The invention discloses an on-line automatic monitoring method and
system for total
alkalinity in water, and relates to the technical field of
water quality on-line monitoring. When the current measuring state of the
system is a starting state, a sampling unit is controlled to convey a target
water sample to a mixed reaction unit based on a preset
water sample flow; the
reagent unit is controlled to convey a target
reagent to the mixed reaction unit; dynamically adjusting the flow rate of the target
reagent based on a
proportional integral differential control strategy, so that the pH value of a
mixed solution formed by mixing the target
water sample and the target reagent in the mixed reaction unit fed back by the detection unit in real time is stabilized at a preset endpoint pH threshold value; and determining the total
alkalinity of the target water sample based on the flow velocity of the target reagent when the pH value is stable, the concentration of the target reagent and the preset water sample flow. The pH value is stabilized at the
titration end point by dynamically adjusting the reagent flow rate, the total
alkalinity is calculated according to the reagent flow rate, the water sample flow rate and the reagent concentration during balance, continuous and rapid measurement can be realized, and the reagent consumption is low.