2020results about How to "Not easy to reunite" patented technology

The invention discloses graphene based conductive ink, comprising 2-25 wt% of conductive component, 5-25 wt% of bonding agent, 0.1-5 wt% of additive, 0.1-2 wt% of pH (Potential of Hydrogen) adjusting agent and the balance of solvent. A preparation method comprises the following steps of: dispersing the pH adjusting agent into the solvent to obtain a uniform first mixed liquid; mixing the first mixed liquid with the bonding agent to obtain a second mixed liquid; and mixing the second mixed liquid with the conductive component and the additive to obtain the graphene based conductive ink. The invention further provides a flexible conductive thin film prepared from the conductive ink. The conductive ink disclosed by the invention has the advantages of good dispersity, good conductive effect, easiness for printing, and cheap price. Furthermore, the flexible conductive thin film prepared from the conductive ink disclosed by the invention has good conductive performance.

The invention relates to a graphene/rare earth oxide nanometer composite material and a preparation method and application thereof. The preparation method comprises the following steps of: uniformly mixing oxidized graphene dispersion liquid and a soluble rare earth compound at the weight ratio of (1:1)-(1:10), regulating a pH value to alkalescence, and carrying out hydrothermal reaction to obtain the graphene-rare earth oxide nanometer composite material; and uniformly mixing the oxidized graphene dispersion liquid and the soluble rare earth compound at the weight ratio of (1:1)-(1:10), adding a reducer, and carrying out reflux reaction at certain temperature to obtain the graphene-rare earth oxide nanometer composite material. According to the invention, rare earth oxides are successfully loaded to the surface of graphene, the rare earth oxides can be connected in a physical loading or chemical bonding way because of the electrostatic action of the surface of the oxidized graphene and uniformly dispersed to the surface of a nanometer graphene sheet by being formed into nanometer level particles, the particle size is 5-50 nanometers, and the sheet thickness is 1-5 layers, so that the agglomeration phenomena of the graphene is obviously improved, and the electrochemical property of the graphene nanometer composite material as a cathode material and the circulation stability of the graphene nanometer composite material in the charge-discharge process are effectively enhanced and superior to those the cathode of the traditional commercial lithium ion battery. The preparation method disclosed by the invention has the advantages of simple process, low cost, short period, and the like.

The present invention provides a flaky structure layered composite hydroxide and a preparation method thereof. According to the preparation method, a metal hydroxide, an oxide, a basic carbonate, a metal soluble salt and an alkali are adopted as raw materials, the addition speed of the alkali solution is controlled to prepare the flaky LDH, and the space confinement effect of the metal hydroxide, the oxide or the basic carbonate exists, such that the produced LDH flakes do not easily aggregate so as to finally obtain the LDH with a large specific surface, wherein the BET specific surface area is 130-200 m<2>/g and is much larger than the specific surface area of the ordinary LDH. According to the invention, the preparation method has characteristics of simpleness, no requirement of high temperature, high pressure and special equipment, rich raw material source and low cost; and the flaky structure layered composite hydroxide can be widely used in the fields of absorption separation, catalysis, polymer materials and the like.

The invention provides a method for preparing magnetic ferroferric oxide/conductive polyaniline light-weight composite hollow microspheres, which relates to a method for preparing a magnetic ferroferric oxide/conductive polyaniline composite material. The invention solves the problems of high density and easy agglomeration of the traditional magnetic nanometer particle/conductive polymer composite material. The method comprises the following steps of: regulating ferrous chloride and ferric chloride solutions to be alkaline, adding sodium dodecyl benzene sulfonate and reacting to obtain ferroferric oxide; and modifying hollow glass microspheres by using poly(diallyldimethylammonium chloride) solutions after alkaline cleaning, then reacting the hollow glass microspheres with the ferroferric oxide, sequentially immersing obtained solid particles by using the poly(diallyldimethylammonium chloride) solutions and polystyrene sulfonic acid solutions, then adding the solid particles to aniline solutions, initiating polymerization by using ammonium persulfate, and washing and drying the solid particles to obtain the composite hollow microspheres. The composite hollow microspheres have both conductivity and magnetism, the density is 0.78-0.8g/cm<3>, and the composite hollow microspheres are not easy to agglomerate and are used for fields of military equipment stealth technology and civil anti-electromagnetic radiation.

The invention belongs to the technical field of materials, and particularly relates to a preparation method of graphene with nano ferroferric oxide precipitated on surface, which concretely comprises the steps of: firstly, oxidizing natural flake graphite and obtaining graphite oxide; further carrying out ultrasonic stripping on the graphite oxide and forming graphene oxide suspension; then, carrying out reduction reaction on the graphene oxide suspension under the action of strong reducing agent, and obtaining black flocculent flake graphene; and finally, taking hydrogen peroxide as an oxidant, and depositing Fe3O4 on the surface of the graphene in an alkaline solution. The invention realizes the modification of nanoscale Fe3O4 for the surface of the graphene. The obtained modified graphene is not doped with other elements except the Fe element, and can be well dispersed in a high-performance resin matrix, so that the mechanical property, the thermal performance, the electromagnetic performance and the friction property of the resin matrix can be improved, and phenolic resin, bismaleimide, cyanate ester and other products can be updated, or a new application field can be developed..

The invention relates to a method for modifying a boron nitride nanosheet with polydopamine. The invention aims to provide a method of using a mixed solvent of a polar organic solvent and water to conduct ultrasonic stripping of hexagonal boron nitride and modifying a boron nitride nanosheet surface with polydopamine. The boron nitride nanosheet obtained by the method provided by the invention has the characteristics of good dispersibility in the mixed solvent of the polar organic solvent and water, high yield and long storage time. The polydopamine surface modified boron nitride nanosheet prepared by the method has easy storage properties and good dispersibility in a solvent. The method for modifying a boron nitride nanosheet with polydopamine provided by the invention has the advantages of simple operation, safety and low cost, etc.

The invention discloses a Co3O4 nanometer material for a supercapacitor and a preparation method thereof. The method comprises the following steps: on the basis of using cobalt nitrate as a raw material and a mixture of ethylene glycol and water as a solvent, adding a defined amount of glucose, placing the mixture in an autoclave to react at 120-200 DEG C for 10-25 hours, performing suction filtering, drying at 80 DEG C, calcining in a muffle furnace at 300 DEG C to obtain Co3O4 sea urchin-shaped conjoined spheres which have the diameter of 7-15mu m and are of a three-dimensional hierarchical structure. The Co3O4 nanometer material and the preparation method have the characteristics that the operation method is simple, the yield is high, and the product has the three-dimensional hierarchical structure and superior electrochemical performance. The prepared Co3O4 spheres with the three-dimensional hierarchical structure have the characteristics that the stability is higher, the particle size distribution is uniform, the dispersibility is good, the spheres are difficult in agglomeration and pores with the three-dimensional structure are beneficial to the diffusion of the electrolyte, thus the material can be widely applied in the fields of catalysis, lithium batteries and supercapacitors.

The invention discloses a hydrophilic modification method of a PVDF ultrafilter membrane by the utilization of nano-TiO2 sol and belongs to the field of membrane separation technologies. According to the method, PVDF is used as the main high-molecular membrane preparation material. The hydrophilic TiO2 sol prepared in advance is added into a casting solution containing PVDF, an organic solvent and an additive, and the hydrophilic PVDF ultrafilter membrane is prepared by the utilization of a phase inversion method. By the adoption of the method, water contact angle of the prepared PVDF ultrafilter membrane can be reduced from about 85 degrees to about 60 degrees, and hydrophilicity of the PVDF membrane is obviously raised. Various substances concerned in the invention comprise, by weight, 10-25% of polyvinylidene fluoride (PVDF), 60-80% of a solvent for dissolving polyvinylidene fluoride, 1-10% of the TiO2 sol, and 0-10% of the additive, wherein the additive contains a mixture of anhydrous LiCl and PVP. Porosity of the prepared membrane is 50-80% and its membrane pore size is 0.01-0.2 micron. The method provided by the invention has a simple membrane forming technology, is convenient to operate, and is easy to realize industrial production. In addition, the prepared ultrafiler membrane has good hydrophilicity and high water flux, and has a wide application prospect.

The invention discloses photo-curable 3D (three-dimensional) printing aluminum-base ceramic slurry and a method for preparing ceramic mold cores. The photo-curable 3D printing aluminum-base ceramic slurry comprises ceramic formula powder, photo-curable resin systems and additives. The photo-curable 3D printing aluminum-base ceramic slurry and the method have the advantages that the photo-curable 3D printing aluminum-base ceramic slurry is high in solid phase content, low in viscosity and applicable to photo-curable 3D printing photo-polymerization, the problems of high viscosity and poor flowability of existing slurry for photo-curable 3D printing ceramics, easiness in agglomerating ceramic particles in the existing slurry, uneven dispersion of the ceramic particles, low solid phase contents and the like can be solved, and application of photo-curable 3D printing to ceramic precision components can be expanded.

The invention discloses a finishing method for a textile with ultraviolet-resisting and antibacterial functions. The finishing method comprises the following steps: step (10), preparing a zinc oxide/carboxymethyl chitosan nano compound; step (20), pre-treating the textile with a cold plasma method; and step (30), preparing the zinc oxide/carboxymethyl chitosan nano compound prepared by the step (10) into a zinc oxide/carboxymethyl chitosan nano compound solution, and immersing the textile pre-treated by the step (20) with the solution; and adding an acrylic ester binding agent and adopting a rolling baking process to obtain the treated textile. The textile prepared by the finishing method has good ultraviolet-resisting and antibacterial functions.

The invention relates to nanometer material and in particular relates to porous nanometer zero-valent iron composite material mainly made from main active constituent component, a skeleton component and an auxiliary component. The main active constituent component is nanometer zero-valent iron; the skeleton component is made from one or more than one metal of Al, Mn, Si and Zn; and the auxiliary component is made from one or a plurality of components of the Ni, Pt, La, Cu and Pd. The invention further relates to the preparation method for the porous nanometer zero-valent iron composite material and purposes of the porous nanometer zero-valent iron composite material on fields of water pollution processing, soil pollution processing and environment repairing.

The invention discloses a method for preparing superfine nano-silicon by taking a silicon-containing biomass as the raw material. The method comprises the following steps: eliminating an inorganic salt ion impurity by performing acid boiling on the silicon-containing biomass, grinding and smashing the white powders processed by air annealing to obtain a nano-silicon dioxide granule, uniformly mixing the white product, the magnesium powder and the fused salt, putting into a tube furnace, reacting under an inert atmosphere to obtain the silicon and the magnesium oxide, and removing the magnesium oxide by performing acid dipping on the reaction product to obtain the superfine nano-silicon granule. The reaction step is simple and practicable, the sources of the raw materials are extensive, most importantly the reaction temperature is controlled by adding the fused salt to melt and absorb heat, the reactant is hard to agglomerate, the specific surface area of the prepared nano-silicon is 302.13m<2>/g, the purity is greater than 98%, the granules are uniform with mesopores and the nano-silicon can be used in the fields such as the lithium ion battery, the semiconducting material and the medicine.

The invention discloses a preparing method for green synthesis of nanoscale zero-valent iron through water hyacinth extraction liquid and application. Water hyacinth stem and leaf extraction liquid serves as a reduction agent to reduce iron ions or ferrous ions to the zero-valent iron, a chromium pollution water green repairing material-green synthesis nanoscale zero-valent iron particles are obtained through preparing. The synthesis method is low in synthesis cost, small in energy consumption, simple in process, and free of a special device, the used reduction agent is the water hyacinth stem and leaf extraction liquid, wastes are utilized, and the synthesized particles are easily agglomerated and have the beneficial effects of being good in flowability, large in specific surface area, high in stability and the like. The repairing material prepared through the method is suitable for repairing the chromium pollution water and is high in repairing efficiency.

The invention discloses a graphene-supported copper-nickel composite nanometer photocatalyst, and a preparation method and application thereof. Oxidized graphene modified by an organic molecule and a metal precursor are subjected to thermal recovery under an alkaline and high temperature environment so as to obtain highly disperse and uniform Cu-Ni/ graphene composite nanomaterial without using other surface active agents, and poisonous reducing agents such as sodium borohydride and hydrazine hydrate, and duplex-metal loading capacity is 10-15wt%. The preparation method provided by the invention has the advantages that a reaction condition is gentle, a synthetic process is simple and easy to operate, a reaction medium is green and the like, the synthetized product is capable of efficiently performing catalytic degradation on rhodamine b, and the graphene-supported copper-nickel composite nanometer photocatalyst has a good catalytic effect, and has a wide application prospect in fields such as sewage treatment and organic matter degradation.

The invention provides high-conductivity aluminum-doped nano-zinc oxide powder and a preparation method thereof. The method of the invention comprises the steps that aluminum-doped zinc oxide nanocrystals are first prepared by solvothermal reaction and then sintered in the atmosphere of hydrogen to obtain nanometer-degree quasi-spherical conductive powder. The conductive powder is white and slightly gray and is non-toxic, light in weight and environment-friendly and also has less conglobation, good dispersity and repeatability and uniform size distribution; in addition, the particle size of the powder synthesized in different solvents is different and the minimum resistivity of the powder can reach 15 Omega cm and can be suitable for the various demands of products. The preparation method of the invention is simple in operation, short in period and low in cost, needs no surface active agents and templates and can be applied to mass production. The nanometer-degree conductive powder obtained by utilizing the method can be taken as conductive filler to be widely applied to fields such as paints, rubber, plastics and fibers, etc., for carrying out electrostatic prevention and electromagnetic shielding.