The invention discloses a wide-band-gap
perovskite solar cell and a preparation method thereof, and belongs to the technical field of
new energy, the method comprises the following steps: 1) spin-
coating a NiOx solution on a pretreated substrate, and
drying to obtain a NiOx
hole transport layer; 2) mixing FAI, CsI, PbBr2 and PbI2, dissolving the mixture in a
mixed solution of DMF and DMSO, and then adding 4, 5-dicyanoimidazole to obtain a
perovskite precursor solution; the NiOx
hole transport layer obtained in the step 1) is coated with a
perovskite precursor solution through a two-step spin-
coating method, and a perovskite layer is obtained after annealing treatment; and 3) successively preparing an
electron transport layer and an
electrode layer to obtain the wide-band-gap
perovskite solar cell. By providing a 4, 5-dicyanoimidazole additive strategy, the strong coordination effect between 4, 5-dicyanoimidazole and
iodide ions effectively inhibits the
precipitation of
iodine, thereby significantly improving the stability of the wide-band-gap
solar cell.