2770 results about "Carboxymethyl cellulose" patented technology

The invention discloses an absorbable suture line for surgical suture and a preparation method thereof, and relates to the technical field of medical materials. The absorbable suture line for surgical suture is prepared from the following raw materials in parts by weight: 50 to 65 parts of polylactic acid, 15 to 20 parts of polyglycolic acid, 3 to 5 parts of sodium carboxymethyl cellulose, 3 to 8 parts of a toughening agent, 3 to 6 parts of an antibacterial agent, 0.3 to 0.8 part of a lubricating agent, 1 to 2 parts of sodium hyaluronate and 5 to 10 parts of polyvinyl alcohol. The toughening agent is obtained by reacting hydroxyethyl acrylate with ethylenediamine to generate a four-arm compound and then reacting with 6-caprolactone and DL-lactide. The absorbable suture line for surgical suture prepared by the invention has excellent tensile property and antibacterial property, and can meet the application requirements of clinical medical treatment.

The invention relates to the technical field of sole processing, in particular to a sole composite processing method, which comprises the following steps: according to the rigidity requirement of an arch support area, preparing high-density slurry in which silicon nitride ceramic powder accounts for 30-40%, forming # imgabs0 # crystal phase through microwave-assisted sintering, and controlling the porosity to be 10-20%; according to the energy rebound requirement of the forefoot buffer area, graphene oxide / carboxymethyl cellulose aerogel powder is added into the slurry until the concentration is 25%, and the porosity is increased to 40-60% by combining the honeycomb porous network design; a nano silicon dioxide reinforcing agent is introduced into a wear-resistant area of the heel to 15%, a diamond-like carbon coating is formed through plasma surface treatment, and the porosity is limited to be 5-15%. According to the invention, silane is encapsulated by adopting polyurea microcapsules, and is released only when the material is damaged, so that dynamic self-repairing is realized, the shoe sole is endowed with dynamic repairing capability, and the service life is prolonged.

The invention discloses an oral care desensitization paste and a preparation method thereof, and mainly relates to the technical field of dental medicines. The oral care desensitization cream is prepared from the following components: bioactive glass, strontium chloride, sodium chloride, silicon dioxide, sodium carboxymethyl cellulose, polyethylene glycol 400, a xanthan gum solution, sodium lauryl sulfate, sodium lauroyl sarcosinate, titanium dioxide, beta-glucan, saccharin sodium salt, sorbitol, methylparaben, propyl hydroxybenzoate, edible essence and water. Compared with the prior art, the oral care desensitization paste disclosed by the invention can be used for sealing dentinal tubules and treating hemodia; the traditional Chinese medicine composition can also be used for treating plaque gingivitis, relieving and reducing gingival bleeding and inhibiting and reducing dental plaque; and meanwhile, the condition of mistakenly swallowing and eating in the using process is reduced.

The invention provides a dump leaching method for improving the leaching rate of gold ore, and belongs to the technical field of mineral processing. The method comprises the following steps: firstly, separating minerals into oversize products and undersize products; mixing sodium carboxymethyl cellulose, bentonite and ferrous sulfate to obtain a mixture, and granulating the undersize product by using the mixture as a binder; and mixing the undersize product particles with the oversize product, and carrying out cyanide-free dump leaching. According to the method, through graded granulation and heap building, the problem that heap building permeability is poor due to the fact that the gold ore contains many clay minerals is solved. In the granulation stage, ferrous hydroxide colloid generated by hydrolysis of ferrous sulfate in the binder can assist ore particle agglomeration, and particle stability is enhanced; during subsequent cyanide-free dump leaching, ferrous sulfate can be used as an auxiliary reducing agent and a catalyst in a thiourea gold leaching system to promote oxidation and dissolution of gold; meanwhile, ferrous ions can adjust the oxidation-reduction potential of a system, so that the thiourea gold leaching reaction is in a more favorable potential interval, the oxidation efficiency of thiourea is improved, invalid decomposition of thiourea is reduced, and therefore the use amount of thiourea and the use amount of agents are reduced.

The invention discloses light self-repairing concrete and a preparation method thereof, and relates to the technical field of concrete. The method comprises the following steps: firstly, efficiently packaging a calcium nitrate solution in hollow glass beads by utilizing a negative pressure impregnation technology; then growing a porous zeolite crystal coating on the surface of the microbead in situ by adopting a sol-gel method to form a self-repairing filler with a core-shell-hole gradient structure; when the concrete cracks to cause the cracking of the microbeads, the Ca < 2 + > in the cavity is quickly released, and the Ca < 2 + > adsorbed in the zeolite layer is gradually dissociated along with water permeation, so that the new microcracks are continuously repaired. Then, uniformly coating the surface and pores of the carboxymethyl cellulose hydrogel network with polydopamine in an in-situ oxidative polymerization manner to form composite hydrogel with photo-thermal responsiveness; lighting and heating to trigger dynamic coordination bond dissociation; meanwhile, heat drives rapid directional crystallization of a repair product by promoting the ion diffusion rate, and a compact mineralization layer is formed. The concrete prepared by the invention has the effects of light weight and self-repairing.

The invention relates to the technical field of medical dressings, in particular to a perianal drug dressing of a multi-layer flow guide composite fabric and a preparation method and application of the perianal drug dressing of the multi-layer flow guide composite fabric. The perianal drug dressing is of a four-layer structure, a wet tissue adhesion layer is made of polydopamine modified chitosan / oxidized hyaluronic acid hydrogel, and wet-state adhesion is achieved; the drug sustained-release layer is used for dispersing mesoporous silica loaded with ciprofloxacin hydrochloride / defensin and chitosan microspheres loaded with epidermal growth factors / lonicera japonica into a polycaprolactone fiber membrane to achieve synergistic antibacterial and healing promotion; the directional flow guide layer is of a gradient wettability sandwich structure with a bionic micro-channel, and one-way rapid drainage can be achieved; the high-absorption outer layer is carboxymethyl cellulose / sodium polyacrylate composite sponge, liquid is locked efficiently, the wound surface is kept dry and comfortable, the clinical problem in perianal infection wound treatment can be effectively solved, and the treatment effect and the patient comfort are remarkably improved.

The invention provides a biochar composite porous material for heavy metal contaminated soil remediation and a preparation method and application of the biochar composite porous material. The preparation method comprises the steps that biomass raw materials are subjected to high-temperature pyrolysis carbonization and then smashed, ground and sieved, and biochar powder is obtained; dispersing in a phosphoric acid solution to obtain a biochar solution, and filtering, washing and drying after a hydrothermal activation reaction to obtain activated biochar; dispersing in a chitosan solution, carrying out ultrasonic oscillation, filtering, washing and drying to obtain modified charcoal; mixing sodium bentonite, attapulgite and deionized water, uniformly mixing the modified charcoal, the functional slurry and a sodium carboxymethyl cellulose solution to obtain composite slurry, performing compression molding to obtain a green body, and then drying and calcining the green body. The biochar composite porous material prepared by the invention can simultaneously play multiple roles of physical adsorption, chemical chelation, ion exchange and the like in a heavy metal contaminated soil treatment process, so that efficient fixation of various heavy metal ions is realized.

The invention discloses an all-solid-state composite dry conductive agent and a preparation method thereof, and belongs to the technical field of batteries. The all-solid-state composite dry conductive agent is prepared by the following steps: uniformly mixing carbon nanotubes, high-dispersion carbon black and graphene to obtain a primary mixture; then preparing a uniformly dispersed glue solution from the composite dispersant and water; and then adding the primary mixture into the glue solution, uniformly mixing, sanding, homogenizing, drying and crushing to obtain the product, the high-dispersion carbon black is obtained by oxidizing carbon black to form active groups such as carboxyl and hydroxyl on the surface of the carbon black, halogenating acyl and then reacting with lithium 2, 5-diaminobenzene sulfonate. The preparation method comprises the following steps: grafting histidine ester into carboxymethyl cellulose by using propylene glycol diglycidyl ester as a cross-linking agent, then introducing allyl-1, 3-sultone, then copolymerizing with lithium 2-acrylamido-2-methylpropanesulfonate and 3-aminobenzoic acid allyl ester protected by fluorenylmethoxycarbonyl, and then deprotecting to obtain the composite dispersant.

The invention belongs to the technical field of batteries, and particularly discloses a secondary battery, a battery pack and an electric device. A negative electrode film layer of the secondary battery contains an additive; the additive comprises a carboxymethyl cellulose compound and a modified compound thereof; the compound is beneficial to improving the ionic conductivity of alkali metal ions and reducing the diffusion polarization phenomenon, so that the internal resistance of the battery is reduced. And the content of the additive in the negative electrode film layer close to the current collector is controlled to be higher than the content of the additive in the negative electrode film layer far away from the current collector, so that the technical effects of reducing the internal resistance of the battery, controlling the cost and reducing the influence on the energy density of the battery are achieved.

The present invention discloses a 3D three-dimensional glaze, which comprises the following components in percentage by weight: 45% - 60% of silicon dioxide, 17% - 25% of aluminum oxide, 1% - 2% of calcium oxide, 0.06% - 1.2% of magnesium oxide, 0.4% - 0.6% of sodium oxide, 1% - 3% of potassium oxide, 10% - 20% of zirconium oxide, 0.2% - 0.6% of zinc oxide, and 1% - 3% of boron oxide; the loss on ignition of the 3D three-dimensional glaze is 1.8% - 3.6%. The preparation method of the 3D three-dimensional glaze is to quantitatively weigh powders such as zirconium silicate, quartz powder, calcined alumina, potassium feldspar, ceramic frit powder, sodium carboxymethyl cellulose, and industrial tripolyphosphate, and then sequentially add the powders and emulsifying wax into water and stir to obtain a glaze slurry. After adjusting the viscosity of the glaze slurry, the 3D three-dimensional glaze is obtained by passing through an 80-mesh sieve. The present invention improves the adhesion of the 3D three-dimensional glaze on the surface of the green body, and when fired directly or in combination with other glazes, the three-dimensional glaze lines will not collapse, crack, have bubbles or breakpoints.

The invention belongs to the field of preparation of organic fertilizers, and particularly relates to a moisturizing and drought-resisting bio-organic fertilizer and a preparation method thereof. The preparation method comprises the following steps: carrying out a cross-linking reaction on a boiled and crushed starch matrix, carboxymethyl cellulose and epoxy chloropropane to form a compound solution, and mixing the compound solution with mixed animal bone meal capable of enhancing the stress resistance of plants, so that the obtained nutritional base material can quickly provide nutrients for the plants for a long time; kelp and seaweed are mixed and ground into thick liquid, under the combined action of calcium chloride and tannic acid, a three-dimensional net-shaped structure is formed, the plant component containing the fungicide is put into the colloid component, and the obtained moisture-preserving and drought-resisting component can keep soil moisture for a long time; the long-acting stability-maintaining suspension can form a protective layer on the surface of soil, the moisturizing and drought-resisting component and the organic fertilizer mixture are mixed, and the prepared moisturizing and drought-resisting bio-organic fertilizer can efficiently and rapidly provide nutrients for crops, has the moisturizing and drought-resisting capacity and can play the moisturizing and drought-resisting roles in a long term.

The invention relates to the technical field of glazes, and discloses a high-performance ceramic glaze for bacteriostatic domestic porcelain and a preparation method thereof. The high-performance ceramic glaze of the antibacterial domestic porcelain is prepared from the following raw materials in parts by weight: 5 to 15 parts of albite, 20 to 30 parts of potassium feldspar, 10 to 30 parts of kaolin, 13 to 26 parts of quartz, 0.3 to 7 parts of talc, 5 to 10 parts of limestone, 2 to 5 parts of ludwigite, 0.5 to 1 part of rare earth, 2 to 5 parts of honeysuckle-loaded CuS, 1 to 3 parts of modified polysiloxane, 0.1 to 0.5 part of sodium tripolyphosphate and 0.1 to 0.3 part of carboxymethyl cellulose. The high-performance ceramic glaze for the antibacterial domestic porcelain prepared by the invention has relatively good long-acting antibacterial performance and high strength.

The invention provides a composite soil conditioner and a preparation method thereof, and belongs to the technical field of agriculture, and the preparation method comprises the following steps: step S1, preparing a multi-arm polymer; step S2, preparing modified biochar; step S3, preparing a sustained-release microcapsule; s4, mixing the modified biochar, the sustained-release microcapsules and the sodium carboxymethyl cellulose solution, and granulating to obtain the composite soil conditioner. The soil conditioner disclosed by the invention can achieve the purposes of efficiently adsorbing heavy metals, adjusting the pH value of soil and helping the soil to retain water.

The invention relates to the technical field of resin preparation, in particular to a preparation method of cellulose degradable water-absorbent resin, which comprises the following steps: mixing sodium carboxymethyl cellulose with water, heating and stirring to obtain a homogeneous solution; a multi-section temperature curve of a freezing procedure is determined according to solution parameters, the solution is placed in one-way freezing equipment, the temperature of a bottom plate is controlled to range from-60 DEG C to-40 DEG C, and ice crystals directionally grow in the vertical direction of the surface of the solution; adding citric acid into the frozen sample, and reacting for 1-2 hours; heating to 40 + / -5 DEG C under the vacuum pressure of 1-5kPa, drying at constant temperature for 12-36 hours, soaking and washing twice with deionized water, 1 hour each time, finally drying for 6-10 hours, and crushing until the particle size is 0.5-2.0 mm. According to the invention, one-way freezing equipment capable of accurately controlling the freezing rate is adopted, and a magnetic field with specific parameters is applied in a slow cooling stage, so that the growth direction, size and distribution of ice crystals can be more effectively controlled; therefore, a more uniform and controllable pore structure is formed in the final water-absorbent resin.

The invention provides a flexible fluorescence sensor as well as a preparation method and application thereof. The flexible fluorescence sensor comprises TCTG particles and dual-network hydrogel, the TCTG particles are distributed in network pores of the dual-network hydrogel to form functional gel, the TCTG particles are formed by Ti3C2TxMXene nanosheets and graphene quantum dots, the dual-network hydrogel is formed by acrylamide and sodium carboxymethyl cellulose, and the TCTG particles are distributed in the network pores of the dual-network hydrogel to form functional gel. The functional gel is soaked in a hydrochloric acid glycol solution for treatment. The flexible fluorescence sensor provided by the invention can integrate the structural advantages of all the components, so that a synergistic coupling effect is possibly generated, a fluorescence detection function with excellent mechanical strength, frost resistance and high sensitivity is integrated into a multifunctional system, the food spoilage condition can be reliably monitored in real time under a harsh environmental condition, and the application prospect is wide. And health and economic risks caused by occupational exposure and environmental emission in an aquatic product supply chain are solved.

The invention relates to the technical field of steel-cored aluminum stranded wires, and provides an overhead high-conductivity steel-cored aluminum stranded wire which comprises a galvanized steel core and aluminum wires stranded on the surface of the galvanized steel core, the galvanized steel core is formed by stranding 19 steel wires, and the aluminum wires are divided into two layers and stranded on the outer side of the galvanized steel core; the preparation method of the galvanized steel core comprises the following steps that after being galvanized, a steel wire is added into a passivation solution to be passivated, and the galvanized steel core is obtained after drying and twisting; the passivation solution is prepared from the following raw material components: waterborne acrylic resin, nickel nitrate, sodium carboxymethyl cellulose, sodium dodecyl sulfate, functionalized single-walled carbon nanotubes and water; the functionalized single-walled carbon nanotube is prepared from the following raw materials: a single-walled carbon nanotube and 5-carboxyl-2, 3-diaminopyridine. According to the technical scheme, the problem that the corrosion resistance of the manufactured overhead steel-cored aluminum stranded wire is poor due to the fact that the corrosion resistance of a galvanized steel core is poor in the prior art is solved.

The invention relates to the technical field of polyurethane impermeable materials, and particularly discloses a high-molecular impermeable material with oil resistance and impermeability as well as a preparation method and application thereof, and the high-molecular impermeable material comprises the following components in parts by weight: 120 parts of a polyurethane prepolymer, 20-45 parts of a diluent, 10-30 parts of an auxiliary agent, 15-20 parts of a micro-powder filler, 10-15 parts of carboxymethyl cellulose and 3-8 parts of dibasic hydrogen phosphate; wherein the polyurethane prepolymer is prepared from a diisocyanate compound and polyether polyol through a reaction; wherein the micro powder filler is a mixture of sodium acrylate hydrogel micro powder and sodium alginate hydrogel micro powder; wherein the dibasic hydrogen phosphate is monovalent ion salt. The high-molecular anti-seepage material has excellent anti-seepage performance in an oil storage environment, has relatively high adhesive force, and can be suitable for grouting in a humid environment; and water resistance and oil resistance of an underground water-sealed stone cavern oil depot environment can be better realized.

The invention provides a fresh-keeping composite solution sprayed before picking fruits in cold-chain logistics transportation and a preparation method of the fresh-keeping composite solution, and relates to the field of fruit fresh keeping. The fresh-keeping composite solution is prepared from the following raw materials in parts by weight: 2.8 to 3.5 parts of schizochytrium limacinum powder, 2.3 to 2.8 parts of salvia officinalis extract, 1.8 to 2.2 parts of brown algae extract, 1.2 to 1.8 parts of banana peel polysaccharide, 0.8 to 1.2 parts of sodium carboxymethyl cellulose, 0.8 to 1.2 parts of tea polyphenol, 0.8 to 1.2 parts of beta-cyclodextrin, 0.8 to 1.2 parts of sodium alginate, 0.8 to 1.2 parts of calcium chloride, 0.4 to 0.6 part of olive oil, 0.1 to 1 part of malic acid and 80 to 90 parts of water. The composite fresh-keeping solution is developed for cold-chain logistics transportation of fruits and is applied before fruit picking, the synergistic effect of multiple natural components is utilized, sterilization and oxidation resistance can be achieved, the growth of microorganisms can be effectively inhibited, the respiration rate of the fruits is reduced, the moisture of the fruits is kept, and the optimal fresh-keeping effect is achieved. The fruit preservative is sprayed before the fruits are picked, so that decay and quality reduction of the fruits in the cold-chain logistics transportation process can be effectively reduced.

The invention discloses antibacterial polypeptide and application thereof in preparation of pet shower gel, and belongs to the technical field of antibacterial polypeptide. The antibacterial polypeptide is prepared from the following raw materials in parts by weight: 2 to 5 parts of glycerol, 3 to 5 parts of plant polypeptide, 20 to 40 parts of sorbitol, 1 to 2 parts of sodium carboxymethyl cellulose, 0.5 to 1 part of xanthan gum, 2 to 5 parts of sodium methyl hydroxybenzoate, 0.5 to 1 part of a surfactant, 0.5 to 1 part of chlorhexidine, 0.05 to 0.3 part of triclosan and 100 parts of deionized water. The antibacterial polypeptide prepared by the invention can be applied to the preparation process of pet shower gel, and has good antibacterial performance.

The invention provides a gel dressing and a preparation method thereof, and belongs to the technical field of medical materials.The gel dressing comprises a basement membrane which is a PVA membrane; the gel layer is arranged on the surface of the basement membrane, and the gel layer is prepared from recombinant collagen, exosome, sodium hyaluronate, sodium carboxymethyl cellulose, chitosan and water; the microneedles are evenly arranged on the side, away from the basement membrane, of the gel layer, the microneedles are made of polylactic acid-hydroxy acid copolymer, and the needle tips of the microneedles are loaded with recombinant collagen and exosomes. A skin channel is opened through the microneedle array, the permeation efficiency of recombinant collagen and exosome is improved by multiple times, a large number of active ingredients can quickly reach the deep layer of the skin, and the skin repairing effect is remarkably enhanced.

The invention relates to a sodium carboxymethyl cellulose modified ultrathin alkaline water electrolysis composite diaphragm as well as a preparation method and application thereof. The alkaline electrolytic water diaphragm provided by the invention not only has excellent hydrophilicity and low surface resistance, but also has high gas barrier property and excellent mechanical property. In addition, the diaphragm is simple in preparation process and low in cost, and has industrial application potential.

The invention discloses a solid-state flash-release acne-removing composition and an application thereof in a soluble microneedle, and particularly belongs to the technical field of cosmetics. The acne-removing composition is prepared from the following components in parts by mass: 0.5 to 1 part of acne-removing functional component, 4 to 5 parts of hyaluronic acid and 1 to 2 parts of carboxymethyl cellulose, the acne-removing functional component contains a spruce extract, a yeast / zinc fermentation product and dipeptide-15, and the spruce extract is prepared through supercritical extraction. The soluble microneedle containing the acne-removing composition is prepared by utilizing a soluble microneedle preparation technology, and the effects of quickly resisting inflammation, inhibiting bacteria and quickly transdermal repairing can be achieved.

The invention belongs to the technical field of bioengineering medicines, and particularly relates to a gel dressing for repairing skin wounds and a preparation method of the gel dressing. The anti-fouling coating is prepared from the following raw materials in parts by weight: 65 to 75 parts of polyvinyl alcohol, 14 to 20 parts of sodium alginate, 4 to 8 parts of sodium carboxymethyl cellulose, 1 to 3 parts of sodium hyaluronate, 12 to 22 parts of glycerol, 1 to 3 parts of surface anti-fouling additive, 6 to 10 parts of antibacterial microcapsule and 2 to 2.8 parts of compound ion. According to the invention, a PVA freeze-thaw physical network and an alginic acid Ca / Zn composite ion network cooperate to limit a pore channel, so that stable forming is realized; a chitosan / sodium tripolyphosphate microcapsule is prepared from polyhexamethylene biguanide hydrochloride and covered with sodium alginate, release sensitive to pH / ionic strength, acceleration in an inflammation stage and self-limiting in a later stage are constructed, and long-acting bacteriostasis is formed by SA-Zn site slow release; the stability and staged adaptation are highlighted through processes such as encapsulation, low-shear doping and the like and raw material synergy.

The invention relates to the technical field of water pollutant removal, in particular to a UiO-66 / sodium carboxymethyl cellulose / polyvinyl alcohol / melamine sponge composite material and a preparation method and application thereof.The preparation method comprises the steps that zirconium chloride and terephthalic acid are dissolved in an organic solvent to obtain a mixed solution, the mixed solution is transferred into a reaction kettle, and through solvothermal reaction, the UiO-66 / sodium carboxymethyl cellulose / polyvinyl alcohol / melamine sponge composite material is obtained; the preparation method comprises the following steps: preparing UiO-66 powder; putting UiO-66 powder into the sodium carboxymethyl cellulose solution, and uniformly stirring the UiO-66 powder and the sodium carboxymethyl cellulose solution to obtain a UiO-66 / CMC mixed solution; placing the UiO-66 / CMC mixed solution in a polyvinyl alcohol solution, and uniformly stirring the UiO-66 / CMC / PVA mixed solution to obtain a UiO-66 / CMC / PVA mixed solution; the preparation method comprises the following steps: dipping a melamine sponge in a UiO-66 / CMC / PVA mixed solution to obtain an adsorption saturated melamine sponge; the UiO-66 / CMC / PVA / coated MS composite material is obtained by repeatedly freezing and thawing the adsorption saturated melamine sponge for multiple times and then freeze-drying, the composite material can be used for rapidly, efficiently and selectively removing phosphate or fluorine ions and the like in water and is convenient to separate and recycle, and a new thought is provided for development of efficient water treatment adsorbent materials.

The invention discloses a special organic-inorganic compound fertilizer for improving the yield and quality of rice in a rice field, and belongs to the technical field of agricultural fertilizers. The compound fertilizer comprises a three-layer structure consisting of a porous core layer, a quick release coating layer and a biodegradable film, wherein the porous core layer is prepared from ammonium polyphosphate, potassium humate, nano charcoal modified chicken manure, mineral source potassium fulvate and sodium carboxymethyl cellulose-bentonite composite colloid; the quick-release coating layer is prepared from sulfur-resin double-layer coated urea, amino acid chelated zinc, alginic acid complex boron, silica sol, ammonium molybdate, 5-aminolevulinic acid and nano cerium oxide; the biodegradable film is prepared from a film forming solution and a bioactive microbial agent. Through the design of a three-layer structure and the combination of an organic-inorganic-microorganism synergistic technology, accurate matching of nutrient release and a rice fertilizer requirement rule is achieved, meanwhile, soil health and environmental protection are considered, and an innovative solution is provided for green high-yield rice planting.

The invention discloses a lignin-inorganic oxide composite binder, preparation thereof and application of the lignin-inorganic oxide composite binder in a hard carbon negative electrode. The preparation method comprises the following steps: firstly, carrying out quaternization modification on lignosulfonate to obtain quaternized lignosulfonate, and then utilizing the action of quaternary ammonium and sulfonate of the quaternized lignosulfonate, hydroxyl and inorganic oxyacid radicals of inorganic nano oxide and carboxyl and hydroxyl of sodium carboxymethyl cellulose to prepare the modified lignosulfonate. The lignin-inorganic oxide composite binder with the interpenetrating network structure is formed. According to the binder, sodium carboxymethyl cellulose serves as a hard phase to enhance the mechanical rigidity, quaternized lignosulfonate rich in flexible long chains serves as a soft phase to bear part of loads, and inorganic nano oxide rich in hydroxyl serves as a crosslinking point or physical filler to enhance the structural stability of the binder. Besides, a multi-network structure formed by hydrogen bond crosslinking not only endows the binder with an excellent ion transmission rate, but also helps to enhance the interfacial compatibility of the binder with an ester electrolyte, thereby significantly improving the rate capability and cycle performance of the hard carbon negative electrode.

The invention relates to the technical field of lithium ion batteries, and discloses a preparation method of silicon-carbon negative electrode slurry, the silicon-carbon negative electrode slurry and a lithium ion battery. The silicon-carbon negative electrode slurry comprises the following components: a silicon-based material, a graphite material, a carbon black conductive agent, a single-walled carbon nanotube conductive slurry, a sodium carboxymethyl cellulose binder, a polyacrylic acid binder, a styrene butadiene rubber binder, N-methyl pyrrolidone and deionized water. The silicon-carbon negative electrode slurry is prepared by adopting a dry process and a method of adding the binder step by step, so that the uniformity of the silicon-carbon negative electrode slurry is ensured, the expansion of the silicon-carbon negative electrode material is inhibited, and the cycle performance of the prepared lithium ion battery is finally improved. The silicon-based negative electrode paste has the following beneficial effects that the prepared silicon-based negative electrode paste is good in stability, and the single-walled carbon nanotube conductive paste, the sodium carboxymethyl cellulose binder, the polyacrylic acid binder and the styrene butadiene rubber binder form a multi-stage synergistic effect through complementary conductive, binding, dispersing and mechanical properties.

The invention discloses a low-temperature vacuum microwave freeze-dried sinomenine hydrochloride preparation and a preparation method thereof in the technical field of pharmaceutical preparations, and solves the problems of long drying time, high energy consumption and poor product stability in the traditional freeze-drying technology. A vacuum microwave collaborative freeze-drying technology is adopted, microwave internal heating is achieved through a 2.45 GHz magnetron microwave generator and a rectangular waveguide tube under the conditions that the vacuum degree is 20-30 Pa and the plate layer temperature ranges from-40 DEG C to-35 DEG C, the microwave power density in the primary drying stage ranges from 0.3 W / g to 0.5 W / g, the microwave power density in the secondary drying stage ranges from 0.1 W / g to 0.3 W / g, and collaborative control over the microwave power, the vacuum degree, the temperature and the time is achieved in cooperation with a quaternary coupling precise control system. The preparation contains 50 mg of sinomenine hydrochloride, 100 mg of mannitol and 10 mg of sodium carboxymethyl cellulose grafted modified polyvinylpyrrolidone, the residual moisture is controlled to be 0.4-0.6%, the activity retention rate is 94-96%, and the drying time is shortened to 12-16 hours.

The invention discloses bacillus subtilis MY-01 as well as a microbial preparation and application of the bacillus subtilis MY-01. The strain (preservation number is CCTCC NO: M 20242596) can efficiently degrade cellulose, total sugar and nicotine in tobacco stems and remarkably improve sensory indexes such as aroma quality and aroma amount, and the cellulase activity is greatly improved when the strain and sodium carboxymethyl cellulose act synergistically. The microbial preparation is obtained through the processes of strain activation, fermentation culture and microbial agent preparation, and when the microbial preparation is applied to tobacco stem treatment, the technical breakthrough of reduction of the cellulose content, increase of the filling value and reduction of the tar release amount is achieved through the steps of water content adjustment, preparation spraying, sealed fermentation, low-temperature drying and the like. Compared with a traditional method, the technology has the advantages that the treatment period is greatly shortened, the cost is remarkably reduced, the COD value of wastewater is reduced, the cigarette quality and the production environmental protection property are remarkably improved, and the industrial application prospect is wide.

The invention relates to the technical field of ferrous metallurgy, in particular to low-reactivity Al-Ti inhibition type casting powder for continuous casting based on premelted hollow particles and a preparation technology of the low-reactivity Al-Ti inhibition type casting powder. Wherein the water-quenched melt particles comprise an Al-Ti inhibitor, a melt, aluminum oxide short fibers and carbon black, pre-sintered aluminum oxide and titanium dioxide serve as the Al-Ti inhibitor, a stable Al-Ti-O network structure is formed in the melt, the reaction activity of the slag and the high-activity Al-Ti molten steel is effectively reduced, the aluminum oxide short fibers are introduced to form an enhanced network, and the high-activity Al-Ti molten steel is obtained. According to the casting powder, nano silicon carbide and boron carbide are matched to form synergistic reinforcement, ethyl silicate hydrolysate, water glass and sodium carboxymethyl cellulose are adopted to construct a dual-bonding system, the casting powder of the hollow structure is prepared, and the mechanical strength of the casting powder is effectively improved.