10364results about How to "Improve catalytic performance" patented technology

New ligands, compositions, metal-ligand complexes and arrays with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene / olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

Catalysts comprising metal-loaded non-zeolitic molecular sieves having the CHA crystal structure, including Cu-SAPO-34, methods for preparing such catalysts, and systems and methods for treating exhaust gas incorporating such catalysts are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stability at high reaction temperatures.

The invention describes a process for tetramerisation of olefins wherein the product stream of the process contains more than 30% of the tetramer olefin. The process includes the step of contacting an olefinic feedstream with a catalyst system containing a transition metal compound and a heteroatomic ligand.

The present invention is directed to a novel capacitor. The capacitor may be used in electric double layer capacitors. The capacitors include a polarizable electrode including activated carbon and a non-polarizable electrode including lead dioxide and lead sulfate. The capacitors of the present invention provide considerably higher electric capacity, higher durability, and low resistance, while maintaining high conductivity. Additionally, the electrodes may be produced more quickly and inexpensively.

The invention discloses a catalyst, which is carried by an AlSn-SBA-15 molecular sieve with SnAl double metal-containing framework, for dehydrogenation of propane for preparing propylene. In the catalyst, the AlSn-SBA-15 molecular sieve with SnAl double metal-containing framework is used as a carrier, platinum-group element metal is used as a main catalyst, IVA-group, IA-group or IIA-group element metal is used as an auxiliary agent, and high-temperature-resistant inorganic oxide is used for forming an adhesive. A multi-step dipping method is used in the preparation of the catalyst, namely the alkaline metal auxiliary agent is dipped, so that the acidity and alkalinity of the catalyst and the types of cations in pores of the molecular sieve are effectively modulated by cation exchange technology, and the platinum-group element metal is dipped. The catalyst has superior anti-carbon deposit performance, high propane conversion rate under the reaction conditions of high temperature and low pressure, propylene selectivity and reaction stability.

There is described Pd enriched diesel oxidation catalysts and their application as catalysts for the oxidation of CO and HC emissions from a compression ignition / diesel engine. The catalysts are characterised by increased performance and hydrothermal durability these goals being achieved by employing a layered design to eliminate low temperature catalyst quenching by toxic HC species in the exhaust stream.

The invention discloses a preparation method of a nitrogen-doped porous-structure carbon material and belongs to the technical field of inorganic material preparation. The preparation method utilizes a micromolecular carbon-containing compound as a raw material and comprises the following steps of based on the weight of the raw material, adding 0-400wt% of an inorganic base, 0-400wt% of an organic nitrogen-containing compound and 0-50wt% of a metal or metal oxide or inorganic metal salt into the raw material, carrying out uniform dispersion, and carrying out a reaction process in an inert gas protective atmosphere at a temperature of 400-900 DEG C for 0.5-12h so that the nitrogen-doped porous-structure carbon material having micropores, mesopores and macropores is obtained. The preparation method has simple processes, can be controlled easily, and realizes one-step combination of porous structure, functionalization nitrogen doping and metal particle modification. The nitrogen-doped porous-structure carbon material having high nitrogen content has a large capacitance value and good cycle performances, can be used as an oxygen reduction reaction catalyst having high activity, high selectivity and high stability and has a very large application prospect.

Provided is a catalyst composition having an aluminosilicate molecular sieve having an AEI structure and a mole ratio of silica-to-alumina of about 20 to about 30 loaded with about 1 to about 5 weight percent of a promoter metal, based on the total weight of the molecular sieve material. Also provided are method, articles, and systems utilizing the catalyst composition.

The present invention relates to a silicoaluminophosphate molecular sieve comprising at least one intergrown phase of molecular sieves having AEI and CHA framework types, wherein said intergrown phase has an AEI / CHA ratio of from about 5 / 95 to 40 / 60 as determined by DIFFaX analysis, using the powder X-ray diffraction pattern of a calcined sample of said silicoaluminophosphate molecular sieve. It also relates to methods for its preparation and to its use in the catalytic conversion of methanol to olefins.

The invention describes a process for tetramerisation of olefins wherein the product stream of the process contains more than 30% of the tetramer olefin. The process includes the step of contacting an olefinic feedstream with a catalyst system containing a transition metal compound and a heteroatomic ligand.

A method of using coated and / or magnetic particles to deposit structures including solder joints, bumps, vias, bond rings, and the like. The particles may be coated with a solderable material. For solder joints, after reflow the solder material may comprise unmelted particles in a matrix, thereby increasing the strength of the joint and decreasing the pitch of an array of joints. The particle and coating may form a higher melting point alloy, permitting multiple subsequent reflow steps. The particles and / or the coating may be magnetic. External magnetic fields may be applied during deposition to precisely control the particle loading and deposition location. Elements with incompatible electropotentials may thereby be electrodeposited in a single step. Using such fields permits the fill of high aspect ratio structures such as vias without requiring complete seed metallization of the structure. Also, a catalyst consisting of a magnetic particle coated with a catalytic material, optionally including an intermediate layer.

The invention relates to an in-situ composite silicon-based multibasic oxide oxide aerogel material and its preparation method, especially to a multibasic oxide oxide aerogel material which is prepared by the following steps: using soluble glass as a silicon source, mixing metallic oxide corresponding water-soluble metal salt, adding acid or alkali to adjust pH value of the system so as to form multibasic oxide sol; mixing the multibasic oxide sol with a water-soluble organic solvent, filtering to remove produced precipitate so as to obtain salt-free multibasic oxide sol, carrying out a sol-gel method, aging, modifying and drying. By a mature silica aerogel technology, the multibasic oxide oxide aerogel material is prepared by in-situ polymerization of other oxide components which are not easy to separately prepare aerogel. In addition, the multibasic oxide oxide aerogel material has excellent properties, such as high temperature stability, high activity, magnetic property and the like, none of which are present in single-component silica aerogel. The product is widely applied in fields of high temperature insulation, sound insulation, catalysts, catalytic carriers, battery electrodes, electromagnetism, resistance, gas sensitivity, humidity sensitivity, luminescent materials and the like.

The invention provides a multiphase wet oxidation catalyst, in which noble metal elements, which are selected from one or more than one of the group consisting of platinum, ruthenium, rhodium, iridium and aurum, are taken as active components; and rare earth elements, which are selected from one or more than one of the group consisting of lanthanum, cerium, praseodymium and neodymium, are taken as auxiliary components; the active components and the auxiliary components are carried on a ceramic-activated carbon carrier, wherein the content of activated carbon accounts for 1 to 15% of the totalweight of the ceramic-activated carbon carrier, and the weight of elements in the active components and the auxiliary components accounts for 0.25 to 5% of the weight of the activated carbon respectively. The invention further provides a preparation method and uses thereof. The catalyst of the invention is particularly suitable for the treatment of high-concentration organic waste water which is hardly degraded.

A catalyst for preparing low-carbon olefins by one-step conversion of synthetic gas and a preparation method thereof relate to catalysts; the catalyst is made from 20-60% of a zirconium-based solid solution,30-70% of a double-micropore zeolite molecular sieve and 0.1-10% of metal oxides; the preparation method comprises: adding salt compounds of at least one element from IA, IIIA, VIIB, IB, IIB and the like into deionized water or alcohol to obtain solution A having a mass concentration of 0.1-15%; adding the zirconium-based solid solution into the solution A, heating, drying by distillation, and drying to obtain solid powder; adding the solid powder and the double-micropore zeolite molecular sieve into ethylene glycol, ultrasonically dispersing, and moving a filtered and washed sample to a vacuum drying box, drying at 50-100 DEG C for 2-24 h, calcining in a muffle furnace, and tableting obtained solid sample to obtain the catalyst.

The present invention relates to a silicoaluminophosphate molecular sieve comprising at least one intergrown phase of molecular sieves having AEI and CHA framework types, wherein said intergrown phase has an AEI / CHA ratio of from about 5 / 95 to 40 / 60 as determined by DIFFaX analysis, using the powder X-ray diffraction pattern of a calcined sample of said silicoaluminophosphate molecular sieve. It also relates to methods for its preparation and to its use in the catalytic conversion of methanol to olefins.

The invention describes a process for tetramerisation of olefins wherein the product stream of the process contains more than 30% of the tetramer olefin. The process includes the step of contacting an olefinic feedstream with a catalyst system containing a transition metal compound and a heteroatomic ligand.

The invention provides a catalyst for high-selectivity preparation of light aromatic hydrocarbon by using synthesis gas and a preparation method thereof and belongs to the field of catalysts. The catalyst is prepared from, by mass, 20%-60% of modified zeolite molecular sieve and 40%-80% of zirconium-containing composite oxide. The preparation method comprises the steps that the zirconium-containing composite oxide is added to a solvent, and ultrasonic dispersion is performed to obtain a solution A; the modified zeolite molecular sieve is added into the solution A; the mixture obtained after ultrasonic dispersion is subjected to suction filtration, and the obtained filter cake after washing is dried; the sample obtained after drying is grinded into powder; the powdery sample is calcinated, and the obtained sample is the catalyst for high-selectivity preparation of the light aromatic hydrocarbon by using synthesis gas. The light aromatic hydrocarbon can be prepared in a high-selectivity mode, and the stability is good. The preparation method of the catalyst for high-selectivity preparation of the light aromatic hydrocarbon by using the synthesis gas is simple and low in cost and has good industrial application prospect.

The invention discloses a compound nano material of graphene and molybdenum disulfide (MoS2) and a preparation method thereof. The compound material is formed by mixing graphene and a MoS2 nano material in a mass ratio of (1 to 1)-(4 to 1). The preparation method comprises the following steps of: preparing an oxidized graphite nano slice from graphite by a chemical oxidization method; then dissolving molybdate into deionized water so as to form 0.02 to 0.07M of solution; adding L-cysteine serving as a sulfur source and a reduction agent, wherein the mass ratio of the L-cysteine to the molybdate is (5 to 1)-(12 to 1); adding the oxidized graphite nano slice into the solution, and ultrasonically treating so that the oxidized graphite nano slice can be fully dispersed in the hydrothermal reaction solution; transferring the mixture into a hydrothermal reaction kettle and sealing; and synthesizing by a one-step hydrothermal method to obtain the compound nano material of graphene and MoS2, wherein the mass ratio of the graphene nano slice to the MoS2 is (1 to 1)-(4 to 1). The method has the characteristics of mild reaction condition and simple process. The compound nano material of graphene and MoS2 synthesized by the method can be widely used as electrode materials of new energy batteries, high-performance national lubricants, catalyst carriers and the like.

The invention relates to a catalyst carrier, an SCR denitrifying catalyst of electric plant flue gas that is prepared by the catalyst carrier and a preparation method of the SCR denitrifying catalyst. The invention adopts purple mud clay and anatase TiO2 to form the carrier; by weight, the content of the TiO2 is 50 to 99 percent and the content of the purple mud clay is 1 to 50 percent. The catalyst carrier can further contain active carbon, CaSO4 and ammonia-typed Y molecular sieve, which respectively account for 0 to 20 percent of the weight of the catalyst carrier. The active ingredients of the catalyst comprise V2O5 accounting for 1.0 to 6.0 percent of the weight of the catalyst, WO3 accounting for 4.0 to 10.0 percent of the weight of the catalyst, MoO3 accounting for 0 to 9.0 percent of the weight of the catalyst, and CeO2 accounting for 0 to 2.0 percent of the weight of the catalyst. The working temperature of the catalyst is 200 to 500 DEG C, has high catalytic activity, large specific surface and strong toxin immunity, hardly has inactivation phenomenon in long-time running, and is insensitive to vapor and sulfur dioxide.

The invention discloses a titanium silicalite TS-1 catalyst preparation method. Cheap inorganic Titanium silicalite is used as raw material, low quantity of tetrapropylammonium hydroxide or tetrapropylammonium bromide is adopted as template agent, and inorganic alkali such as ammonia water is used as alkali source so that the raw materials for preparation have low price and the production cost isgreatly reduced. The precursor preparation process is simple and easy to control, seed crystal is added to reduce the crystallization time and the repeatability is good. As secondary crystallization is adopted, the non-framework titanium is further reduced, and the acid site of the molecular sieve is reduced, the grain size is controllable within certain range, the molecular sieve channel becomessmoother to facilitate direct membrane separation of micrometer crystalline grains, and the obtained Titanium silicalite TS-1 catalyst has large grains, high activity, stable catalytic performance and broad industrial application prospect.

The invention relates to an integral honeycombed catalyst for SCR flue-gas denitration and a preparation method therefor. Titanium dioxide, bentonite and meerschaum are taken as carries, soaked for loading active components, formed, dried and baked to prepare the integral honeycombed catalyst. The carries comprise titanium dioxide 60-90%, bentonite 0-20% and meerschaum 0-10% by weight; the active components comprise WO3 5.0-10.0% OR MoO3 5.0-9.0%, V2O5 0.3-5.0%, and CeO2 0.0-2.0% or Nb2O5 0.0-1.0% by weight; and the total of the components is 100%. The catalytic activity is high, the denitration efficiency is high, and the service life is long; titanium dioxide, bentonite and meerschaum are taken as the carries, soaked for loading the active components, formed, dried and baked to prepare the integral honeycombed catalyst; and the preparation method is scientific, reasonable, simple and feasible.

The invention relates to a composite material of a nitrogen-doped porous carbon-wrapped carbon nano tube as well as a preparation method and an application of the composite material. The preparation method comprises the following steps: dispersing the carbon nano tube in water, adding a carbon source to obtain a reaction system, subsequently performing hydrothermal reaction, performing thermal treatment on the carbon nano tube wrapped with a carbon layer on the surface, and a nitrogen source at the high temperature so as to obtain the composite material of the nitrogen-doped porous carbon-wrapped carbon nano tube. According to the preparation method, the carbon source is polymerized under a hydrothermal reaction condition so as to obtain the carbon layer, the outer surface of the carbon nano tube is wrapped with the carbon layer, subsequently the carbon layer is carbonized and decomposed to generate a porous structure under high temperature treatment, and at the same time, the gasified nitrogen source is diffused to the carbon layer through ducts to be subjected to in-situ doping. The composite material provided by the invention can be used as a cathode oxidation reduction catalyst of a fuel battery, is excellent in catalysis, and is high in oxidation activity when being compared with other nitrogen-doped materials reported in documents. The preparation method provided by the invention is simple and economic in process, convenient to operate and easy to achieve the large-scale production.

This invention relates to an iron-based Fischer-Tropsch cataylst composition wherein the iron phase is ferrihydrite. The catalyst composition optionally includes a structural promoter which may be selected from manganese or chromium or a mixture thereof and chemical promoters selected from magnesium, zinc, copper and an alkaline or alkali metal such as potassium. The catalyst is best bound to a refractory oxide support such as silica. This catalyst composition produces significant yields of higher parafins, olefins and alcohols.

A structured catalyst for selective reduction of nitrogen oxides with ammonia using an ammonia-supplying compound. The catalyst is preferably used for exhaust gas treatment of diesel vehicles powered by diesel motors. The catalyst is characterized by the fact that it contains a reduction catalyst for selective reduction of nitrogen oxides with ammonia and a hydrolysis catalyst for the hydrolysis of urea, where the hydrolysis catalyst is applied in the form of a coating onto the reduction catalyst. By this arrangement of the two catalytic functions in one catalyst the exhaust gas system can be made very compactly and space saving. Moreover, advantageous synergistic effects result from the direct contact of the hydrolysis catalyst and the reduction catalyst.

The invention relates to a biomass magnetic carbon material for degrading organic dye. The material is prepared by mixing a biological raw material and an iron precursor at a ratio of (2-20kg):1kg. Meanwhile, the invention also discloses a preparation method of the biomass magnetic carbon material. The biomass magnetic carbon material provided by the invention is cheap and efficient and has double effects of adsorption catalysis and degradation; serving as an efficient catalyst in a process of constructing a Fenton-like system for treating high-concentration wastewater, the biomass magnetic carbon material has high catalytic activity in thoroughly oxidizing and degrading organic dye; the degradation effect is better than that of a ferrous ion homogeneous catalysis reaction and a Fenton-like reaction taking ferroferric oxide as a catalyst.

The invention discloses a low-temperature selective catalytic reduction denitration catalyst and a preparation method thereof, wherein the catalyst takes an attapulgite as a carrier to load nano-composite materials of manganese oxide nano-particles; the structure thereof is as follows: manganese oxide particles with the particle diameter of less than 20nm are loaded on the rod-shaped crystal surface of the attapulgite with the diameter of 40-50nm; one or more types from iron, copper and nickel are added as an additive; and calculated according to the mass percentage of manganese, the content of the manganese oxide in the catalyst is 0.1-20. The preparation method comprises the steps of: firstly extruding, drying and crushing the attapulgite clay, and then preparing attapulgite clay powderinto suspension liquid; adding acid solution to wash and remove carbonate impurities, adding manganese salt, and then adding alkali solution for stirring so as to lead the manganese ion to be hydrolyzed and precipitated and loaded onto the crystal surface of the attapulgite, and finally obtaining the product after centrifugal washing, dewatering, drying and calcinations. The catalyst takes ammoniaas a reducing agent, and has higher activity of catalyzing NH3 and reducing NO reaction within the scope of 120 DEG C to 350 DEG C.

The invention relates to a method for preparing olefin by conversion of methanol by using Zn-SAPO-34 molecular sieve and bonding agent as the catalyst for alkene production through methanol converstion, and employing a reaction temperature of 300-500 deg. C, a reaction pressure of atmospheric pressure, methanol weight space velocity of 1.0-10hr-1, the prepared low carbon alkene can be used in the industrial production of alkene from methanol.

The invention relates to a method for pre-vulcanizing a hydrogenation catalyst outside a hydrogenation reactor and activating the hydrogenation catalyst in the hydrogenation reactor. The method comprises the following steps of: (1) pre-vulcanizing the catalyst outside the hydrogenation reactor; (2) passivating the catalyst; and (3) reactivating the catalyst. A vulcanization method for the hydrogenation catalyst provided by the invention can guarantee high vulcanization rate of the catalyst; the passivated catalyst does not have abnormal odor and does not release hydrogen sulfide gas when being in contact with air or vapor; and the catalyst does not spontaneously combust and is not required to be protected by inert gas. Storage, transportation and filling methods and the like of the catalyst are simple and convenient. The catalyst can reach an activated state in a few hours during reactivation of an atmosphere containing a vulcanizing agent and hydrogen, is short in processing time, convenient to operate and has high catalytic performance.

A single layer high performance catalyst containing on an inert carrier body a catalytic coating comprising platinum, rhodium and various oxide materials. The catalyst contains a catalytic coating having at least one first support material selected from the group having a first active alumina, a ceria rich ceria / zirconia mixed oxide and a zirconia component, said at least one first support material being catalyzed with a first part of the total platinum amount of the catalyst, and a second support material catalyzed with the second part of the total platinum amount and with rhodium said second support material being a second active alumina.