2018 results about "Inorganic nanoparticles" patented technology

Multi-component particles comprising inorganic nanoparticles distributed in an organic matrix and processes for making and using same. A flowing aerosol is generated that includes droplets of a precursor medium dispersed in a gas phase. The precursor medium contains a liquid vehicle and at least one precursor. At least a portion of the liquid vehicle is removed from the droplets of precursor medium under conditions effective to convert the precursor to the nanoparticles or the matrix and form the multi-component particles.

The present invention relates to methods for the preparation of inorganic nanoparticles capable of fluorescence, wherein the nanoparticles consist of a host material that comprises at least one dopant. The synthesis of the invention in organic solvents allows to gain a considerably higher yield compared to the prior art synthesis in water. All kinds of objects can advantageously be marked and reliably authenticated by using an automated method on the basis of a characteristic emission. Further, the size distribution of the prepared nanoparticles is narrower which renders a subsequent size-selected separation process superfluous.

The invention relates to a colorless and transparent polyimide nano-composite material membrane and a preparation method thereof. The polyimide nano-composite material membrane is prepared by a method of compounding alicyclic dianhydride and fluorinated diamine serving as monomers with a certain amount of inorganic nano-particles by using nano-composite technology and performing thermal imidization with gradient temperature increase. The amount of added nano-particles is controlled between 0.01 and 5.00 weight percent to obtain the colorless and transparent polyimide nano-composite material membrane with high heat resistance. The membrane has a glass transition temperature of over 250 DEG C, a light transmittance of over 90 percent at 450 nanometers and an ultraviolet wavelength of about 300 nanometers, and can be used as a substrate material for a photoelectric device, a semiconductor material, an optical waveguide material and the like.

An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer, a C═C double bond group containing silane ester agent, and an optional multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles. In another aspect, the multi-olefinic crosslinker is an alkoxysilyl-containing multi-olefinic crosslinker.

The present invention relates to a polymer nano-composite of the functional inorganic nano-particle with intermingle prepared by electrospinning method, and the use of the composite. The precursory sol of the functional inorganic nano-particle is prepared by the sol-gel method, and is mixed with the polymer solution to form spinning fluid, adding precursor of dopant if necessary, and then the mixed spinning fluid is sprayed on to the electric collecting board with the action of the electric field force by electrospinning method to obtain functional polymer nano-composite with intermingle. The equipment of the invention is simple, the operation is easy, the components, structure and characteristics of the composite is easy to control, the structure is stable, the inorganic nano-particle is dispersed uniformly. According to the difference of the functionality of the inorganic nano-particles, the composite can be used in conducting material, antistatic material, magnetic material, electrochromic material, photocatalysis and ecology environment material, antibiosis material and biomaterial.

The invention relates to a nano transparent heat insulation coating, which comprises the following components: inorganic nano particle hybrid high molecular resin, coating additive and thinner. Wherein, the inorganic nano particle hybrid high molecular resin is the resin with core/shell structure and synthesized by inorganic nano heat insulation powder and high molecular resin through in-situ polymerization and the high molecular resin covers the nano heat insulation powder. The invention also provides a preparation method of the nano transparent heat insulation coating. The nano transparent heat insulation coating film forming material is the inorganic nano particle hybrid high molecular resin and is characterized by strong adhesive force, transparency and shielding infrared for heat insulation, which can be coated on the surfaces of glass, metals and cement and is especially for glass of cars or buildings. The invention adopts the inorganic nano particle hybrid high molecular resin with core/shell structure prepared through in-situ polymerization, which is simple and easy and has good coating properties.

The invention discloses a profile control oil-displacement agent for a core-shell type inorganic/organic polymer composite microballoon. A preparation method of the core-shell type inorganic/organic polymer composite microballoon comprises the following steps of carrying out surface modification of inorganic cores of inorganic nano-particles such as silica particles and magnetic particles, and carrying out graft polymerisation by a dispersion polymerization method or an inverse emulsion polymerization method to form polymer shells (such as polyacrylamide cross-linked copolymers) on the surfaces of the inorganic cores. The inorganic components and the organic components bind by chemical bonds so that the core-shell type inorganic/organic polymer composite microballoon has very stale structure. The core-shell type inorganic/organic polymer composite microballoon retains the advantages of polymer microballoons and inorganic particles, and has strong heat-resistant and mineralization-resistant capabilities, high plugging strength and good dilatancy. The core-shell type inorganic/organic polymer composite microballoon can move in rock pores and can plug the rock pores. When a plugging pressure difference is improved to a certain degree, elastic deformation of the core-shell type inorganic/organic polymer composite microballoon can be produced and the deformed core-shell type inorganic/organic polymer composite microballoon sequentially moves to a deep rock stratum part so that a liquid flow direction is changed gradually and a crude oil yield is improved. The profile control oil-displacement agent provided by the invention has a large potential.

Composite particles comprising inorganic nanoparticles disposed on a substrate particle and processes for making and using same. A flowing aerosol is generated that includes droplets of a precursor medium dispersed in a gas phase. The precursor medium contains a liquid vehicle and at least one precursor. At least a portion of the liquid vehicle is removed from the droplets of precursor medium under conditions effective to convert the precursor to the nanoparticles on the substrate and form the composite particles.

An electrochemical cell, such as Li-Ion, having (a) a positive electrode; (b) a negative electrode, (c) a porous inorganic/organic composite layer interposed between the positive electrode and the negative electrode, and (d) an electrolyte comprising a lithium salt and a non-aqueous solvent. The composite layer includes inorganic nanoparticles and a binder to form a nanocomposite separator (NCS). In addition to the composite layer, the electrochemical cell includes a porous separator.

The invention provides an ultraviolet curable organic silicon-acrylic resin electronic adhesive, which comprises the following components: (1) 100 parts of doublebond-containing acrylic monomers or prepolymer, (2) 5 to 500 parts of doublebond-containing organic silicon resin with a molecular weight of 1,000 to 10,000, (3) 1 to 100 parts of vinyl compound modified inorganic nano particle, (4) 1 to 50 parts of radical ultraviolet initiator, (5) 1 to 100 parts of organosilan, (6) 0 to 200 parts of inorganic reinforcing agent, and (7) 0 to 50 parts of auxiliary agent, wherein the ultraviolet curable organic silicon-acrylic resin is prepared by carrying out ultraviolet curing on the materials, and the solid content thereof is 100 weight percent. The product produced by the invention has the excellent characteristics of firm bonding with metal, glass and plastic materials and electronic devices, good optical property, good elasticity, good weather resistance, safety, non-toxicity, convenient construction and the like, can replace traditional solvent electronic adhesives, and is used for protective coatings, protective adhesives, packaging materials and the like of electronic devices, integrated circuits, printed circuits, LED chips and the like.

The invention provides a super-hydrophobic nanometer transparent coating and a preparation method thereof and belongs to the technical field of super-hydrophobic paint. The method includes the steps that firstly, a first category of inorganic nanometer particles are added into an organic solution, and ultrasonic dispersion is performed; secondly, dispersing agents and a second category of inorganic nanometer particles are added, and ultrasonic dispersion is performed so that a dispersion solution can be obtained; crosslinking agents and additives are added in the dispersion solution, ultrasonic dispersion is performed, finally, low-surface energy polymers are added, mixtures are evenly mixed, and transparent and clear super-hydrophobic paint is obtained; the surface of a solid base materials is coated with the transparent and clear super-hydrophobic paint, and the super-hydrophobic nanometer transparent coating is obtained through low-temperature thermal drying and curing. The super-hydrophobic performance of the super-hydrophobic nanometer transparent coating prepared through the method is excellent, the contact angle can be 160 degrees, the rolling angle is 1-7 degrees, the super-hydrophobic nanometer transparent coating can be sprayed to the surfaces of most of common materials, the morphology of the surfaces of the materials are not changed, and the application prospects and the application potency are very wide.

A flexible material for optical applications in a wavelength range of λ₁ to λ₂, λ₁ being smaller than λ₂, composed of a flexible support and at least one multilayer that comprises a porous or nanoporous layer which has a low refractive index and contains inorganic nanoparticles and at least one binder, and a non-porous polymer layer which has a high refractive index and is in direct contact with the porous or nanoporous layer; said flexible material is characterized in that the maximum thicknesses of the boundary layers, in which the refractive index changes from one value to the other and which are located between the porous or nanoporous layers and the non-porous polymer layers that are in direct contact therewith, amount to 0.2 times wavelength λ₂; and the difference in the refractive indices of the porous or nanoporous layers and the non-porous polymer layers is at least 0.20, 200 nm and 2500 nm being typical values for λ₁ and λ₂.

An inorganic nanowire having an organic scaffold substantially removed from the inorganic nanowire, the inorganic nanowire consisting essentially of fused inorganic nanoparticles substantially free of the organic scaffold, and methods of making same. For example, a virus-based scaffold for the synthesis of single crystal ZnS, CdS and free-standing L10 CoPt and FePt nanowires can be used, with the means of modifying substrate specificity through standard biological methods. Peptides can be selected through an evolutionary screening process that exhibit control of composition, size, and phase during nanoparticle nucleation have been expressed on the highly ordered filamentous capsid of the M13 bacteriophage. The incorporation of specific, nucleating peptides into the generic scaffold of the M13 coat structure can provide a viable template for the directed synthesis of a variety of materials including semiconducting and magnetic materials. Removal of the viral template via annealing can promote oriented aggregation-based crystal growth, forming individual crystalline nanowires. The unique ability to interchange substrate specific peptides into the linear self-assembled filamentous construct of the M13 virus introduces a material tunability not seen in previous synthetic routes. Therefore, this system provides a genetic tool kit for growing and organizing nanowires from various materials including semiconducting and magnetic materials.

Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one emboidiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.

The invention relates to an inorganic/organic composite polyimide nanometer fibrous film. The inorganic/organic composite polyimide nanometer fibrous film is formed by an inorganic nanoparticle-doped polyimide nanometer fiber, wherein the mass of the inorganic nanoparticles accounts for 0.1-30% of the mass of polyamide acids; the diameter of the polyimide nanometer fiber is 20-500nm, the thickness of the film is 15-100mum, and the air permeability of the film is 10-500s, apertures on the upper surface; and apertures on the upper surface and the lower surface and in the film symmetrically and uniformly distribute, diameters of the apertures are less than 300nm, and the tensile strength of the film is 100-250MPa. According to the invention, a mixed solution of the inorganic nanoparticles and the polyamide acids is subjected to static spinning, machinery rolling, and high temperature imidization to prepare the film, so a preparation method of the film is suitable for large scale preparation. The inorganic/organic composite polyimide nanometer fibrous film can be applied to high capacity energy storage batteries and high power density power lithium ion batteries.

The present invention provides a composite quasi-solid-state electrolyte, a composite quasi-solid-state electrolyte membrane, preparation methods of composite quasi-solid-state electrolyte and the composite quasi-solid-state electrolyte membrane, and a lithium battery or a lithium ion battery containing the composite quasi-solid-state electrolyte membrane. The composite quasi-solid-state electrolyte comprises a solid electrolyte, a lithium salt-containing liquid electrolyte, inorganic nanoparticles and a binder, wherein the static electricity or functional groups on the surface of the inorganic nanoparticles can adsorb the electrolyte so as to make the composite quasi-solid-state electrolyte have strong adsorption capacity and strong liquid retention ability, and the inorganic nanoparticles can adsorb the lithium salt so as to change the lithium ion conduction mechanism, reduce the interfacial resistance between the liquid electrolyte and the solid-state electrolyte, change the deposition morphology of lithium, hinder the formation of lithium dendrite, and reduce the pulverization of lithium. In addition, by adding the solid electrolyte, the composite quasi-solid-state electrolyteof the present invention can maintain the high conductivity and can effectively reduce the content of the liquid electrolyte so as to improve the safety of the battery.

The inorganic nanometer particle modified high performance regenerated plastic consists of recovered plastic 5-98 wt%, new plastic in the same type 0-93 wt%, inorganic nanometer particle 1-30 wt%, flexibilizer and compatilizer 1-30 wt%, and alkali free glass fiber 0-45 wt%, and the surface of the alkali free glass fiber is treated with silane coupler in the amount of 0.2- 5% of the added alkali free glass fiber. The said components are mixed homogeneously through stirring, melted and extruded to form.

The invention belongs to the technical field of preparation of phase change materials and microcapsules, and specifically relates to a method for preparing a hollow polymer microsphere coated with a phase change material. The method comprises the following steps of: performing surface modification on hydrophilic inorganic nanoparticles by an ionic surfactant, and adding the phase change material and monomers to the modified inorganic nanoparticles, which are taken as a stabilizer, to prepare the hollow polymer microsphere coated with the phase change material through a Pickering suspension polymerization method. The preparation process is simple, the raw materials are cheap and easily available, the inner wall of the prepared hollow polymer microsphere is made from polymers, the outer layer of the prepared hollow polymer microsphere is made from the inorganic nanoparticles, and the organic phase change material is coated inside the prepared hollow polymer microsphere. The prepared microsphere has a small size, the coating rate of the phase change material is high, and the outer inorganic nanoparticle layer enhances thermal stability, heat transfer efficiency, sealing performance and mechanical properties of the microsphere.

The invention provides a preparation method of fibrous membrane with a super hydrophobic multi-stage nanometer structure, which is characterized by comprising the following specific steps: 1, at room temperature, adding hydrophobic polymer and hydrophobic inorganic nanoparticles into a sealed container filled with solvent, putting the sealed container on a magnetic stirrer to stir at the revolving speed of 10-200 rpm, and obtaining solution with even property; 2, at room temperature, inputting solution obtained in step 1 onto a spinning nozzle at constant flow velocity; connecting the spinning nozzle to a high voltage static generator to carry out electrostatic spinning; and receiving spun fiber by a receiver to obtain the fibrous membrane with super hydrophobic multi-stage nanometer structure. The invention can drastically improve the hydrophobic performance of the fibrous membrane.

The present invention discloses process of preparing selectively laser sintered inorganic nanometer particle reinforced nylon part. The process includes the following steps: surface organizing treatment of inorganic nanometer particle and ultrasonic treatment to disperse the inorganic nanometer particle homogeneously in mixed solvent to form inorganic nanometer particle suspension; heating the mixture of inorganic nanometer particle suspension, nylon resin and antioxidant inside a sealed container to dissolve the nylon resin in the solvent; cooling, decompression distilling to recover solvent, vacuum drying, ball milling and sieving to obtain composite nylon/inorganic nanometer particle composite material; and final selectively laser sintering to form. The selectively laser sintered inorganic nanometer particle reinforced nylon part has raised strength and high toughness.

An economical, flexible, breathable polymer film composite modified in at least one of its surfaces by the formation of pores opening out in a funnel shape at the surface thereof, with a nanoscale particle system and which is particularly suitable for packaging purposes. The modification further includes at least one composite layer construction made from a binding agent layer of chemically inert inorganic nanoparticles and a lining layer of hydrophilic non-toxic metal oxide particles which are photocatalytically active under short wave light radiation and which have an anti-bacterial and self-cleaning effect.

An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer and a fluoroalkyl containing multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles.

The invention relates to a highly-transparent ultraviolet-resistant energy-saving film and a preparation method thereof, belonging to the field of composite films synthesized by compounding polymer and inorganic nano-particles and aiming at overcoming the defects that the prior film has low visible light transmission and high production cost. The highly-transparent ultraviolet-resistant energy-saving film comprises the following components by the weight percent: 50-99.8 of organic polymer, 0.2-50 of metal-oxide nano-particles and 0-39.9 of polymer auxiliary agent. The highly-transparent ultraviolet-resistant energy-saving film is prepared by a solution mixing method or a solution-melting mixing method; with the solution mixing method, the organic polymer and the metal-oxide nano-particles are dispersed in dispersing medium to prepare film preparing stock solution, and the film preparing stock solution is used for preparing the energy-saving film on a substrate; with the solution-melting mixing method, the mixture of the organic polymer and the metal-oxide nano-particles is dried to prepare master batch, and the master bath is mixed with the organic polymer and the polymer auxiliary agent to prepare the energy-saving film. The highly-transparent ultraviolet-resistant energy-saving film has high visible light transmission, good ultraviolet resistance and energy-saving effect, simple preparation process and low cost, thereby being suitable for industrial production.

The present invention provides micro- and nanofibers made from polymers that comprise nanoparticles, such as carbon nanoparticles and inorganic nanoparticles, and methods of making such fibers.