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1534 results about "Hexagonal boron nitride" patented technology

Hexagonal Boron Nitride (HBN) is an advanced bullet-coating material. HBN, also known as ‘White Graphite’, has similar (hexagonal) crystal structure as graphite, though it is a much better lubricant. For those who prefer shooting coated bullets, HBN appears to have many advantages over molybdenum disulfide (moly).

Flame-retardant aging-resistant polyolefin cable material, preparation method and cable prepared from cable material

The invention discloses a flame-retardant aging-resistant polyolefin cable material, a preparation method and a cable prepared from the cable material. The flame-retardant aging-resistant polyolefin cable material is prepared from the following ingredients in parts by weight: 20 to 40 parts of polyethylene, 20 to 30 parts of polyolefin elastomers, 5 to 10 parts of organic compatilizers, 5 to 15 parts of modified nano aluminum hydroxide / hexagonal boron nitride nano composite powder and 10 to 30 parts of flame retardants. The flame-retardant and aging-resistant polyolefin cable material provided by the invention has good mechanical properties and scratch and wear resistance, has high flame retardance and is suitable for the cable industry.
Owner:SHENZHEN WOER HEAT SHRINKABLE MATERIAL

Small-particle-size spherical hexagonal boron nitride nano-powder and preparation method thereof

The invention relates to small-particle-size spherical hexagonal boron nitride nano-powder and a preparation method thereof. The method comprises the following steps: uniformly mixing boric acid and a nitrogen source, adding borax, uniformly mixing, and treating the obtained mixture at 75-85 DEG C or 250 DEG C for 2-5 hours; the obtained precursor is subjected to ball milling and drying or freeze drying, and then the obtained ball-milled precursor is heated to 900 DEG C in a high-pressure nitrogen atmosphere at the heating rate of 3-5 DEG C / min and subjected to heat treatment for 0.5-3 h; and putting the obtained product into water at 80-90 DEG C, stirring for 5-8 hours, and then performing post-treatment to obtain the small-particle-size spherical hexagonal boron nitride nano-powder. The prepared spherical boron nitride powder has the advantages of small particle size, high specific surface area and high sintering activity or the prepared spherical boron nitride powder has the advantages of small particle size and high crystallinity, and the preparation method is low in energy consumption, green and efficient.
Owner:UNIV OF SCI & TECH BEIJING +1

Flexible flame-retardant polyolefin insulating material for high-flexibility drag chain cable as well as preparation method and application of flexible flame-retardant polyolefin insulating material

The invention relates to the field of cable materials, and provides a flexible flame-retardant polyolefin insulating material for a high-flexibility drag chain cable and a preparation method thereof.The flexible flame-retardant polyolefin insulating material comprises phosphorus-containing flame retardant surface modified boron nitride, polyphosphazene modified magnesium hydroxide nanowires, polyolefin matrix resin and the like. The phosphorus-containing flame retardant surface modified boron nitride is prepared by carrying out surface modification on hydroxyl modified hexagonal boron nitride through 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and vinyl trimethoxy silane, and shows excellent flame retardant property and flexibility. The polyphosphazene modified magnesium hydroxide nanowire is prepared through silane coupling agent functionalization and polyphosphazene cross-linking polymerization, and has flame retardance and a reinforcing effect. The preparation method of the material comprises the steps of raw material premixing, melt blending, cooling granulation and extrusion molding. The material has the characteristics of flame retardance, high flexibility and the like, and is widely applied to dynamic high-flexibility cables in the fields of industrial automation equipment, robots, machine tool manufacturing, logistics conveying systems and the like.
Owner:HANGZHOU LINAN GUANGDA CABLE

Preparation method of h-BN / PI high-temperature-resistant anticorrosive coating

The invention provides a preparation method of an h-BN / PI high-temperature-resistant anticorrosive coating, and relates to the technical field of polymer composites.The preparation method of the h-BN / PI high-temperature-resistant anticorrosive coating comprises the steps that under the protection of inert atmosphere, aromatic diamine containing impurity element five-membered rings and aromatic dianhydride containing ether bonds are taken and subjected to a polymerization reaction in a polar aprotic solvent, and the h-BN / PI high-temperature-resistant anticorrosive coating is obtained. A polyamide acid solution is obtained; performing ultrasonic-assisted liquid phase stripping on the micron-sized hexagonal boron nitride to obtain single-layer hexagonal boron nitride; adding the single-layer hexagonal boron nitride into the polyamide acid solution for multiple times, and uniformly stirring to obtain a hexagonal boron nitride / polyimide composite solution; and coating the hexagonal boron nitride / polyimide composite liquid on a to-be-coated surface, and carrying out gradient heating curing to obtain the h-BN / PI high-temperature-resistant anticorrosive coating. The h-BN / PI high-temperature-resistant anticorrosive coating based on interaction of multiple hydrogen bonds has relatively good high temperature resistance, relatively good resistance mechanical property and excellent corrosion resistance.
Owner:HARBIN INST OF TECH

Modified hexagonal boron nitride and organic silicon double-component doped high-flame-retardant epoxy resin powder coating as well as preparation method and application thereof

The invention relates to the technical field of coatings, and discloses a modified hexagonal boron nitride and organic silicon double-component doped high-flame-retardant epoxy resin powder coating as well as a preparation method and application thereof. Comprising the following raw materials in parts by weight: 25-50 parts of modified hexagonal boron nitride, 90-110 parts of organic silicon resin, 120-150 parts of epoxy resin, 5-8 parts of dicyandiamide, 100-120 parts of silica powder, 8-12 parts of other auxiliaries and 80-100 parts of filler. The flame-retardant epoxy resin powder coating is prepared by uniformly mixing the components, melting, extruding a sheet material, grinding and sieving. The flame-retardant and fireproof performance of the epoxy resin powder coating is greatly improved in a modified hexagonal boron nitride and organic silicon double-component doping mode.
Owner:MINNAN NORMAL UNIV

High-hardness and high-brittleness semiconductor anti-deterioration cutting fluid and production process thereof

The invention relates to the field of cutting fluids, and discloses a high-hardness brittle semiconductor anti-deterioration cutting fluid and a production process thereof, the cutting fluid comprises the following components by weight: 15-25 parts of a lubricant, 10-20 parts of an anti-wear modifier, 1-5 parts of organic acid, 5-15 parts of organic amine, 1-3 parts of a lubricating antibacterial additive, 0.1-0.3 part of a bactericide, 0.5-2 parts of a wetting agent, 0.1-0.5 part of an antifoaming agent, and 25-35 parts of deionized water; the anti-wear modifier is prepared by taking aminated nano hexagonal boron nitride as a carrier to grow silicon dioxide nanoparticles in situ and carrying out composite hybridization on the silicon dioxide nanoparticles and binary acid ionic liquid, and the binary acid ionic liquid is prepared from 2-(1, 3-benzothiazole-2-sulfenyl) succinic acid and choline hydroxide; the lubricating antibacterial additive is prepared from aminated nano hexagonal boron nitride, chitosan and ethylene glycol diglycidyl ether, and by adding the anti-wear modifier and the lubricating antibacterial additive, the cutting fluid is endowed with excellent lubricating wear resistance, antibacterial property and anti-rust performance.
Owner:OEMETA (WUHAN) CO LTD

Modified chrome corundum ramming material as well as preparation and construction processes thereof

The invention relates to a modified chrome corundum ramming material and a preparation and construction process thereof, and belongs to the technical field of chrome corundum ramming materials. The ramming material comprises a material A, a material B and a material C, wherein the material A comprises chrome corundum aggregate, titanium dioxide coated aluminum oxide microspheres, calcium sulfide dehydrate and silicon carbide porous microspheres; the material B comprises chromium oxide-zirconium oxide composite nano powder, sodium thiosulfate pentahydrate, tricalcium phosphate and hexagonal boron nitride flaky crystals; and the material C comprises an aluminum dihydrogen phosphate-magnesium hydroxide compound, a calcium fluoride-aluminum oxide co-melt and a silane coupling agent. The preparation process comprises the steps of pretreatment of all the components, preparation of composite powder and layered preparation. The construction process comprises the steps of pretreatment, wet-process mixing, layered ramming, negative-pressure permeation, medium-temperature reaction, spraying curing, integral firing and the like. Generation of hexavalent chromium can be effectively inhibited, the thermal shock resistance, the mechanical strength and the heat-conducting property of the material are remarkably improved, and the material has the advantages of being good in environment friendliness, long in service life, excellent in construction performance and the like.
Owner:YING KOU SHI XING REFRACTORY TECH CO LTD

Anti-ultraviolet acrylic resin coating and preparation method thereof

The invention discloses an uvioresistant acrylic resin coating and a preparation method thereof, and belongs to the technical field of acrylic resin paints.The uvioresistant acrylic resin coating is characterized in that step-by-step functional design is adopted, a functional polyurethane prepolymer is constructed through prepolymerization reaction and double-bond end capping, fluorosilicone modified acrylate emulsion is prepared through a core-shell emulsion polymerization process, and the uvioresistant acrylic resin coating is obtained. Then carrying out surface silane modification on hexagonal boron nitride and carrying out composite coating to obtain a modified boron nitride auxiliary agent; and finally, carrying out composite emulsification and dispersion compounding on all the components to obtain the anti-ultraviolet acrylic resin coating. Through the synergistic enhancement effect of the fluorosilicone modified core-shell structure and the surface modified boron nitride, the ultraviolet aging resistance and the insulation reliability of the coating are remarkably improved on the basis of keeping high adhesive force, excellent flexibility and impact resistance of the coating; the problems that a traditional acrylic coating is prone to yellowing and pulverization under long-term ultraviolet radiation, and the mechanical property is reduced are effectively solved, and the acrylic coating is suitable for the field of electronic equipment protective coatings with high requirements for weather resistance, mechanical strength and electrical insulating property.
Owner:ANHUI PUMIYANG NEW MATERIAL CO LTD

Preparation method of barrier type antimonide infrared detector and infrared detector

The invention provides a preparation method of a barrier type antimonide infrared detector. The preparation method comprises the following steps: selecting a gallium antimonide substrate; a gallium antimonide buffer layer, an indium arsenide heavily-doped layer, a class II superlattice absorption layer and an aluminum-arsenic-antimony barrier layer are sequentially grown on the substrate in an epitaxial mode through a molecular beam epitaxy method; mechanically stripping the hexagonal boron nitride two-dimensional material, and transferring the stripped hexagonal boron nitride to the aluminum-arsenic-antimony barrier layer to form a Van der Waals heterojunction and composite barrier layer structure; depositing electrodes by using an ultraviolet lithography technology and a thermal evaporation mode to form one electrode arranged on the gallium antimonide buffer layer and the other electrode arranged on the boron nitride; a large-numerical-aperture micro-lens array is processed on a substrate, and the micro-lens array is composed of gallium antimonide cylinders with a phase modulation function; therefore, the antimonide medium-wave infrared detector with the composite barrier layer can be formed, the quantum efficiency is improved, the order of magnitude of dark current is reduced, and room-temperature medium-wave infrared detection can be realized.
Owner:CHINA ACADEMY OF SPACE TECHNOLOGY

Pouring sealant and preparation method thereof

The invention provides a pouring sealant and a preparation method thereof. The pouring sealant comprises a component A, a component B, a component C and a component D, wherein the component A comprises hydroxyl-terminated polydimethylsiloxane, inorganic filler, phase change microcapsules and surface-modified hexagonal boron nitride nanosheets; the component B comprises dimethyl silicone oil, a silane cross-linking agent, a silane coupling agent and an organic tin catalyst. The pouring sealant provided by the invention can effectively prevent corrosive ions and the like in salt mist from entering a diode area of the junction box while ensuring the sealing performance of the diode of the junction box, prevents the phenomenon of corroding the diode, and controls the temperature rise of the junction box in operation through effective thermal management, so that the service life of the junction box is prolonged. And the service performance and the service life of the photovoltaic module junction box in an offshore environment are improved and prolonged.
Owner:TRINA SOLAR CO LTD

Hexagonal boron nitride / titanium dioxide heterojunction-based doped material and preparation method thereof

The invention discloses a doped material based on a hexagonal boron nitride / titanium dioxide heterojunction and a preparation method thereof. According to the material, a heterojunction is formed by hexagonal boron nitride and titanium dioxide, and the light absorption performance, the carrier mobility and the photocatalytic efficiency are optimized by doping a nitrogen element, an iron element and a fluorine element; wherein the doped nitrogen element can reduce a band gap by introducing a defect energy level, and broaden a light absorption range to a visible light region and an infrared light region; the doped iron element can promote carrier separation by introducing an intermediate energy level; the doped fluorine element can inhibit carrier recombination by reducing surface defects. The light absorption efficiency of the material in the ultraviolet light range can be improved by constructing the layered # imgabs0 # heterojunction composite material, and the migration rate of electrons and holes can be improved by doping the N element, the Fe element and the F element in the # imgabs1 #, so that the oxidation-reduction reaction is promoted, and reference significance is provided for further improving the application effect of a photocatalyst in sewage treatment.
Owner:GUANGDONG UNIV OF TECH

Flame-retardant insulating powder coating for new energy automobile and preparation method of flame-retardant insulating powder coating

The invention discloses a flame-retardant insulating powder coating for a new energy automobile and a preparation method of the flame-retardant insulating powder coating, and belongs to the technical field of coatings. The flame-retardant insulating powder coating for the new energy automobile is prepared from the following raw material components in parts by mass: 380 to 384 parts of epoxy resin, 56 to 58 parts of a toughening agent, 5 to 10 parts of modified flame-retardant filler, 100 to 101 parts of a composite curing agent, 5 parts of a flatting agent, 1 part of benzoin and 0.7 part of an accelerant, the toughening agent is obtained by carrying out a reaction on an isophorone diisocyanate tripolymer, 4-bromophenol and N-p-coumaroyl tyramine; the modified flame-retardant filler is obtained by firstly wrapping hexagonal boron nitride with polydopamine and then modifying with a silane coupling agent; the silane coupling agent is obtained by combining 4-benzonitrile oxygen butyl trimethoxy silane and a sulfydryl silane coupling agent; and the composite curing agent is obtained by combining 4, 4-diaminodiphenylmethane and amino-sulfydryl functional organic polysiloxane.
Owner:JIANGSU HUAGUANG POWDER +3

Anti-corrosion epoxy composite coating and preparation method thereof

The invention relates to the technical field of coating materials, in particular to an anti-corrosion epoxy composite coating and a preparation method thereof. The anti-corrosion epoxy composite coating is prepared from the following raw materials in parts by mass: 40 to 60 parts of epoxy resin, 10 to 20 parts of alkoxy silane, 4 to 6 parts of pigment, 1 to 4 parts of auxiliaries, 2 to 6 parts of solvents, 14 to 18 parts of hexagonal boron nitride type preservatives and 10 to 30 parts of curing agents, and the hexagonal boron nitride type preservatives contain hexagonal boron nitride and polythiophene. According to the anti-corrosion epoxy composite coating, the defect that hexagonal boron nitride particles are prone to agglomeration can be overcome, and the anti-corrosion epoxy composite coating has more excellent anti-corrosion performance.
Owner:NINGBO KEXIN CORROSION CONTROL ENG

Nano photocatalytic self-cleaning composite material, fresh-keeping cover and preparation method of fresh-keeping cover

The invention belongs to the field of polymer modification and processing, and particularly relates to a nano photocatalytic self-cleaning composite material, a fresh-keeping cover and a preparation method of the fresh-keeping cover. The composite material comprises aliphatic nylon, a maleic anhydride grafted copolymer, nano titanium dioxide, carbon nanotubes, boron nitride, a coupling agent, a release agent and an antioxidant. The nano photocatalytic self-cleaning composite material is prepared by taking nano titanium dioxide as an antibacterial active agent and adding a certain amount of carbon nanotubes and boron nitride powder. The carbon nanotubes can conduct electrons, have high surface area and high adsorption capacity, and are good dopants and carriers for titanium dioxide as photocatalysts. Hexagonal boron nitride can effectively improve separation and transfer of photo-induced electron-hole pairs of the material, so that the visible light response photocatalytic activity is enhanced. And by adding the carbon nanotubes and boron nitride, the dispersing performance of nano titanium dioxide can be physically improved, titanium dioxide agglomeration is prevented, and the photocatalytic self-cleaning performance of the nano titanium dioxide is improved.
Owner:淄博仟佰源家居用品有限公司

Preparation method of modified self-extinguishing insulating oil with flame-retardant and self-repairing functions

The invention discloses a preparation method of modified self-extinguishing insulating oil with flame-retardant and self-repairing functions. Wherein the insulating liquid is mixed oil of mineral oil and palm oil-based modified natural ester, and the inherent high flash point characteristic of the natural ester improves the fireproof safety of the insulating oil. The modified hexagonal boron nitride (h-BN), the magnesium hydroxide nano material and the microcapsule repairing agent are added into the insulating oil, and the h-BN can capture free electrons in the oil, so that the formation and expansion of electric arcs are inhibited, and the breakdown voltage is improved. Magnesium hydroxide is heated to decompose and absorb heat, the fault temperature is reduced, and therefore the arc self-extinguishing effect is achieved. Under the action of a high electric field and a high temperature, the capsule wall of the microcapsule repairing agent is broken, meanwhile, the repairing material is released, a chemical reaction is carried out, and the insulating property of the insulating oil is repaired. The modified insulating oil prepared by the invention has high insulating strength and high flame retardance, and also has a performance self-repairing function, so that the service life of the insulating oil is prolonged.
Owner:CHINA UNIV OF MINING & TECH +1

Preparation method of high-thermal-conductivity hexagonal boron nitride film

The invention relates to a preparation method of a high-thermal-conductivity hexagonal boron nitride film in the technical field of new materials, which comprises the following steps: acquiring particle size distribution data of hexagonal boron nitride powder treated by silane, and measuring the distribution condition of hexagonal boron nitride particles with different particle sizes by a particle size analyzer to obtain a particle size distribution curve; the influence of key process parameters on the heat-conducting property, the mechanical strength and the flame-retardant property is verified through experiments, performance data under different process parameters are obtained, and the influence rule of silanization treatment conditions on the surface property of hexagonal boron nitride and the performance of the composite material is focused on; and according to the heat-conducting property, the mechanical strength and the flame-retardant property data, optimizing process parameters by adopting a particle swarm optimization algorithm in a multi-objective optimization algorithm to obtain an optimal process parameter combination.
Owner:DONGGUAN YIPIN SILICONE ELECTRONIC MATERIAL CO LTD

Cool-feeling anti-ultraviolet nylon fabric and preparation method thereof

The invention belongs to the field of functional textile materials, and provides a cool-feeling anti-ultraviolet nylon fabric and a preparation method thereof, and the cool-feeling anti-ultraviolet nylon fabric adopts a design scheme of combining a boron nitride / titanium dioxide composite filler with a beta-hydroxyl ether type ultraviolet absorption silane coupling agent surface modification technology. Uniform loading of hexagonal boron nitride on the surface of anatase type titanium dioxide is realized through an in-situ heat treatment process, a composite structure with heat conduction and ultraviolet shielding functions is constructed, and a complete process flow of master batch preparation, melt spinning, weaving, after-treatment and the like is matched; the ultraviolet protection coefficient UPF of the fabric is not lower than 40, the UPF retention rate after 20 times of household washing cycles is not lower than 80%, and the cool feeling qmax at the contact moment is not lower than 0.20 W / cm, the technical problem that an existing nylon fabric is insufficient in ultraviolet resistance and cool feeling function is solved, and the fabric has wide industrial application value.
Owner:SUZHOU GONGYEYUAN DISTRICTHEXIANG TEXTILE CO LTD

Magnetic recording medium, magnetic storage apparatus, and method for manufacturing magnetic recording medium

A magnetic recording medium includes a substrate, an underlayer, a first magnetic layer, and a second magnetic layer in this order. The first magnetic layer includes magnetic grains having a L10 structure, and the second magnetic layer has a granular structure including magnetic grains having a L10 structure, and a grain boundary portion including hexagonal boron nitride. A (111) plane of the magnetic grains included in the first magnetic layer is covered with boron nitride at an interface with the second magnetic layer. The magnetic grains included in the second magnetic layer are epitaxially grown from a (001) plane of the magnetic grains included in the first magnetic layer. The magnetic grains included in the first magnetic layer and the magnetic grains included in the second magnetic layer are columnar crystals penetrating the first magnetic layer and the second magnetic layer, respectively.
Owner:RESONAC HARD DISK CORP

Polyimide-based dielectric heat-conducting composite material and preparation method thereof

The invention provides a polyimide-based dielectric heat-conducting composite material and a preparation method thereof.The preparation method comprises the steps that a hexagonal boron nitride nanosheet is modified through polydopamine to obtain a modified boron nitride nanosheet (MBN), and the modified boron nitride nanosheet (MBN) is mixed with a polyamide acid (PAA) solution to obtain an MBN / PAA solution; mBN is directionally distributed in PAA nanofibers through an electrostatic spinning technology, meanwhile, dispersion liquid of silver wires is electrostatically sprayed, and the silver wires serve as a bridge, so that a heat conduction path is constructed under the condition that less filler is doped; finally, the MBN-AgNW / PI dielectric heat-conducting composite material is prepared through a staggered stacking-compression molding-thermal imidization technology, and the prepared composite material is good in heat conductivity, low in dielectricity and high in insulativity and has huge application potential in electronic packaging equipment.
Owner:TIANJIN POLYTECHNIC UNIV

Graphite crucible silicon infiltration resistant coating based on gradient boron nitride-silicon carbide composite structure and preparation method thereof

PendingCN120774738ACarbon layerNanowire
The invention discloses a graphite crucible silicon infiltration resistant coating based on a gradient boron nitride-silicon carbide composite structure and a preparation method thereof. The coating is composed of hexagonal boron nitride nanosheets, beta-type silicon carbide nanowires, yttrium aluminum garnet precursor sol and the like, and effective blocking of 1500-1600 DEG C silicon melt is achieved through gradient structural design and an in-situ self-repairing mechanism. The preparation process comprises the steps of h-BN activation, S C carbon layer deposition, slurry mixing and spraying and segmented heat treatment. The molten silicon contact angle of the coating reaches 158 + / -2 degrees at the temperature of 1550 DEG C, through cracks do not exist after 50 times of thermal shock circulation, the coating is effective after being continuously used for 48 batches under the industrial working condition, the problems of silicon infiltration interface adhesion and thermal shock failure of a traditional graphite crucible are solved, and the coating has remarkable industrial application value.
Owner:YIBIN JINGYANG NEW MATERIALS TECHNOLOGY CO LTD

Microwave-transmitting and infrared-compatible low-emissivity coating

The invention provides a microwave-transmitting and infrared-compatible low-emissivity coating, and belongs to the technical field of camouflage materials. The microwave-transmitting and infrared-compatible low-emissivity coating is of a double-layer structure composed of a bottom microwave transparent layer and a surface infrared functional layer. The microwave transparent layer is made of hollow dielectric microbeads and polyvinylidene fluoride; the infrared functional layer is made of modified flaky aluminum powder, modified hexagonal boron nitride nanosheets and polyvinylidene fluoride. The microwave-transmitting compatible infrared low-emissivity coating provided by the invention has an infrared radiation inhibition effect in two atmospheric window wave bands of 3-5 microns and 8-14 microns, and has high transmissivity in an electromagnetic wave band of 2-18 GHz; the method is especially suitable for the scenes, such as stealth unmanned aerial vehicles, ship decks and 5G base station shells, where infrared characteristics need to be suppressed and microwave signal transmission needs to be kept at the same time.
Owner:HEFEI ZHONGYIN NEW MATERIAL CO LTD

Copper-based static disc material for aviation and preparation method of copper-based static disc material

The invention belongs to the technical field of aviation static disc materials, and aims to solve the problem that the application of an existing copper-based static disc material in an aviation brake system is limited due to the fact that the comprehensive performance of the existing copper-based static disc material is weak. In order to achieve the purpose, the invention provides the aviation copper-based static disc material and the preparation method thereof. The aviation copper-based static disc material comprises, by mass, 55%-65% of high-purity electrolytic copper, 10%-15% of aluminum bronze alloy, 4%-8% of nano nickel powder, 2%-5% of chromium molybdenum alloy, 2%-6% of nano silicon carbide particles, 1.5%-4% of continuous carbon fiber bundles, 1%-3% of hexagonal boron nitride nanosheets, 0.5%-2% of tungsten carbide particles, 0.5%-2% of multilayer graphene, 0.3%-1.5% of sodium molybdate, 0.5%-1.5% of a coupling agent, 0.2%-1% of a nano lubricant and 0.1%-0.8% of an antioxidant. The comprehensive properties such as strength, hardness, high-temperature wear resistance, friction coefficient stability and corrosion resistance of the aviation copper-based static disc material are remarkably improved, the requirements of an aviation brake system are met, and the aviation copper-based static disc material is particularly suitable for being applied under complex working conditions.
Owner:YOUCAITEC MATERIAL CO LTD

Composite diaphragm, preparation method thereof and lithium ion battery

The invention provides a composite diaphragm, a preparation method thereof and a lithium ion battery. The composite diaphragm comprises a base diaphragm and a solid electrolyte-water-soluble gel electrolyte composite coating, wherein the surface of the base diaphragm is coated with the solid electrolyte-water-soluble gel electrolyte composite coating by utilizing a roller coating process; the water-soluble gel electrolyte is obtained by co-polymerizing an intermediate I prepared from methyl methacrylate and N-isopropylacrylamide and neopentyl glycol diglycidyl ether. In the composite diaphragm provided by the invention, the water-soluble gel electrolyte can effectively improve the adhesion of the solid electrolyte on the base membrane, and ensure that the solid electrolyte can be effectively adhered to the surface of the base membrane; lithium titanium aluminum phosphate and the like can effectively promote transmission of lithium ions through the solid electrolyte, the hexagonal boron nitride composite coating can prevent direct contact between the lithium titanium aluminum phosphate solid electrolyte and the like and lithium, and the solid electrolyte is protected. And the interface stability of the composite diaphragm is relatively good, and a compact phase formed in the circulation process can effectively inhibit the permeation of lithium dendrites, so that the safety of the battery is improved.
Owner:HU ZHOU YAO NING GU TAI DIAN CHI YAN JIU YUAN YOU XIAN GONG SI

Preparation method of wurtzite boron nitride material

The invention provides a preparation method of a wurtzite boron nitride material, which comprises the following steps: performing high-temperature and high-pressure treatment on hexagonal phase boron nitride powder at the pressure of 10-15 GPa and the temperature of 900-1300 DEG C, keeping the pressure for 120-240 minutes, and keeping the temperature for 40-120 minutes, thereby obtaining the wurtzite boron nitride material. According to the method provided by the invention, the pure-phase wurtzite boron nitride block material is prepared by taking low-cost hexagonal boron nitride powder as a starting material, and synthesis of the high-purity and high-performance wurtzite boron nitride block material is realized under relatively mild conditions by optimizing high-temperature and high-pressure synthesis parameters and an experimental assembly structure. The Vickers hardness of the obtained material reaches 46 + / -2.3 GPa under the loading of 1 kg, the thermal stability reaches 1085 DEG C, and excellent superhardness and high temperature resistance are shown. The method is simple in process, raw materials are easy to obtain, the dependence of a traditional method on a high-cost precursor and a complex process is broken through, and the method has a good industrial application prospect.
Owner:INSTITUTE OF PHYSICS CHINESE ACADEMY OF SCIENCES

Nano ceramic-based composite insulating paint and preparation method thereof

The invention relates to the technical field of polymer composite materials, and discloses a nano-ceramic-based composite insulating coating and a preparation method thereof, and the coating is prepared from a composite resin matrix, a composite functional ceramic filler, a double-reactivity organosilicon linker and an initiator. Wherein the composite resin matrix is composed of vinyl-terminated polydimethylsiloxane and a vinyl ether functionalized fluorocarbon copolymer, and a soft and rigid interpenetrating network structure is formed. The composite functional ceramic filler is prepared from needle-shaped silicon nitride, flaky hexagonal boron nitride, nano silicon dioxide, nano cerium oxide and nano barium titanate. According to the invention, a chemical bonding interface is constructed between the inorganic filler and the organic resin, and the synergistic effect of the composite matrix and the multifunctional filler is optimized, so that the coating has excellent adhesive force, flexibility and thermal shock resistance, obtains high volume resistivity and breakdown strength, and meets the insulation protection requirements under harsh working conditions.
Owner:CHINA SOUTHERN POWER GRID GENERAL AVIATION SERVICE CO LTD

Preparation process of environment-friendly film coating

The invention provides a preparation process of an environment-friendly film coating, and belongs to the technical field of coatings, the preparation process comprises the following steps: S1, mixing 3-4 parts of epoxy resin, 25-28 parts of polyurethane emulsion, 35-38 parts of water-based acrylic resin emulsion, 0.5-1 part of a curing agent, 0.5-1 part of an accelerant, 2-2.5 parts of a dispersing agent, 0.3-0.5 part of a wetting agent and 6-8 parts of PVA emulsion to obtain a first mixture; s2, adding 4-5 parts of fluorine-doped hexagonal boron nitride and 10-12 parts of nano aluminum oxide into the first mixture, and stirring to obtain a second mixture; adding 2-3 parts of polyoxyethylene, 0.4-0.5 part of citric acid, 2-4 parts of a coalescing agent and 0.5-1 part of a defoaming agent into the second mixture, and stirring to obtain a coating; s3, performing plasma activation on the PET film to obtain a pretreated PET film; and S4, uniformly coating the pretreated PET film with the coating, and curing to obtain the environment-friendly film coating. The ink-jet adhesive force is improved, and meanwhile, the mechanical property of a PET film coated with a coating is improved.
Owner:NANYANG DAZZLE DIGITAL PRINTING MATERIAL CO LTD

Magnesium alloy high-pressure-resistance surface treatment liquid and preparation method thereof

The invention belongs to the technical field of insulation heat dissipation coatings, and particularly relates to a magnesium alloy high-pressure-resistance surface treatment liquid and a preparation method thereof. The coating comprises the following raw materials in parts by weight: 30-40 parts of organic silicon modified waterborne epoxy resin, 9-12 parts of modified hexagonal boron nitride, 10-15 parts of modified graphene, 2-4 parts of a curing agent, 0.5-2 parts of a flatting agent, 1-2 parts of a defoaming agent and 25-50 parts of acetone. A coating formed on the surface of a magnesium alloy base material through the magnesium alloy high-pressure-resistance surface treatment liquid has high volume resistance, high breakdown voltage resistance, high corrosion resistance and high heat conductivity coefficient, and the magnesium alloy high-pressure-resistance surface treatment liquid can be applied to the field of new energy and can also be applied to the fields of aerospace, 3C electronics and the like. And the market prospect is wide.
Owner:HEFEI HUAQING FANGXING SURFACING TECH CO LTD

Thermally conductive boron nitride films and multilayered composites containing them

Composite multilayered material compositions are provided which contain one or more hexagonal boron nitride (hBN)-containing layers, together with layers comprising optional polymeric binders, glass fibers, magneto-ceramic materials, and a super-hydrophobic outer coating. Methods are provided for making the composite materials and products containing them. The composite materials are useful for making radomes and other coverings for electronic components and equipment.
Owner:NORTHEASTERN UNIV (US)

Flame-retardant waterproof coiled material and preparation method thereof

The invention relates to the technical field of waterproof coiled materials, and discloses a flame-retardant waterproof coiled material and a preparation method thereof.The flame-retardant waterproof coiled material is prepared from, by weight, 100 parts of thermoplastic polyolefin elastomer, 20-40 parts of modified flame retardant, 5-18 parts of fiber filler, 0-3 parts of lubricant, 0-3 parts of antioxidant, 0-3 parts of stabilizer and 0-15 parts of pigment; the modified flame retardant takes MOF, hexagonal boron nitride and phytic acid as an inner core, and polysiloxane is cross-linked and polymerized on the surface of the inner core. According to the flame-retardant waterproof coiled material provided by the invention, if the MOF or the modified MOF material is independently added into the resin material, the problem of poor compatibility of the MOF or the modified MOF material and the resin system cannot be avoided. According to the invention, a microcapsule technology is creatively utilized to polymerize polysiloxane on the surface of the MOF material, so that not only can the problem of dispersion of the MOF material be effectively solved, but also the compatibility of polysiloxane and the flame-retardant characteristic of organic silicon are utilized to promote formation of carbon at high temperature by utilizing phosphorus, and the thermal stability of a carbon layer is improved by utilizing silicon; therefore, the purpose of synergistic flame retardance is achieved.
Owner:CHENGDU SAITE WATERPROOF MATERIAL CO LTD

Purification technology for regenerated DMT in chemical recovery process of waste polyester

The invention provides a purification technology for regenerated DMT in a chemical recovery process of waste polyester, which comprises the following steps: S1) mixing divalent metal salt, trivalent metal salt, an alkaline reagent and water, and carrying out vacuum drying on the reaction product to obtain a layered double-metal hydroxide precursor; s2) mixing the precursor with a solution containing functional anions, and carrying out vacuum drying on a product obtained after intercalation modification to obtain functional anion modified layered double hydroxide; s3) carrying out electrostatic self-assembly on the hydroxylated hexagonal boron nitride and the layered double-metal hydroxide, carrying out suction filtration on the obtained mixed solution on a carrier, and drying to obtain an adsorption film; s4, the waste polyester alcoholysis solution is adsorbed through the adsorption film.According to the pretreatment technology for purification of the waste polyester alcoholysis solution, the purified alcoholysis solution has higher purity, and meanwhile the difficulty of follow-up reduced pressure distillation purification of regenerated DMT is effectively reduced.
Owner:ZHEJIANG SCI-TECH UNIV