767 results about "Glass microsphere" patented technology

The invention discloses a cement-based aerogel heat preservation and heat insulation coating material for concrete and a spraying construction process of the cement-based aerogel heat preservation and heat insulation coating material, and belongs to the technical field of concrete materials. The coating material is prepared from powder, composite emulsion and water, and the powder is prepared by mixing superfine sand, cement, modified silicon dioxide-carbon nanotube composite aerogel powder, hollow glass beads, nanofibers, graphene nanosheets, an ultraviolet light absorber, a water reducing agent and a defoaming agent. The composite emulsion is composed of an acrylate copolymer emulsion, a polyvinyl acetate-ethylene emulsion, a temperature-sensitive polymer emulsion and a coalescing agent. Based on the multi-stage pore network and multi-component emulsion optimization design and multi-component synergistic effect, the material has good fluidity after being mixed, and has low heat conductivity coefficient, high strength and high toughness after being hardened; the construction technology of high-pressure water flushing and layered spraying is provided, and the method has the advantages of being efficient in construction, stable in quality and the like and can be applied to heat preservation and heat insulation of a concrete structure in a severe environment.

The invention discloses a coating as well as a preparation method and application thereof. The coating comprises the following raw materials: potassium silicate; ethyl orthosilicate; a nanometer titanium dioxide sol; rare earth is doped with nano titanium dioxide; compounding zinc oxide nanoparticles; nano silicon dioxide sol; a fluorosilane coupling agent; a fluorocarbon surfactant; a conductive carbon nanotube; nano aluminum oxide sol; an organic silicon modified acrylate emulsion; a boron nitride nanosheet; hollow glass beads; a shape memory polymer; the invention discloses a self-repairing nanofiber. After a coating is formed by using the coating, the coating has the characteristics of high light transmittance, good self-cleaning effect, high hardness, good adhesive force and excellent weather resistance, and can be applied to a photovoltaic module to replace an existing photovoltaic module coating product.

The invention discloses a composition based on hollow glass beads and a preparation method thereof, and relates to the technical field of material science. The preparation method comprises the following steps: firstly, constructing a pre-composite functional microsphere with a specific hierarchical structure as a core basic functional unit, then matching with a plurality of components such as a thermosetting resin matrix, a latent curing system, a functional synergistic aid package and a composite solvent system, and matching with a preparation process which has a synergistic effect with the components. The composition based on the hollow glass beads is expected to realize uniform dispersion of the hollow glass beads in a coating system and strong bonding of a microscopic interface on the premise of ensuring the structural integrity of the hollow glass beads. Therefore, the high-performance composite coating material with ultra-light weight, high heat insulation efficiency, excellent mechanical strength and long-term service stability is obtained.

The invention discloses a passive radiation refrigeration coating and a preparation method thereof, and relates to the technical field of industrial coatings. Comprising a fluoroacrylate emulsion, hollow glass beads, nano titanium dioxide, flaky silicon dioxide aerogel powder, polytetrafluoroethylene micro powder, hydroxyl-terminated polydimethylsiloxane, a hydroxyl acrylic acid modified silane coupling agent, a super-hydrophobic modified fluorosilicone surface additive, nano cerium oxide, aluminum fluoride doped zinc oxide infrared enhancement powder and deionized water. The paint is prepared on the basis of the formula. According to the invention, a multi-scale spectrum regulation and control and surface self-cleaning system is constructed cooperatively, so that the synergistic effect of high reflection of a sunlight region and high emission of a middle infrared region is realized. The coating can maintain continuous passive refrigeration in a day and night period, the surface of the coating has self-cleaning capability and excellent ultraviolet aging resistance, and high reflectivity and high radiation emissivity can be maintained for a long time in a complex outdoor environment, so that the thermal management efficiency of buildings and equipment is remarkably improved.

The invention discloses light self-repairing concrete and a preparation method thereof, and relates to the technical field of concrete. The method comprises the following steps: firstly, efficiently packaging a calcium nitrate solution in hollow glass beads by utilizing a negative pressure impregnation technology; then growing a porous zeolite crystal coating on the surface of the microbead in situ by adopting a sol-gel method to form a self-repairing filler with a core-shell-hole gradient structure; when the concrete cracks to cause the cracking of the microbeads, the Ca < 2 + > in the cavity is quickly released, and the Ca < 2 + > adsorbed in the zeolite layer is gradually dissociated along with water permeation, so that the new microcracks are continuously repaired. Then, uniformly coating the surface and pores of the carboxymethyl cellulose hydrogel network with polydopamine in an in-situ oxidative polymerization manner to form composite hydrogel with photo-thermal responsiveness; lighting and heating to trigger dynamic coordination bond dissociation; meanwhile, heat drives rapid directional crystallization of a repair product by promoting the ion diffusion rate, and a compact mineralization layer is formed. The concrete prepared by the invention has the effects of light weight and self-repairing.

The invention relates to an asphalt mixture, in particular to a modified heavy-load asphalt mixture based on a basalt fiber composite material as well as a preparation method and application of the modified heavy-load asphalt mixture. The modified heavy-load asphalt mixture based on the basalt fiber composite material is prepared from the following raw materials in parts by weight: 10 to 15 parts of asphalt, 1 to 3 parts of modified basalt fiber, 1 to 3 parts of aminated chitin whisker, 85 to 90 parts of mineral aggregate, 5 to 8 parts of hollow glass microspheres, 3 to 6 parts of compatilizer and 1 to 3 parts of stabilizer. Wherein the modified basalt fiber improves the low-temperature crack resistance, high-temperature rutting resistance and water stability of the asphalt mixture, and the aminated chitin whisker improves the fatigue resistance of the asphalt mixture.

The invention relates to the technical field of coating compositions, and particularly discloses an ardealite-based heat-insulation fireproof coating and a preparation method thereof.The ardealite-based heat-insulation fireproof coating is prepared from titanium dioxide modified ardealite, hollow glass beads, styrene-acrylic emulsion, modified composite flame-retardant fibers, calcium sulfate whiskers, microencapsulated red phosphorus, redispersible latex powder, deionized water, a dispersing agent and a defoaming agent; the preparation method comprises the following steps: firstly, preparing titanium dioxide modified phosphogypsum, secondly, modifying the composite flame-retardant fiber, and finally, mixing and stirring all the components. Through the synergistic effect of the titanium dioxide modified phosphogypsum and the composite flame-retardant fiber and in combination with an ultrasonic-assisted preparation process, a double heat-insulating barrier and a synergistic flame-retardant mechanism is formed; and calcium sulfate whiskers are matched for toughening, so that the fireproof heat-insulating performance and the structural stability of the coating are improved, and the problem that the coating is easy to crack is solved.

The invention relates to the technical field of packaging materials, in particular to a chip inductor packaging material and a preparation method thereof. The packaging material is prepared from epoxy resin serving as a matrix, composite boron nitride modified hollow glass beads, spherical silica powder, a silane coupling agent, a curing agent, an accelerant and a defoaming agent. Wherein the boron nitride modified hollow glass beads are obtained by constructing a boron nitride functional layer through branched polyamidoamine grafting and a melamine-boric acid in-situ method and carrying out high-temperature calcination. By means of the innovative structural design, efficient bonding of a filler interface and ordered construction of a heat conduction path are achieved, the heat conduction performance and the mechanical strength of the composite material are remarkably improved, and the dielectric constant and the dielectric loss are effectively reduced. The packaging material provided by the invention has excellent electrical, thermal and mechanical comprehensive performance, meets the requirements of light weight and high reliability packaging of a new generation of high-performance chip inductor devices, and has important industrialization and application prospects.

The invention relates to a coating, in particular to a radiation refrigeration heat insulation coating and a preparation method thereof, and the radiation refrigeration coating comprises a water-based emulsion, a reflective inorganic filler, a radiation inorganic filler water-based emulsion, a radiation inorganic filler, functional nanocellulose and a functional additive. The radiation refrigeration coating can reflect energy of a sunlight wave band (0.3-2.5 [mu] m) and perform radiation heat exchange with the universe by utilizing an atmospheric window (8-13 [mu] m), and the cooling effect lower than the environment temperature can be achieved. In high-temperature weather in summer, the surface temperature of a building can be effectively reduced, and the use frequency of an air conditioner is reduced, so that energy consumption is remarkably reduced. Meanwhile, by adding heat insulation type inorganic filler (such as hollow glass beads, silicon dioxide aerogel and the like), the heat conductivity of the coating is reduced, the loss of heat in a building is reduced, and the heating energy consumption in winter is reduced. Due to the dual functions, the coating can achieve an energy-saving effect throughout the year, and the environment-friendly concept of energy conservation and carbon reduction is met.

The invention discloses a quick response flexible temperature sensor with low thermal crosstalk and a preparation method thereof. The sensor comprises a contact layer, a sensing layer, an electrode layer and a substrate layer, wherein the contact layer comprises a heat conduction layer and a heat insulation network; the heat-conducting layer is made of a heat-conducting composite material and comprises polydimethylsiloxane and flake carbon powder; the heat insulation network and the substrate layer are made of a heat insulation composite material which comprises polydimethylsiloxane and hollow glass microspheres; the sensing layer comprises a plurality of sensing units arranged in an array, the sensing units are connected with the electrode layer and output resistance signals, the heat conduction layer and the substrate layer are arranged over and under the sensing units respectively, and the heat conduction and heat insulation synergistic structure can enhance the quick response of the sensing units to the temperature; a thermal insulation network is embedded in the contact layer to block thermal crosstalk between adjacent sensing units. The temperature sensor has the advantages of quick response, low thermal crosstalk and high reliability in a wide range, and large-scale production and preparation can be realized.

The invention discloses a bending-resistant and low-dielectric transparent polyimide film for a flexible electronic device as well as a preparation method and application of the bending-resistant and low-dielectric transparent polyimide film. The surfaces of glass beads are subjected to grafting modification treatment by adopting alkali liquor and a coupling agent; performing ultrasonic dispersion to uniformly disperse the grafted and modified glass beads in a solvent; the preparation method comprises the following steps: dissolving a fluorine-containing diamine monomer in a solvent containing graft modified glass beads under a nitrogen protection atmosphere, after the fluorine-containing diamine monomer is completely dissolved, slowly adding a fluorine-containing dianhydride monomer in batches under a continuous stirring condition, and preparing a transparent polyamide acid solution containing glass beads through a condensation polymerization reaction; and uniformly coating the polyamide acid solution containing the glass beads on a glass substrate through a blade coating machine, and then carrying out gradient heating to obtain the glass bead compounded transparent polyimide film. Fluorine atoms are introduced into molecular structures of dianhydride and diamine, and grafting modified glass beads are doped to serve as filler, so that the transparent polyimide film with bending resistance and low dielectric constant characteristics is successfully prepared.

The invention provides a composite protection structure suitable for underwater seepage prevention and explosion prevention of a concrete gravity dam and a preparation and construction method, and belongs to the technical field of engineering explosion prevention and seepage prevention. The composite protection structure comprises a reinforced concrete slab anchored on the outer surface of the gravity dam by a certain distance through an anchor rod; a reserved interlayer between the reinforced concrete slab and the outer surface of the gravity dam is filled to form an anti-seepage and anti-explosion composite layer; the anti-seepage and anti-explosion composite layer is formed by pouring hollow glass bead-asphalt concrete, and the hollow glass bead-asphalt concrete is prepared from asphalt concrete with modified hollow glass beads as filler; the modified hollow glass beads account for more than 15% of the asphalt concrete by volume, and the asphalt concrete has enough sealing gas for reflecting explosive shock waves and has the characteristics of seepage prevention and energy dissipation. The composite protection structure has anti-seepage and anti-explosion functions, the service life of the dam is prolonged, and the ability of the dam to resist sudden extreme working conditions is improved.

The invention provides a holmium and ytterbium co-doped mid-infrared microsphere Raman laser and a preparation method thereof, and relates to the technical field of laser preparation, the holmium and ytterbium co-doped mid-infrared microsphere Raman laser comprises an infrared transmission optical fiber, a pump light source, holmium and ytterbium co-doped tellurate glass microspheres and passive tellurate glass microspheres, pump light emitted by the pump light source is guided to a conical region through the infrared transmission optical fiber, and the holmium and ytterbium co-doped tellurate glass microspheres and the passive tellurate glass microspheres are arranged in the conical region; sequentially carrying out optical coupling with holmium and ytterbium co-doped tellurate glass microspheres and passive tellurate glass microspheres; in the holmium and ytterbium co-doped tellurate glass microspheres, the doping amount of the holmium element is 0.3%, and the doping amount of the ytterbium element is 0.45% according to the mass percentage. Compared with the prior art, through the cascade structure of the holmium-ytterbium co-doped microspheres and the passive microspheres, three-step wavelength conversion of pump light-rare earth ion lasing-Raman frequency shift is realized in a single system for the first time, and the wavelength limitation that a traditional single microsphere depends on a rare earth ion fixed energy level is broken through.

The invention discloses a carbon fiber-glass bead synergistically reinforced PA56 / PPO composite material and a preparation method thereof, and relates to the technical field of high polymer materials. The PA56 / PPO composite material comprises the following components in percentage by mass: 20%-40% of PA56 resin, 20%-30% of PPO resin, 20%-40% of modified carbon fibers, 10%-20% of silane modified glass beads, 0.5%-5% of a toughening agent and 0.5%-5% of a compatilizer. Through compound use of the modified carbon fibers and the silane modified glass beads, the addition amount of a single carbon fiber material can be reduced, and weight reduction is realized while the cost is reduced; the toughening agent has good compatibility with matrix resin and can generate a better toughness modification effect after being added into a PA56 / PPO system, and the added compatilizer can improve the interfacial effect among the components so as to effectively improve the mechanical properties and antistatic properties of the composite material. The carbon fiber-glass bead synergistically reinforced PA56 / PPO composite material provided by the invention is balanced in rigidity, toughness and antistatic property, and can be used in automotive electronic and electrical products with requirements on high strength, high toughness and antistatic property.

The invention provides a marking coating capable of preventing normal-temperature layering and a preparation method of the marking coating, and belongs to the technical field of coatings. Comprising the following raw materials in parts by weight: 1-2 parts of a temperature-sensitive reversible cross-linking agent, 15-30 parts of epoxy resin, 10-20 parts of an acrylic monomer, 1-2 parts of an emulsifier, 2-4 parts of temperature-sensitive microcapsules, 0.5-1 part of nano titanium dioxide, 1-2 parts of inorganic asbestos fibers, 0.5-1.5 parts of polymer fibers, 0.01-0.02 part of an initiator, 3-4 parts of a water-soluble epoxy curing agent, 2-3 parts of hollow glass beads, 2-4 parts of an auxiliary agent and 40-80 parts of water. The marking paint has the temperature-sensitive characteristic, is a weak gel network at normal temperature, inhibits filler sedimentation, hydrogen bond fracture during construction heating, paint fluidity recovery and cooling recovery crosslinking, and has high strength and hardness, so that the tensile strength, bending strength, hardness and other mechanical properties of a paint film are remarkably improved, and the wear resistance and impact resistance are also enhanced.

The invention relates to the technical field of UV coatings, in particular to a waterproof wear-resistant UV coating for a floor and a preparation method of the waterproof wear-resistant UV coating. The waterproof and wear-resistant UV coating for the floor is prepared from the following raw materials in parts by mass: 30 to 60 parts of polyurethane acrylate, 20 to 40 parts of fluorinated epoxy acrylate oligomer, 20 to 40 parts of pentaerythritol tetraacrylate, 1 to 5 parts of tetraethoxysilane, 15 to 25 parts of hollow glass beads, 1 to 3 parts of ammonia water, 1 to 2 parts of trifluoropropane trimethoxysilane and 1 to 2 parts of amino-terminated polyamidoamine. The coating is prepared from 1-3 parts of graphene oxide, 1-2 parts of a photoinitiator, 1-2 parts of polytetrafluoroethylene wax, 0.5-1.5 parts of a dispersing agent, 1-2 parts of a flatting agent and 1-2 parts of a defoaming agent. The waterproof coating is excellent in waterproof effect, high in adhesive strength and excellent in dimensional stability; when the coating is subjected to mechanical actions such as friction and impact, the surface of a coated object is comprehensively protected, the wear rate is remarkably reduced, and the wear resistance is improved.

The invention discloses a lightweight concrete safety energy storage cabinet and a preparation method thereof, and the lightweight concrete safety energy storage cabinet is obtained by injecting lightweight concrete into a mold and performing steam curing; the lightweight concrete is prepared from the following raw materials in parts by weight: 20 to 40 parts of cement, 8 to 20 parts of silica fume, 8 to 25 parts of slag powder, 0 to 10 parts of fine sand, 15 to 35 parts of lightweight fine ceramsite sand, 0 to 21 parts of coarse ceramsite sand with the particle size of 5 to 10 mm, 0 to 3 parts of steel fiber, 0 to 1.5 parts of PP fiber, 0.5 to 2.0 parts of polycarboxylic acid type water reducing agent, 0 to 14 parts of hollow glass beads, 0.1 to 0.5 part of release agent and water. Wherein the water-binder ratio is 0.15 to 0.22; the use amounts of the steel fibers and the PP fibers are not 0 at the same time; the light ceramsite sand and the coarse ceramsite sand are subjected to pre-wetting treatment before being used; the fireproof, explosion-proof and heat-insulating material has the characteristics of light weight, safety and impermeability, and has excellent fireproof, explosion-proof and heat-insulating properties.

The invention discloses a self-repairing waste felt-based carbon fiber electromagnetic shielding concrete structure and a design method, and relates to the field of protective engineering building materials and multifunctional concrete structural design, the self-repairing waste felt-based carbon fiber electromagnetic shielding concrete structure comprises a base material, waste felt-based carbon fibers, hollow glass microsphere cell bodies and a synergistic enhancement mechanism, the base material comprises cement, silica fume, quartz sand and a high-efficiency water reducing agent, the waste felt-based carbon fibers are crushed to the particle size of 50-100 meshes, the crushed waste felt-based carbon fibers are modified by a specific silane coupling agent and then are uniformly dispersed in the ultra-high performance concrete base, graphene or carbon nanotube conductive particles are combined and doped, and the ultra-high performance concrete is prepared. A continuous three-dimensional conductive network is formed, the electromagnetic shielding effectiveness in the wide frequency band of 1-40 GHz reaches 30 dB or above, compared with a traditional metal shielding layer, the weight is reduced by 60%, the cost is reduced by 50%, and meanwhile the problem of metal corrosion is avoided.

The invention discloses a two-component photoinduced energy storage diffuse reflection nano coating as well as a preparation method and application thereof, and belongs to the technical field of building materials. Comprising prime paint and surface paint, the prime paint comprises 45-55 parts of paint emulsion, 30-40 parts of titanium dioxide, 5-10 parts of precipitated barium sulphate powder, 5-10 parts of pearl powder, fumed silica, an anti-settling agent, a light stabilizer, a dispersing agent and a coalescing agent; the surface layer coating is prepared from 55 to 65 parts of coating emulsion, 20 to 30 parts of alkaline earth aluminate, 10 to 15 parts of hollow glass beads, 5 to 10 parts of pearl powder, an anti-settling agent, a light stabilizer, a dispersing agent and a coalescing agent; the coating emulsion comprises acrylic resin and epoxy acrylate; the coating disclosed by the invention has excellent photoinduced energy storage performance and a good diffuse reflection effect, and can meet illumination requirements in environments such as underground parking lots, underground commercial plazas, traffic tunnels, civil air defense projects or military underground facilities.

The invention discloses a water-based single-component super-amphiphobic refrigeration coating, a coating and a preparation method of the coating, and relates to the technical field of coatings. 20-35 parts of a second filler; 5-10 parts of a third filler; 20-35 parts of a film-forming substance, 1-9 parts of an auxiliary agent and 3-50 parts of water; the first filler comprises fluorine-containing silane modified fumed silica; the second filler comprises at least one of long-chain silane modified precipitated barium sulfate, long-chain silane modified calcium carbonate and long-chain silane modified hollow glass beads; the third filler comprises an infrared emission filler treated by an organic silicon modifier. By modifying the filler, the purposes of stable dispersion and functional synergy of low-surface-energy substances and high-proportion inorganic nano filler in a water-based system are achieved.

The invention discloses an unmanned underwater vehicle floating material fixing structure, and relates to the technical field of underwater vehicle buoyancy materials. In order to solve the problems that in the prior art, a buoyancy material of an underwater vehicle is generally fixedly connected with the vehicle through a bolt, a polycarbonate protective layer is sprayed outside a hollow glass bead floating material, the floating material is easily damaged by replacing the buoyancy material and disassembling the bolt in the later period, and the buoyancy material is relatively fragile and cannot be damaged. The floating material is abraded due to repeated disassembly, and the polycarbonate protective layer is easy to fall off after long time, and the like. The device comprises a floating material, a screw sleeve, a nut sleeve and a protective layer, the floating material is arranged in an aircraft cabin composed of a framework and a non-pressure-resistant shell, a bolt through hole is machined in the floating material, a screw sleeve and a nut sleeve are embedded in the bolt through hole, and the outer portion of the floating material is integrally wrapped with a protective layer. The method is used for mounting and fixing the floating material of the unmanned underwater vehicle.

The invention relates to a high-reflection-high-emissivity radiation refrigeration coating for power equipment and a preparation method of the high-reflection-high-emissivity radiation refrigeration coating. The coating comprises deionized water, styrene-acrylic emulsion, titanium dioxide, hollow glass beads, zinc oxide, hexacyclic stone powder, a dispersing agent, a defoaming agent, a coalescing agent and a mildew preventive, and mica powder, calcined kaolin, talcum powder, silicon oxide micro powder or block copolymer emulsion can be optionally added. According to the coating, the synergistic effect of various infrared functional fillers and an emulsion matrix is optimized, so that high reflection of sunlight and high emission of middle and far infrared bands are realized. The coating has excellent cooling capacity, self-cleaning performance and environmental adaptability.

The invention discloses a dual-wavelength microsphere laser based on tri-doped rare earth ions and a preparation method thereof, the dual-wavelength microsphere laser based on tri-doped rare earth ions comprises a silica fiber, the middle part of the silica fiber is provided with a conical region; the pump light source is arranged at one end of the silica fiber; the erbium, holmium and ytterbium tri-doped tellurate glass microspheres are arranged in the conical region; pump light emitted by the pump light source is guided to the conical region through the single-mode optical fiber and is optically coupled with the erbium-holmium-ytterbium tri-doped tellurate glass microsphere; in the erbium-holmium-ytterbium triple-doped tellurate glass microspheres, infrared-transmitting tellurate glass is used as a matrix, and the doping amount of an erbium element is 0.11%, the doping amount of a holmium element is 0.22%, and the doping amount of an ytterbium element is 0.80% in percentage by mass. According to the dual-wavelength microsphere laser based on the three-doped rare earth ions, efficient and stable dual-wavelength laser output is achieved.

The invention discloses an ultraviolet-aging-resistant high-toughness wind power cable and a preparation method thereof, belongs to the technical field of cable preparation, is used for solving the technical problem that the ultraviolet aging resistance and toughness of a wind power cable in the prior art need to be further improved, and specifically comprises a wire layer, a shielding layer and a sheath layer; the preparation method comprises the following steps: coating an organic silicon layer on the outer side of a nano titanium dioxide particle and modifying amino to obtain a modified chain extender, carrying out chain extension on a long-chain polyurethane structure to obtain composite polyurethane, and carrying out hydrolysis by taking activated glass microspheres as a matrix and tetramethyl orthosilicate as a supplement to obtain modified aerogel. The preparation method comprises the following steps: preparing modified aerogel, modifying ferroferric oxide particles on the modified aerogel by using in-situ loading, further modifying perfluoro groups to obtain composite aerogel, finally mixing composite polyurethane, the composite aerogel and auxiliary materials, and performing melt extrusion to obtain a sheath layer of the wind power cable, thereby obtaining the wind power cable.

The invention provides a low-density high-strength aluminum-based composite material and a preparation method, and relates to the technical field of aluminum alloy powder metallurgy preparation. The composite material is composed of two parts: a matrix alloy and hollow glass beads, wherein the addition amount of the hollow glass beads is 5-30 wt.%. The matrix alloy comprises the following components in percentage by mass: 0 to 6.0 percent of Cu, 0 to 3.0 percent of Mg, 0 to 8.4 percent of Zn and the balance of Al and inevitable impurities; the hollow glass beads are prepared from the following components in percentage by mass: 70 to 80 percent of SiO2, 8 to 15 percent of CaO, 5 to 15 percent of Na2O, 3 to 8 percent of B2O3 and 2 to 3 percent of Al2O3. The composite material is prepared through surface modification of hollow glass beads, preparation of composite powder, preparation of a composite material green body, sintering densification, deformation processing and heat treatment. According to the technology, low-cost preparation and processing of the low-density and high-strength aluminum-based composite material can be achieved, the technological process is simple, the production efficiency is high, the method is suitable for large-scale industrial production, and the application prospects in the fields of aerospace, new energy automobiles, ships, electronic communication and the like are huge.

The invention provides a water-soluble core mold material based on direct-writing forming photocuring 3D printing and a preparation method of the water-soluble core mold material. The preparation method comprises the following steps: mixing polyvinylpyrrolidone and absolute ethyl alcohol to prepare a water-soluble adhesive; fully mixing a photocuring monomer hydroxyethyl methylacrylate with a photoinitiator TPO (Thermoplastic Polyolefin) to prepare water-soluble photocuring resin; mixing the two materials, stirring with a high-speed stirrer, sequentially adding heavy calcium carbonate powder, glass beads, white carbon black and glass fiber powder in the stirring process, and fully stirring to obtain slurry; and the slurry is printed through a printer, a core mold primary blank is obtained, and the final core mold material is obtained through secondary curing. According to the water-soluble core mold material based on direct-writing forming photocuring 3D printing and the preparation method of the water-soluble core mold material, the technical problems that a traditional metal mold is difficult to design, high in manufacturing cost and low in demolding efficiency are solved, and the water-soluble core mold material which is good in rheological property, low in cost and easy to demold can be prepared.

The invention discloses low-silver-content composite conductive silver paste based on a three-dimensional conductive network and a preparation method, and relates to the technical field of composite conductive silver paste preparation, and the low-silver-content composite conductive silver paste comprises a low-silver-content conductive phase, an interface bonding layer, a support body and an organic carrier; and the conductive phase with low silver content comprises the following components: 25 wt%-30 wt% of silver-plated hollow glass beads and 12 wt%-18 wt% of a three-dimensional conductive network. According to the invention, through accurate proportioning of the conductive phase with low silver content, the use amount of silver is greatly reduced. The silver-plated hollow glass bead takes light glass as a core and an ultrathin silver layer as a conductive shell, so that the silver consumption is reduced by more than 60wt%; the three-dimensional conductive network adopts a synergistic structure of silver nanowire fragments and graphene composite fragments, and the high conductivity of graphene is utilized to replace part of silver materials, so that the dependency degree of silver is further reduced. The silver content of the silver paste is greatly reduced, the cost of raw materials is greatly reduced, and the economical efficiency of the silver paste in large-scale application scenes such as photovoltaic and electronic packaging is remarkably improved.

The invention relates to hollow glass microsphere modified expanded graphite anti-settling polyurethane and a preparation method thereof.The hollow glass microsphere modified expanded graphite anti-settling polyurethane is composed of a polyurethane prepolymer, expanded graphite, hollow glass microspheres, a silane coupling agent, a catalyst, a foaming agent and a stabilizer, the expanded graphite and the hollow glass microspheres are mixed in proportion, an ethanol solution of the silane coupling agent is added, stirring is conducted, and the hollow glass microsphere modified expanded graphite anti-settling polyurethane is obtained. Performing ultrasonic treatment and drying to obtain modified composite filler; the preparation method comprises the following steps: mixing polyether polyol and polyisocyanate for reaction to prepare a polyurethane prepolymer; and adding the modified composite filler into the prepolymer, and sequentially adding the catalyst, the foaming agent and the stabilizer. Through composite modification of the hollow glass microspheres and the expanded graphite, the low density of the hollow glass microspheres and the high specific surface area of the expanded graphite are utilized, a stable three-dimensional network structure is formed, filler sedimentation is effectively prevented, the sedimentation rate is smaller than 5% and is far superior to that of a traditional polyurethane composite material, and long-term stability of material performance is ensured; the characteristics of light weight, high strength, heat insulation and settlement prevention are realized.

The invention relates to a preparation method of a high-elasticity composite buoyancy material with high compression resistance and high tensile strength, which comprises the following steps: 1, preparing raw materials: selecting rubber or synthetic resin as a base material, and selecting polyester synthetic fiber wires or meshes, hollow glass beads and compounding agents; step 2, mixing: adding the base material, the hollow glass beads and the compounding agent into mixing equipment according to a certain formula proportion to form a mixture; step 3, calendaring: calendaring the mixture through a calendaring machine to form a blank sandwiched with polyester fibers; 4, stacking is conducted, specifically, the blanks and the polyester synthetic fiber wires or meshes are stacked in a mold in a staggered mode according to the preset sequence and the preset layer number, and pre-pressing is conducted after stacking is completed; step 5, vulcanization molding: placing the mold in a hot press, and further vulcanizing and curing the mold; and 6, post-treatment is conducted, specifically, after the vulcanized flexible composite material plate is subjected to trimming and inspection procedures, the qualified flexible composite material plate is packaged.

The invention discloses a high-wear-resistance antiskid road marking coating and a preparation method thereof, and belongs to the technical field of road marking coatings. The coating comprises the following components in parts by weight: 15-25 parts of petroleum resin, 2-5 parts of a plasticizer, 30-40 parts of a composite wear-resistant aggregate, 15-25 parts of a composite antiskid aggregate, 5-10 parts of titanium dioxide, 0.5-2 parts of a silane coupling agent, 0.5-1.5 parts of polyethylene wax, 5-10 parts of glass beads, 0.1-0.3 part of an antioxidant 1010 and 10-20 parts of a filler. Through the synergistic effect of two types of specific aggregates, a hard-supporting and elastic-buffering wear-resistant matrix and a lasting multi-stage anti-skid surface are constructed in the coating, and the technical problems that a traditional marking coating is poor in wear resistance, insufficient in anti-skid performance and short in reflective life are solved; the obtained coating has the characteristics of ultrahigh wear resistance, lasting high skid resistance, strong adhesive force and slow reflection performance attenuation.