1045 results about "Propanediol" patented technology

The invention belongs to the technical field of oil and gas development, and particularly relates to an oil and gas well blocking remover and a preparation method thereof. The blocking remover comprises the following components: 5-8% of low-carbon composite organic acid, 5-7% of fluoboric acid, 6-9% of ammonium bifluoride, 4-6% of an anti-acid sludge mutual solvent, 2-4% of a corrosion inhibitor, 2-4% of polyoxypropylene polyoxyethylene propylene glycol ether, 8-12% of a permeation dispersion surfactant, 2-5% of a sulfur dissolving agent, 2-5% of a stable chlorine dioxide solution and the balance of water. The preparation method comprises the following steps: adding the low-carbon composite organic acid, the fluoboric acid and the ammonium bifluoride into water and stirring; adding an acid sludge resisting mutual solvent and a sulfur dissolving agent, and stirring; adding the corrosion inhibitor, the polyoxypropylene polyoxyethylene propylene glycol ether and the permeation dispersion surfactant, and stirring; and finally, reducing the stirring speed, adding the stable chlorine dioxide solution, and stirring to uniformly mix. The blocking remover provided by the invention is comprehensive in blocking removal function, very good in dissolving and dispersing performance on complex blocking substances, very small in corrosion damage to a shaft pipe wall and wide in applicability.

The invention discloses a supported nickel catalyst for preparing 1, 3-propylene glycol through hydrogenation of 3-hydroxypropionaldehyde as well as a preparation method and application of the supported nickel catalyst, and relates to the technical field of catalysts. The modified long-chain multi-carbon inducer is used, and a special long-chain molecular structure and a branched chain group of the inducer can effectively and selectively adsorb and occupy a micropore impregnation site; the preparation method has the beneficial effects that more active component nickel species are obviously promoted to be dispersed in main reaction confinement spaces such as mesopores and macropores and interact with the carrier to form effective active sites, and active component steeping liquor is inhibited from entering micropore channels due to capillary action; the active site failure caused by agglomeration of nickel species in micropores in the subsequent drying and roasting process of the catalyst precursor is avoided, the efficient and directional reaction is ensured, the generation of by-products is greatly reduced, the pressure is relieved for the subsequent product rectification separation, and the final product purity is improved. The catalyst provided by the invention can still keep an excellent catalytic effect when the air speed of a 3-hydroxypropionaldehyde solution is increased to 6.5 h <-1 >.

The invention relates to the technical field of pharmaceutical preparations, and provides a minoxidil film coating agent as well as a preparation method and application thereof. The minoxidil film coating agent provided by the invention comprises 40-60% of propylene glycol, 3-7% of polyvinyl alcohol, 20-30% of ethanol, 1-7% of minoxidil and the balance of water. According to the invention, propylene glycol is taken as a solvent, a plasticizer and a transdermal absorption enhancer, polyvinyl alcohol is taken as a film-forming material, and ethanol is taken as a volatile agent, after administration, ethanol is volatilized to promote film formation of polyvinyl alcohol, and propylene glycol enhances the plasticity of the formed film, so that the effect of reducing liquid medicine loss is achieved, the local medicine concentration is increased, and the bioavailability is improved. The minoxidil liniment disclosed by the invention has excellent skin permeability, can effectively convey a medicine to a required part, and can ensure that the medicine is released at a fixed position of the skin and is accurately administered in a medicine release process, so that the stimulation of liquid medicine flow to other parts is reduced, and a good treatment effect is achieved.

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The application discloses a thickened oil viscosity reducer for a main viscosity contribution component of colloid and a preparation method thereof. The thickened oil viscosity reducer comprises the following components in percentage by weight: diethylene glycol methyl ether 25-35%, propylene glycol formate 15-25%, dispersant 5-8%, chelating agent 2-4%, anti-coking agent 0.5-1%, anti-swelling agent 1-2% and corrosion inhibitor 1-2%; and the balance is water. The application is a polar + non-aromatic hydrocarbon solvent system; completely avoids high-risk substances such as nonylphenol polyoxyethylene ether, petroleum sulfonate sodium and organic chlorine; is designed in pertinence and can effectively inhibit metal-induced asphaltene bridging; can withstand working conditions from normal temperature to 250 DEG C and up to 300 DEG C; thermal stability is significantly enhanced, and residual carbon after aging is lower than 8%; viscosity reduction efficiency is higher; the system is more stable, flexible in compounding and suitable for field construction.

The invention discloses a high-temperature-resistant flame-retardant CPVC power cable protection pipe and a preparation method thereof, and relates to the technical field of cable protection pipes. The high-temperature-resistant flame-retardant CPVC power cable protection pipe at least comprises the following raw materials in parts by mass: 100 parts of chlorinated polyvinyl chloride; 15 to 25 parts of high impact resistance type MCS resin; 8 to 12 parts of poly (1, 2-propylene glycol adipate); 12 to 20 parts of a sepiolite-methyl methacrylate-butyl acrylate compound; 8-15 parts of aluminum-titanium composite coupling agent modified magnesium-aluminum-lanthanum hydrotalcite; 3-6 parts of a rare earth composite heat stabilizer; 2-4 parts of a processing aid; 0.5 to 1.5 parts of an antioxidant; and 1-2 parts of a lubricant. The prepared high-temperature-resistant flame-retardant CPVC power cable protection pipe has high heat resistance, high flame retardance and high impact resistance, and is excellent in comprehensive performance, high in safety and reliability and long in service life.

A method for preparing 1,2-propanediol involves reacting propene with hydrogen peroxide in the presence of a catalyst mixture containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase. The process then involves separating the reaction mixture into an aqueous phase (Pa) containing 1,2-propanediol and an organic phase (Po); recycling at least part of the separated organic phase (Po) to the reaction; and recovering 1,2 propanediol from the separated aqueous phase (Pa). In the recovery, 1,2-propanediol is separated from the aqueous phase (Pa) by distillation and the apparent pH of the separated aqueous phase (Pa) is adjusted to at least 9 prior to the distillation to reduce the content of formic acid and acetic acid in the recovered 1,2-propanediol.

The invention discloses a hyperbranched flame retardant as well as a preparation method and application thereof. The flame retardant is prepared by the following steps: dehydrating and pre-polymerizing a boron-containing component (such as tetrahydroxy diborane) and dihydric alcohol (such as 1, 3-propylene glycol), and condensing with trihydroxymethyl phosphine oxide. 4 parts of the flame retardant is added into epoxy resin, phosphorus-containing free radicals can be released in a gas phase for quenching and smoke suppression, a compact boron-containing expanded carbon layer is formed in a condensed phase, and synergistic flame retardance is achieved. The hyperbranched structure can be embedded into an epoxy network, synchronous reinforcement and toughening are achieved, the impact strength is improved by 123.5%, and the tensile strength is improved by 47.7%. The flame retardant has efficient flame retardance (the limit oxygen index is 33.9%, UL-94V-0 level), high transparency and excellent mechanical properties, and is suitable for epoxy resin composite materials in the fields of electronic packaging, aerospace and the like.

According to the method, industrial-grade 1, 2-propylene glycol co-produced by a dimethyl carbonate process through a transesterification method is taken as a raw material, and purification processes of activated carbon adsorption impurity removal, deodorant impurity removal and rectification impurity removal are carried out, so that various indexes such as chromaticity, odor, purity and ultraviolet light transmittance of the obtained 1, 2-propylene glycol product reach the quality indexes of an imported pharmaceutical-grade 1, 2-propylene glycol product. According to the method disclosed by the invention, the pharmaceutical grade propylene glycol can be prepared with high quality, and a good development prospect and huge economic benefits are undoubtedly brought to the propylene glycol industry.

The present application relates to the field of cosmetic technology, in particular to a quick-drying and shaping spray and a preparation method thereof, in particular to a hair styling product which is quickly dried, permanently shaped and has hair care effect through the synergistic effect of specific film-forming agents and volatile systems, comprising the following components: ethanol 30-50%, aminomethyl propanol 0.1-1%, butanediol 1-5%, octyl acrylamide / acrylate / methyl acrylate copolymer 5-15%, PEG-12 dimethicone 0.5-2%, keratin 0.1-2%, hydrolyzed keratin 0.1-2%, oxidized keratin 0.1-2%, aloe barbadensis leaf extract 0.5-3%, selaginella kurata extract 0.5-3%, radix falatoniae extract 0.5-3%, radix salviae miltiorrhizae extract 0.5-3%, water 20-40%, essence 0.1-2%, cetrimonium chloride 0.1-1%, phenoxyethanol 0.5-1.5%, propylene glycol 1-5%, p-hydroxyacetophenone 0.5-1.5%, chlorphenesin 0.1-0.5%, ethylhexylglycerin 0.5-1.5%.

The present application relates to a kind of powder coating hydroxyalkylamide matting curing agent and its preparation method, the matting curing agent using including citric acid, 2-methyl-1,3-propanediol, dimethylbenzene, anhydrous methanol, N-methyl monoethanolamine, catalyst, nanometer titanium dioxide is reacted to obtain raw materials.In first, citric acid and 2-methyl-1,3-propanediol are grafted to carry out reaction, then the remaining four carboxyl groups of grafting are methyl esterification reaction, obtain methyl esterification product, then with N-methyl monoethanolamine acylation reaction obtains hydroxyalkylamide curing agent;Add nanometer titanium dioxide, fully mix and process to obtain the matting curing agent.The curing agent product functionality is higher, the hardness of coating film after curing is higher, and the boiling water resistance is excellent;And the coating film after curing has obvious matting effect, coating film gloss is basically reached 50-70%, and the decorative property is excellent.

A method for preparing 1,2-propanediol involves continuously reacting propene with hydrogen peroxide in the presence of a catalyst mixture, containing a quaternary ammonium salt and a polytungstophosphate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase containing an alkylaromatic hydrocarbon solvent. The method then involves withdrawing the liquid reaction mixture from the reaction and adding a water-soluble sulfate salt or sulfuric acid to provide a mixture containing from 500 to 10,000 mg / kg of sulfate ions in the aqueous phase. The method further involves separating the mixture obtained into an aqueous phase (Pa) containing 1,2-propanediol and an organic phase (Po), recycling at least a part of the organic phase (Po) to the reaction, and recovering 1,2-propanediol from the aqueous phase (Pa). The method allows for extended operation of the reaction with little loss of tungsten and phase transfer catalyst.

This invention belongs to the field of natural product extraction technology, specifically relating to a method for extracting total polyphenolic active substances from Gastrodia elata in food and cosmetics. The method uses a eutectic solvent as the extraction solvent, combined with ultrasonic extraction. The hydrogen bond acceptors of the eutectic solvent include polyethylene glycol-200, polyethylene glycol-400, and Tween 80, while the hydrogen bond donors include ethylene glycol, 1,2-propanediol, glucose, glycerol, and xylitol. This invention, using a eutectic solvent combined with ultrasonic extraction, achieves high extraction efficiency of total polyphenolic substances from Gastrodia elata, reaching a maximum of 33.2 mg / g. The extraction method of this invention is simple, has a short extraction time, and is practical, showing great development potential in the fields of medicine, food, and cosmetics.

The invention discloses a novel compound rapid surface anesthetic and a preparation method thereof, and belongs to the field of pharmaceutical preparations. According to the anesthetic, core anesthetic components of lidocaine and tetracaine are compounded with propylene glycol-laurocapram synergistic penetration enhancer, menthol auxiliary penetration enhancer, carbomer 980 gel matrix, triethanolamine pH regulator, glycerol humectant, panthenol soothing agent, purified water and the like, a surface smearing agent is prepared through a specific process, and the anesthetic can be administered in combination with an iontophoresis technology. Compared with the existing surface anesthetic for the cosmetic surgery, the surface anesthetic disclosed by the invention solves the problems of slow effect taking and poor effect, can realize rapid penetration of local skin, has short anesthesia effect taking time, long duration and good effect, has no obvious irritation to the skin, has good product stability, can effectively reduce the drug toxicity, and has a good application prospect. The device is suitable for surface anesthesia of non-surgical medical beauty items such as skin beauty, laser treatment and water-light micro-needles.

The invention discloses a method for preparing 1, 3-propylene glycol by hydrating and hydrogenating acrolein, which comprises the following steps: carrying out hydration reaction by taking an acrolein aqueous solution as a raw material and taking acylated and aminated modified polystyrene resin as a catalyst; carrying out flash evaporation or gas stripping on the product after the reaction to remove acrolein, condensing and recovering the removed acrolein, and carrying out hydrogenation reaction on the acrolein-removed mixed solution serving as a hydrogenation raw material on a metal catalyst; and after the reaction is finished, performing flash evaporation on the product to remove water and light components, and performing vacuum rectification to obtain a high-purity 1, 3-propylene glycol product. According to the method, the modified resin is used for catalyzing the acrolein hydration reaction, the overall yield of the 1, 3-propylene glycol can be increased, the catalyst modification process is simple, the cost is low, the additional value of the final product is high, and the method is suitable for industrial production.

The invention belongs to the technical field of chemical component detection, and particularly relates to a method for detecting residues of 1, 3-dichloro-2-propanol, 2, 3-dichloro-1-propanol and 3-chloro-1, 2-propylene glycol in dihydroxypropyl theophylline. The detection method comprises the following steps: (1) adding a solvent into diprophylline for dilution, and uniformly shaking to prepare a test solution; (2) detecting the liquid to be detected by adopting a gas chromatography-tandem mass spectrometry method, and calculating the content of 1, 3-dichloro-2-propanol, the content of 2, 3-dichloro-1-propanol and the content of 3-chloro-1, 2-propylene glycol in the diprophylline according to an external standard method; the solvent is a mixture of formic acid and DMF (Dimethyl Formamide). The method provided by the invention is good in specificity, high in sensitivity, good in repeatability and high in accuracy, and can be used for simultaneously detecting 1, 3-dichloro-2-propanol, 2, 3-dichloro-1-propanol and 3-chloro-1, 2-propylene glycol in the diprophylline.

The invention belongs to the field of chemical engineering, and relates to a process device and method for continuously synthesizing glycidyl (3-chloro-1, 2-propylene glycol and sodium hydroxide (hereinafter referred to as NaOH) as raw materials). The device comprises a raw material feeding pump, a heat exchanger, a micro-reactor, a delay tube reactor 1, a neutralization micro-reactor and a delay tube reactor 2 which are sequentially in fluid communication through pipelines, the heat exchangers are divided into two groups, one group is used for heat exchange of 3-chloro-1, 2-propylene glycol solution, and the other group is used for heat exchange of alkaline solution. According to the method, a 3-chloro-1, 2-propylene glycol solution and a sodium hydroxide solution (NaOH) are adopted as raw materials, glycidol is continuously prepared through a microchannel reactor, on the basis, an acid-base neutralization reaction can be carried out in situ according to needs to remove redundant alkali, redundant heat generated by the acid-base neutralization reaction is absorbed through a low-temperature material, and energy consumption is reduced; the product is analyzed by gas chromatography, and the generated glycidol does not have hydrolysates or auto-polymerization products, so that the product selectivity is higher.

The application relates to the technical field of ink solvents, and particularly discloses an environmentally-friendly water-based ink solvent with high drying efficiency and a preparation method thereof, the environmentally-friendly water-based ink solvent with high drying efficiency comprises the following raw materials in parts by weight: 40-60 parts of water, 30-50 parts of a bio-based alcohol compound, 5-15 parts of n-propyl acetate, 0.3-1 part of tripropylene glycol n-butyl ether, 1-3 parts of nano-cellulose, 0.5-1 part of calcium chloride, 1-2 parts of a pH regulator and 0.2-0.4 parts of a chelating agent. The environmentally-friendly water-based ink solvent with high drying efficiency and the preparation method thereof can be used for ink printing, and have the advantages of high drying efficiency and good stability.

The invention relates to the technical field of biodegradable high polymer materials, in particular to a tear-resistant high-barrier biodegradable mulching film and a preparation method thereof, and the tear-resistant high-barrier biodegradable mulching film is prepared from the following raw materials in parts by weight: 60-90 parts of poly (butylene adipate-co-terephthalate); 10 to 40 parts of poly (propylene carbonate); 0.5-5 parts of a plasticizer; 0.05 to 0.3 part of a cross-linking agent; 0.1 to 10 parts of talcum powder; 0.1 to 2 parts of a lubricant; 0.1-1 part of an anti-blocking agent; 0.1 to 1 part of an antioxidant; 0.1 to 1 part of an anti-ultraviolet agent; 0.1-1 part of a light stabilizer; 0.1 to 1 part of an anti-hydrolysis agent; 0.1-1 part of a nucleating agent; the plasticizer is poly (1, 2-propylene glycol adipate); and the cross-linking agent is 1, 4-bis (tert-butylperoxy) diisopropyl benzene. The film has good mechanical properties and water vapor transmission amount, can be completely biodegraded, and has good aging resistance.

The invention belongs to the technical field of skin care products, and discloses a quick-acting red-removing repair product which comprises the following components: water, caprylic / capric triglyceride, glycerol, sorbitol, phosphatidylcholine, 1, 3-propylene glycol, xanthan gum, eicosapentaenoic acid, docosahexaenoic acid, phytosphingosine, centella asiatica extract and tocopheryl acetate. A turmeric rhizome extract and 1, 2-hexanediol. Through mutual cooperation of the turmeric root extract and the centella asiatica extract, by taking enhancement of skin immune regulation and skin barrier functions as an action mechanism, on one hand, skin inflammatory response can be inhibited, and inflammation, microorganisms and bacteria can be effectively resisted, and on the other hand, skin barrier reconstruction can be promoted, wound healing can be promoted, and an ECM matrix can be protected; in addition, the eicosapentaenoic acid, the docosahexaenoic acid, the turmeric root extract, the phytosphingosine and the centella asiatica extract are wrapped by the nano-microcapsule liposome, so that the activity of the product can be ensured.

The invention relates to the technical field of ink solvents, and particularly discloses an environment-friendly water-based ink solvent with high drying efficiency and a preparation method of the environment-friendly water-based ink solvent. The environment-friendly water-based ink solvent with high drying efficiency is prepared from the following raw materials in parts by weight: 40 to 60 parts of water, 30 to 50 parts of bio-based alcohol compound, 5 to 15 parts of n-propyl acetate, 0.3 to 1 part of tripropylene glycol n-butyl ether, 1 to 3 parts of nano cellulose, 0.5 to 1 part of calcium chloride, 1 to 2 parts of pH regulator and 0.2 to 0.4 part of chelating agent. The environment-friendly water-based ink solvent with high drying efficiency and the preparation method thereof can be used for ink printing, and have the advantages of high drying efficiency and good stability.

The invention discloses a sialic acid mild brushing acid composition and application thereof, and relates to the technical field of cosmetics. The sialic acid mild brushing acid composition comprises sialic acid and a solvent, the mass concentration of the sialic acid is 2%-15%, and the solvent is selected from at least one of 1, 3-propylene glycol, butanediol, dipropylene glycol and water. The sialic acid is creatively used as one of the mild brushing acid components, can soften old and waste cutin mildly and promote cutin exfoliation and permeation and absorption of the sialic acid, so that the sialic acid can fully play a skin protection role, has an excellent mild cutin exfoliation effect and has the effects of improving hyperpigmentation and coarse pores; and a dynamic balance skin care strategy of breaking while standing and breaking while standing can be realized. The prepared cosmetics have better moisture retention and safety, repair barriers through moisture retention, improve pigmentation through oxidation resistance, stimulate collagen to remodel a supporting structure to improve coarse pores, and finally consolidate the health state of the skin through immunoregulation.

The invention relates to a double-self-repairing hydroxyl acrylic coating and a spraying process thereof, and belongs to the technical field of coatings. Comprising 50 to 60 parts of a hydroxy acrylic resin-furan modified copolymer, 5 to 10 parts of a maleimide compound, 3 to 8 parts of propylene glycol methyl ether acetate, 5 to 10 parts of dimethyl carbonate, 5 to 8 parts of polyurethane microcapsules, 5 to 7 parts of carbon black, 2 to 5 parts of modified titanium dioxide, 0.8 to 1.2 parts of a modified polyether siloxane leveling agent and 0.2 to 0.4 part of an organic bismuth-zinc composite drier. 2 to 5 parts of fumed silica; and 1 to 2 parts of nano montmorillonite. The paint provided by the invention can form a uniform and continuous coating on the surface of a base material. When the coating is damaged by scratches and the like, self-repairing can be achieved through double mechanisms. According to the spraying process, the polyurethane microcapsules and the matrix resin are separately mixed, and breakage caused by direct mixing of the microcapsules and the resin can be effectively avoided.

The invention discloses a special ergothioneine-containing skin repair hydrogel for pets and a preparation method of the special ergothioneine-containing skin repair hydrogel, and belongs to the technical field of pet skin care hydrogels. The invention relates to a skin care product which comprises the following components in parts by weight: 1.6-3.8 parts of a functional active component consisting of ergothioneine, quaternized chitosan and oat beta-glucan, 0.15-0.35 part of a cross-linking agent, 5-10 parts of 1, 3-propylene glycol, 5-10 parts of glycerol, 0.2-0.5 part of a preservative and the balance of water, totaling 100 parts. Through precise compatibility of functional active components and synergistic construction of the ionic cross-linked gel matrix, systematic integration of three effects of oxidation resistance, bacteria resistance and healing promotion is achieved, and the technical problems that an existing pet skin care product is single in function, insufficient in synergy and limited in repairing effect are solved.

The invention discloses a bio-based modified high polymer material and a preparation method thereof, and relates to the technical field of high polymer materials. When the bio-based modified high polymer material is prepared, firstly, lignin reacts with terephthalaldehyde to prepare formylated lignin; carrying out multi-component reaction on the aldehyde lignin to obtain modified lignin; the preparation method comprises the following steps: reacting 4-mercaptophenylboronic acid with 1-mercaptoglycerol to prepare a dimercaptoborate cross-linking agent; the preparation method comprises the following steps: reacting isophorone diisocyanate with polytetrahydrofuran ether glycol, and then reacting with a flame-retardant chain extender, 1, 2-propylene glycol and hydroxyethyl methylacrylate to prepare modified polyurethane; and mixing the modified polyurethane, the modified lignin and a dimercaptoborate cross-linking agent, casting and curing to obtain the bio-based modified high polymer material. The bio-based modified high polymer material prepared by the invention has the advantages of flame retardance, antibacterial property, aging resistance, self-repairing property, repeatable processing and high mechanical strength.

Disclosed is a process for the synthesis of mono- and bis-nitrosylated propanediols, as well as compositions and pharmaceutical formulations that includes the compounds. The process proceeds by reacting a corresponding propanediol that is not nitrosylated with a source of nitrite, optionally in the presence of a suitable acid. When the source of nitrite is an organic nitrite, reacting step is performed in a suitable organic solvent, and when the source of nitrite is an inorganic nitrite, the reacting step is performed in a bi-phasic solvent mixture comprising an aqueous phase and a non-aqueous phase. Also disclosed are methods of treating a condition wherein administration of nitric oxide (NO) has a beneficial effect by administering said compounds, compositions or formulations.

The invention discloses a polyurea composite coating based on MXene at carbon dots. The composite coating is prepared by heating and curing a polyurea composite elastomer based on MXene at carbon dots and an organic solvent, the polyurea composite elastomer based on the MXene (at) carbon dots is prepared by mixing a polyurea elastomer and MXene (at) carbon dot powder; the polyurea elastomer is prepared from the following raw materials: isophorone diisocyanate, poly (propylene glycol) bis (2-aminopropyl ether), isophthaloyl hydrazine and 4, 4 '-diaminodiphenyl disulfide through a two-step condensation polymerization reaction. Based on the synergistic effect of dynamic hydrogen bonds and flexible disulfide bonds of a self-repairing polyurea elastomer structure in the composite coating, the self-repairing characteristic of the composite coating is remarkably enhanced, meanwhile, a brick mud structure is formed through uniform embedding of MXene at carbon dots, and the mechanical strength, corrosion resistance, heat stability and rapid self-repairing capacity of the composite coating are greatly improved.

The invention relates to a method for producing 1, 3-propylene glycol by fermenting recombinant Escherichia coli, which comprises the following steps: (1) a fermentation growth stage: enabling the recombinant Escherichia coli to grow in a culture medium and inducible expression of an enzyme capable of regulating the production of the 1, 3-propylene glycol; and (2) fermentation metabolism stage: cells of recombinant escherichia coli obtained by centrifuging the fermentation liquor obtained in the fermentation growth stage convert substrate glycerol into 1, 3-propylene glycol in a nitrogen-source-free culture medium. According to the method disclosed by the invention, the engineering bacteria are subjected to independent two-stage fermentation metabolism, so that the growth of the bacteria is limited and the activity of the bacteria is kept during biotransformation, and the mass conversion rate from glycerol to 1, 3-propylene glycol is remarkably improved compared with that of the existing method.

A composition of tirzepatide, comprising an agent selected from NaCl and propylene glycol; and dibasic sodium phosphate is provided.

A composition of tirzepatide, comprising an agent selected from NaCl and propylene glycol; and dibasic sodium phosphate is provided.