803 results about "Reverse flotation" patented technology

The invention discloses a benefication method for recovering specularite. The method comprises the processes of primary grinding, grading, primary low intensity magnetic separation, and tailings discarding by primary high intensity magnetic separation; rough concentrate pre-classification by the primary low intensity magnetic separation and the primary high intensity magnetic separation, secondary grinding, secondary low intensity magnetic separation to obtain concentrates, secondary high intensity magnetic separation to obtain concentrates; and selective flocculation desliming secondary conducted on high intensity magnetic separation tailings (middlings), and anionic reverse flotation. The method further comprises the step of arranging a cylindrical slag separating sieve before the primary high intensity magnetic separation. With the advantages that the iron concentrate grade and the iron recovery are high, the loss of granular iron minerals is low, the mineral process flow is short, concentrates and tailings can be obtained in advance and the energy consumption of the benefication is low, the invention can be used not only for selecting specularite ores, but also for selecting weakly magnetic iron minerals, such as hematite, goethite, siderite, limonite, and the like.

The invention relates to a positive-negative floatation technology for cellophane, which comprises the following steps: subjecting siliceous-calcareous collophane ore to breaking and grinding process to dissociate ore monomer; adding water to it get ore pulp with concentration of 20 -50%; Leading the mixture to agitated tank; adding modifying agent sodium silicate and positive collector agent to ore pulp; processing the mixture in positive floating system to get foamed product; adding negative floatation agent inorganic acid and collector agent to the foamed product in negative flotation agitated tank; processing the mixture in negative floating system with carbonate vein mineral negative flotation to get foamed product as negative flotation debris and product in tank as clean ore. The invention can simplify process, deduce cost and recycle the water.

The invention relates to the field that biquaternary ammonium compounds are applied in silicate mineral flotation, and discloses a collector which applies the biquaternary ammonium compound with the constitutional formula shown as the formula I in bauxite or ironstone reverse flotation desiliconization. In the formula I, R<1> and R<2> are alkyls with 6-18 carbon atoms; R<3>, R<4>, R<5> and R<6> are respectively methyl, ethyl, -(CH2CH2O)nH, or -(CH(CH3)CH2O)nH, wherein, n is equal to 1-6; R<7> is alkylene with 2-6 carbon atoms; and X is Cl, Br or I. The collector of the invention has strong ability to collect quartz, kaolinite, illite and pyrophyllite, and is applicable to the silicate mineral separation from the bauxite or ironstone by reverse flotation, the suitable pH range of the flotation pulp is 5-13, and the dosage is equal to 50-500 g/t according to the content change of the silicate mineral in ores.

The invention relates to a low-temperature-resistant collophanite reverse-flotation collecting agent. The low-temperature-resistant collophanite reverse-flotation collecting agent is composed of a basic active flotation material, an auxiliary component and water, wherein the basic active flotation material is composed of, by weights, 10 parts to 30 parts of unsaturated sulfonated aliphatic acid and 50 parts to 80 parts of higher aliphatic acid, the auxiliary component is composed of, by mass, 5 parts to 10 parts of surface active agents, 5 parts to 15 parts of foaming agents and 10 parts to 20 parts of inorganic base, and the ratio of the sum of the mass of the basic active flotation material and the mass of the auxiliary component to the mass of the water ranges from 1:1 to 1:10. When the low-temperature-resistant collophanite reverse-flotation collecting agent is used for collophanite flotation, phosphorus concentrate with the low MgO content (1.60%) can be obtained, and the high P2O5 recovery rate (90.03%) can be achieved. The low-temperature-resistant collophanite reverse-flotation collecting agent has the advantages that the range of sources of raw materials is wide, the preparing technology is simple and easy to execute, the stability is high, the environmental friendliness is achieved, and the market promotion value is high.

The invention relates to a phosphorite reverse flotation process which comprises the following steps: after carrying out ore crushing, ore grinding and size mixing on phosphorite, enabling the obtained product to enter the reverse flotation process, wherein ore pulp obtained after size mixing is added with sulfuric acid or phosphoric acid to form a regulator and an inhibitor and then is added with micromolecule organic acid to form a combined inhibitor for inhibiting phosphate minerals; carrying out reverse flotation to separate out carbonate minerals by using fatty acids or fatty acid soaps as a collecting agent so as to obtain high-grade low-magnesium phosphate concentrates. The phosphorite reverse flotation process has the following advantage that the micromolecule organic acid inhibitor is adopted to implement effective separation of collophanite and dolomite, so that the grade of the phosphate concentrates is improved, the grade of tailings is reduced and the recovery rate can be improved. Meanwhile, application of phosphoric acid and derivatives thereof to phosphorite reverse flotation is replaced, so that phosphorus resources are saved, service time of phosphate rock resources is prolonged and the defects in the prior art are overcome.

The invention discloses a method for raising iron content and reducing silicon in concentrate by means of a low-intensity magnetic separation process. Aimed at the problems of floatation (reverse flotation) in the prior art in terms of raising iron content and reducing silicon in concentrate, a magnetic field screening method for separation and corresponding crashing and grinding process and equipment are adopted in order to achieve the goal of raising iron content and reducing silicon in concentrate. The method has the advantages of simple process, advanced equipment, low operating cost and remarkable economic benefit.

The invention relates to a new technology for sorting a lean red magnetite ore containing iron carbonate, which is characterized by comprising the following steps of: enriching and discarding tailings by adopting a 'technology for stage grinding and strong magnetic discarding tailings', thereby obtaining a mixed magnetic concentrate; sorting the mixed magnetic concentrate by adopting an 'open-circuit reverse flotation technology with one-stage roughing, one-stage fining and two-stage scavenging', thereby obtaining a high-grade hematite and magnetite concentrate; adopting a 'close-circuit centrifuge technology with one-stage roughing and one-stage fining' for sorting a high iron carbonate ore enriched in mine obtained by adopting the 'open-circuit reverse flotation technology', thereby obtaining a siderite concentrate; feeding the centrifuge tailings into a weak magnetic machine and sorting; and recycling fine fraction magnetic concentrates. The new technology provided by the inventionhas the advantages that the lean hematite and magnetite ore containing iron carbonate is sorted by adopting a 'combined sorting process flow with stage grinding, strong magnetic discarding tailings, reverse flotation-centrifuge', so that the sorting indexes of the whole iron grade of the obtained comprehensive concentrate being more than 65% and the metal recovery rate being more than 65% are achieved and the maximization of utilization benefit of iron ore resources is realized.

The invention discloses a flotation desliming process of collophanite. The flotation desliming process of collophanite comprises the following steps of: scrubbing collophanite crude ore; dividing the crude ore into a coarse fraction part and a fine fraction part according to different particle diameters of particles; feeding the coarse fraction part into a grinding and classification flow after getting the coarse fraction part through an ore washer; feeding into a hydraulic cyclone to deslime for the first time; feeding a settled sand part into a direct and reverse flotation flow after getting the settled sand part through the hydraulic cyclone to obtain flotation concentrate and flotation tailing; removing fine silt from the fine fraction part after getting the fine fraction part throughthe hydraulic cyclone; concentrating and filtering the flotation concentration to obtain finished products phosphate concentrate and concentrate backwater; concentrating and filtering desliming tailing of the ore washer, desliming tailing of the hydraulic cyclone and flotation tailing to obtain phosphorus tailing and tailing backwater; recycling the concentrate backwater and tailing backwater; and returning to each backwater utilization site in the ore washer or a flotation plant. According to the flotation desliming process, the flotation recovery rate and the concentrate grade can be improved, the agent consumption is reduced, and the utilization efficiency of flotation equipment is increased.

The invention belongs to the technical field of mineral engineering and provides a mineral processing technology for recycling fluorite from baotite, magnetite and tailing. In the tailing, mineral particle size of the fluorite is thin, iron-bearing mineral, rare-earth mineral, gangue mineral and the fluorite mineral are closely symbiotic and floatability of minerals such as rear earth, barite, apatite, calcite and dolomite is close to the fluorite mineral, so that separation of the fluorite mineral is difficult. According to the mineral processing technology for recycling the fluorite from the baotite, the magnetite and the tailing, priority desulfuration, rear earth flotation, ore grinding, iron selection through magnetic separation, fluorite selection through direct flotation and a reverse flotation sorting technology are performed on the magnetite and the tailing to enable pyrite, the rare earth, the iron-bearing mineral and the fluorite to be picked out in sections, efficient, high selective, easy-to-operate inhibitor and collecting agent combination is utilized in sorting of fluorite which is mostly performed monomer separation, so that fine fluorite of high grade and high recovery rate is obtained, a purpose of synthetically recycling valuable minerals is achieved, and effective separation of the fluorite mineral and the gangue mineral is achieved.

The invention relates to a coarse grain pre-selection and magnetic-floating separation process for mixed ores with embedded micro-fine particles. The coarse grain pre-selection and magnetic-floating separation process is characterized in that a 'half-self-grinding, wet-type pre-selection, continuous ore grinding, weak magnetic-strong magnetic fine screening and re-grinding and strong magnetic reverse flotation' operating system is adopted to sort the mixed ores with embedded micro-fine particles, and iron ore concentrates with grade of 65%-65.5% and yield of 35%-40% are obtained. The coarse grain pre-selection and magnetic-floating separation process has the advantages that 15%-20% large-particle qualified tailings are obtained from the ores through the wet-type pre-selection, the magnetic ores with yield of 15%-20% and grade of higher than 65% can be separated in advance through magnetic-floating separation, the ore feeding amount of separation operation is reduced, the number of flotation machines is decreased, agent using amount is decreased, and ore separation cost is reduced.

The invention discloses a method for separating oolitic hematite, and the process of the method comprises discarding tailings of ores by intense magnetic separation through stage grinding and stage separation, and de-phosphorizing and increasing iron to the intense magnetic concentrated by reverse flotation. The intense magnetic separation is functioned of concentrating iron minerals and desliming, thereby preventing smile from influencing flotation. The highly-effective regulator is made from sodium carbonate, sodium silicate and sodium hydroxide, the collecting agent is a composite medicine made from hydroximic acid and alkyl sulfate, and the method for separating oolitic hematite is a key technology for the reverse flotation to further upgrade the concentrate of iron ore. The invention has the advantages of simple technological process, low energy consumption, low cost and good product index, and solves the defects in prior art.

The invention relates to a method for separating and extracting feldspar ore with complex impurity components, which comprises the following steps of: 1) performing ball milling on the feldspar ore with complex impurity components through a ball mill; 2) performing classification and de-sliming on the milled feldspar ore by using an improved hydraulic classifier; 3) performing low-intensity magnetic separation on the classified feldspar ore through a low-intensity magnetic separator to obtain high-intensity magnetic substances and rough feldspar concentrate for high-intensity magnetic separation; 4) performing high-intensity magnetic separation on the rough feldspar concentrate obtained by the low-intensity magnetic separation through a high-intensity magnetic separator to obtain low-intensity magnetic substances and rough feldspar concentrate for flotation; and 5) performing size mixing and segmentation on the rough feldspar concentrate obtained by the high-intensity magnetic separation, adding a flotation agent, and performing reverse flotation, impurity removal and dehydration through a flotation machine to remove impurities and obtain fine feldspar and quartz mixed powder and flotation water.

The invention relates to phosphorite double-reverse flotation process, which comprises reverse flotation de-magging, desliming and pulp mixing and reverse flotation desilicication. The phosphorite double-reverse flotation process is characterized in that ore pulp after reverse flotation de-magging realizes desliming, the concentration of a desliming bottom flow and the content of fine particles are controlled, and reverse flotation desilicication is realized after pulp mixing of the bottom flow. The phosphorite double-reverse flotation process can eliminate or mostly remove interference of slime to reverse flotation desilicication, increases flotation efficiency, more importantly, improves fluidity of flotation foam, and lead phosphorite double-reverse flotation to be engineered.

The invention relates to a selective flocculation reverse flotation desilication process of collophanite containing primary slime. The process comprises the following steps of: adding a modifier sodium hydroxide or sodium carbonate to the pulp obtained after the collophanite containing primary slime is subjected to the reverse flotation demagging till the pH value of the slurry is between 9.5 and10.5; then, adding a dispersant water glass or alkali metal phosphate, a flocculant anionic starch and a collector ethers propylamine or alkyl diaminopropane for roughing and obtaining concentrate ina roughing groove; and adding a collector to roughed foam, concentrating, using concentrated foam as tailing, returning middling in a concentrating groove for roughing or mixing with the concentrate in the roughing groove into mixed phosphor concentrate, wherein flotation machine impellers have the rotating speed of 1900-2400 rounds/min. In the process provided by the invention, the anti-flotation separation of siliceous gangue of quartz class is realized by adjusting the pH value of the slurry, adding various agents and selectively flocculating and inhibiting the collophanite according to the surface acting force of the various medicaments on the collophanite surface, and the optimal separation effect is achieved through adjusting the rotating speed of the flotation machine impellers.

The invention relates to a method for preparing ultralow-metallic-element ultrahigh-purity quartz through mixed acid hot-pressing leaching reaction. The method is characterized by comprising the following steps of crushing and classifying; performing magnetic separation; performing three-section preferential reverse flotation; performing roasting and water quenching; performing hot-pressing leaching, namely putting a product of roasting and water quenching in a reaction kettle, and performing hot-pressing acid leaching reaction in a mixed acid system while stirring, wherein the reaction temperature is 120-400 DEG C, the reaction pressure is 0.5-15.0MPa, the reaction time is 0.5-8h, and the mixed acid system for the hot-pressing leaching chemical reaction is a mixed solution of HF, HNO3 and HCl; after hot-pressing acid leaching, filtering and washing the product until the product is neutral, and drying to obtain the ultralow-metallic-element ultrahigh-purity quartz. The purification method is simple in process and easy to operate; the ultralow-metallic-element ultrahigh-purity quartz of which the SiO2 content reaches 99.995wt%, preferably 99.999wt%, can be prepared by the method.

The invention relates to a collophane low-temperature reverse flotation collector and a preparation method thereof. The collector is prepared by mixing basic substance with water in a weight ratio of 1:20-100, wherein the basic substance comprise the following components by weight percent: 90-95% of higher fatty acid soap with the fatty acid content of no less than 40% and 5-10% of terpenol. The collector is characterized in that the grade of the selected crude ore is low, the applicable scope is wide, the recovery rate of the concentrate is high, the MgO content of the concentrate is low and the cost of ore dressing is low. Compared with the prior art, the gelation of the collector is difficult to appear below 10 DEG C, the flotation index is qualified and the collector can adapt to the low-temperature flotation.

The invention provides a beneficiation method for high iron bauxite. The invention adopts strengthening magnetic separating-anionic reverse flotation flow, stage grinding and stage magnetic separating. Under the condition of ensuring the magnetic separating iron concentrate recovery rate, strengthening magnetic separating has the priority to obtain higher quality aluminum concentrate one and high grade iron rough concentrate, thus improving the selection grade of the reverse flotation and opening circuit fully in the reverse flotation process, a reverse flotation rougher flotation device adopts a flotation column with large charge and fine even bubbles, thus obtaining iron concentrate with higher quality. In addition, the beneficiation method optimizes and reduces the production rate of material entering reverse flotation operation, and achieving the purposes of energy saving and consumption reducing.

The invention relates to a mineral separation process for magnetic hematite rough concentrates, which comprises the following steps of: feeding the magnetic hematite rough concentrates into a closed circuit grinding system; once grading, overflowing and feeding into weak magnetism at first section; feeding the concentrates in the weak magnetism at the first section into a dewatering tank; feedingthe concentrates in the dewatering tank into a fine sieve; returning rough particle products on the sieve into the first section for grinding; feeding fine particle products under the sieve into weakmagnetism at second section; mixing tailings in the weak magnetism at the second section, tailings in the weak magnetism at the first section and tailings in the dewatering tank to obtain low intensity magnetic separation tailings; concentrating the low intensity magnetic separation tailings by a concentrating machine; feeding into a closed circuit regrinding system; grading, overflowing and feeding again into strong magnetism; concentrating strong magnetic concentrates by the concentrating machine; feeding into a negative ion reverse flotation process including one-time rough separation, one-time fine separation and three-time scavenging; combining the strong magnetic tailings with the floatation tailings to obtain final tailings; and combining the concentrates in the weak magnetism at the second section with the flotation concentrates to obtain final concentrates. The mineral separation process provided by the invention is simple, high-efficiency, particularly low-cost, good in effect and high in concentrate quality and metal recovery rate, and realizes high-efficiency utilization of resources.

The invention relates to a branch flotation technology for collophanite, which comprises the following steps: crushing and grinding silicon calcium collophanite ores, and then adding water and mixing into slurry, and guiding the slurry to flow into a flotation groove; adding a regulator and a collecting agent for mixing the slurry, and then pouring into a reverse flotation system for performing reverse flotation, wherein products in the groove are reverse flotation concentrates; grading the reverse flotation concentrates into coarse fraction and fine fraction; pouring the coarse fraction partinto a desilicification reverse flotation groove, adding a desilicification regulator and a desilicification collecting agent for mixing the slurry, and then pouring into a desilicification system for performing reverse flotation, wherein products in the groove are desilicification reverse flotation concentrates; pouring the fine fraction part into a normal flotation groove, adding a normal flotation pH (Potential of Hydrogen) regulator, the regulator and the collecting agent for mixing the slurry, and then performing normal flotation, wherein foam products of the normal flotation are normal flotation concentrates; mixing the normal flotation concentrates with the desilicification reverse flotation concentrates, thereby forming the final phosphorus concentrates; and concentrating, filtering and drying, thereby obtaining phosphorus concentrates. The branch flotation technology for collophanite has the advantages that the separation efficiency is high, the technic index is excellent, the content of MgO in the obtained phosphorus concentrates is lower, the quality of the concentrates is high, and the comprehensive cost of the final product of the phosphor concentrates is lower.

The invention discloses a compound maghemite ore dressing method. The compound maghemite ore dressing method comprises the following steps: feeding compound maghemite ore into an ore grinding-grading-low-intensity magnetic separation operation segment to obtain low intensity magnetic separation concentrate and low-intensity magnetic separation tailings; feeding the low-intensity magnetic separation concentrate into a fine sieving operation segment to obtain finely-sieved concentrate C1; feeding the low-intensity magnetic separation tailings into a high-intensity magnetic separation operation segment, and throwing out high-intensity magnetic separation tailings T1 to obtain high-intensity magnetic separation concentrate; combining coarse fraction low-intensity magnetic separation concentrate with the high-intensity magnetic separation concentrate, and feeding the mixture into a pre-grading-two-stage ore grinding-reverse flotation operation segment to obtain reverse flotation concentrate C2, and throwing out reverse flotation concentrate T2. In the method, staged ore grinding and high-intensity tailing throwing are adopted, so that discarding as soon as possible is realized; the low-intensity magnetic separation concentrate is obtained by fine sieving, so that collection as soon as possible is realized; oversize finely-sieved and high-intensity coarse concentrate is ground, so that the amount of ore ground at a second segment is lowered greatly, and energy-saving and consumption lowering are facilitated; an oversize finely-sieved product is reground and floated, so that the flotation grade is raised, and the adaptability of negative ion reverse floatation to ore characteristic fluctuation is improved.

The invention discloses composite modified starch as a hematite reverse flotation inhibitor and a preparation method thereof. The composite modified starch comprises 100 weight portions of raw material starch, 0.5-10 weight portions of sodium hypochlorite as an oxidizing agent, 1.2-7.0 weight portions of sodium hydrosulphite, 0.2-1.2 weight portions of sodium nitrite as esterification reagents, 0.5-3.5 weight portions of 3-chloro-2-hydroxypropyl-trimethyl quaternary ammonium salt as a cationic reagent, 3.0-7.0 weight portions of caustic alkali, and 25-40 weight portions of water. The composite modified starch contains carboxylic groups, sulfonic anions, and quaternary ammonium cations, and has the advantages of cold water solubility and low viscosity, and has the advantages of increasing the yield of hematite concentrate, improving the filtering conditions of iron ore pulp, and the like.