1713results about "Hydroxy compound separation/purification" patented technology

The invention belongs to the technical field of pervaporation membrane preparation and application, and relates to a covalent organic framework pervaporation hybrid membrane with a combination sequence regulation interlayer structure, in particular to preparation of the pervaporation membrane and application of the pervaporation membrane in water / butanol separation. Adding the aldehyde monomer solution into the amino monomer solution, and standing for reaction; taking a water phase, and carrying out dialysis treatment; diluting the covalent organic framework nanosheet dispersion liquid to obtain dispersion liquid A; adjusting the pH of a polyelectrolyte aqueous solution to obtain a solution B; adjusting the pH value of the metal ion dispersion liquid to obtain a solution C; uniformly mixing the dispersion liquid A and the solution C at normal temperature, adding the solution B, and heating for reaction to obtain a membrane casting liquid; and carrying out suction filtration on the membrane casting solution to a base membrane, and carrying out vacuum drying to obtain the pervaporation membrane. At 70 DEG C, the separation flux of a 10wt% / 90wt% water / butanol mixture is 7.52 g / (m < 2 > h), and the separation factor reaches 13709.

The invention relates to a preparation method and application of an organosilicon / MOF-303 mixed matrix membrane, a silicon source precursor is uniformly dissolved in an ethanol solvent, then a mixture of water and hydrochloric acid is added according to a certain proportion, a water bath heating reaction is carried out for a period of time to obtain an organosilicon sol, prepared MOF-303 powder is added into the organosilicon sol according to a certain proportion, and the organosilicon / MOF-303 mixed matrix membrane is obtained. The preparation method comprises the following steps: uniformly mixing the raw materials through ultrasound to obtain a separation layer sol, coating the prepared separation layer sol on a ceramic support body through a hot coating method, and calcining in an air atmosphere for a period of time to obtain the MOF-303 / mixed matrix membrane. An organic silicon substance BTESA with a rigid acetylene bridge structure is preferably selected as a precursor, an MOF-303 material with a high specific surface area is doped into the precursor, the pore channel structure of the membrane is modified, more adsorption sites are provided for water molecules, and the composite membrane material with the optimal separation performance is obtained by optimizing the composite proportion.

The invention discloses a high-performance composite solvent-resistant nanofiltration membrane with a rigid twisted non-planar structure polyamide layer and a preparation method of the high-performance composite solvent-resistant nanofiltration membrane. The preparation method comprises the steps of preparation of the rigid twisted non-planar structure polyamide layer and surface modification. A water phase solution containing adamantane diamine and m-phenylenediamine and an organic phase solution containing 1, 3, 5-trimesoyl chloride and acetone are subjected to interfacial polymerization reaction to prepare a polyamide layer with a rigid twisted non-planar structure, and then a polyphenol modifier is used for carrying out hydrophilic modification on the polyamide layer, so that the rigid twisted non-planar structure is obtained. The pure water permeability and retention rate of the solvent-resistant nanofiltration membrane are obviously improved; due to the introduction of adamantane diamine, the interfacial polymerization process and the formation of a polyamide layer are remarkably regulated and controlled, and the separation performance of the solvent-resistant membrane is greatly improved on the premise that the interception performance of the membrane is hardly reduced; the preparation process is simple, and the prepared membrane is excellent in performance and has a good application prospect in the aspect of organic solvent separation.

The invention discloses a citron and cichorium intybus composite solid beverage, and relates to the technical field of solid beverages, and the solid beverage comprises the following components: 20-30 parts of a citron extract, 50-70 parts of a cichorium intybus extract, 5-10 parts of erythritol, 1-2 parts of vitamin C, 1-2 parts of probiotic powder, 1-2 parts of citric acid, and 1-2 parts of ginger powder. According to the citron and cichorium intybus composite solid beverage, the cichorium intybus extract in the citron and cichorium intybus composite solid beverage is rich in dietary fibers and can help to improve intestinal health and promote digestion, citron and cichorium intybus contain rich antioxidant components and are beneficial to neutralizing free radicals and slowing down the aging process, and the components in the beverage can help to improve energy and promote digestion. The physical and mental states are improved.

The invention relates to the technical field of chemical engineering, in particular to a method and a device for removing heavy components from cyclohexanol. Comprising the following steps: a, rectifying a cyclohexanol-containing material from a cyclohexene hydration reaction to obtain a first solution containing cyclohexanol and heavy components in a tower kettle; b, carrying out heavy component removal operation on the first solution to obtain a third solution containing a catalyst and heavy components, a first gas phase and a second gas phase; and c, rectifying the first gas phase and the second gas phase to obtain a fourth solution subjected to heavy component removal, namely cyclohexanol subjected to heavy component removal. The entrained catalyst and heavy components are removed together, and the fluidity required by the catalyst waste liquid is maintained by using the heavy components, so that the loss of cyclohexanol is reduced.

The invention relates to the technical field of purification of organic chemicals, in particular to an aroma purification method of leaf alcohol. Comprising the following steps: preparing a methanesulfonic acid magnetic catalyst; esterification of leaf alcohol; and alcoholysis and fractionation of the esterification solution. According to the method, acetic acid is used for esterification of leaf alcohol, then clear water and a sodium carbonate solution are used for washing, the clear water can effectively remove some water-soluble impurities and acidic byproducts, and the sodium carbonate solution not only can neutralize residual acidic substances, but also can promote siloxane impurities in initial leaf alcohol to be hydrolyzed and then taken away by a water phase, so that the content of the siloxane impurities in the leaf alcohol is reduced; in the subsequent process of producing leaf alcohol through alcoholysis of the organic phase I, pure water and ethanol, silyl ether impurities are hydrolyzed in a high-temperature and strong-alkali environment, products are dissolved in waste liquid to be removed, olefine aldehyde impurities with the boiling point lower than that of leaf alcohol are removed through azeotropic fractionation with ethanol, in conclusion, the impurities in the finished product leaf alcohol can be effectively reduced, and the yield of the finished product leaf alcohol is increased. And the prepared finished product leaf alcohol is high in purity and pure in fragrance.

The invention relates to the technical field of ethylene glycol purification, and discloses a purification method of an ethylene glycol solution, a membrane separation device and application of the membrane separation device. The purification method comprises the steps that (1) an ethylene glycol solution is fed for purification treatment, a purification system comprises a membrane separation device composed of a booster pump and a first membrane assembly, and the first membrane assembly at least comprises an I-1 membrane set, an I-2 membrane set and an I-3 membrane set and is used for intercepting ethylene glycol and metal ions; (2) the obtained primary concentrated solution of the purification system is subjected to concentration treatment, a concentration system comprises a membrane separation device composed of a booster pump, a circulating concentration water tank II-1 and a membrane separation assembly II-2 membrane, the II-2 membrane intercepts one or more of monovalent ions, divalent ions and trivalent ions, and purified ethylene glycol clear liquid is obtained. The method is energy-saving and easy to implement, is suitable for purifying the low-concentration ethylene glycol solution, and has a very good industrial application prospect.

The invention relates to the technical field of potassium tert-butoxide preparation, in particular to potassium tert-butoxide refining equipment which comprises a rectifying tower, a reboiler, a cooler and a phase splitter, the crystallization tower is located on the outer side of the rectifying tower, a rectifying chamber of the rectifying tower is connected with a crystallization chamber of the crystallization tower through the pre-filtering assembly, and the heater is installed at the bottom of the crystallization chamber of the crystallization tower; the input end of the low-pressure exhaust pipe is connected with the top of a crystallization chamber of the crystallization tower, the output end of the low-pressure exhaust pipe is connected with the input end of the cooler, the discharging pipe is installed on the side wall of the upper portion of the crystallization tower and communicated with the crystallization chamber of the crystallization tower, and the flashboard is inserted into the discharging pipe in a lifting mode. And the filter plate hopper is mounted in a crystallization chamber of the crystallization tower in a lifting and sliding manner. The azeotropic distillation kettle liquid can be subjected to efficient evaporation drying, redispersion, cooling crystallization and other processes after azeotropic distillation, potassium tert-butoxide can be efficiently discharged, and the practicability is good.

The invention relates to the technical field of eutectic crystals, in particular to a lutein and mannitol eutectic crystal as well as a preparation method and application thereof, an XRD (X-Ray Diffraction) pattern of the eutectic crystal has characteristic diffraction peaks at least at positions where 2 theta angles are 9.71 degrees, 19.44 degrees, 20.4 degrees, 21.17 degrees, 22.07 degrees, 24.67 degrees, 25.32 degrees, 36.1 degrees, 40.39 degrees and 44.9 degrees, and error tolerance of + / -0.2 degrees exists; a characteristic endothermic peak exists at 163.7 DEG C in a DSC spectrum, and an error tolerance of + / -0.2 DEG C exists; the preparation method comprises the following steps: respectively dissolving mannitol and xanthophyll in water and absolute ethyl alcohol, mixing, carrying out high-temperature and high-pressure reaction, standing, crystallizing, filtering, spray-drying and grinding to obtain the eutectic crystal, and the eutectic crystal can be applied to cosmetics, health-care products, foods and medicines. The eutectic crystal provided by the invention has the advantage of good stability.

The invention discloses a method for preparing methanol from carbon dioxide by coupling biomass direct combustion with wind, light, green and hydrogen. The method comprises the following steps: feeding biomass into a biomass boiler through a screw feeder and a trestle for direct combustion to obtain flue gas with high carbon dioxide content; the flue gas is treated to generate carbon dioxide gas with the pressure ranging from 1.4 MPaG to 1.6 MPaG; the method comprises the following steps: mixing carbon dioxide gas and hydrogen according to a molar ratio of about 1: 3, and compressing the mixture into 9.0 MPaG synthesis gas through a synthesis gas compressor; the synthesis gas flows to a gas-gas heat exchanger for heat exchange and temperature rise, and then is introduced into a methanol synthesis tower to form a material; the materials are subjected to heat exchange and cooling through a gas-gas heat exchanger and then flow to a high-pressure flash tank to be separated to form first gas and first liquid; the first liquid flows to a low-pressure flash tank to be separated to form second gas and second liquid conveyed to a crude methanol rectifying tower; separating and purifying the crude methanol in a rectifying tower to form methanol, fusel and overhead gas flowing to the biomass boiler; the utilization rate of the biomass carbon is improved.

The invention belongs to the technical field of chemical engineering, and particularly relates to an aluminum alkoxide salt and a preparation method thereof. According to the method, argon non-thermal plasma is adopted for bombarding the surface of the aluminum foil, an oxidation film on the surface of the aluminum foil is stripped, active aluminum free radicals are formed, the reaction energy barrier of the aluminum alkoxide salt is reduced, the aluminum alkoxide salt can be synthesized under the catalyst-free condition, and green and efficient synthesis of the aluminum alkoxide salt is achieved; a thiosemicarbazide-carboxylic acid bidentate ligand is adopted for complexing impurity iron in alkoxide aluminum salt, sulfur and nitrogen double coordination sites in a thiosemicarbazide unit are matched with oxygen coordination sites in a carboxylic acid group, higher complexing capacity is formed for the impurity iron, and the stability of the complex is improved; the crystallization is regulated and controlled through the pH response characteristic of the carboxylic acid group, so that the impurity iron in the aluminum alkoxide salt is efficiently removed.

The invention discloses a device and a method for preparing methanol through hydrogenation of carbon dioxide. The device for preparing methanol through hydrogenation of carbon dioxide comprises a circulating compressor, a feed gas preheater, a primary heat exchanger, a methanol reactor, a first cooling gas-liquid separator and a second cooling gas-liquid separator, the circulating compressor is used for compressing feed gas entering the circulating compressor to a preset pressure range to obtain compressed feed gas; the raw material gas preheater can be used for receiving the compressed raw material gas and preheating the compressed raw material gas to obtain preheated raw material gas; the primary heat exchanger can be used for receiving the preheated raw material gas and inputting the preheated raw material gas and a product mixture of the methanol reactor into the methanol reactor after heat exchange; the methanol reactor comprises a shell and a plurality of reaction sections arranged in the shell, wherein the plurality of reaction sections comprise a first-stage reaction section, a second-stage reaction section, a third-stage reaction section and the like. The total carbon conversion rate can be increased, and the energy consumption, the circulating gas amount and the equipment investment cost can be reduced.

The invention relates to the field of biomass energy and chemical industry, in particular to an efficient methanol preparation method based on biomass graded catalytic conversion and cycle coupling. The method comprises the following steps: in a graded catalytic oxidation reaction system, mixing a biomass raw material with a composite vanadium-based catalyst, water, oxygen and circulating methanol for reaction to generate a gas-liquid mixture containing methyl formate; recycling methyl formate by using a gradient variable-pressure rectification separation system; carrying out an interface hydrogenation reaction under the action of a copper-zinc-LTA hierarchical pore catalyst to generate methanol; finally, part of methanol is purified and recycled through membrane separation. The method realizes efficient conversion from biomass to methanol, has the advantages of mild reaction conditions, low energy consumption, high yield and good catalyst stability, and opens up a new path for industrialization of preparation of methanol from biomass.

The present disclosure is directed to methods and systems of purifying solvents. The purified solvents can be used for cleaning a semiconductor substrate in a multistep semiconductor manufacturing process.

Disclosed herein are systems and embodiments for improving energy efficiency of a chemical separations plant through heat integration. Heat integration may provide heating loops between distillation columns and / or integrated electric heating components configured to supply heat to reboilers in the chemical separations plant. Heat integration may use heat from an associated chemical synthesis plant configured to carry out an exothermic reaction (e.g., production of methanol from CO2 and H2). Such integrated process designs allow for the use of “low-grade” heat, thereby improving energy efficiency. Furthermore, such integrated process designs allow for electrification of exemplary chemical separations plants, replacing the use of steam as a heating medium with more energy efficient and carbon-emission neutral, electrical methods.

The invention discloses a sesterterpenoid compound, a preparation method thereof and application of the sesterterpenoid compound in preparation of a medicine for treating psoriasis, and belongs to the technical field of biological medicine. Comprising a compound 1-4, and the structural formula of the compound 1-4 is as follows: # imgabs0. A new molecular template is provided for developing a new psoriasis treatment medicine, and a new thought is provided for further developing a novel treatment strategy with an immunomodulatory effect.

The invention relates to a lignin-based polymer pervaporation membrane, a preparation method thereof and a method for separating and purifying cyclohexane-KA oil. The invention aims to provide a pervaporation membrane which is high in permselectivity, high in stability and good in mechanical property. The pervaporation membrane is used for cyclohexane-KA oil separation and has the advantages of high separation efficiency, low energy consumption and simple process. The preparation method comprises the following steps: adding the surfactant, the polymer and the solvent into a reactor, and stirring at 50-70 DEG C for 4-6 hours to obtain a mixed solution; the method comprises the following steps: adding lignin and a solvent into a reactor, and stirring at room temperature for 4-6 hours to obtain a lignin solution; dropwise adding the lignin solution into the mixed solution, and continuously stirring at constant temperature for 12-24 hours to obtain a membrane casting solution; transferring the membrane casting solution to a centrifugal tube, performing centrifugal separation, and uniformly coating the membrane casting solution on an ultrafiltration membrane material with the membrane thickness of 100-200mm to form a uniform liquid membrane; and drying the liquid membrane to obtain the lignin-based polymer pervaporation membrane. Belongs to the technical field of membrane separation.

The present disclosure relates to an organic solvent purification process and a dehydration system for obtaining a high-purity organic solvent, and according to the present disclosure, a high-purity organic solvent may be obtained by removing an inflow of impurities during a dehydration process.

The invention relates to the field of polyester, and discloses a method for continuously producing 1, 4-cyclohexanedimethanol by taking waste polyester as a raw material. Comprising the following steps: 1) mixing waste polyester with ethylene glycol, and performing alcoholysis under the action of an alcoholysis catalyst to obtain alcoholysis liquid containing diethylene glycol terephthalate; 2) performing primary hydrogenation on the alcoholysis solution under the catalysis of a hydrogenation catalyst A to obtain a reaction solution containing 1, 4-cyclohexane dioctyl phthalate diglycol ester; 3) performing secondary hydrogenation on the reaction liquid under the catalysis of a hydrogenation catalyst B to obtain a reaction liquid containing 1, 4-cyclohexanedimethanol; and 4) carrying out gas-liquid separation and rectification on the reaction liquid to obtain ethylene glycol and 1, 4-cyclohexanedimethanol. According to the method, the CHDM is produced by taking the waste polyester as the raw material, the method is simple in production process flow, and continuous production can be realized; through optimization of the catalyst and the process, high PET conversion rate, high CHDM selectivity, high CHDM yield and low production cost can be realized under relatively mild reaction conditions.

The invention belongs to the technical field of ethanol recovery, and relates to a preparation method of a tubular ceramic carrier-based C-ZIF-67 derived nano-porous carbon doped PDMS mixed matrix membrane and an application of the membrane in recovery of ethanol by pervaporation of a low-concentration ethanol aqueous solution. Comprising the following steps: synthesizing a ZIF-67 crystal, and carbonizing the ZIF-67 crystal to obtain C-ZIF-67 filler particles; the ZIF-67-derived nano-porous carbon particles are prepared through a high-temperature calcination method, the particles are fully carbonized at a certain calcination temperature, disappearance of characteristic groups after carbonization can reduce the influence of surface electrical properties of the particles, and the size shrinkage of the particles is reduced, so that the dispersity of the particles in a matrix membrane is improved; meanwhile, the MOF skeleton structure is still reserved after carbonization, the pore diameter is increased, the carbon material also has strong hydrophobicity, the hydrophobic large-pore-diameter separation pore channels are more beneficial to passing of ethanol molecules and promotion of the separation effect, the separation factor and the total flux are almost kept unchanged after long-time operation and use, and excellent performance is shown; good application prospects are realized.

A phase transfer separation method of an anhydride cured epoxy resin degradation product comprises the following steps: adding anhydride cured epoxy resin into an alkaline degradation solution for degradation to obtain a degradation solution; adding ethanol into the degradation solution, standing to generate a precipitate, and collecting the precipitate by utilizing suction filtration; carrying out vacuum rotary evaporation on the solution subjected to suction filtration at 80 DEG C for 10 minutes to remove ethanol in the solution; adding water into the solution without the ethanol, standing for layering, and taking out a lower-layer oil phase; the method realizes complete degradation of the material under mild conditions, the recovered degradation product is separated by a phase transfer separation method, the separated product can be re-synthesized into a new epoxy resin insulating material, the problem that the insulating material in waste electrical equipment cannot be recovered and utilized in a green manner is solved, resources are effectively saved, the environment is protected, and the method is suitable for industrial production. The practical application value is realized.

Crystalline polymorphic lutein and cocrystal forms of lutein are disclosed. The new forms have enhanced bioavailability and stability, and may be used, for example, for topically delivering lutein to the eye for inhibiting or preventing cataracts, macular degeneration, and photooxidative damage to retinal pigment epithelium.

A gas separation method includes supplying a mixed gas to a zeolite membrane complex and permeating a high permeability gas through the zeolite membrane complex to separate the high permeability gas from other gases. The mixed gas includes a high permeability gas and a trace gas that is lower in concentration than the high permeability gas. The molar concentration of a first gas included in the trace gas in the mixed gas is higher than the molar concentration of a second gas included in the trace gas in the mixed gas. The adsorption equilibrium constant of the first gas on the zeolite membrane is less than 60 times that of the high permeability gas. The adsorption equilibrium constant of the second gas on the zeolite membrane is 400 times or more that of the high permeability gas.

The invention relates to a method for producing high-purity electronic-grade methanol by using industrial-grade methanol. The method comprises the following steps: removing organic impurities and water in a methanol raw material through primary rectification, carrying out microfiltration to preliminarily remove particle impurities, removing zwitterions, carrying out secondary rectification to further remove organic impurities and water, and carrying out nanofiltration to further remove particle impurities. Compared with the prior art, the method has the advantages of high product purity, high process yield, low impurity content, strong process continuity and the like, and the produced electronic-grade methanol product meets SEMI C12 and above standards, so that the method has a relatively strong industrial prospect.

The invention relates to a method for purifying and recovering monoethylene glycol (MEG) from a solution obtained by depolymerizing at least one polyester having at least one MEG unit. The solution is preferably obtained from enzymatic depolymerization of polyethylene terephthalate (PET) contained in a plastic article under alkaline conditions. The invention also relates to a process for recycling and recovering the monomers of a polymer-containing material (e.g., a plastic article) comprising at least one polyester (e.g., PET) having at least one MEG unit.

The invention provides a method for removing acetone in isopropanol. The method comprises the following steps: S1, converting acetone in isopropanol into acetoxime; and S2, rectifying the product obtained in the step S1. According to the method disclosed by the invention, the acetone is removed by innovatively converting the acetone in the isopropanol into acetoxime which is greatly different from the isopropanol in boiling point, the ppm-level acetone in the isopropanol can be effectively removed, the removal rate can reach 100%, and the content of the acetone is as low as 0 ppm through gas chromatography detection. Acetone oxime and other impurities can be almost completely removed in a conventional rectification, ion exchange or adsorption mode, so that the high-purity electronic-grade isopropyl alcohol is obtained.

The utility model discloses an absolute ethyl alcohol preparation purification device which comprises a stable bottom plate, the top of the stable bottom plate is fixedly connected with a protective cover, the top of one side of the inner wall of the protective cover is fixedly connected with an ethyl alcohol storage box, and the bottom of the ethyl alcohol storage box is communicated with a purification assembly used for removing moisture. The purification assembly comprises a guide pipe communicated with the ethanol storage box, the bottom end of the guide pipe is communicated with an operation cylinder, a feed hopper is arranged at the top of the operation cylinder, and calcium oxide is arranged in the operation cylinder. According to the absolute ethyl alcohol preparation and purification device, the operation cylinder is blocked by the blocking plate, when calcium oxide needs to be replaced, the calcium oxide in the operation cylinder can be completely released by directly rotating the screw rod and pulling the moving sleeve and the blocking plate outwards, and even if internal particles are hardened and semi-hard, the operation cylinder is not damaged. And after the blocking plate is moved away, workers can conveniently clear and draw out the residual calcium oxide in the operation cylinder.

The invention relates to a preparation method of propargyl alcohol, and belongs to the technical field of organic chemistry. The reaction formula is as follows: # imgabs0 #; comprising the following steps: (1) taking Z-1, 3-dichloropropene as a raw material, adding dimethyl sulfoxide and solid alkali into an organic solvent, heating, carrying out heat preservation reaction until the content of the Z-1, 3-dichloropropene is less than or equal to 1%, and cooling to room temperature; (2) adding a phase transfer catalyst and water into the reaction liquid obtained in the step (1), heating, and carrying out a heat preservation reaction until an intermediate 3-chloropropyl-2-ene-1-ol is less than or equal to 0.5%; cooling to room temperature; (3) filtering, separating liquid, and adding an extracting agent into a water phase for extraction; and rectifying the extracted organic phase to obtain propargyl alcohol. By controlling the alkaline strength and reaction parameters in the reaction, the production of organic impurity ether compounds can be effectively controlled, the purity and yield of the product are improved, and meanwhile, the reaction time is shortened.

The invention discloses a separation and preparation method of D-chiro-inositol, and relates to the technical field of D-chiro-inositol production, a D-chiro-inositol conversion liquid is subjected to thallus removal, deproteinization, desalination and concentration, then ethanol is added for primary separation, ethanol is added again for crystallization after dealcoholization, D-chiro-inositol is purified, and the D-chiro-inositol is obtained. The ethanol is an inert solvent, more chiral inositol in the solution can be crystallized by adding the ethanol, the yield is increased, after the ethanol is added, the viscosity of a crystallization system is reduced, the flowability of the system is better, the crystal can grow more uniformly during crystallization, the crystal is more uniform, and the purity of the product is improved. And the quality of the D-chiro-inositol is improved.

The invention discloses a polysilsesquioxane / polyether-ether-ketone composite membrane, a preparation method thereof and application of the polysilsesquioxane / polyether-ether-ketone composite membrane in organic mixed solvent separation, and aims to solve the problem of large-area deposition of a defect-free polysilsesquioxane hybrid membrane on a polymer substrate in the prior art. According to the present invention, the 1, 2-bis (triethoxysilyl) ethane polysilsesquioxane precursor is adopted as the raw material to prepare the membrane material, the new membrane preparation method is provided, the processing process is designed and optimized from the aspects of the simplicity and convenience of the membrane preparation process, the industrialization of the membrane separation technology, the improvement of the membrane preparation efficiency and the like, the membrane preparation efficiency is improved, and the certain separation performance is provided; the method has an excellent effect on separation and recovery of methanol / toluene and methanol / dimethyl carbonate.