The invention relates to a multi-layer composite black film and a preparation method thereof. The multi-layer composite black film is formed by sequentially stacking a base material layer, a multi-layer film
system and a top covering layer, the multi-layer film
system is formed by alternately stacking a plurality of absorption
layers and a plurality of
oxide layers, the number of the
layers is 7-30, an initial layer is an
oxide layer, the refractive indexes of the
oxide layers are the same (1.4-1.5), the thickness ratio of the oxide layers to the absorption layers is larger than 2, and the thickness ratio of the top covering layer to the absorption layers is larger than 1. And the thicknesses of the two layers are increased and then reduced from the substrate layer to the top covering layer. A buffer layer with gradually changed
oxygen content is arranged between the oxide layer and the
absorption layer, and both the oxide layer and the top covering layer are made of
silicon dioxide. The preparation method comprises the following steps: providing the substrate layer, alternately depositing the
absorption layer and the oxide layer by using a magnetron
sputtering or
electron beam
evaporation process to form a multilayer film
system, then forming the top covering layer, controlling parameters such as vacuum degree, power, temperature and the like during deposition, and forming the buffer layer in the same cavity. The multilayer composite black film has the inner surface
reflectivity of less than 1% and the appearance surface
reflectivity of less than 5%, and is simple in structure and low in preparation cost.