2280 results about "Butanediol" patented technology

The invention discloses an anti-allergy soothing composition as well as a preparation method and cosmetics thereof. The anti-allergy soothing composition comprises the following components in percentage by mass: 2%-8% of a cactus extract, 1%-5% of a radix scutellariae root extract, 0.5%-3% of a Chinese herbaceous peony root extract, 2%-5% of a radix ophiopogonis root extract, 2%-5% of an oat bran extract, 40%-50% of butanediol and the balance of water. The composition has good anti-allergy and soothing effects, when the composition is applied to skin care products and cosmetics, the cosmetics can have the good anti-allergy and soothing effects, and the skin care products and the cosmetics can have good universality. Meanwhile, the preparation method of the anti-allergy soothing composition is simple and easy to implement and easy to popularize and use.

The present invention relates to the field of biomedicine technology, specifically a preparation method of a silk fibroin hyaluronic acid filler for injection. The present invention concentrates a silk fibroin solution to obtain a concentrated silk fibroin solution, and then dilutes it to obtain a diluted silk fibroin solution; the diluted silk fibroin solution is heated to form a silk fibroin gel, granulated to obtain silk fibroin gel particles; 1,4-butanediol diglycidyl ether and a sodium hydroxide solution are mixed uniformly, hyaluronic acid and 1 / 3 of the mass fraction of hydroxyapatite are added, after stirring uniformly, swelling, purification and granulation are carried out, and the remaining mass fraction of hydroxyapatite is added to obtain composite gel particles; the composite gel particles and the silk fibroin gel particles are mixed uniformly, added to the gel to mix, and a silk fibroin hyaluronic acid filler is obtained, which effectively prolongs its degradation time.

The invention relates to the field of hot melt adhesives, and discloses a biodegradable hot melt adhesive based on castor oil and rosin resin and a preparation process thereof, the biodegradable hot melt adhesive comprises EVA resin, modified castor oil, rosin resin, a modified additive, a lubricant and an antioxidant; the modified castor oil is prepared by crosslinking castor oil and isophorone diisocyanate and reacting lignin, 1, 4-butanediol and isocyanate groups; the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, and the modified castor oil and the modified additive are added, so that the modified castor oil and the modified additive are added, and the modified castor oil and the modified additive are added; the tensile property and the adhesive property of the hot melt adhesive are improved, and meanwhile, the flame retardant property and the high and low temperature resistance of the hot melt adhesive can be improved.

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The invention provides a robot joint dynamic cable made of a self-repairing polyurethane material and a preparation method of the robot joint dynamic cable, and belongs to the field of cables. Polytetrahydrofuran glycol and hexamethylene diisocyanate react to form a soft and hard segment structure, 1, 4-butanediol is added for chain extension, dopamine hydrochloride is introduced, the hard segment structure is enhanced, and a self-repairing hydrogen bond network is formed; carbon nanotubes are introduced, and through plasma treatment and silane coupling agent modification, the tensile resistance, fatigue resistance and electrical properties of the material are improved; montmorillonite is compounded with polyethyleneimine through organic treatment, so that the cracking resistance and wear resistance of the material are enhanced; epoxy groups are introduced to the surface of boron nitride, and dopamine hydrochloride is self-polymerized, so that excellent heat dissipation capability and dimensional stability are provided. Through the synergistic effect of the components, the composite material has excellent mechanical properties, electrical properties, heat dissipation, wear resistance and the like, is especially suitable for a dynamic cable of a robot, and can stably work in a complex environment for a long time.

The invention discloses a preparation method of a non-additive nitrogen-phosphorus-cerium synergistic flame-retardant polyurethane elastomer, and the polyurethane elastomer is prepared by taking isocyanate as a hard segment and poly (1, 4-butanediol adipate) as a soft segment, and compounding the hard segment and the soft segment with 2-amino-4-hydroxy-6-methylpyrimidine, a phosphorus reactive flame retardant and cerium oxide. The preparation method is simple, the process is easy to control, and the prepared polyurethane elastomer has good tensile strength; besides, the limit oxygen index of the polyurethane elastomer reaches 27.4, the polyurethane elastomer meets commercial standards of flame-retardant materials and UL-94 V-0 flame-retardant grade requirements, the ultraviolet band light transmittance is 0%, ultraviolet rays can be completely isolated, and the polyurethane elastomer has a good anti-oxidation function and can be applied to the industries of wires, cables, pipe profiles, films, general molding and the like.

The invention relates to the technical field of adhesives, and discloses an antibacterial mildew-proof water-based adhesive and a preparation method thereof. The preparation method of the antibacterial and mildew-proof water-based adhesive comprises the following steps: reacting 2, 2-dimethylolpropionic acid with castor oil to obtain hyperbranched bio-based polyol; modifying the hyperbranched bio-based polyol by using a modifier to obtain modified bio-based polyol; the preparation method comprises the following steps: preparing a waterborne polyurethane dispersion liquid by taking modified bio-based polyol, a hybrid modified BN / MOF composite material and hexamethylene diisocyanate as raw materials and 1, 4-butanediol as a chain extender; the preparation method comprises the following steps: mixing a waterborne polyurethane dispersion liquid, a wetting agent, a defoaming agent, a thickening agent and water to obtain a component A; an aliphatic curing agent is used as a component B; during use, the component A and the component B are mixed and stirred. The antibacterial and mildewproof water-based adhesive disclosed by the invention has excellent adhesion performance, water resistance, self-repairing performance and lasting antibacterial and mildewproof performance.

The invention discloses a collagen composition for skin substrate repair and skin care application thereof, and the collagen composition comprises the following components: 1-3% of soluble III-type collagen, 1-5% of hyaluronic acid, 1-2% of plant extract, 0.1-0.5% of allantoin, 0.2-0.5% of dipotassium glycyrrhizinate, 1-5% of glycerol, 1-5% of butanediol, 1-5% of 1, 2-propylene glycol, 1-5% of 1, 3-propylene glycol, 1-5% of propylene glycol and the balance of water. The cleaning agent is prepared from the following components in percentage by weight: 1 to 2 percent of 1, 2-hexanediol, 0.1 to 0.5 percent of phenoxyethanol, 0.1 to 0.5 percent of ethylhexylglycerin, 0.1 to 0.5 percent of carbomer, 0.1 to 0.5 percent of triethanolamine and the balance of water. The collagen III is added, so that the problems of wrinkles and skin aging are remarkably relieved. According to the skin-care lotion, the oily composition and the water-based composition are reasonably proportioned, so that excellent moistening and moisturizing effects are provided, the moisture balance of the skin is favorably maintained, and the skin is kept soft and moist. The added plant extract, hydrolyzed protein and mineral substances not only nourish and repair the skin, but also can improve various skin problems, enhance the endurance capacity of the skin and avoid the condition that the skin wrinkles are increased during the period of stopping using.

The invention discloses an anti-pollution flashover coating with arc durability, which comprises the following components in parts by weight: 100 parts of hydroxyl-terminated polydimethylsiloxane, 10-25 parts of dimethyl silicone oil, 5-15 parts of a phosphorus flame retardant, 8-20 parts of white carbon black, 5-15 parts of modified mica powder, 15-30 parts of modified calcium carbonate, 10-20 parts of modified glass powder, 5-12 parts of aluminum hydroxide, 5-10 parts of 1, 3-butanediol, 5-10 parts of a flame retardant, 1-5 parts of an anti-aging agent, 1-5 parts of an anti-aging agent, and 1-5 parts of an anti-aging agent. The invention discloses a high-temperature-resistant coating which is prepared from the following components in parts by weight: 0.5-2 parts of 1, 2-bis (trimethoxysilyl) ethane, 5-10 parts of potassium titanate whiskers, 2-6 parts of color paste, 50-150 parts of a solvent, 3-10 parts of a cross-linking agent, 2-6 parts of a silane coupling agent and 1-5 parts of a catalyst. The invention also provides a preparation method of the anti-pollution flashover coating with arc durability. By introducing the modified mica powder, the modified glass powder and the modified calcium carbonate with specific particle sizes and reasonable gradation, the proportion of the filler in the base rubber is ensured, so that the modified mica powder, the modified glass powder and the modified calcium carbonate form a compact and firm ceramic high-temperature-resistant and arc-resistant layer after encountering high temperature of an arc; and the purpose of improving the arc durability is achieved.

The invention discloses herbal oil control essence. A component A comprises deionized water and sodium hyaluronate; the component B comprises methylpropanediol, a hyperforin perforatum flower / leaf / stem extract, cyclodextrin and a rehmannia chinensis root extract; the component C is prepared from water, butanediol, amur corktree bark extract, coptis root extract, radix sophorae flavescentis extract, rhus chinensis insect gall extract, cnidium monnieri fruit extract, zanthoxylum bungeanum fruit extract and camphor tree leaf extract; and the component D comprises 1, 2-hexanediol. The preparation method of the herbal oil-control essence comprises the following steps: S1, preparing raw materials; s2, preparing the component A; s3, preparing the component B; s4, preparing a component C; s5, a mixing process; and S6, adding a component D and carrying out post-treatment. The herbal components form a synergistic effect network and act on a skin grease secretion system in a targeted manner, grease secretion is balanced from the source by adjusting the biological activity of sebaceous gland cells, meanwhile, biological signal channels related to skin anti-inflammation, moisturizing and tightening are activated, and the multiple-effect-in-one skin care effect is achieved.

The utility model provides an emission reduction system for producing tetrahydrofuran from 1, 4-butanediol, and relates to the technical field of chemical production equipment. By arranging the 1, 4-butanediol raffinate separation unit, the 1, 4-butanediol raffinate generated in the tetrahydrofuran production unit can directly enter the film evaporator to be separated, the light component 1, 4-butanediol is rapidly evaporated and flows out from the first gas phase outlet, and the light component 1, 4-butanediol is condensed by the gas phase condenser and then returns to the tetrahydrofuran production unit to serve as a raw material to be recycled. And heavy components of tar in the film evaporator flow out from a first liquid phase outlet at the bottom and are discharged and incinerated. The system can further separate the 1, 4-butanediol raffinate generated in the tetrahydrofuran production unit, and recycle the 1, 4-butanediol in the raffinate, so that the material waste of the 1, 4-butanediol is reduced, and the utilization rate of the 1, 4-butanediol raw material is improved. And meanwhile, the 1, 4-butanediol residual liquid discharge incineration treatment amount is greatly reduced, energy conservation and emission reduction are achieved, and the production cost is reduced.

The invention relates to a whitening composition containing pH-sensitive oxidized resveratrol hydrogel and application. The whitening composition is a composition of oxidized resveratrol hydrogel, a hydrolyzed opuntia pear flower extract and a mexican agastache rugosus flower / leaf / stem extract in a weight ratio of 1: (0.6-0.7): (0.01-0.02). The oxidized resveratrol hydrogel is prepared from the following raw materials in percentage by weight: 1 to 3 percent of oxidized resveratrol, 1 to 3 percent of 3-o-ethyl ascorbic acid, 15 to 20 percent of butanediol, 0.1 to 0.5 percent of sodium alginate, 0.1 to 0.5 percent of carboxymethylcellulose, 0.3 to 0.8 percent of calcium chloride and the balance of water. The three components of the whitening skincare product have a remarkable synergistic effect in the whitening aspect, the skin color can be jointly improved from different mechanisms, and meanwhile, the mildness and the safety are considered.

The invention discloses an anti-hair loss shampoo capable of effectively inhibiting bacteria and controlling oil and a preparation method of the anti-hair loss shampoo, and belongs to the technical field of anti-hair loss shampoo. The anti-hair loss shampoo is prepared from the following components in percentage by weight: 0.2 to 0.5 percent of plant extract nano-liposome, 0.5 to 1.5 percent of surfactant, 0.5 to 1 percent of nitrilotriacetic acid, 0.2 to 0.8 percent of EDTA (Ethylene Diamine Tetraacetic Acid) disodium, 0.1 to 0.5 percent of D-panthenol, 0.5 to 1 percent of piroctone olamine salt, 1 to 5 percent of glycerol, 1 to 5 percent of 1, 3-butanediol, 0.4 to 0.8 percent of hyaluronic acid, 0.2 to 0.5 percent of preservative, 0.2 to 0.5 percent of essence, 0.5 to 1 percent of thickening agent and the balance of deionized water. 0.1-0.3% of tocopherol and the balance of water. According to the invention, a plurality of natural plant extracts with bacteriostatic, oil-control and anti-hair-loss effects are screened and are wrapped by using a nano-liposome technology, and other functional components are reasonably matched, so that the preparation of the efficient, stable and mild anti-hair-loss shampoo capable of effectively inhibiting bacteria and controlling oil is realized, the scalp environment is improved from multiple aspects, and the anti-hair-loss effect is improved. The hair loss problem is effectively reduced, and the requirements of people on anti-hair loss hair washing products are met.

The invention relates to the field of wear-resistant fabrics, and discloses a high-strength wear-resistant fabric and a preparation method thereof.The high-strength wear-resistant fabric comprises a surface coating and a base cloth layer, the surface coating and the base cloth layer are formed by coating and drying modified waterborne polyurethane emulsion, and the modified waterborne polyurethane emulsion comprises isophorone diisocyanate, ethylene glycol terephthalate, 2, 3, 4-trimethyl-1, 3-pentanediol monoisobutyrate, polyisobutylene glycol monoisobutyrate, according to the present invention, 2, 2-dimethylolpropionic acid, a modified additive, a flame retardant modifier, 1, 4-butanediol, trimethylolpropane and the like are adopted to prepare the modified additive, dopamine is subjected to in-situ auto-polymerization on the surface of a titanium dioxide nanotube, nano-silica is grown on the surface in situ, and modification is performed through a polysiloxane solution to prepare the modified titanium dioxide nanotube flame retardant; the polysiloxane solution is prepared by carrying out a reaction on methyl triethoxysilane and dihydroxyl-terminated polydimethylsiloxane; the flame-retardant modifier is prepared by reacting 2-chloro-4, 6-diamino-1, 3, 5-triazine, 5-hydroxymethylfurfural and phosphorous acid, so that the fabric is endowed with good mechanical properties and wear resistance, and the fabric has a hydrophobic surface and is excellent in flame retardance and durability.

The invention discloses a preparation method of sandwich type immunomagnetic beads with high thermal stability, which comprises the following steps: by taking polystyrene microspheres as a template, introducing oil-phase Fe3O4 nanoparticles into the polystyrene microspheres through a swelling method, and then carrying out hydrolytic condensation reaction on the surface of a microsphere assembly by utilizing n-octyltrimethoxysilane OTMS to obtain the sandwich type immunomagnetic beads with high thermal stability. The preparation method comprises the following steps: carrying out surface amination modification on a silicon dioxide thin layer which is grown by hydrolysis of tetraethoxysilane TEOS to realize coating of an outermost organic shell layer, carrying out surface amination modification, and carrying out cross-linking on 1, 4-butanediol diglycidyl ether and erythritol on the surface to form an epoxy polymer layer so as to obtain the sandwich-type immunomagnetic bead with a cross-linked epoxy polymer layer introduced to the outer layer. According to the epoxy group modification process on the surface of the magnetic bead, a direct cross-linking modification process is adopted, so that the operation steps are simplified, and the obtained epoxy group magnetic bead is ensured to show excellent biocompatibility. In addition, the method omits the tedious process of functional group activation, and allows direct coupling with the antibody, thereby greatly improving the efficiency and convenience of the experiment.

The invention provides a modified amine curing agent, a preparation method, epoxy resin anticorrosive paint and application, and belongs to the technical field of paint. The modified amine curing agent provided by the invention is prepared from preparation raw materials including alicyclic diamine, m-xylylenediamine, a first glycidyl ether reagent, a second glycidyl ether reagent and a glycidyl ester reagent through amination reaction, the alicyclic diamine contains at least one primary amine group; the first glycidyl ether reagent is ethylene glycol diglycidyl ether and / or bisphenol A type diglycidyl ether; and the second glycidyl ether reagent is 1, 4-butanediol diglycidyl ether and / or C12-14 glycidyl ether. The modified amine curing agent is combined with the curing characteristics of amide and phenolic aldehyde amine, the epoxy resin anticorrosive paint prepared from the modified amine curing agent has a proper curing speed, the adhesive force of a cured coating is high, the anticorrosive effect is good, and the epoxy resin anticorrosive paint is particularly suitable for a high-humidity environment and an underwater environment.

The invention relates to the field of fermentation processes, in particular to a method for preparing 1, 4-butanediol through multi-strain synergistic fermentation, which comprises the following steps: inoculating a first strain and a second strain into a culture medium containing glucose and / or xylose for synergistic fermentation, producing ornithine by the first strain by taking glucose and / or xylose as a substrate, and converting ornithine into 1, 4-butanediol by the second strain. The invention discloses 1, 4-butanediol. Glucose is converted into ornithine through the first strain, ornithine is converted into 1, 4-butanediol through the second strain, the first strain and the second strain are subjected to synergistic fermentation, preparation of 1, 4-butanediol through microbial synergistic fermentation is achieved, and higher metabolic capacity and higher production efficiency are achieved. The mixed sugar of xylose and glucose prepared from biomass raw materials is used as a substrate for fermentation, so that the method has the advantages that the raw materials are easy to obtain, renewable and low in cost, and the production cost can be reduced.

The invention belongs to the technical field of coatings, and discloses an anti-yellowing and high-hardness UV (ultraviolet) laminating varnish as well as a preparation method and application thereof. The UV film coating varnish comprises six-functionality alicyclic polyurethane acrylic resin, two-functionality linear polyurethane acrylic resin, pure acrylic resin, an acrylate reactive diluent, a filler, an ultraviolet light absorber, a non-alkaline hindered amine free radical scavenger and a photoinitiator. The weight ratio of the six-functionality alicyclic polyurethane acrylic resin to the two-functionality linear polyurethane acrylic resin to the pure acrylic resin to the acrylate reactive diluent is (2.5-3.5): (1-1.5): 0.5: (2.0-3.0); the bifunctional linear polyurethane acrylic resin is prepared from the following raw materials: isocyanate, poly (1, 4-butanediol) and hydroxyethyl acrylate. A paint film formed by the UV film-coated varnish has good yellowing resistance and high hardness, and is not easy to crack after thermal cycling.

The invention provides a bio-based 1, 4-butanediol composition and a preparation method thereof, and polyester prepared from the bio-based 1, 4-butanediol composition, the bio-based 1, 4-butanediol composition comprises bio-based 1, 4-butanediol, an acidic compound, a nitrogen-containing compound and acetal; the content of acetal in the bio-based 1, 4-butanediol composition is less than or equal to 195ppm. According to the invention, polyester prepared by taking the bio-based 1, 4-butanediol composition as a raw material has a low color value and a low melt index.

The invention discloses collagen polypeptide firming and anti-wrinkle freeze-dried powder, and relates to the technical field of cosmetics. The invention relates to a biological preservative which is prepared from water, butanediol, a bacillus / soybean fermentation product extract, soluble collagen, acetyl hexapeptide-8, panthenol, 1, 2, 4-trimethyl-1, 3-pentanediol and a proper amount of water. The cosmetic is prepared from 1, 2-hexanediol, tetrahydromethylpyrimidine carboxylic acid, hydroxypropyl tetrahydropyrantriol, tremella polysaccharide, saccharide isomeride, a bifidus yeast fermentation product lysate, sodium hyaluronate, DNA sodium, a radix gentianae extract, mannitol, palmitoyl tripeptide-1, palmitoyl tetrapeptide-7, oligopeptide-1, decapeptide-4, oligopeptide-3, hydrolyzed royal jelly protein, folic acid and disodium hydrogen phosphate. The additive is composed of sodium dihydrogen phosphate, citric acid and sodium citrate. The mask can provide rich nutrients for skin, deeply care the skin, moisturize and relieve the skin, tighten the skin, resist wrinkles and make the skin moisturized, glossy, elastic and tight, and is high in use safety and wide in application prospect.

The invention discloses a polyurethane protective adhesive tape for aviation and a preparation method thereof, and relates to the technical field of adhesives. When the polyurethane protective adhesive tape for aviation is prepared, polyester glycol, an ultraviolet absorption monomer, 3-(4-pyridyl) pentane-1, 5-diol, 1, 4-butanediol and isophorone diisocyanate are polymerized to prepare polyurethane; the preparation method comprises the following steps: carrying out a reaction on polyurethane and 2-bromoethyl acrylate to prepare modified polyurethane; enabling the pretreated magnesium hydroxide to react with 3-epoxypropoxy-1, 1, 3, 3-tetramethyldisiloxane and ammonia water in sequence, so as to obtain modified magnesium hydroxide; the modified polyurethane and the modified magnesium hydroxide are mixed and then subjected to compression molding to prepare a polyurethane film; and coating a polyurethane film with the polyacrylate glue solution, and drying to obtain the polyurethane protective adhesive tape for aviation. The polyurethane protective adhesive tape for aviation prepared by the invention has excellent flame-retardant, anti-aging, antibacterial and self-repairing properties.

The invention discloses a method for increasing the content of pyrazines and 2, 3-butanediol substances through high-temperature Daqu micro-ecological regulation and control, and belongs to the technical field of microbial food processing. The invention discloses a method for improving the content of pyrazines and 2, 3-butanediol substances through micro-ecological regulation and control of high-temperature yeast for making hard liquor, and the method comprises the following steps of: combining and inoculating strains, namely bacillus subtilis CGMCC (China General Microbiological Culture Collection Center) 10830, bacillus velezensis CGMCC 7044 and bacillus licheniformis CGMCC 20675, into wheat flour according to a proportion to prepare the high-temperature yeast for making hard liquor. According to the invention, not only are the contents of pyrazine substances and 2, 3-butanediol increased, but also the abundance of beneficial microorganisms such as bacillus, thermophilic fungi and the like is remarkably improved, and a good saccharification fermentation agent is provided for brewing high-quality white spirit.

The invention relates to the technical field of polyurethane adhesives, and provides a heat-conducting polyurethane structural adhesive and a preparation and use method thereof.The heat-conducting polyurethane structural adhesive comprises a first component and a second component, and the first component comprises modified bio-based polyol, polythiol, heat-conducting filler, a first water removal agent, a thixotropic agent, a first catalyst and a second catalyst; the second component comprises epoxy resin, diisocyanate, polyisocyanate, a heat-conducting filler, a coupling agent, a second dewatering agent, a dispersing agent and a retarder; the modified bio-based polyol is selected from at least one of modified castor oil polyol, modified grease polyol and modified cashew nut shell oil polyol; the polythiol is selected from at least one of trimethylolpropane tri (3-mercaptopropionic acid ester), pentaerythritol tetra (3-mercaptopropionic acid ester), butanediol mercaptopropionic acid ester and polythiol. Through the arrangement, the heat-conducting polyurethane structural adhesive has relatively long openable time, and is rapidly cured at room temperature within a short time to generate relatively high initial curing strength.

The present invention relates to a recombinant Escherichia coli strain for producing 1, 3-butanediol from glucose and a method for producing 1, 3-butanediol by using the same, in which a recombinant Escherichia coli strain is developed in which a gene of a pathway required for biosynthesis of 1, 3-BDO from acetyl-CoA is cloned, and removing genes interfering with the pathway or a pathway competing with the pathway. Furthermore, a strain of Escherichia coli has been developed in which the pathways and genes involved in the conversion of glucose to acetyl-CoA, the rate of regeneration of NADPH used as a cofactor, and the effective utilization of the TCA cycle pathway are modified and optimized, which are necessary to improve the biosynthesis efficiency of 1, 3-BDO. Therefore, the recombinant Escherichia coli strain of the present invention can produce 1, 3-butanediol from glucose at high concentration, high yield, and high rate.

The invention relates to the technical field of flame-retardant materials, and particularly discloses a graphene-modified flame-retardant polyurethane material and a preparation method thereof.The graphene-modified flame-retardant polyurethane material is prepared from, by weight, 60-70 parts of polyhydric alcohols, 30-40 parts of isophorone diisocyanate, 0.4-0.8 part of dibutyltin dilaurate, 3-6 parts of dimethylolpropionic acid, 15-20 parts of composite flame retardant, 2-4 parts of 1, 3-butanediol, 2-4 parts of 1, 3-butanediol, 2-4 parts of 1, 3-butanediol, 2-4 parts of 1, 3-butanediol, 2-4 parts of 1, 3-butanediol, 2 and 1 to 3 parts of 1, 4-butanediol and 1 to 3 parts of perfluorooctyltriethoxysilane. The preparation method comprises the following steps: 1) preparing castor oil-based polyester polyol through hydroxylation reaction and polycondensation; 2) taking graphene oxide as a core, grafting phosphorus and nitrogen flame-retardant groups and carrying out silane-titanate synergistic modification to prepare a composite flame retardant; 3, polyhydric alcohol and isocyanate are pre-polymerized, then the chain extender, the composite flame retardant and the auxiliaries are sequentially added, and curing molding.The material has low smoke and excellent flame retardance, mechanical property and hydrophobic stability through the synergistic effect of graphene and a phosphorus-nitrogen flame-retardant system, and is suitable for the field of flame-retardant high polymer materials for buildings, electronic packaging and the like.

This invention discloses a visible-light-responsive dynamically covalently cross-linked self-healing polyurethane and its preparation method, belonging to the field of self-healing materials technology. The material is prepared by reacting diisocyanate, long-chain diol, butanediol, trimethylolpropane, and a monool containing an azophenylboronic acid structure in a certain proportion at 60°C. This invention achieves visible-light-responsive self-healing of the polyurethane material by introducing a visible-light-responsive azophenylboronic acid structure into the polyurethane and utilizing the photoresponsive cis-trans isomerization of the azo structure to regulate the reversible breakage and recombination of the boron-oxygen hexacyclic ring. The visible-light-responsive dynamically covalently cross-linked self-healing polyurethane material prepared by this invention maintains high mechanical strength (16.47 MPa) while exhibiting a strength self-healing efficiency of 95.8% after 8 hours of visible light irradiation, showing broad application prospects in smart materials, anti-corrosion coatings, and other fields.

The invention discloses a medical sodium hyaluronate skin repair gel and a preparation method thereof, and mainly relates to the technical field of hyaluronic acid, the medical sodium hyaluronate skin repair gel comprises the following components: sodium hyaluronate, a synergist, glycerol, carbomer, 1, 3-butanediol, triethanolamine and water. Compared with the prior art, the medical sodium hyaluronate skin repair gel prepared by the invention can relieve erythema, pruritus and other symptoms caused by skin inflammation; the wound dressing can also be used for nursing non-chronic wounds, such as superficial wounds, sutured wounds after operations, mechanical wounds and the like; meanwhile, a bacteriostatic environment for wound healing is kept, and skin repair is accelerated; the scar hyperplasia phenomenon in the skin wound repairing process is reduced.

The invention discloses a catalyst for preparing gamma-butyrolactone through liquid phase dehydrogenation of 1, 4-butanediol as well as a preparation method and application of the catalyst. Belongs to the technical field of catalyst preparation. The catalyst is composed of a carrier, CuO and MOx, the CuO and the MOx are loaded on the carrier, Cu accounts for 10-50% of the total mass of the catalyst, M accounts for 1-25% of the total mass of the catalyst, M is one of Mn, Zn, Co, Ni, Fe, Cr, Ce, Nb, Ru, Pt, Ir and Pd, and the carrier is one of silicon oxide, aluminum oxide, magnesium oxide, lanthanum oxide, hydroxyapatite and magnesium-aluminum hydrotalcite. An oxide-oxide interface is formed between CuO and MOx through roasting and reduction, and relatively strong electron interaction exists between highly dispersed Cu nanoparticles and the oxide-oxide interface, so that the stability of the catalyst can be enhanced.

The invention provides a clostridium endophyllum engineering bacterium as well as a construction method and application thereof, and belongs to the technical field of biology, compared with a wild type strain, the clostridium endophyllum engineering bacterium can only produce acetic acid in a low-pH environment under the condition of taking CO2 and H2 as raw materials, and does not generate by-products such as ethanol, lactic acid, 2, 3-butanediol and the like. Besides, the fermentation liquor of the clostridium endophyllum engineering bacteria can be directly used as an acidic substrate to adjust the pH value of downstream yeast fermentation liquor, meanwhile, automatic addition of a carbon source is achieved, zero addition of inorganic salt in the cascade conversion process from CO2 and H2 to grease or yeast protein is achieved, and the economical efficiency and environmental friendliness of the whole process are improved.

The invention provides a bio-based 1, 4-butanediol composition as well as a preparation method and application thereof, and the bio-based 1, 4-butanediol composition comprises bio-based 1, 4-butanediol, 4-hydroxybutyric acid-(4-hydroxyl) butyl ester and bis (4-hydroxyl) dibutyl ether. The total mass content of 4-hydroxybutyric acid-(4-hydroxyl) butyl ester and bis (4-hydroxyl) dibutyl ether in the bio-based 1, 4-butanediol composition is 51 to 220 ppm. The bio-based 1, 4-butanediol composition has low hygroscopicity, and can maintain low water content after long-term storage; meanwhile, when the bio-based 1, 4-butanediol composition is used for polyester synthesis, the esterification time can be shortened, the reaction efficiency can be improved, side reactions can be reduced, and a polyester product with better damp-heat resistance stability can be obtained.