36 results about "Dihydrate Calcium Sulfate" patented technology

Polymerization of siloxane is improved using a gypsum-based slurry that includes stucco, Class C fly ash, magnesium oxide and an emulsion of siloxane and water. This slurry is used in a method of making water-resistant gypsum articles that includes making an emulsion of siloxane and water, then combining the slurry with a dry mixture of stucco, magnesium oxide and Class C fly ash. The slurry is then shaped as desired and the stucco is allowed to set and the siloxane polymerizes. The resulting product is useful for making a water-resistant gypsum panel having a core that includes interwoven matrices of calcium sulfate dihydrate crystals and a silicone resin, where the interwoven matrices have dispersed throughout them a catalyst comprising magnesium oxide and components from a Class C fly ash.

An improved, fire-resistant, set gypsum composition contains set calcium sulfate dihydrate as the major ingredient and a reinforcing ingredient of resilient, flexible, boron-free glass fibers. Continuous filament forming glass compositions with a softening point preferably greater than about 1580° F. (about 860° C.) and more preferably greater than about 1681° F. (about 916° C.) may be used. The fibers typically are distributed as their separate constituent individual glass filaments uniformly throughout the set calcium sulfate dihydrate.

The invention discloses a technique method for producing high-concentration nitric phosphate, which comprises the following steps of: adding nitric acid into phosphorus ore for acidolysis, depositing and separating acid non-soluble substance, freezing and crystallizing calcium nitrate, filtering the calcium nitrate, neutralizing the mother liquid, vaporization, pelleting and drying. The invention is characterized in that: a step of thoroughly removing the calcium of the mother liquid is arranged between the steps of filtering the calcium nitrate, and neutralizing the mother liquid. The steps comprise the following steps of: I) thoroughly removing the calcium of the mother liquid and adding sulfuric acid or ammonium sulfate; the calcium ions and the sulfate ions in the mother liquid generate dihydrate calcium sulfate crystal; II) the grading processing of reaction slurry: employing a grading device to carry out grading processing to the reaction slurry; returning the reaction slurry provided with small grain calcium sulfate to the mother liquid for thoroughly removing the calcium, and feeding the reaction slurry provided with large grain calcium sulfate to the calcium sulfate for filtering; and III) filtering and washing the filtering reaction slurry of calcium sulfate by a filter, feeding the primary filtrate and the primary lavage fluid into the working procedure of neutralizing, and returning the secondary lavage fluid to the filter. The invention has the advantage of using middle-low quality phosphorite to prepare the high-concentration nitric phosphate.

The invention relates to a restoration agent for saline-alkali land soil, which consists of free gypsum dehydration, nature organic substance, microbial fertilizer and inorganic nutrient with weight ratio of 60-70:25-35:1-4:3-6; the content of dihydrate calcium sulfate in the free gypsum dehydration is over 80 percent; the nature organic substance consists of weathered coal and grass carbon with weight ratio of 1.0:0.93; the content of effective bacteria in the microbial fertilizer is 2.0 hundred millions/g; and the inorganic nutrient consists of urea, ordinary superphosphate and potassium chloride with weight ratio of 1.0:2.42:075. The restoration agent can utilize calcium ions in the free gypsum dehydration for replacing sodium ions in the soil so as to lower the alkalinity in the soil and provide calcium and sulfur elements for crops, while the nature organic substance can lower and regulate the slat content and the alkalinity in the soil. In addition, the nature organic substance, the microbial fertilizer and the inorganic nutrient can supply large amount of nutrient elements such as nitrogen, phosphorus, potassium and the like to the crop for normal growth, thereby being capable of improving the yield of the crop.

The invention relates to a method for preparing calcium sulfate crystal whiskers (CaSO4) by using impurity-containing gypsum as a raw material. The method comprises the following steps of: removing main impurities in the raw material which is the low-priced impurity-containing gypsum resource in a mode of roasting, acid-complex leaching and alkaline leaching and simultaneously thinning crystal grains to obtain a superfine dihydrate calcium sulfate precursor which is high in purity and dispersibility; and preparing the anhydrous calcium sulfate crystal whiskers with a length of 20 to 2,000mu m, a diameter of 0.5 to 20 mu m, a length-diameter ratio of 40 to 1,000 and a weight percent content of over 95 percent in a mode of hydrothermal conversion-roasting of a fluxing agent. The method has the advantages of low-priced and easily bought raw materials, simple process, wide application range, and high added value. The calcium sulfate crystal whiskers prepared by the method have a big length-diameter ratio and regular shape, and can be used as reinforcing, heat insulating or flame retardant materials in industries of plastics, rubbers, coatings, papermaking, building materials and the like.

A method is provided which uses an improved emulsion to imparting water-resistance to gypsum products. In one embodiment, gypsum products comprise calcium sulfate dihydrate and an emulsion which comprises a saponified wax, a nonsaponifiable wax, an alkyl phenol, a surfactant/dispersant salt of polynaphthalenesulfonic acid, and carboxymethylcellulose. Optionally, the emulsions may contain a preservative, e.g., a biocide (mildewcide, fungicide, etc.). These gypsum products resist the uptake of water and therefore resist biological infestation without addition of a preservative.

The invention discloses a resource utilization method for titanium white by-product ferrous sulphate, which solves the technical problem of incomplete utilization of titanium white by-product ferrous sulphate with low cost in the prior art. The method of the invention comprises the following steps: a, purifying and processing titanium white by-product ferrous sulphate; b, introducing ammonia gas in a ferrous sulphate solution obtained by purifying and processing, fully reacting and filtering to obtain ferrous hydroxide deposition and an ammonium sulfate solution; c, adding calcium hydrate in the ammonium sulfate solution and fully reacting to obtain dihydrate calcium sulphate deposition and ammonia gas, recovering ammonia gas as a raw material of a step b, drying the dihydrate calcium sulfate deposition and processing to obtain the product gypsum. According to the invention, sulfur and iron resources in titanium white by-product ferrous sulphate are fully used for producing industrial grade gypsum and iron ore concentrate, the problem of titanium white by-product on environmental pollution is solved; The ammonia gas can be circularly used without consumption based on theory, the loss amount needs to be added in practical production, and the production cost is low.

The invention relates to a method for preparing the calcium sulfate with the sulfate-contained brine and the calcium-salt-contained brine; the two refined brines in a crystallization control reactor are uniformly and consecutively mixed with the cycling liquid inside a cycling lifting device to form dihydrate calcium sulfate crystal with large grain diameter; the dehydrate calcium sulfate crystal is centrifugally washed and dried to prepare the product of the high-purity dehydrate calcium sulfate. The flow rate of the refined sulfate-contained brine that is continuously added in a reaction crystallization barrel is determined according to the ratio between the flow rate of the refined sulfate-contained brine and the flow rate of the cycling liquid in the cycling lifting device in the reactor of 1:10 to 1:30. The flow rate of the refined calcium-salt-contained brine that is consecutively added is determined according to the mol ratio of 1:1 between the sulfate radical ion and the calcium ion in the refined sulfate-contained brine and the calcium-salt-contained brine.

The invention discloses a method for recovering high purity calcium hydrogen phosphate in sulfur acid-containing waste phosphoric acid, which comprises the following processes: adding 0.5% of active carbon powder in the sulfur acid-containing waste phosphoric acid, filtering and adding excessive calcium carbonate suspending liquid or a calcium hydrate emulsion, filtering to obtain dihydrate calcium sulfate and aluminium phosphate, adding calcium with theoretical amount of 0.95-1.1 mole time required by phosphoric acid in the obtained filtrate with the forms of calcium carbonate suspending liquid and the calcium hydrate emulsion, filtering and drying to obtain high purity dihydrate calcium hydrogen phosphate; adding purified water in the obtained high purity dihydrate calcium hydrogen phosphate, beating, controlling the concentration of the solid content at 10-30%, heating a slurry to the temperature of 90-100 DEG C, stirring and aging for 0.5-1.5 hours, performing solid-liquid separation, and drying to obtain the high purity dicalicium phosphate anhydrous. The method has the advantages of simple process and low cost, and effectively uses sulfuric acid and phosphoric acid in waste acid, and reduces the harm on environment.

A gypsum slurry includes calcium sulfate hemihydrate, water and calcium sulfate dihydrate is coated with a hydrophilic, dispersible coating. The coating is less soluble than the calcium sulfate hemihydrate to delay exposure of the landplaster to the remainder of the slurry, preventing premature crystallization and the early stiffening that accompanies it. Another embodiment is a gypsum slurry that includes calcium sulfate hemihydrate, a polycarboxylate dispersant, water and coated calcium sulfate dihydrate. In this case, the hydrophilic, dispersible coating is selected to serve as a modifier to enhance the ability of the dispersant to fluidize the gypsum slurry.

In a first embodiment of the invention, aged brushite is combined with calcium sulfate hemihydrate and water to make a gypsum slurry. Aged brushite slurry behaves similarly to calcium sulfate dihydrate to act as a seed crystal and rapidly initiate crystallization. The brushite slurry does not require the addition of a coating to maintain its activity over time compared to calcium sulfate dihydrate set accelerators. A gypsum-based product made using brushite slurry as the set accelerator is a second embodiment. The product has the brushite molecules integrated as part of the calcium sulfate dihydrate matrix and is distributed throughout the matrix.

The present invention provides a method for producing phosphoric acid by using 93%-98% concentrated sulfuric acid to extract phosphorus ore and its equipment. The sulfuric acid and phosphorus ore pulp are respectively added into two series-connected cylindrical reactor tanks with identical volume, according to a certain proportion, every reactor tank is equipped with several sulfuric acid distributors, surface cooling device and central stirring poddle with large circulation quantity, and the extraction reaction can be implemented in two reactor-tanks at the same time, and the operation condition of every reactor tank can be respectively controlled. Said invention can effectively raise extraction rate of P2O5, improve dihydrated calcium sulfate crystal and can raise filtering strength.

The invention relates to a coated granular fertilizer, preferably wherein granules are sulfate-based or phosphate-based. When sulfate based granules, as in ammonium sulfate, the coating substance is an inorganic salt of alkaline earth elements, preferably calcium, such that when applied to the surface of fertilizers, forms calcium sulfate, preferably a calcium sulfate-dihydrate, as a protective coating. For a reactive coating of a thiosulfate, free sulfuric acid present on the granule reacts to provide an elemental sulfur coating. For ammonium phosphate-based granules, coatings may comprise compounds of Ca⁺⁺, Al⁺⁺⁺ and/or Fe⁺⁺⁺ salts thereby forming a calcium, an aluminum, an iron, or mixed cation phosphate protective coating. Thiosulfate is also effective with phosphate based granules which are manufactured with sulfuric acid. Granules coated according to the disclosure have advantageous properties as the coating can be applied in a specified and sparing manner due to its tendency to adhere to surfaces during the reaction. Coated fertilizer granules of the disclosure are also advantageous in that, with regard to the applied amount of coating, they provide increased resistance to dusting in long term warehouse storage, to moisture uptake and to oxidative heating. Coating components also add nutrients to plants that can provide nutrients over a longer period of time such as a slow-release characteristic.

The present invention is directed to an improved gypsum board and a method of making such gypsum board. For instance, the method comprises: providing a first facing material, depositing a gypsum slurry comprising at least stucco and water on the first facing material, providing a second facing material on the gypsum slurry, and allowing the stucco to convert to calcium sulfate dihydrate, wherein the method further comprises a step of providing a dry starch layer including a dry starch at an interface between the first facing material and the gypsum slurry, the second facing material and the gypsum slurry, or both.

The invention provides a method for preparing manganese sulfate, manganese hydroxide and calcium sulfate, which comprises the following steps: pulverizing manganosite into coarse powder, soaking with titanium dioxide produced by a sulfuric acid method at 60-80 DEG C for 8-15 hours, performing suction filtration to obtain a clarified filtrate, adding manganese hydroxide for impurity removal so as to obtain a pure manganese sulfate solution; performing reduced pressure distillation of the pure manganese sulfate solution to obtain a saturated manganese sulfate solution, cooling, precipitating manganese sulfate crystals with crystal water, drying and crushing the manganese sulfate crystals to obtain a manganese sulfate crystal product; allowing the pure manganese sulfate solution to react with a calcium hydroxide solution under stirring, filtering the reaction product to obtain a calcium sulfate filter cake and a manganese hydroxide filtrate, performing reduced pressure distillation of the manganese hydroxide filtrate to obtain a supersaturated manganese hydroxide solution, performing cooling and crystallization to obtain manganese hydroxide crystals, drying and crushing the manganese hydroxide crystals to obtain a manganese hydroxide product; washing, drying, crushing the calcium sulfate filter cake to obtain a dihydrate calcium sulfate product.

The invention discloses medicinal powder for stopping toothache and a preparation method for the medicinal powder and relates to the field of traditional Chinese medicines. The medicine powder is prepared from the following components including menthol, calcium sulfate dihydrate, anhydrous calcium sulfate, honeysuckle, Japanese cinnamon fruits, radix rehmanniae, bamboo leaves and flos chrysanthemi, wherein the ratio of the menthol to the calcium sulfate dehydrate to the anhydrous calcium sulfate is 1 to 1 to 3; the ratio of the honeysuckle to the Japanese cinnamon fruits to the radix rehmanniae to the bamboo leaves to the flos chrysanthemi is 1 to 1 to 1 to 1; and the medicinal powder contains totally 5g of the trace honeysuckle, Japanese cinnamon fruits, radix rehmanniae, bamboo leaves and flos chrysanthemi per 100g. The medicinal powder is low in cost of the adopted raw materials, simple to prepare and remarkable in analgesic effect, is convenient for adults and children to use withmultiple use methods and does not have toxic or side effect.