7497 results about "Water reducer" patented technology

The invention relates to the technical field of concrete wall materials, and discloses a recycled concrete wall material and a preparation method thereof, the recycled concrete wall material comprises the following components by weight: 300-500 parts of recycled coarse aggregate, 200-400 parts of recycled fine aggregate, 150-300 parts of cement, 30-80 parts of fly ash, 3-8 parts of a water reducer, 5-15 parts of reinforced fiber, and 20-30 parts of a modified composition. Comprising the following steps: S1, raw material pretreatment, S2, mixing and stirring, S3, molding and curing, and S4, quality detection. The building waste is efficiently utilized, exploitation of natural aggregate is reduced, energy consumption and carbon emission in the production process are reduced, the landfill amount of the building waste and land occupation are reduced, the material strength and durability are good, the waterproof performance is improved, and the crack resistance and seismic resistance of the wall are enhanced.

The invention relates to the field of concrete, and provides high-strength concrete and a preparation method thereof, and the high-strength concrete comprises modified basalt chopped fiber, a self-repairing agent, cement, fly ash, slag powder, coarse aggregate, natural sand, a water reducing agent and an air entraining agent. The modified basalt chopped fiber is oxidized by hydrogen peroxide, etched by hydrochloric acid and modified by a nano silicon dioxide coating, so that the interface bonding force is enhanced. The self-repairing agent is prepared by adopting expanded perlite to load bacillus through thallus culture, purification, dipping adsorption and low-temperature vacuum drying, CaCO3 deposition can be induced at concrete cracks, and self-repairing is achieved. The invention further provides a preparation method of the concrete. The preparation method comprises the steps of aggregate screening, hydrated liquid preparation, wet mixing, fiber and self-repairing agent adding, vibration forming and curing. The crack resistance of the concrete is improved by enhancing the fiber-matrix interface bonding force, meanwhile, the service life of the concrete is prolonged by utilizing a biological self-repairing technology, and the concrete is suitable for high-durability concrete engineering.

The invention provides a self-leveling rapid repair mortar based on a steel slag solid waste cementing material and a preparation method thereof, the self-leveling rapid repair mortar comprises the following components in parts by mass: 100 parts of a self-leveling rapid repair mortar cementing material: 20-32 parts of steel slag powder, 20-30 parts of slag powder, 10-23 parts of raw ash, 10-15 parts of desulfurized gypsum, 5-8 parts of silica fume, and 8-25 parts of rapid hardening sulphoaluminate cement; the fine aggregate comprises 50 parts of quartz sand and 50 parts of steel slag aggregate; 0.3 to 0.7 part of a polyether defoaming agent, 0.05 to 0.25 part of lithium carbonate and 6 to 12 parts of a polycarboxylic acid water reducing agent; and 25-28 parts of water. According to the self-leveling rapid repair mortar based on the steel slag solid waste cementing material, on the basis of an alkali excitation synergistic sulfate excitation mechanism, the solid waste materials such as the steel slag powder, the slag powder, the raw ash and the desulfurized gypsum are utilized, and through proportioning optimization, the self-leveling rapid repair mortar which can open traffic within 2 hours and has the compressive strength gt within 28 days is prepared; the bonding strength is gt; the self-leveling mortar for rapidly repairing the cement concrete pavement has the advantages of self-leveling, no shrinkage of later strength and excellent durability.

The invention relates to the technical field of building materials, and particularly discloses high-strength lightweight concrete containing hollow glass beads and a preparation method of the high-strength lightweight concrete. The high-strength lightweight concrete containing the hollow glass beads is prepared from cement, fly ash, carbon fiber grafted hollow glass beads, lightweight sand, deionized water, polypropylene fiber grafted rubber particles and a water reducing agent according to the mass ratio of (58-75): (25-38): (45-65): (20-40): (42-55): (35-55): (5-12) through mixing, mold filling, vibration molding, covering and demolding. The addition amount of the hollow glass beads is strictly controlled, the influence on the overall strength of the concrete is avoided, the density and weight of the concrete are reduced due to the addition of the light sand and the hollow glass beads, the compactness and integrity of the concrete are improved due to the synergistic effect of the two added fibers, and the raw materials have excellent cohesiveness; the concrete can effectively absorb and disperse stress, and has the advantages of excellent strength, light weight, good durability and excellent comprehensive performance.

The invention discloses fiber-reinforced anti-crack concrete and a preparation method thereof, and relates to the technical field of building materials, the fiber-reinforced anti-crack concrete comprises the following raw material components: 310-450 parts of cement, 150-190 parts of water, 930-1200 parts of coarse aggregate, 630-800 parts of fine aggregate, 80-180 parts of mineral active admixture, 1.2-18 parts of multi-element composite fiber, 1.8-4.5 parts of polycarboxylic acid water reducer, and 20-35 parts of anti-crack synergistic system. Through a quaternary fiber system, a three-dimensional interlocking net-shaped crack-resistant framework is formed in concrete slurry, the problems that the single fiber reinforcement effect is limited, and the interface bonding force with a concrete matrix is insufficient are solved, and the crack resistance and the mechanical property of the concrete are improved.

The invention relates to the technical field, and particularly discloses a nano-modified epoxy building thermal insulation material and a preparation method thereof. The nano modified epoxy building thermal insulation material is prepared from the following raw materials in parts by mass: 80 to 120 parts of Portland cement, 20 to 40 parts of slag powder, 5 to 10 parts of hollow mesoporous silicon dioxide, 0.1 to 1 part of pyrrole, 0.1 to 0.2 part of ammonium persulfate, 5 to 10 parts of nano silicon dioxide, 10 to 15 parts of bisphenol S epoxy resin, 1 to 5 parts of acrylic acid, 1 to 2 parts of polylysine, 0.01 to 0.1 part of catalyst and 1 to 2 parts of curing agent. The concrete is prepared from the following raw materials in parts by weight: 20-30 parts of epoxy resin, 4-8 parts of loaded aerogel, 0.1-1 part of polycarboxylate superplasticizer, 1-4 parts of composite fiber and 0.2-1.25 parts of hydrogen peroxide. The fireproof building material has excellent toughness, can better resist cracking and absorb energy, effectively avoids cracking and damage under the action of thermal stress, and ensures that the building material has a fireproof effect.

The present invention relates to a slump-retaining water-reducing agent and a preparation method therefor. The slump-retaining water-reducing agent is prepared from the following raw materials in parts by weight: 8-12 parts of a synthetic monomer, 180-300 parts of an unsaturated polyether monomer, 8-12 parts of an unsaturated carboxylic acid monomer, 15-30 parts of a functional monomer, 1.6-3.0 parts of an oxidizing agent, 0.2-0.8 parts of a reducing agent, 0.6-1.5 parts of a chain transfer agent, and 2-5 parts of a pH regulator, wherein the preparation raw materials of the synthetic monomer comprise an amino acid and a hydroxyalkyl acrylate. By introducing the synthetic monomer in the present invention, on one hand, hydrophilic groups hydrolyzed from an ester group can supplement a carboxyl consumed in a cement paste, and on the other hand, polyhydroxy and long-chain structures contained in the synthetic monomer also further improve the adsorption and dispersion capacity. The water-reducing and slump-retaining water-reducing agent of the present invention can alleviate the problems of a high mixing amount, serious losses, etc. of concrete admixtures, has both water-reducing and slump-retaining properties, and does not influence the strength of concrete. In addition, the water-reducing agent has relatively good adaptability to auxiliaries, such as common water-reducing agents, water-retaining agents, and defoaming agents.

The invention relates to the field of self-repairing concrete, in particular to high-strength self-repairing concrete and a preparation method thereof. The high-strength self-repairing concrete comprises the following substances in parts by weight: 45-60 parts of cement; 100 to 120 parts of recycled coarse aggregate; 65 to 80 parts of fine aggregate; 10 to 20 parts of water; 0.1 to 0.3 part of a water reducing agent; the recycled coarse aggregate is the recycled coarse aggregate immobilized with self-repairing microorganisms, and the self-repairing microorganisms comprise at least one of bacillus subtilis, bacillus megatherium and bacillus pasteurii. The concrete crack self-repairing capability is endowed through the immobilized self-repairing microorganisms. The microorganisms form resting spores in the concrete, when cracks are generated and water permeates into the cracks, the microorganisms are activated and metabolize a calcium source and urea in the surrounding environment, calcium carbonate crystals are generated through the mechanism that the microorganisms induce carbonate precipitation, the cracks are filled, and the structural integrity is recovered. The process does not need external intervention, and the mechanical structure and mechanical properties of the concrete structure can be remarkably improved.

The invention discloses a cement-based aerogel heat preservation and heat insulation coating material for concrete and a spraying construction process of the cement-based aerogel heat preservation and heat insulation coating material, and belongs to the technical field of concrete materials. The coating material is prepared from powder, composite emulsion and water, and the powder is prepared by mixing superfine sand, cement, modified silicon dioxide-carbon nanotube composite aerogel powder, hollow glass beads, nanofibers, graphene nanosheets, an ultraviolet light absorber, a water reducing agent and a defoaming agent. The composite emulsion is composed of an acrylate copolymer emulsion, a polyvinyl acetate-ethylene emulsion, a temperature-sensitive polymer emulsion and a coalescing agent. Based on the multi-stage pore network and multi-component emulsion optimization design and multi-component synergistic effect, the material has good fluidity after being mixed, and has low heat conductivity coefficient, high strength and high toughness after being hardened; the construction technology of high-pressure water flushing and layered spraying is provided, and the method has the advantages of being efficient in construction, stable in quality and the like and can be applied to heat preservation and heat insulation of a concrete structure in a severe environment.

The invention relates to the field of solidified soil, and particularly discloses solid-waste-based premixed flow-state solidified soil and a preparation method thereof. The solid-waste-based premixed flow-state solidified soil comprises soil, water and a curing agent according to the weight ratio of (28-36): (50-54): (6-9), according to the total weight of the curing agent, the curing agent comprises the following components in parts by weight: 20-40 parts of fly ash, 30-47 parts of slag, 6-18 parts of silica fume, 10-15 parts of sea sludge, 1-3 parts of a water reducing agent, 1-3 parts of sodium hydroxide, 1-3 parts of calcium sulphoaluminate, 3-10 parts of a fiber reinforced material and 1-3 parts of phosphate. The problems that stress generated by the solidified soil in the hydration process is excessively concentrated and shrinkage is excessive can be solved, and therefore cracking of the solidified soil subjected to premixed flow state solidification is reduced.

The invention discloses crack-chloride ion double-triggered subsea tunnel corrosion-resistant concrete and a preparation method thereof, and relates to the field of subsea tunnel engineering materials. The concrete is prepared from the following components in parts by weight: 400 to 500 parts of Portland cement, 50 to 80 parts of fly ash, 60 to 100 parts of superfine mineral powder, 1000 to 1100 parts of coarse aggregate, 700 to 800 parts of fine aggregate, 140 to 160 parts of water, 10 to 20 parts of self-repairing microcapsules and 1 to 5 parts of a water reducing agent, the self-repairing microcapsule comprises a capsule wall material, a self-repairing material and a layered dihydroxyl composite metal oxide. A crack-chloride ion double-response system is constructed, and the limitation of traditional single trigger repair is broken through. When a crack with a certain width appears in the concrete, the capsule wall of the self-repairing microcapsule is broken to release the repairing component, so that effective filling of the crack is realized; and meanwhile, the layered double-metal hydroxide can directionally adsorb chloride ions to form a stable compound, so that the migration rate of the chloride ions is remarkably reduced.

The invention discloses a jet type high-toughness fiber reinforced cement-based composite material and a preparation method thereof, and belongs to the technical field of material preparation. The invention provides a jet type high-toughness fiber reinforced cement-based composite material, which is prepared from the following raw materials in parts by mass: 320 to 400 parts of coarse aggregate, 220 to 260 parts of fine aggregate, 90 to 110 parts of cement, 40 to 50 parts of water, 10 to 15 parts of modified fiber, 5 to 10 parts of zeolite powder, 5 to 10 parts of polymerizing agent, 4 to 7 parts of accelerator and 2 to 5 parts of water reducing agent. The chemical bonding force of the fiber and the concrete interface is improved, meanwhile, the mechanical property of a hydration product at the interface is improved, the dispersity of the fiber in the concrete is improved, and the stress transmission and dispersion capacity of the fiber is effectively enhanced, so that the mechanical property and durability of the fiber concrete are enhanced.

The invention discloses low-shrinkage all-solid waste concrete and a preparation method thereof. The low-shrinkage all-solid waste concrete is prepared from the following raw materials in parts by mass: 14 to 20 parts of solid waste-based cementing material, 25 to 40 parts of high-titanium heavy slag sand, 35 to 50 parts of high-titanium heavy slag gravel, 5.5 to 7.5 parts of water and 0.2 to 0.5 part of water reducing agent, the solid waste-based cementing material comprises the following components in parts by mass: 40-70 parts of water-quenched slag powder, 10-30 parts of carbide slag, 10-20 parts of gypsum, 5-20 parts of fly ash and 0-5 parts of silica fume. By utilizing the internal curing effect of the titanium slag aggregate, continuous water can be provided for concrete hydration, the later-stage dry shrinkage of the concrete is reduced, and the strength of the concrete is improved; the high alkalinity of the carbide slag and the high sulfate content of the gypsum are utilized, and the alkali-sulfate synergistic excitation effect is utilized, so that the activity of the water-quenched slag powder and the like can be fully excited under the condition that cement and a chemical exciting agent are not used, and the strength performance of the concrete is ensured; meanwhile, steel slag is not used as a component material, so that the problem of poor concrete volume stability caused by the steel slag can be avoided.

The invention discloses sound-insulation and heat-insulation building mortar and a preparation method thereof, and relates to the technical field of building materials, the sound-insulation and heat-insulation building mortar comprises, by weight, 42-48 parts of a cementing material, 15-25 parts of an auxiliary material, 17-22 parts of lightweight aggregate, 30-35 parts of a functional filler, and 1-2 parts of an additive; the cementing material is a mixture of sulphoaluminate cement and Portland cement; the auxiliary material is a mixture of fly ash and quartz sand, the lightweight aggregate is a mixture of 20-40-mesh hollow vitrified microbeads and 70-90-mesh hollow vitrified microbeads, and the mass ratio of the hollow vitrified microbeads to the hollow vitrified microbeads is 1: (2-3); the functional filler is a mixture of modified waste rubber particles and modified fibers; the additive is a mixture of a polycarboxylate superplasticizer and hydroxypropyl methyl cellulose ether. The mortar disclosed by the invention is good in thermal insulation performance and excellent in mechanical property, the method disclosed by the invention is simple to operate and low in cost, and the prepared mortar is excellent in performance.

The invention discloses ultra-high performance concrete and a preparation method thereof. The ultra-high performance concrete comprises the following components in percentage by mass: 15%-25% of cement, 3%-6% of nano SiO2, 30%-35% of fly ash or steel slag powder, 35%-40% of recycled aggregate, 1%-4% of fiber, 0.5% of a microbial remediation agent and 1%-3% of nano TiO2. The preparation method comprises the following steps: S1, pretreating the recycled aggregate; and S2, packaging the microbial remediation agent: mixing the bacillus pasteurii spores with calcium lactate, and wrapping the mixture in calcium phosphate microspheres. S3, step-by-step stirring; S3.1, dry mixing: uniformly stirring the cement, the fly ash, the nano SiO2, the nano TiO2 and the recycled aggregate; s3.2, wet mixing is carried out, water solution fibers containing the polycarboxylic acid water reducing agent are added, uniform stirring is carried out, and the water-binder ratio of the water solution containing the polycarboxylic acid water reducing agent is 0.18; s3.3, final mixing: adding the packaged microbial remediation agent, and uniformly stirring; and S4, directional curing: performing steam curing at 80 DEG C for 48 hours, performing ultraviolet irradiation, and performing constant-temperature and constant-humidity curing for 7 days. The ultra-high performance concrete has the effects of low cost, low carbon emission, multi-function integration and repeatable crack self-repairing.

The invention discloses recycled coarse aggregate early-strength low-resilience sprayed concrete and a preparation method thereof, and belongs to the technical field of building materials. The recycled coarse aggregate early-strength low-resilience sprayed concrete is prepared from the following components in parts by weight: 450 to 500 parts of cement, 800 to 910 parts of fine aggregate, 800 to 920 parts of coarse aggregate, 15 to 25 parts of an exciting agent, 160 to 190 parts of water, 4.5 to 10 parts of a water reducing agent and 27 to 45 parts of an accelerator, the used coarse aggregate is regenerated hardened concrete, and the exciting agent is a special material. The recycled coarse aggregate early-strength low-resilience shotcrete provided by the invention is high in cohesiveness, strong in cohesion and high in early strength, is more easily adhered to the surface of surrounding rock when being sprayed to tunnel surrounding rock or a side slope, is not easy to fall off, and is low in resilience rate.

The invention relates to a flame-retardant inorganic quick-setting material and a preparation method thereof, and the flame-retardant inorganic quick-setting material is prepared from the following raw materials: sulphoaluminate cement, aluminum-magnesium hydrotalcite, phosphorus slag powder, waste PBO fiber, an accelerator, a water reducer, a functional auxiliary agent, and 3, 3 '-diamino-4, 4'-difluorodiphenyl sulfone. The functional auxiliary agent comprises structural units introduced by the following monomers: 3-[N, N-dimethyl-[2-(2-methylpropyl-2-enoyloxy) ethyl] ammonium] propane-1-sulfonic acid inner salt, diphenyl (4-vinyl phenyl) phosphine oxide, 1, 3-bis (oxirane methyl)-5-(2-allyl)-1, 3, 5-triazine-2, 4, 6 (1H, 3H, 5H)-triketone, 10-(4-vinyl phenyl)-10H-phenoxazine and itaconic acid. The material is high in strength, remarkable in rapid hardening and flame-retardant effect, and safe and environment-friendly to use.

The invention relates to the technical field of concrete preparation, in particular to high-performance self-compacting concrete and a preparation method thereof, solves the defects in the prior art, and comprises the following components: cement, fly ash, slag powder, graphene oxide, nano-silica aerogel, a water reducer and an air entraining agent. Through silanization modification and magnetic field induction, the problem of interface incompatibility of GO and SA is solved. Graded mass transfer paths are formed between nano layers of GO and mesopores and macropores of SA. And the CaCO3 seed crystal in the SA hole directionally guides the oriented growth of the C-S-H gel, so that the early strength development rate is increased.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The invention relates to the technical field of building materials, and particularly discloses a high-performance solid-waste-based grouting material and a preparation method thereof. Comprising the following raw materials in parts by weight: 32 to 54 parts of Portland cement, 12 to 16 parts of a modified admixture, 2.4 to 3.6 parts of a functional filler, 42 to 56 parts of aggregate, 45 to 55 parts of a photoinitiator solution, 0.6 to 0.8 part of a water reducing agent, 0.9 to 1.1 parts of a composite expanding agent, 0.04 to 0.06 part of a defoaming agent and 9.2 to 12.4 parts of deionized water. Siloxane groups, acylamino groups, ester groups and benzene rings are chemically bonded on the surface of the modified admixture, so that the hydrophilicity of the modified admixture is reduced, the modified admixture can form hydrogen-bond interaction with hydroxyl groups and cement hydrates on the functional filler, and meanwhile, a flexible long-chain alkane structure on the functional filler can be entangled with the modified admixture, so that the flexibility of the modified admixture is improved. The mechanical property, the durability and the fluidity of the grouting material are improved.

The invention relates to the technical field of cement-based soil curing agents, and particularly discloses a roadbed soil cement cementing material curing agent and a use method thereof. The curing agent comprises Portland cement, coal gangue particles, fly ash, silica fume, an anti-permeability reinforcing agent, a water reducing agent and fibers. The anti-permeability reinforcing agent is prepared by the following steps: (1) dispersing polyaluminum sulfate powder into absolute ethyl alcohol, then adding a silane coupling agent and a water repellent agent, and heating and preserving heat under a stirring condition; and then separating out solids to obtain the modified polyaluminum sulfate. And (2) adding the modified polyaluminum sulfate into water, heating and preserving heat under a stirring condition, drying by distillation to remove water, and grinding the obtained solid product. The curing agent provided by the invention not only reduces the adverse effect of acid soil on the stability of a formed soil consolidated body, but also improves the impermeability and the durability of the soil consolidated body.

The invention relates to low-carbon high-durability concrete in the field of concrete. The low-carbon high-durability concrete comprises the following components in parts by weight: 30-35 parts of cement, 40-46 parts of a cementing material, 180-190 parts of coarse aggregate, 150-160 parts of fine aggregate, 4-6 parts of an air entraining and water reducing agent and 60-70 parts of water, the cementing material comprises the following components in percentage by weight: 50-55% of granulated blast-furnace slag, 5-10% of steel slag, 3-5% of desulfurized gypsum, 1-3% of tailings, 2-4% of desulfurized fly ash, 2-4% of red mud, 3-5% of a reinforcing agent and the balance of silicon hydrochloric acid cement clinker. The method has the effect of improving the durability and strength of the low-carbon concrete.

The invention relates to the technical field of concrete, and discloses residue soil type construction waste regenerated pervious concrete and a preparation method thereof.The residue soil type construction waste regenerated pervious concrete is prepared from 850-1250 parts of regenerated residue soil aggregate, 220-380 parts of cement, 60-110 parts of fly ash, 25-55 parts of silica fume, 4-9 parts of a water reducing agent, 6-18 parts of reinforced fibers, 3-7 parts of a pervious additive and 4-9 parts of nano titanium dioxide; the self-repairing coating is prepared from, by weight, 12-35 parts of zeolite powder, 35-65 parts of superfine slag powder, 5-10 parts of magnetic adsorption particles and 3-8 parts of self-repairing microcapsules. By adding the reinforced fibers, the compressive strength is improved, the crack risk is reduced, the permeation coefficient is improved by adding the permeation accelerant, the drainage pressure is relieved, the self-repairing efficiency is improved by utilizing the self-repairing microcapsules, the magnetic adsorption particles are added, the water environment is improved, the composite water reducing agent is adopted, the cost is reduced, and the durability is enhanced.

The invention belongs to the field of electrode materials, and relates to a cement-based electrode material capable of 3D printing and a preparation method and application thereof. The cement-based electrode material comprises 500 to 600 parts of cement, 10 to 25 parts of aluminum sulfate, 70 to 84 parts of surface activated carbon black, 150 to 300 parts of surface modified quartz sand, 7.5 to 15 parts of carbon fiber, 500 to 600 parts of water and 6 to 10 parts of a water reducing agent. The material has excellent mechanical properties and electrical properties, can realize integration of energy storage and structural functions, has high practical application value, and is especially applicable to the fields of intelligent building materials and green energy storage. And through the 3D printing technology, complex structure customization of the cement-based material can be achieved, structural energy storage integration is expected to be achieved, and a new thought is provided for development of a smart energy system in the building field.

The invention discloses a soft rock cave slag green concrete and a preparation method thereof, and belongs to the technical field of solid waste resource utilization, the soft rock cave slag green concrete comprises the following raw materials: cement, a cave slag rock-based mineral admixture, a continuous grading soft rock cave slag coarse aggregate, a soft rock cave slag fine aggregate, a soft rock modifier, a water reducer and water. According to the preparation method, the waste soft rock cave slag in the tunnel excavation process is used for processing the coarse aggregate and the fine aggregate, the waste cave slag is used for processing the cave slag rock-based mineral admixture, meanwhile, the soft rock modifier is adopted for modifying the soft rock coarse aggregate and the soft rock fine aggregate, and the soft rock cave slag green concrete is prepared. The prepared soft rock cave slag green concrete has the advantages of being green, environmentally friendly, low in cost, good in durability and the like.

The invention discloses a high-performance green and environment-friendly single-component polymer cement waterproof dry blend and a preparation method thereof, and relates to the technical field of building materials, the high-performance green and environment-friendly single-component polymer cement waterproof dry blend comprises the following components: an inorganic cementing material, latex powder, graded quartz sand, a functional filler, cellulose ether, an organic silicon defoamer, a polycarboxylic acid water reducer and compound fibers; the functional filler is modified waste glass powder prepared through mechanical activation and silanization modification; the compound fiber is a mixture of modified glass fiber and modified polypropylene fiber; the preparation of the modified glass fiber comprises tannic acid and polyethyleneimine combined modification and graphene oxide modification, and the preparation of the modified polypropylene fiber comprises plasma activation. The polymer cement waterproof dry blend prepared by the method adopts the glass powder to replace natural mineral filler, is energy-saving and environment-friendly, and the cement matrix is modified by various fibers, so that the prepared polymer cement dry blend is excellent in comprehensive performance.

The invention provides a mining inorganic environment-friendly reinforcing material and application thereof, and belongs to the technical field of mining reinforcing materials. A component A comprises the following components in parts by mass: 60-80 parts of anhydrite, 5-20 parts of lime, 5-10 parts of silica fume, 2-8 parts of sodium silicate, 1-0.5 part of a naphthalene water reducer, 3-7 parts of an early strength agent and 0.2-0.8 part of lithium salt; the component B comprises the following components in parts by mass: 50-70 parts of cement clinker, 10-30 parts of slag cement, 5-10 parts of iron powder, 1-8 parts of aluminum sulfate, 5-10 parts of calcium carbonate and 0.5-1 part of sodium tripolyphosphate; the component C is prepared from the following components in parts by mass: 10 to 25 parts of water glass, 10 to 20 parts of emulsion, 40 to 60 parts of water, 5 to 10 parts of high-efficiency water reducing agent and 1 to 5 parts of triethanolamine. The mining inorganic environment-friendly reinforcing material provided by the invention is low in reaction heat and is not easy to cause coal combustion.

The invention relates to the technical field of cement-based repair mortar, and particularly discloses a preparation method of an early-strength quick-hardening anti-carbonization cement-based repair mortar material, which comprises the following steps: (1) uniformly mixing calcium silicate or pseudo-wollastonite and saturated lime water, adding basalt fiber, and carrying out heating reaction, and uniformly mixing the fiber with sodium silicate powder, calcining in a protective atmosphere, uniformly mixing the obtained fiber with saturated lime water, and drying to obtain the anti-carbon modified fiber. And (2) uniformly mixing red mud, silica fume, sodium silicate powder and water, curing, grinding, and calcining the powder to obtain the anti-carbonization additive. And (3) mixing sulphoaluminate cement, fine aggregate, solid waste-based filler, the anti-carbon modified fiber, the anti-carbonization additive, a water reducing agent and a defoaming agent, adding mixing water, and uniformly stirring to obtain the cement-based repairing mortar material. According to the invention, the carbonization resistance of the sulphoaluminate cement-based repair mortar is effectively improved, the durability is improved, and the problem of strength shrinkage in the later period is prevented.

The invention discloses a high-toughness impervious polymer modified cement-based grouting material and a preparation method thereof, and belongs to the technical field of building repair materials. The component A is prepared from a cementing material, an admixture, a fine aggregate, a composite expanding agent, a polymer for concrete modification, fibers, an early strength agent, a water reducing agent, a composite retarder, a defoaming agent, an air entraining agent, a nano material and a functional component. The system solves the technical contradiction of toughness-strength-impermeability in the polymer modified cement-based material, and the material has excellent comprehensive performance: the initial fluidity is greater than or equal to 330 mm, the 28d compressive strength is greater than or equal to 82 MPa, the breaking strength is greater than or equal to 16.8 MPa, the bending-compression ratio is greater than or equal to 0.19, the impermeability pressure value is greater than or equal to 2.6 MPa, and the material is suitable for the fields of prefabricated buildings, tunnel engineering and the like.

The invention discloses a preparation process of waste porcelain ball high-wear-resistance chloride ion erosion-resistant marine concrete, which comprises the following steps: (1) uniformly mixing mineral powder, glass powder, chopped basalt fiber and nano silicon dioxide, heating and sintering, crushing after completion, and curing the product in saturated lime water to obtain regenerated anti-cracking coarse aggregate; and (2) dipping the waste brick and tile powder in an ethanol mixed solution containing a hydrophobic agent, separating out a solid product after dipping, drying the solid product, uniformly mixing the solid product with a saturated solution containing a Fe < 2 + > and / or Fe < 3 + > source, drying, mixing with an alkali solution to form a wet material, and drying to obtain the hydrophobic anti-chlorine agent. And (3) mixing a cement binding material, a fine aggregate, waste porcelain balls, the regenerated anti-crack coarse aggregate, the hydrophobic anti-chlorine agent, a filler, a water reducing agent and water, and uniformly stirring to obtain the high-wear-resistance chloride ion erosion-resistant marine concrete. According to the process, the wear resistance of a concrete structure is effectively improved, and the prepared concrete also has good chloride ion erosion resistance.