1210 results about "Propanol" patented technology

An absorbent retail paper product comprised of cellulosic fibers having a concentration of 1, 3-dichloro-2-propanol that is not detected to 50 ppb, as measured using the ACOC official method 2000.0150, a concentration of 3-monochloro-1, 2-propanediol that is not detected to 1000 ppb, as measured using the ACOC official method 2000.0150, as measured by the "adipic acid test", as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150. Polyaminoamide-epihalohydrin at a concentration of not detected to 0.09% has a lateral wet strength of from 80 n / m to 200 n / m wherein all of the cellulosic fibers contained in the absorbent paper product are non-synthetic, the cellulosic fibers and the absorbent paper product are substantially free of formaldehyde.

The invention discloses a preparation method of an ester polycarboxylic acid water reducer, and belongs to the technical field of concrete admixtures. The preparation method of the ester polycarboxylic acid water reducing agent comprises the following steps: under an alkaline condition, carrying out free radical polymerization reaction on a polyether macromonomer and an unsaturated carboxylic acid monomer under the action of a chain transfer agent A, a chain transfer agent B and an initiator, continuously adding a catalyst, and carrying out dehydration esterification reaction under the action of the catalyst, so as to prepare the ester polycarboxylic acid water reducing agent, the polyether macromonomer is monohydroxy polyether of which the molecular weight is between 500 and 5000; the chain transfer agent A is one of acetone, isopropanol, sodium hydrogen sulfite, sodium hypophosphite, sodium formate and the like; the chain transfer agent B is one of mercaptoethanol, mercaptopropanol, mercaptoacetic acid, mercaptopropionic acid and the like; the catalyst is a phosphonic acid compound with hydroxyl or amino. The preparation method is simple in process and low in energy consumption, and the prepared ester polycarboxylic acid water reducer product is excellent in performance.

The invention discloses a haloalkane dehalogenase mutant and an application thereof in degradation of 1, 2, 3-tribromopropane, haloalkane dehalogenase DhaA31 coded by dhaA gene of a Rhodococcus rhodococcus NCIMB 13064 strain is modified to obtain the haloalkane dehalogenase mutant F168W / I246C, the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutant 1, 2, 3-tribromopropane, and the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutant 1, 2, 3-tribromopropane under the condition of water phase normal temperature. The degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane within 1 h reaches 100%, and the degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane reaches 100%. The haloalkane dehalogenase mutant has high stereoselectivity on (R)-2, 3-dibromo-1-propanol, and the e.r. Value of the haloalkane dehalogenase mutant reaches 6: 94. The haloalkane dehalogenase mutant provided by the invention has high catalytic efficiency and high stereoselectivity, is beneficial to recognition and further degradation of downstream enzymes, and has a good application prospect in bioremediation of emerging haloalkane pollutants.

Provided herein, inter alia, are ruminant feed or feed additive compositions, and methods of using these feed or feed additive compositions to reduce methane emissions in ruminants while improving animal performance, these feed or feed additive compositions comprise one or more compounds that increase hydrogen production in ruminants, such as, but not limited to, 3-nitroxypropanol (3NOP) and one or more acetogens.

The invention belongs to the technical field of medicine detection, and particularly relates to a high-sensitivity liquid chromatography method for detecting mutagenic impurities in atomoxetine hydrochloride key starting material 3-chlorobenzene propanol, the method adopts an HPLC (High Performance Liquid Chromatography) analysis method, a chromatographic column adopts octadecylsilane chemically bonded silica as a filler, and the composition of a mobile phase A is a buffer solution; the mobile phase B is methanol or acetonitrile; carrying out gradient elution on the mobile phase; the flow velocity is 0.4 to 0.8 ml / min; the detection wavelength is 230 to 250 nm; by adopting an HPLC analysis method, the content of mutagenic impurities in the key starting material 3-chlorobenzene propanol of atomoxetine hydrochloride can be effectively separated and measured, and the method is high in sensitivity, strong in specificity and good in accuracy and repeatability, and has extremely important significance on quality control of the key starting material 3-chlorobenzene propanol of atomoxetine hydrochloride.

An organic silicon resin toughening agent, a single-component high-strength epoxy structural adhesive, and preparation methods for both. The organic silicon resin toughening agent is prepared by reacting epoxy modified hydrogen-containing silicone oil and vinyl six-membered cyclic oligomeric silsesquioxane; and the epoxy modified hydrogen-containing silicone oil is prepared by reacting allyl alcohol glycidyl ether and hydrogen-containing silicone oil which contains hydrogen at both ends. Compared with toughening agents such as nitrile rubber and core-shell structured rubber, the synthesized organic silicon resin toughening agent having a cyclic mesh structure unit in the present invention has better high and low temperature resistance, and can significantly improve the high and low temperature resistance of the single-component high-strength epoxy structural adhesive while improving the toughness of the single-component high-strength epoxy structural adhesive.

The invention discloses a synthetic method of glabridin with optical purity, which comprises the following steps: by taking (R)-3-acetoxyl-2-(2, 4-dimethoxyphenyl) propanol and 2-isopentenyl resorcinol as raw materials, carrying out Mitsunobu reaction to obtain a key intermediate compound I, then carrying out hydrolysis and iodination to obtain an intermediate compound II, and then carrying out cyclization to obtain the glabridin with optical purity. Reducing and removing a protecting group to obtain glabridin. By introducing the isopentene side chain, the reaction activity of an olefin functional group is reserved, a key site is provided for subsequent cyclization conversion, the precise spatial configuration of the product is ensured, and finally glabridin with optical purity is prepared. The method is short in route, low in cost, mild in reaction condition and suitable for industrial production.

The invention discloses a composite carrier supported hydrogenation catalyst and application thereof, the composition of the catalyst is Pd-M-Nb2O5-B, and the content of the active component palladium Pd is 0.2-1.5%; the auxiliary agent M is one or two of silver and bismuth, and the molar ratio of the content of the auxiliary agent M to the active component Pd is 1: (0.5-4); nb2O5-B is a composite carrier, and the composite carrier accounts for 97.0-99.5% of the total weight of the catalyst; in the composite carrier Nb2O5-B, the content of Nb2O5 is 8 to 15 percent; b is one or more of TiO2, SiO2 and Al2O3, and the weight ratio of TiO2 to SiO2 to Al2O3 is (1-3): (5-20): 100. The catalyst has excellent water resistance, the complex carrier has stronger acidity compared with common solid acid, the product yield is higher, and the stability of the acetyl n-propanol generated by the reaction of the catalyst can be improved.

The invention relates to the field of chemical synthesis, in particular to a production process of allyl diethylene glycol dicarbonate, which comprises the following steps: by taking allyl alcohol and dimethyl carbonate as raw materials, carrying out transesterification under the action of a core-shell catalyst to generate dipropylene carbonate; carrying out solid-liquid separation, carrying out reduced pressure distillation to recover methanol and dimethyl carbonate, and then carrying out second-step ester exchange reaction with diethylene glycol under the action of the same catalyst to generate allyl diethylene glycol dicarbonate; and finally, performing multi-stage reduced pressure distillation purification to obtain a high-purity product. According to the core-shell type catalyst, an MCM-41 molecular sieve is used as a carrier, an inner core is formed after amino modification and zirconium ion coordination, then an interface layer and a phenyl modified silicon dioxide shell are used for packaging, and the core-shell type catalyst has high activity, high selectivity and excellent structural stability. The method has the advantages of mild process conditions, recyclable catalyst, high product yield and excellent purity, and is suitable for industrial production.

The invention relates to the technical field of propyl alcohol rectification detection, and discloses a quality detection method and system for a propyl alcohol rectification process. According to the method, a data acquisition module acquires initial operation data, counts operation time and task requirements of partitioned tower section equipment, matches available time of the equipment with man-hour distribution of personnel, and generates a tower section equipment distribution result; the quality analysis module calculates key quality parameter detection time and interval based on the result, sorts a man-hour priority calling sequence, and generates a parameter sorting result; the constraint evaluation module is used for calculating material supply and equipment operation time, calibrating resource conflicts, adjusting a detection interval and generating a constraint adjustment parameter set; the progress monitoring module counts time node and parameter distribution difference values and recombines resource distribution to generate a rectification progress plan; and the deviation response module monitors environment and equipment states, calculates deviation, adjusts equipment allocation and time nodes, and generates a deviation correction result. The system realizes precise and dynamic management and control of quality detection in the propyl alcohol rectification process.

The invention relates to the technical field of advanced ceramic materials, in particular to high-entropy ceramic powder and a preparation method and application thereof.The preparation method comprises the following steps that a metal source is dissolved in n-propyl alcohol and mixed to be uniform, and an n-propyl alcohol solution of the metal source is obtained; adding triethylamine into the normal propyl alcohol solution of the metal source to obtain a first mixed solution of the metal source; adding water into the first mixed solution of the metal source to obtain a second mixed solution of the metal source; freeze-drying the second mixed solution of the metal source to obtain a first solid; adding an aqueous solution of glucose into the first solid, carrying out high-temperature reaction, and freeze-drying to obtain a second solid; cracking the second solid in an inert atmosphere to obtain high-entropy ceramic powder; wherein the molecular formula of the high-entropy ceramic powder is MC, and M is a combination of four elements of Nb, Zr, Ta and Ti in an equal molar ratio. The high-entropy ceramic powder disclosed by the invention has the advantages of small agglomeration, low oxygen content, uniform particle size distribution, good particle dispersion and excellent electrochemical performance.

The invention discloses a preparation method of ulinastatin adsorption resin, and belongs to the technical field of adsorption resin. Comprising the following steps: (1) preparing a water phase: adding pure water, gelatin, cellulose, sodium chloride and lignin into a reaction kettle until the materials are fully dissolved; (2) preparing an oil phase, wherein the oil phase contains divinylbenzene, methyl acrylate, benzoyl peroxide, tert-butyl peroxy-2-ethylhexanoate, triallyl isocyanurate, tripropanol alkyl trimethacrylate and methylbenzene, and the oil phase is uniformly stirred and mixed with the methylbenzene and the trivinylbenzene, the methyl acrylate, the benzoyl peroxide, the tert-butyl peroxy-2-ethylhexanoate, the triallyl isocyanurate, the tripropanol alkyl trimethacrylate and the methylbenzene; (3) suspension polymerization: putting the oil phase into the water phase, and carrying out staged heating reaction; (4) amination reaction; (5) alkylation reaction; and (6) acid-base alcohol treatment. Compared with the existing resin, the resin disclosed by the invention has the characteristics of high adsorption exchange rate, high desorption rate and high desorption concentration on ulinastatin, and the yield of ulinastatin is increased by 1.17 times compared with that of D215 resin.

The present invention belongs to the technical field of microbial fermentation, and discloses the application of a compound bacterium agent of Lactobacillus rhamnosus and Bacillus licheniformis for reducing acids and higher alcohols, Lactobacillus rhamnosus, and in Baijiu. Lactobacillus rhamnosus L21 has a preservation number of: CGMCC NO. 32609, a preservation date of: November 13, 2024, and a preservation unit of: China General Microbiological Culture Collection Center. The use of the compound bacterium agent of Lactobacillus rhamnosus L21 and Bacillus licheniformis XDNZ_Bl_27 can effectively reduce organic acids such as lactic acid and propionic acid in the Baijiu fermentation system, and at the same time can also reduce the content of n-propanol in the fermented grains, which is beneficial to the regulation of acidity and higher alcohols in the process of Baijiu production.

The invention belongs to the technical field of polyester polyol preparation, and particularly relates to phosphorus-nitrogen synergistic flame-retardant polyester polyol and a preparation method thereof.The phosphorus-nitrogen synergistic flame-retardant polyester polyol is obtained by conducting condensation polymerization on a phosphate carboxylic acid compound I, a phosphate carboxylic acid compound II, micromolecular polyol and micromolecular polybasic acid under the action of a catalyst; wherein the phosphate carboxylic acid compound I is obtained by carrying out esterification reaction on 2-phosphonobutane-1, 2, 4-tricarboxylic acid and coniferyl alcohol under the action of concentrated sulfuric acid; the phosphate carboxylic acid compound II is obtained by carrying out esterification reaction on 2-phosphonobutane-1, 2, 4-tricarboxylic acid and 1H-imidazole-5-propanol under the action of concentrated sulfuric acid. The flame retardant property is improved through phosphorus-nitrogen synergism, and meanwhile, the aging resistance is improved. The invention also provides a preparation method thereof.

The invention belongs to the field of preparation of allyl polyether, and particularly relates to a preparation method of epoxy allyl alcohol polyether. The invention aims to solve the problems of complex traditional multi-step synthesis process and long reaction period. The preparation method comprises the following steps: mixing allyl alcohol polyether with alkali, adding an epoxy end-capping reagent under the protection of nitrogen, carrying out a curing reaction, carrying out solid-liquid separation after the reaction to obtain a crude product, removing impurities by using an adsorbent, and carrying out demonomerization treatment and filtration to obtain a final product. According to the method, the production process is simplified, the cost is reduced, the purity and the performance of the product are improved, the product has relatively low viscosity, good flexibility and high chemical reaction activity, in addition, the epoxy end-capping reagent recycled in the demonomerization process can be recycled, and the economic benefit and the environmental protection property are further improved.

The invention discloses a mixed organic amine absorbent as well as a preparation method and application thereof. The absorbent consists of a main absorbent, an absorption enhancer, a regulator and a solvent, the mass ratio of the main absorbent to the absorption enhancer to the conditioning agent is (0.5-5.0): (0.2-4.0): 1.0; the total mass concentration of the main absorbent, the absorption enhancer and the conditioning agent is 30-50 wt%; the main absorbent is diethylenetriamine, the absorption enhancer is N-methyldiethanolamine, the conditioning agent is 2-amino-2-methyl-1-propanol, and the solvent is water. According to the invention, by compounding and regulating the proportion of the organic amines, the synergistic effect of different types of organic amines is fully exerted, so that the mixed organic amine absorbent has high cycle capacity, low regeneration energy consumption, low absorbent loss, good dynamic performance and other good carbon dioxide capture performance.

The invention discloses a preparation method of PBA nanoparticle in-situ modified halloysite nanotube-polyethyleneimine cross-linked composite aerogel, which comprises the following steps: modifying halloysite nanotubes by using an epoxy silane coupling agent to obtain epoxidized HNTs, and further grafting ethylenediamine on the surfaces of the epoxidized HNTs to obtain HNTs rich in amino groups and hydroxyl groups; the preparation method comprises the following steps: respectively stirring and dissolving K4Fe (CN) 6.3 H2O and polyvinylpyrrolidone in a hydrogen chloride solution, then adding HNTs rich in amino groups and hydroxyl groups, ultrasonically dispersing uniformly, and reacting to obtain PBA-coated HNTs; the preparation method comprises the following steps: taking polyethyleneimine as a raw material, taking 1, 3-dichloropropanol as a cross-linking agent, adding an acid-binding agent, carrying out a cross-linking reaction on the polyethyleneimine and PBAatHNTs, finally freeze-drying a reaction solution, then removing the residual acid-binding agent and salts thereof by soaking and cleaning, and drying again to obtain a finished product of aerogel. According to the invention, the problems that polyethyleneimine is easy to remain in a solution and a nano-powder material is not easy to recover and reuse are solved, and the adsorption performance on heavy metal ions is improved.

The invention discloses a self-repairing composite floor for a clean room and a preparation method of the self-repairing composite floor, and the preparation method comprises the following steps: carrying out amination treatment on nano silicon dioxide and carbon quantum dots by using a silane coupling agent, and sulfonating polyethersulfone ketone by using concentrated sulfuric acid; the preparation method comprises the following steps: carrying out curing treatment on epoxy resin, an amine curing agent, N-hydroxyethyl maleimide and tetrakis (3-mercaptopropionic acid) pentaerythritol ester to obtain epoxy-mercaptan resin; the preparation method comprises the following steps: carrying out prepolymerization reaction on vacuum dehydrated polyester polyol, tetrahydroxyethyl ethylenediamine, furanpropanol, diisocyanate, a catalyst, 2, 2 '-thiodiethanol and hydroxyl silicone oil to obtain a star-shaped polyurethane prepolymer, adding epoxy-thiol resin, glyceryl borate, sulfonated polyethersulfone ketone, aminated silicon dioxide, aminated carbon quantum dots and an auxiliary agent, carrying out ultrasonic treatment, and carrying out drying to obtain the star-shaped polyurethane resin. The self-repairing coating material is obtained; and coating the self-repairing coating material on the surface of a base plate, and performing hot-pressing curing molding to obtain the self-repairing composite floor for the clean room.

The invention discloses a two-phase absorbent for capturing CO2, which is characterized by being prepared from the following components in percentage by mass: 25%-30% of N-(2-ethoxyl) ethylenediamine, 0%-3% of N-aminoethyl piperazine, 0%-3% of 2-(1-ethoxyl) pyridine, 10%-13% of N, N '-diethyl ethylenediamine, 15%-20% of N, N'-diethylethylenediamine, 5%-10% of N, N '-diethylethylenediamine, 5%-10% of N, N'-diethylethylenediamine and the balance of water. The invention relates to a cleaning agent which is prepared from the following components in percentage by weight: 1 to 5 percent of N, N-diethylhydroxylamine, 1 to 5 percent of pentamethyldiethylenetriamine, 0 to 2 percent of tert-butylamine ethoxyethanol, 0 to 3 percent of 2-amino-2-methyl-propyl alcohol, 5 to 8 percent of sulfolane, 5 to 8 percent of dimethyl ether, 5 to 8 percent of p-xylene and 5 to 8 percent of n-butyl alcohol. The composition can be prepared by uniformly stirring the components. The preparation method is simple, and the prepared two-phase absorbent can improve the saturated absorption capacity, improve the desorption rate and optimize the performance of the phase change absorbent.

The invention relates to the technical field of waste treatment, in particular to a kitchen waste treatment method, a carbon source and application thereof. The kitchen waste treatment method comprises the following steps: performing directional fermentation treatment on kitchen waste in an acid environment to obtain a fermentation mixture; filtering the fermentation mixture to obtain filtrate; the filtrate is sequentially subjected to distillation treatment and condensation treatment, volatile organic compounds are collected, and condensate containing volatile fatty acid and low-molecular alcohol is obtained. According to the kitchen waste treatment method, directional fermentation treatment is carried out, and a fermentation mixture is rich in volatile organic compounds including volatile fatty acids (VFAs) such as propionic acid, butyric acid and acetic acid and low-molecular alcohols such as propyl alcohol and ethyl alcohol. And carrying out filtration treatment to reduce the nitrogen content and the suspended matter value in the filtrate. After distillation treatment, the small-molecular organic matters in the filtrate are evaporated, less water is evaporated, and the nitrogen-containing components in the filtrate are almost not evaporated. And the prepared condensate is high in COD value, high in content of micromolecular organic matters and extremely low in nitrogen content.

The present invention proposes a method for removing odor impurities from 1,2-hexanediol, and belongs to the field of purification technology. The method for removing odor impurities from 1,2-hexanediol comprises the following steps: 1) mixing 1,2-hexanediol and an entrainer to obtain a mixed material; the entrainer is one or more of pure water, methanol, ethanol, n-propanol, isopropanol and n-butanol; 2) transferring the obtained mixed material to an azeotropic distillation tower for azeotropic distillation, extracting an azeotrope of the entrainer and odor impurities at the top of the tower, and obtaining the deodorized 1,2-hexanediol in the tower bottom. The method provided by the present invention does not involve chemical reactions, and has a short production process, generates less solid waste, and has a high purity of the purified 1,2-hexanediol product.

The present application relates to the field of cosmetic technology, in particular to a quick-drying and shaping spray and a preparation method thereof, in particular to a hair styling product which is quickly dried, permanently shaped and has hair care effect through the synergistic effect of specific film-forming agents and volatile systems, comprising the following components: ethanol 30-50%, aminomethyl propanol 0.1-1%, butanediol 1-5%, octyl acrylamide / acrylate / methyl acrylate copolymer 5-15%, PEG-12 dimethicone 0.5-2%, keratin 0.1-2%, hydrolyzed keratin 0.1-2%, oxidized keratin 0.1-2%, aloe barbadensis leaf extract 0.5-3%, selaginella kurata extract 0.5-3%, radix falatoniae extract 0.5-3%, radix salviae miltiorrhizae extract 0.5-3%, water 20-40%, essence 0.1-2%, cetrimonium chloride 0.1-1%, phenoxyethanol 0.5-1.5%, propylene glycol 1-5%, p-hydroxyacetophenone 0.5-1.5%, chlorphenesin 0.1-0.5%, ethylhexylglycerin 0.5-1.5%.

The invention relates to the technical field of NADPH regeneration and the technical field of antidepressant drug synthesis, and discloses a method for catalytically synthesizing (S)-3-chloro-1-phenyl-1-propanol by driving a WO3-based photoenzyme catalyst through infrared light, and the method comprises the following steps: step S1, preparing an oxygen-deficient WO3 nanosheet; s2, preparing a NaCBR carbonyl reductase (NaCBR carbonyl reductase); s3, mixing the oxygen-deficient WO3 nanosheet and NaCBR carbonyl reductase according to the mass ratio of (1: 0.5)-(1: 2), and stirring for 3-6 hours to obtain the photo-enzyme catalyst (WO3 / NaCBR). According to the method, artificial photosynthesis, namely a method for driving NADPH regeneration, is utilized, other materials are not additionally used as hydrogen transfer and electron transfer media, and the (S)-3-chloro-1-phenylpropanol is catalytically synthesized by utilizing infrared light to drive a photo-enzyme catalyst (WO3 / NaCBR). The method can greatly reduce the cost, is green and environment-friendly, has high catalytic efficiency and mild reaction conditions, is simple to operate, is easy to recover and recycle, and is suitable for large-scale industrial production and application.

The invention relates to a liquid detergent composition comprising a first surfactant selected from fatty alcohol ether sulfates, a second surfactant selected from betaines, optionally at least one solvent selected from ethanol, propanol, isopropanol, ethylene glycol, butyl glycol, propylene glycol, polypropylene glycol, alcoholamine, monoethanolamine, glycerol and mixtures thereof, wherein the salt concentration in the composition is about 0.2 to about 10 wt.-% and wherein the salt is selected from the group consisting of sodium salts such as sodium chloride, sodium sulfate, sodium formate, sodium acetate or sodium propionate, potassium salts such as potassium chloride, potassium sulfate, potassium formate, potassium acetate or potassium propionate, magnesium salts such as magnesium chloride, magnesium sulfate, magnesium formate, magnesium acetate or magnesium propionate, and calcium salts such as calcium chloride, calcium sulfate, calcium formate, calcium acetate or calcium propionate, and mixtures thereof, and wherein the composition is a concentrate that can be diluted with water while maintaining or increasing the viscosity.The present invention further relates to the use of such a cleaning composition for cleaning hard surfaces, in particular dishes, and to a process for preparing a cleaning composition, the process comprising diluting the concentrated liquid cleaning composition with water.

The invention provides a synthesis method of a chloride-free cationic rosin size emulsifier, which comprises the following steps: adding water to dilute dimethyl diallyl ammonium chloride, acrylamide and methacryloyloxyethyl trimethyl ammonium chloride according to a certain proportion to prepare a monomer mixed solution; the monomer mixed solution and the initiator solution are simultaneously pumped into a first microchannel reactor for polymerization reaction, the reaction temperature is 60-100 DEG C, the pressure is 0.2-1.4 Mpa, the retention time is 0.5-3 min, and a cationic polymer is obtained; and simultaneously pumping the cationic polymer and glyoxal into the second microchannel reactor for continuous reaction at the reaction temperature of 10-20 DEG C under the pressure of 2-4.0 Mpa for 0.5-3 minutes. The reaction time is greatly shortened by adopting the microchannel reactor, the method is suitable for industrial production, the synthesized chloride-free cationic rosin size emulsifier is safe, non-toxic, easy to dissolve in water, strong in cohesion, good in hydrolytic stability and free of gelling in 80 days, and rosin emulsion prepared by utilizing the cationic emulsifier is fine in granularity, good in stability and free of chloropropanol.

The invention relates to the technical field of chemical detection, in particular to a sample pretreatment method and a GC-MS (Gas Chromatography-Mass Spectrometer) method for simultaneously detecting glycidol and monochloropropanol in heated cigarette aerosol. The sample pretreatment method for simultaneously detecting the glycidol and the monochloropropanol in the heated cigarette aerosol comprises the following steps: capturing particulate matters in the heated cigarette aerosol; mixing the trapping material with ethyl acetate and an internal standard substance, extracting to obtain an extracting solution, and diluting with n-hexane; adding heptafluorobutyrylimidazole to perform derivatization reaction, washing with water after the derivatization reaction is completed, and drying to obtain a solution to be detected. According to the present invention, ethyl acetate is adopted for extraction, and detection analysis can be performed through dilution, HFBI derivatization, water washing and drying, such that the sample pretreatment step is substantially simplified, and the analysis sensitivity and the accuracy of the simultaneous detection of the three compounds such as the glycidyl, the 3-chloro-1, 2-propylene glycol and the 2-chloro-1, 2-propylene glycol can be easily improved.

The invention relates to the technical field of cement material preparation, and particularly discloses a calcium aluminoferrite-calcium sulphosilicate cement-based expanding agent as well as a preparation method and application thereof. The expanding agent comprises expansion source powder, gypsum powder and a regulating agent. The expansion source powder is prepared from 45 to 55 weight percent of calcium aluminoferrite, 30 to 40 weight percent of calcium sulphosilicate, 5 to 10 weight percent of calcium sulphoaluminate, 5 to 10 weight percent of dicalcium silicate and 2 to 4 weight percent of calcium sulfate; the balance is inevitable impurity mineral phases; the calcium aluminoferrite comprises dicalcium ferrite, hexacalcium dialuminoferrite, tetracalcium aluminoferrite and hexacalcium dialuminoferrite. The gypsum powder accounts for 12-18% of the mass of the expansion source powder; the regulating agent is triethanolamine or propanolamine, and the mass of the regulating agent is 0.1-0.5% of the total mass of the expansion source powder and the gypsum powder. The expanding agent provided by the invention has no interference on the flowability of concrete, can provide continuous and coherent expansion for the whole hydration hardening stage of a cement-based cementing material, and has long-term stable expansion performance.

The invention relates to the technical field of electroplating, in particular to a nickel stripping agent, a preparation method of the nickel stripping agent and a nickel plating layer stripping method. The nickel stripping agent comprises the following raw materials: an oxidizing agent, a complexing agent, a dissolution promoter, a surfactant and a corrosion inhibitor, wherein the mass ratio of the oxidizing agent to the complexing agent to the dissolution promoter to the surfactant to the corrosion inhibitor is (4-15): (3-25): (1-11): (0.01-1): (0.01-5); wherein the oxidizing agent is nitrobenzoic acid; the complexing agent is one or more of 2-amino-2-methyl-1-propyl alcohol, acetylacetone, nitrilotriacetic acid, nitrilotriacetic acid sodium salt, acrylate, sodium gluconate and ethylenediamine hydrochloride; the dissolution promoter is an alcohol ether solvent. According to the nickel stripping agent, the oxidizing agent with relatively low toxicity and a non-toxic or low-toxicity non-volatile complexing system are adopted, nickel can be completely removed, a base material cannot be eroded, and the threat to the health of operators can be remarkably reduced.

The invention belongs to the technical field of chemical component detection, and particularly relates to a method for detecting residues of 1, 3-dichloro-2-propanol, 2, 3-dichloro-1-propanol and 3-chloro-1, 2-propylene glycol in dihydroxypropyl theophylline. The detection method comprises the following steps: (1) adding a solvent into diprophylline for dilution, and uniformly shaking to prepare a test solution; (2) detecting the liquid to be detected by adopting a gas chromatography-tandem mass spectrometry method, and calculating the content of 1, 3-dichloro-2-propanol, the content of 2, 3-dichloro-1-propanol and the content of 3-chloro-1, 2-propylene glycol in the diprophylline according to an external standard method; the solvent is a mixture of formic acid and DMF (Dimethyl Formamide). The method provided by the invention is good in specificity, high in sensitivity, good in repeatability and high in accuracy, and can be used for simultaneously detecting 1, 3-dichloro-2-propanol, 2, 3-dichloro-1-propanol and 3-chloro-1, 2-propylene glycol in the diprophylline.

The invention relates to an anti-aging color master batch for a film and a preparation method of the anti-aging color master batch, and belongs to the technical field of polyester color master batches. The color master batch is prepared from the following components: 25 to 32 weight percent of pigment, 0.35 to 0.48 weight percent of modified anti-aging agent, 1.2 to 1.6 weight percent of dispersing agent, 0.1 to 0.12 weight percent of heat stabilizer, 2.8 to 3.6 weight percent of lubricating agent and the balance of PET (Polyethylene Terephthalate) resin, according to the modified anti-aging agent, 3-bromopropanol and tetramethyl piperidylamine are substituted to form an intermediate, then oxalyl chloride monoethyl ester and active alcoholic hydroxyl groups introduced into intermediate molecules are esterified to form a double-chain diester structure, the modified anti-aging agent has high compatibility with a PET matrix and is easy to disperse, the double-chain diester structure containing tertiary amine forms a chelation effect, and the modified anti-aging agent is chelated with a metal-based pigment during blending, so that the anti-aging effect is good. Interface free radicals are efficiently cleared in situ, interface aging is effectively retarded, and a long-acting anti-aging effect is formed.