer to form a solution; and then uniformly coating the surface of a metal current collector and carrying out heating in-situ polymerization to obtain the negative pole piece for the battery without the negative active material. The negative pole piece is applied to the battery, so that lithium (sodium) can be prevented from directly contacting with other components of the battery to generate side reaction, and high-temperature gas expansion of the battery is inhibited; meanwhile, the negative pole piece without the negative active material has a certain lithium (sodium) supplementing effect, can effectively induce uniform deposition of lithium (sodium) and inhibit generation of dendrites and dead lithium (sodium), and the first efficiency and the cycle capacity retention ratio of the battery are greatly improved.

The utility model relates to a raw gas source upgrading system for an internal heating type vertical furnace. The raw gas source upgrading system comprises a dry distillation furnace, a carbon dioxide removal device and a pure oxygen preparation device, the device further comprises a first multi-stage mixer, a second multi-stage mixer, a gas sampling analysis tube and a gas component detector. Pure oxygen is adopted as a combustion improver, so that the content of nitrogen in the raw gas is greatly reduced, and the application scene of coal gasification production and deep processing of the internal heating type vertical furnace is expanded; the components of combustion-supporting gas, combustible gas and inert gas in mixed gas in a lattice wall of the dry distillation furnace are controlled by adopting double-circulation control of carbon dioxide and recirculated gas, the combustion intensity and the uniformity degree are strictly controlled under the condition that dry distillation heat supply is met, and scabbing and burning loss of a dry distillation furnace body are avoided.

A method for producing a substrate comprising a buried oxide layer (1, 10, 20) or a buried nitride layer for the production of electronic components, comprising at least one step for depositing an oxide layer (1, 10, 20) or a nitride layer on a donor substrate (2, 11, 21) and / or an acceptor substrate, and a step for establishing contact between the donor substrate and the acceptor substrate (9, 14, 22), further comprising at least: a first heat treatment of the oxide layer (1, 10, 20) or the nitride layer deposited on the donor substrate (2, 11, 21) and / or the acceptor substrate (9, 14, 22) before connecting the donor substrate (2, 11, 21) with the Acceptor substrate (9, 14, 22) and a second heat treatment of the substrate, which consists of the acceptor substrate (9, 14, 22), the oxide layer (1, 10, 20) or the nitride layer and the entire donor substrate (2, 11, 21) or a part thereof, at a temperature,which is the same as or higher than the temperature applied in the first heat treatment, wherein the second heat treatment is a compression heat treatment, wherein the first heat treatment consists of applying a temperature of 600 to 1000 °C for a period of a few minutes to a few hours in a non-oxidizing inert gas or a mixture of inert gases.

The invention discloses lithium sulfide, a two-step double decomposition preparation method and application of the lithium sulfide in an all-solid-state battery, and belongs to the technical field of solid-state batteries. According to the preparation method, a two-step decomposition synthesis technology is adopted, lithium carbonate and ammonium thiocyanate are used as raw materials, the raw materials are uniformly mixed and then placed in a high-temperature reactor, a step heating sintering procedure is completed in an inert gas atmosphere, and the purpose of fully decomposing and converting the raw materials is achieved by accurately controlling the temperature and the time; after a product is obtained through reaction, the high-purity lithium sulfide material is obtained after the product is cooled to the room temperature. The method for preparing the lithium sulfide is low in raw material cost, simple in reactant formula and free of side reaction in the reaction process, and the finally generated product is few in impurity, high in purity and good in crystallinity.

The invention belongs to the technical field of aluminum alloy grain refiners, and particularly relates to a grain refiner and a preparation method and application thereof.The preparation method of the grain refiner comprises the following steps that S1, aluminum powder, vanadium powder, boron powder and lanthanum powder are obtained; s2, after uniform mixing, vacuum ball milling is performed to obtain first powder, and the first powder is sieved to obtain second powder; s3, pressing the second powder to obtain a metal cake; s4, sintering the metal cake in an inert gas atmosphere to obtain a grain refiner; the Al-V-B-La refiner is prepared through a sintering method, the distribution condition of a second phase in the grain refiner and the grain refining effect of the grain refiner are improved through the rare earth element La, the VB2 phase in the grain refiner with the La element added is more uniform in distribution, smaller in size and larger in number density, more second phases can play a role in refining, and the grain refining effect of the grain refiner is improved. And the problem that the refining efficiency is low due to the Si poisoning problem of a traditional grain refiner is solved, and therefore the better aluminum alloy grain refining effect is achieved.

The invention discloses a graphene-aluminum composite material and a preparation method thereof, and belongs to the technical field of metal-based composite material preparation. The raw materials comprise modified aluminum particles and a graphene dispersing agent; the production process comprises the steps of aluminum particle interface modification treatment, graphene dispersing agent preparation, modified aluminum particle wrapping with graphene, heating pressing and heating extrusion forming. A nanometer interface modification layer is constructed on the surfaces of aluminum particles through a modifier to improve wettability and inhibit generation of Al4C3, a specially-made pressing device improves the compactness of a green body, inert gas protection is matched for extrusion, the performance of the composite material is optimized, and the problems that graphene and an aluminum matrix are poor in interface compatibility, prone to agglomeration, prone to generating brittleness at high temperature and the like are solved; the graphene is uniformly dispersed, and the composite material has excellent mechanical properties and high conductivity and is suitable for industrial mass production.

Methods and systems are disclosed for depositing aluminum nitride thin films by reactive sputtering using a sequence of negative-polarity voltage pulses applied to an aluminum target, followed by a positive-polarity voltage pulse. HiPIMS-type waveforms may be used to implement the negative-polarity and / or positive-polarity pulses. A substrate is provided in a sputtering chamber, a process gas comprising an inert gas and a nitrogen-containing gas is introduced, and the chamber is maintained at a reduced pressure. A sequence of negative-polarity voltage pulses is applied to an aluminum target, followed by application of a positive-polarity voltage pulse to the target. The disclosed methods and systems can produce aluminum nitride thin films exhibiting improved crystallinity, thermal conductivity, and surface quality at reduced deposition temperatures (e.g., below 200° C.) and with deposition rates of at least about 50 nm / min suitable for industrial applications.

The utility model relates to the technical field of pipelines, and discloses a sealing device of a compensator, which comprises a flange plate, a butt joint cylinder is fixedly arranged on the side wall of the flange plate, and a sealing assembly is arranged in the butt joint cylinder. According to the sealing device of the compensator, by arranging the sealing assembly, when flange plates are in butt joint installation, a bolt pushes an abutting rod to be matched with a disc and a push rod, so that a compressed air bag is extruded, inert gas in an expansion air bag can enter an annular air bag through a connecting pipe, and the size of the annular air bag is increased; by means of the arc-shaped limiting groove, the expansion air bag cannot excessively shift in the horizontal direction, meanwhile, the arc-shaped outer surface of the expansion air bag can increase the coverage area formed by unfolding, and therefore a gap in the connecting position between the butt joint cylinder and an external pipeline is effectively blocked, and the sealing effect between the whole compensator and the pipeline is guaranteed; and the anti-risk capability of the device is improved.

The invention discloses a low-temperature superfine grinding and quality maintaining process for glutinous rice flour. The process comprises the following steps: pretreatment: cleaning a glutinous rice raw material, atomizing, humidifying and tempering, and pre-cooling after wetting; environment construction: an inert gas circulation environment is constructed in a closed crushing system, the temperature of circulation gas in the system is controlled to be within a first low-temperature interval, and the oxygen concentration is controlled to be below a safety threshold value; graded crushing: feeding the treated raw materials into a crushing system, utilizing low-temperature circulating gas as a conveying medium, enabling the glutinous rice raw materials to sequentially pass through a plurality of crushing areas with gradually-decreased grinding gaps in the airflow direction to be subjected to graded crushing, and taking away heat generated by grinding by utilizing the low-temperature circulating gas; and separating fine powder. The system is high in integration level, the ultrafine glutinous rice flour is uniform and fine in particle size and controllable in broken starch rate through a low-temperature inert gas loop and graded crushing design, the gelatinization characteristic and the gel characteristic of the ultrafine glutinous rice flour are closer to those of raw materials, and the application range is wider.

The invention discloses a macro-energy laser light path environment purification method, which specifically comprises the following steps that three stages of purifiers are arranged in a closed environment of a photoelectric same cabin, and the three stages of purifiers comprise a first-stage high-speed airflow purging module, a second-stage electrostatic adsorption module and a third-stage high-efficiency filtering module; a laser scattering type impurity sensor is arranged in a closed environment of the photoelectric same cabin for real-time monitoring; the method comprises the following steps: firstly, carrying out primary purification, and carrying out replacement purging on a closed environment of the photoelectric same bin by adopting high-purity inert gas; then a third-stage purifier is started for deep purification, and when the real-time impurity concentration monitored by the impurity sensor is lower than a set threshold value, the third-stage purifier is closed. According to the technical scheme, the light path can be efficiently, stably and dynamically regulated and controlled to be purified, deep removal of impurities in the light path is achieved, and stable transmission of high-energy laser is guaranteed.

A production process of electronic grade molybdenum dichloride dioxide comprises the following steps: S1, pretreatment: contacting molybdenum trioxide with a dilute acid solution at a low temperature for pickling to remove alkaline impurities and soluble metal impurities adsorbed on the surface, and drying for later use after washing; s2, wet synthesis: in an inert gas atmosphere, reacting the molybdenum trioxide subjected to acid pickling in the step S1 with concentrated hydrochloric acid of which the mass is 4-5 times of that of the molybdenum trioxide at 80-100 DEG C, and after the reaction is finished, evaporating and concentrating in a high-temperature chlorine atmosphere to generate a crude product of dichloromolybdenum dioxide; s3, primary sublimation purification; s4, complexing and decomplexing purification; and S5, secondary sublimation purification: using a quartz sublimation tower to carry out vacuum sublimation on the secondary decomplexed molybdenum dichloride obtained in the step S34, and collecting sublimation condensate to obtain the electronic grade molybdenum dichloride. The final product purity of the production process is greater than or equal to 6N, and the process can be used for large-scale production.

The invention discloses metal ceramic MAX-phase composite powder for spraying and a preparation method of the metal ceramic MAX-phase composite powder, and belongs to the field of metal ceramic composite materials. The method comprises the following steps: mixing Ni powder, Cr powder and Cr2AlC nano powder with deionized water, a binder and a dispersant according to a specific ratio, and carrying out wet ball milling to prepare uniform slurry; carrying out spray granulation to obtain primary spherical powder; and finally, carrying out spheroidizing treatment on the primary powder by adopting radio frequency plasma under the protection of inert gas to obtain a final product. The core of the preparation method is that through an optimized two-step process, many limitations in the application aspect of an existing MAX phase material are solved, and the composite powder which is high in sphericity degree, good in flowability, compact in interior and stable in MAX phase component is successfully prepared. The powder can be directly used for thermal spraying, and an ideal raw material is provided for preparing a high-performance MAX-phase metal ceramic coating.

The invention provides a method for prolonging the high-temperature service life of a thermal barrier coating of a hydrogen-doped gas turbine. The method comprises the steps that Ni, Co, Cr, Fe, Al, Hf, Si and Y are smelted and cast into master alloy according to the proportion; preparing the mother alloy into high-entropy alloy powder through an inert gas atomization process; high-entropy alloy powder is deposited on the surface of the high-temperature alloy substrate by adopting a high velocity oxy-fuel spraying process, and a bonding layer of the thermal barrier coating is obtained; and preparing a thermal barrier coating on the bonding layer by adopting a plasma spraying process, and carrying out vacuum heat treatment on the thermal barrier coating in advance. The high-entropy alloy bonding layer provided by the invention has better thermal stability, and can still keep strong bonding force between the ceramic layer and the bonding layer alloy after water quenching high-temperature thermal cycle service. And the transition group high-entropy alloy bonding layer is beneficial to formation of a thermal growth oxide layer, has an inhibition effect on diffusion of metal elements and coating degradation in the hydrogen-induced corrosion and high-temperature steam corrosion processes, and can prolong the high-temperature thermal shock service time of the hydrogen-doped gas turbine.

The invention discloses a plasma-assisted surface activation method. The method comprises the following steps: placing a material matrix in a reaction cavity, vacuumizing, introducing oxygen and inert gas, exciting a radio frequency power supply and a microwave power supply to form multi-frequency composite plasma, and treating the material. The physical bombardment of the radio frequency plasma and the chemical activation of the microwave plasma have a synergistic effect, and deep cleaning and efficient modification of the surface of the material are realized in a low-vacuum environment. The surface water contact angle of the treated material is reduced to 35 degrees or below, the adhesive force of a coating reaches 0-1 level, the tensile shear strength is improved to 22.5 MPa or above, the problems that a traditional surface treatment method is unstable in effect and insufficient in modification depth are effectively solved, and the surface treatment method has the outstanding advantages of being high in treatment efficiency, uniform and lasting in modification effect, environmentally friendly and the like.

The invention belongs to the technical field of ocean engineering drag reduction, and relates to a self-adaptive chemical gas production underwater drag reduction layer and a preparation method thereof.The surface of an aircraft is regarded as a gas production place and transformed into an intelligent interface with sensing and feedback capabilities, inert gas generated by reaction of reactants is detained and utilized in situ through microstructure design, and the self-adaptive chemical gas production underwater drag reduction layer is obtained. The independent micro chamber structure avoids diffusion of local failure, the macroscopic flow guide structure relieves the problem of non-uniform gas film distribution, external energy input is not needed, the chemical reaction rate is reversely and adaptively regulated and controlled based on the physical effect generated by gas retention, and therefore a closed-loop passive self-adaptive resistance reduction film layer is formed. Reaction byproducts are environment-friendly water-soluble sodium chloride and water and are removed in a pulse type reaction mode of high-speed water flow scouring and gas retention, so that the risk of permanent blockage is reduced, safety and environment friendliness are achieved, the energy utilization efficiency is high, meaningless waste of gas is avoided, and the cruising ability of fuel is equivalently and greatly improved.

The invention discloses an intelligent control system and method for an active fire extinguishing device of a high-voltage switch cabinet, and the system comprises the steps: collecting multi-source heterogeneous environmental parameters in the cabinet, carrying out the LoRa wireless transmission, introducing a dynamic thermal drift compensation mechanism based on an Arrhenius model, and carrying out the zero drift correction and sensitivity dual compensation of the original data of a sensor. A high-fidelity physical monitoring value is reconstructed through high-order polynomial nonlinear mapping, and the risk of false alarm and missing alarm caused by thermal-sensitive coupling is eliminated. After a fire hazard is recognized, the block type fire extinguishing device is excited in a linkage mode, inert gas and free radical groups are instantaneously released through an oxidation-reduction reaction to conduct total flooding type suppression, negative feedback adjustment and automatic termination of the reaction rate are achieved according to the environment temperature change, and therefore accurate early warning is ensured, and meanwhile the safety of the fire hazard is improved. Efficient blocking and reset safety protection of live-line fire disasters are realized.

The invention relates to the field of graphene sensors, and particularly discloses a preparation method of a sweat-erosion-resistant laser-induced graphene sensor, which comprises the following steps: firstly, locally heating laser-induced graphene coated with heat release glue by using 1064 nm laser, so that the laser-induced graphene is stripped from an original polyimide substrate and transferred to a target thermoplastic polyurethane flexible substrate; then using 355 nm laser to ionize mixed gas of inert gas and oxygen, generating plasma to bombard an interface of laser-induced graphene and polyurethane, and inducing covalent bonding between surface functional groups; and then spraying a polydimethylsiloxane-urea / silicon dioxide fluoride composite solution on the surface of the laser-induced graphene-polyurethane composite structure subjected to transfer printing and bonding, and sintering by adopting 532 nm laser to form the self-repairing super-hydrophobic packaging layer with a micro-nano mastoid structure. The problem of ion intercalation in sweat is solved, and the electrical stability, the interface bonding strength and the wear resistance of the sensor are remarkably improved.