The invention relates to the field of new environmental materials, in particular to a
nitrogen-doped hollow carbon polyhedron-carbon@
nanotube-based monatomic
cobalt catalyst capable of efficiently activating
persulfate and a preparation method thereof. According to the invention, ZIF-8 is used as a
seed crystal, ZIF-67 grows on the surface of the ZIF-8 through an epitaxial growth method to obtainZIF-8@ZIF-67 with a core-shell structure, then the ZIF-8@ZIF-67 is calcined in an
inert atmosphere to obtain carbonized ZIF-8@ZIF-67, exposed
cobalt nanoparticles are removed through acid
pickling, and the
nitrogen-doped hollow carbon polyhedron@
carbon nanotube-based monatomic
cobalt catalyst is prepared. According to the catalyst, monatomic cobalt is anchored on a
carbon matrix through coordination, the catalytic site density is high, the
conductivity is good, the
ferromagnetism is good,
persulfate can be efficiently activated to degrade toxic and harmful organic pollutants in water, the useamount of the catalyst and
persulfate is greatly reduced, and the cost is reduced. Moreover, multi-component comprehensive regulation and control of the hollow carbon polyhedron, the carbon nanotubesand the monatomic cobalt are realized for the first time, efficient and stable operation can be realized within a wide temperature range and under the interference of inorganic salt, natural organic matters and the like, and the application prospect is expanded.