The invention discloses a method for preparing a
perovskite solar cell by passivating the surface of pure-phase two-dimensional
perovskite, and belongs to the technical field of
perovskite solar cells. The method comprises the following steps: synthesizing a pure-phase two-dimensional material by using an amine /
ammonium compound, dissolving the pure-phase two-dimensional material in an organic solution, dynamically spin-
coating the pure-phase two-dimensional material on the surface of three-dimensional perovskite, and annealing to form a pure-phase two-dimensional perovskite
passivation layer. The pure-phase two-dimensional perovskite
passivation layer with a
wide band gap is applied to the top of the three-dimensional perovskite, so that
energy level alignment between the perovskite layer and the charge
transport layer can be improved, and electrons are effectively prevented from penetrating through the perovskite and a
hole transport layer interface; meanwhile, the pure-phase two-dimensional perovskite
passivation layer can effectively passivate surface defects of the three-dimensional perovskite thin film; the two-dimensional material has good hydrophobicity, degradation of the perovskite material caused by
moisture can be reduced, and the long-term stability of the device can be improved. According to the method, the photovoltaic performance of the
cell can be effectively improved, and the efficient and stable
perovskite solar cell is obtained.