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Phosphate material having mesoporous structure for lithium secondary batteries and preparation method thereof

The invention relates to a phosphate material having a mesoporous structure for lithium secondary batteries and a preparation method thereof. The material having a mesoporous structure is secondary particles which have a mesoporous spherical or spheroid shape and are formed by the agglomeration of primary particles; the chemical composition of the material having the mesoporous structure is represented by the formula of LixAaMmBbPOzNn; the average particle diameter of the primary particles is 10nm to 1mum, the average particle diameter of the secondary particles is 100nm to 50mum, the average pore diameter of mesopores is 2 to 500nm; and the material having the mesoporous structure also comprises a layer of 2 to 100nm thick carbon coated outside the secondary particles and on the inner walls of the mesopores, wherein the content of the carbon accounts for 1 to 20 weight percent of the total weight of a substrate. The material is prepared by the steps of: firstly preparing pure-phase phosphate LiMPO4 or doped LiMPO4 sol; secondly, forming dry gel through heat treatment; and finally, forming the agglomerate secondary particles through sintering at high temperature. The phosphate material having the mesoporous structure can be directly used in secondary lithium batteries as an anode active material and can also be used by being mixed with the prior anode material as an additive. The material having the mesoporous structure can improve the rate performance and energy density of the prior anode material and batteries. The secondary lithium batteries containing the phosphate material having the mesoporous structure has high power density and high safety.
Owner:INST OF PHYSICS - CHINESE ACAD OF SCI
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