The invention relates to a preparation method of nickel-coated alumina oxide powder, in particular to the preparation method of nickel-coated aluminum oxide powder for thermal spraying in aviation, aerospace and military fields. The invention is characterized in that: a suspension is made from a mixing liquid of nano-aluminum oxide and dispersant, stirred and added with nickel salt solution at the same time, and the obtained mixture liquid is dropped with ammonium water after being fully stirred, added with distilled water, when dark blue mixing solution C of nickel ammonia complex ([Ni (NH3)) 2+and alumina oxide is obtained; the mixing solution C is aged by water, filtered, washed and dried, and a green middle coated product is obtained; the green middle coated product is further reduced and roasted, finally, black nickel-coated aluminum oxide powder is prepared. The nickel-coated aluminum oxide powder prepared through the invention has uniform granularity, with average size less than or equal to 1.0Mum, and can enhance the application performance of nano-alumina and expand the application of nano-aluminum oxide; the product is mainly used for aviation, aerospace and military materials and other high-tech fields. The method of the invention is simple, reproducible and easy to be industrialized.