The application discloses a
cerium ion coordination terpyridyl group anti-
corrosion and
flame-retardant dual-functional filler, a preparation method and application thereof, and has a
structural formula. The application has the dual-functional characteristics of anti-
corrosion and
flame-retardation, uses a
siloxane skeleton structure as a connecting agent to improve the
toughness of EP; DOPO contains
phosphorus elements, and a
phosphorus compound can be decomposed at high temperature to generate
phosphorus oxide, and these oxides can form a protective layer in a
flame to reduce the interaction between
oxygen and combustible materials, and the
combustion reaction is slowed down or inhibited;
pyridine can adsorb
metal ions in a corrosive environment to play an anti-
corrosion role; meanwhile, N atoms on the
pyridine ring can generate N2 in the
combustion process, which can dilute the
oxygen concentration in the gas and play an important role in the
intumescent flame-retardant process; Ce 3+ is coordinated with
pyridine to form a coordination compound, a dense adsorption film is formed on the surface of a matrix, and corrosion protection is provided; meanwhile, it can combine a plurality of
small molecule monomers to form a
long chain chelate, and the performance of the filler is further improved.