1622 results about "Metal substrate" patented technology

The invention relates to environment-friendly hydrophobic ink and a preparation method thereof, and belongs to the technical field of water-based ink. A copolymerization modifier capable of being combined in a water-based polyacrylate emulsion in an initiation polymerization mode in the stage of preparing the modified water-based polyacrylate emulsion is prepared, and an o-hydroxy aromatic ketone structure in the copolymerization modifier can endow water-based ink with lasting ultraviolet absorption performance; the trifluoromethyl structure can reduce the surface energy of the water-based ink, and the benzimidazole ring structure can form stable coordinate bonds with metal ions, so that the bonding performance of the water-based ink and a metal substrate is enhanced; when the copolymerization modifier is used for modifying the water-based polyacrylate emulsion, the long-term performance, the hydrophobic and oil-resistant performance and the adhesion performance on the surface of a metal base material of the finished water-based ink can be effectively improved.

The invention discloses a silicon carbide power module packaging structure with low thermal resistance and low stress, and belongs to the technical field of semiconductor devices. The packaging structure comprises a metal substrate; the insulating ceramic layer is arranged on the metal substrate; the circuit layer is arranged on the insulating ceramic layer; the lower surface of the silicon carbide chip is connected with the circuit layer through a first interface layer; the composite heat dissipation stress buffer layer is arranged on the upper surface of the silicon carbide chip through a second interface layer; the copper clamp is connected with the upper surface of the composite heat dissipation stress buffer layer through a third interface layer; and the composite heat dissipation stress buffer layer is made of a copper-graphite composite material. According to the invention, the junction temperature of the silicon carbide chip can be greatly reduced, the overall thermal resistance is reduced, the surface stress of the chip is reduced, the warping phenomenon of the chip in the working process is effectively improved, and the long-life reliability of the power module under the long-term thermal cycle working condition is ensured.

The invention discloses a coating, a preparation method and application, and relates to the technical field of anticorrosive coatings. A dry film of the coating comprises 0.1 wt%-6wt% of a lamellar filler; the lamellar filler is prepared by loading magnetic nanoparticles on the surfaces of two-dimensional nanoparticles and coating a layer of high-molecular polymer. After the coating forms a film, a specific magnetic control orientation curing method is matched, so that high dispersion stability and planar orientation arrangement of the two-dimensional nano filler in a resin matrix are realized, and corrosion of water and oxygen to a base material can be effectively blocked. When the thickness of the coating dry film is only 1-2 microns, the coating dry film still has no obvious corrosion phenomenon after being subjected to a neutral salt spray test for 2000 hours. The metal base material with the thin coating thickness has heat conductivity, corrosion resistance and weather resistance, the preparation process is simple, the cost is low, and the metal base material has extremely high market application value.

A transparent wideband microwave absorber unit cell, a transparent wideband microwave absorber and a method of forming a transparent wideband microwave absorber, include a metal substrate, a first layer of glass attached to the metal substrate and having a first pattern of indium tin oxide (ITO) configured as a square loop centered about a central vertical axis and a second pattern of ITO including four equidistant square patches, a second layer of glass attached to the first layer of glass and having a third pattern of ITO configured as a dipole having a cross shape with a center axis coaxial with the central vertical axis, and a third layer of glass attached to the second layer of glass and having a fourth pattern of ITO configured as five circular patches, with a first circular patch located coaxially with the central vertical axis and four equidistant circular patches.

The invention discloses a coating for improving the paint adhesion capability of a metal part of a distribution box, and the coating is prepared by the following steps: depositing a first oxide layer on the metal surface, the first oxide layer comprising Zn element and Ce element; a second oxide layer is deposited on the surface of the first oxide layer, the second oxide layer comprises a Zn element and a Ce element, and the molar ratios of the Zn element and the Ce element of the first oxide layer and the second oxide layer are different; a third oxide layer is deposited on the surface of the second oxide layer, and the third oxide layer comprises a Zn element and a Dy element; and a fourth oxide layer is deposited on the surface of the third oxide layer, the fourth oxide layer comprises a Zn element and a Dy element, and the molar ratios of the Zn element and the Dy element of the third oxide layer and the fourth oxide layer are different. The coating provided by the invention can improve the adhesive ability of the paint to a metal substrate.

The invention discloses a method for preparing a sulfur-doped nickel hydroxide-based self-supporting electrolyzed water anode, and belongs to the technical field of preparation of electrolyzed water catalytic electrodes, and the method comprises the following steps: S1, preparing strong oxidizing salt, thiourea and transition metal salt into an active solution; s2, pretreating the nickel-containing metal substrate to obtain a precursor; and S3, immersing the precursor in an active solution for ultrasonic impregnation, and performing in-situ oxidation to prepare the sulfur-doped nickel hydroxide-based self-supporting electrolytic water anode. According to the method for preparing the sulfur-doped nickel hydroxide-based self-supporting electrolytic water anode, an oxidizing agent-thiourea-transition metal salt synergistic reaction system is adopted, an ultrasonic-assisted technology is combined, and a high-performance catalytic layer is directly grown on the surface of the metal substrate in situ at room temperature; the invention aims to synchronously realize high catalytic activity, excellent stability and macro preparation of the electrode and fundamentally solve the core pain points of long process, high energy consumption, difficulty in amplification and the like in the prior art.

The invention relates to the field of semiconductor lasers, and discloses a vertical cavity surface emitting laser based on a composite metal substrate and photonic crystals, which comprises a CIC composite metal substrate, a GaAs buffer layer, a lower n-type DBR, an n-type contact layer, a multi-junction cascade active region, a p-type contact layer and an upper p-type DBR which are sequentially arranged from bottom to top, a plurality of two-dimensional photonic crystals are etched in the light emitting direction of the upper layer p-type DBR; the thermal stability and reliability of the device under a high-power continuous working condition are effectively improved, stable single-mode output is realized, light field limitation is enhanced, light beam quality is improved, array and on-chip integration are facilitated, the problem of low efficiency of a 650nm red light laser in the aspect of single-mode output of a base VCSEL is effectively solved, and the device has a wide application prospect. The method has a good application prospect and a wide application range.

The invention provides a preparation method of a metal-based ceramic composite membrane with a catalytic ozone function. The preparation method comprises the following steps: preparing functional powder by taking tetrabutyl titanate as a titanium source and silver nitrate or ferric nitrate as a catalytic active metal source and adopting a sol-gel method; a porous metal pipe is used as a supporting body, metal powder and functional powder which are made of the same material as the supporting body are mixed to prepare functional slurry, the functional slurry is evenly deposited on the inner wall of the supporting body through vacuum filtration, and powder particles which are not firmly combined are removed through back flushing; and finally, the binding force between the functional film layer and the metal matrix is improved through high-temperature heat treatment. Wherein the thermal expansion coefficient difference between the metal supporting body and the functional film layer can be reduced by adding the metal powder, the metal powder is melted and diffused in the high-temperature heat treatment stage, and metallurgical bonding is formed between the functional powder and the metal substrate. The method is simple in process, and the prepared metal-based ceramic composite membrane has the advantages of being high in membrane layer binding force, not prone to falling off, high in catalytic activity, high in anti-pollution capacity, stable in operation and the like.

The invention relates to the technical field of OLED (Organic Light Emitting Diode) manufacturing process etching processes, in particular to a silver etching solution for an OLED manufacturing process as well as a preparation method and application of the silver etching solution. The silver etching liquid comprises nitric acid, phosphoric acid, a buffer agent, a metal ion chelating agent and an ionic liquid inhibitor, the ionic liquid inhibitor comprises 1-butyl-3-methylimidazole phosphate, the metal ion chelating agent is selected from at least one of pyromellitic acid, diethylenetriamine pentaacetic acid and ethylenediamine tetramethylene phosphoric acid, and the buffer agent is selected from at least one of sodium chloride, sodium chloride and sodium chloride. The buffering agent comprises acetic acid, and all the components are prepared according to a specific mass ratio. The etching solution can balance the etching rate of silver and indium tin oxide, avoid silver residues and black spot defects, prolong the service life of the solution, reduce the use of a volatile buffer agent, adapt to the OLED fine manufacturing process, improve the product yield and reduce the production cost, and is suitable for etching of a metal substrate in the OLED manufacturing process.

The invention relates to the field of preparation of lubricating materials, in particular to a preparation method of composite phase change lubricating gel based on temperature-friction force synergistic response. The lubricating gel adopts a sandwich layered structure; the bottom layer is a porous ceramic layer formed by micro-arc oxidation, is filled with a disulfide bond dynamic network polymer and is anchored on a metal substrate; the middle layer comprises a microencapsulated phase change material which is dispersed in a polyurethane network containing dynamic disulfide bonds and is wetted with ionic liquid; the surface layer is an epoxy resin coating rich in boron nitride nanosheets, and a rapid heat conduction channel is constructed. Compared with the prior art, the lubricating state can be automatically adjusted in the friction process without external energy input, and the method has the advantages of being sensitive in multi-field coupling response, capable of achieving automatic antifriction protection, high in extreme working condition adaptability and the like.

The invention discloses a nickel-cobalt metal-based wear-resistant and corrosion-resistant coating and a preparation method thereof, and relates to the technical field of surface coatings, and the technical key points of the nickel-cobalt metal-based wear-resistant and corrosion-resistant coating comprise the following steps: S1, carrying out oil removal and sand blasting roughening treatment on the surface of a metal substrate, then cleaning with absolute ethyl alcohol, and drying; s2, nickel-cobalt metal-based alloy powder is prepared, wherein the nickel-cobalt metal-based alloy powder is prepared from, by weight, 55-65 parts of nickel, 20-30 parts of cobalt, 15-18 parts of chromium, 4-6 parts of molybdenum, 3-5 parts of tungsten, 1-3 parts of iron, 0.8-1.5 parts of silicon, 0.5-1.2 parts of carbon and 0.5-1.0 part of boron; the technical effect is that a regular non-smooth micro-pit array is manufactured on the surface of a sprayed layer through interlayer laser micro-texturing treatment. And the molten particles of the next layer of spraying material are embedded into the micro pits to form a strong mechanical interlocking effect, so that the interlayer bonding strength and the anti-shearing capability are greatly improved, and interlayer dislocation and stripping are effectively prevented.

The present application provides a heat exchanger and a manufacturing method of a heat exchanger. The heat exchanger includes a metal substrate, the metal substrate has a fluid channel for circulating a heat exchange medium; and the heat exchanger further includes a coating, the coating includes resin, silica and titanium dioxide, and the coating is arranged to cover at least part of a surface of the metal substrate. Silica particles and titanium dioxide particles are conducive to the formation of a complex micro-nano structure, and leveling and stability of hydrophilic resin contribute to long-term maintenance of the micro-nano structure. The coating of the heat exchanger according to the present application has excellent hydrophilic durability.

The invention relates to the technical field of photoresists, in particular to a positive chemical amplification type photoresist as well as a preparation method, a use method and application thereof, and aims to solve the problems that the photoresist is easily subjected to bottom residue on a metal substrate after development, and the etching yield is poor after metal electroplating in a subsequent process. The key points of the technical scheme are as follows: the mixed resin comprises first resin and second resin; an initiator, wherein the initiator comprises a photoacid production compound; the quenching agent is an alkaline agent or an acid-induced alkali production agent; the auxiliary agent comprises a protective agent, and the protective agent is a group modified azole compound; the solvent is used for dissolving the substances to prepare the positive chemical amplification type photoresist, and by optimizing the composition and the process of the positive chemical amplification type photoresist, on the premise of ensuring the adaptability and the stability of the process, the problems of the side wall angle of a product after exposure and development and the residual of the photoresist on the bottom of a metal substrate after development are effectively improved.

The invention relates to the technical field of anti-corrosion treatment, and provides anti-corrosion molding powder and a radiator anti-corrosion treatment technology.The anti-corrosion molding powder is prepared by taking polyethylene glycol terephthalate as a matrix and cooperating with a TGIC curing agent, phosphoric acid activated bamboo charcoal nanofibers, graphene modified zinc oxide, a lanthanum nitrate and cerous nitrate compound, a silane coupling agent and a functional additive; a composite resin system with a compact nano-structure is prepared through high-speed ball milling pre-activation and a twin-screw gradient extrusion process. The treatment process of the radiator comprises the steps of forming the ceramic substrate layer through micro-arc oxidation, performing dynamic temperature control impregnation with acrylic acid water-based paint, spraying anti-corrosion molding powder, performing microwave infrared gradient curing, and constructing a metal substrate-ceramic layer-organic coating multi-stage protection system. The permeability resistance of the coating is remarkably improved, a continuous and compact composite protection structure is formed, the problems of interface stripping, medium permeation and poor environmental adaptability of a traditional coating are solved, and the coating is suitable for the long-acting anti-corrosion requirement of the radiator under the high-corrosion working condition.

The invention relates to the technical field of adhesives, and discloses an imidazolium ionic liquid and a preparation method and application thereof, the preparation method comprises the following steps: reacting omega-bromoalcohol with 1-(methoxymethyl) imidazole in acetonitrile, and washing with methyl tert-butyl ether to obtain a target ionic liquid precursor; and dissolving the product in acetonitrile, adding 4-trifluoromethyl phenyl isocyanate, and washing with methyl tert-butyl ether after the reaction is finished, thereby obtaining the target imidazolium ionic liquid. The imidazolium ionic liquid disclosed by the invention is applied to a PVB (Polyvinyl Butyral) adhesive, and the PVB adhesive shows excellent adhesion strength in a macroscopic adhesion performance test on the basis of multiple interactions, and particularly has excellent adhesion strength on aluminum. The obtained adhesive can be universally adapted to various substrates such as metal substrates and macromolecule substrates, and finally high-strength and high-durability intelligent adhesion performance is achieved.

The invention provides a modified negative electrode current collector for a sodium metal battery and a preparation method of the modified negative electrode current collector, and belongs to the technical field of secondary batteries. The modified negative electrode current collector comprises a metal substrate and an electron-ion composite conductor coating, the electron-ion composite conductor coating is located on the surface of the metal substrate, and the electron-ion composite conductor coating is obtained by compounding any one of a zeolite molecular sieve and an expansive soil material with a graphitized carbon material. The method disclosed by the invention is simple and feasible, the obtained modified negative electrode current collector can be widely applied to a high-energy-density negative-electrode-free sodium metal battery system, and due to the fact that sodium metal deposition is more uniform and stable, compared with a negative electrode current collector modified only by a graphitized carbon material, the modified negative electrode current collector has better cycling stability.

The invention discloses a packaging structure with a heat dissipation structure and a packaging method, through the connection cooperation of a first metal carrier plate, a second metal carrier plate, a first heat conduction insulating film, a second heat conduction insulating film, a first rewiring layer and a second rewiring layer, and the subsequent circulation of a cooling liquid in a cooling pipeline, the heat resistance is greatly reduced, the heat dissipation is enhanced, and the heat dissipation efficiency is improved. Power consumption is reduced; according to the invention, the first metal carrier plate and the second metal carrier plate are directly bonded, the first metal carrier plate and the second metal carrier plate are provided with grooves and holes, and finally, the first metal carrier plate and the second metal carrier plate are matched with the first heat-conducting insulating film and the second heat-conducting insulating film to form the cooling pipeline, so that the stress problem caused by the welding process of a water-cooling plate in the traditional technology is improved, and a packaging body is prevented from being damaged; wiring can be conducted on the two faces of the base material, and multi-dimensional packaging is achieved; according to the invention, the metal substrate is used as the substrate, panel warping is reduced, and the stress problem caused by multi-dimensional packaging is solved.

The invention discloses a discrete device packaging structure based on direct lead bonding, which belongs to the technical field of semiconductor device packaging and comprises a power semiconductor chip, a drain metal substrate, a grid lead terminal, a drain lead terminal, a bonding wire and a supporting shell. The drain electrode metal substrate is connected with the lower surface of the power semiconductor chip through solder. The gate metal electrode on the upper surface of the power semiconductor chip is connected with the gate lead terminal through a bonding wire, and the source metal electrode on the upper surface of the power semiconductor chip is connected with the source lead terminal through solder. The interior of the supporting shell is filled with silica gel or an injection molding process, and the supporting shell covers the power semiconductor chip to serve as an insulating medium. The power density of the device is improved, the parasitic parameter of the whole device is reduced, and the reliability of the interconnection structure is improved.

The invention discloses a preparation method of a high-quality self-supporting polycrystalline diamond substrate. The preparation method comprises the following steps: obtaining a larger first substrate and a smaller second substrate; the molybdenum substrate is a polished molybdenum metal substrate; sowing diamond seed crystals on the first substrate by using an ultrasonic sowing method, and growing a nanocrystalline diamond epitaxial layer by using a CVD (Chemical Vapor Deposition) process; cutting the first substrate by using precise laser to obtain an annular polycrystalline diamond solid seed crystal of which the inner diameter is greater than that of the second substrate; placing a second substrate in the inner diameter of the second substrate, guiding generated tiny diamond grains to the second substrate through a boundary induction mechanism and applying direct current bias voltage, and uniformly wrapping the tiny diamond grains to form a self-supporting polycrystalline diamond substrate; according to the preparation method of the self-supporting polycrystalline diamond substrate, the orientation consistency and the crystallization quality of a diamond film are remarkably improved, and the prepared self-supporting polycrystalline diamond substrate has the advantages of being low in surface roughness, compact in structure, simplified in follow-up process and the like.

The utility model discloses heat insulation type laminated iron, which comprises a metal substrate and a PET (polyethylene terephthalate) layer adhered on the surface of the metal substrate, the PET layer comprises a base layer and a conical array structure formed on the surface of the base layer, the conical array structure comprises a plurality of conical convex structures, and an Ag layer and an oxide protection layer are sequentially arranged on the side surface of each conical convex structure. According to the laminated iron, the reflectivity of the laminated iron in an infrared band can be improved, the heat insulation performance of a material is enhanced, meanwhile, the risk of migration of harmful substances is avoided, and the laminated iron has good safety.

The invention discloses a water-based paint composition of a fingerprint-resistant color coated steel plate and a preparation method of the water-based paint composition, and relates to the technical field of fingerprint-resistant coating materials and functional water-based paint compositions.The water-based paint composition comprises a functional paint composition system composed of water-based film-forming resin and a poor-polarity block type surface conditioning agent; the water-based coating composition is applied to the surface of a metal base material in a roller coating, spraying or blade coating mode, and the oriented migration behavior of an oleophobic chain segment is excited through heat treatment; and the coated steel plate is dried and cured, preferably, a hot air drying or hot-pressing crosslinking mode is adopted, and an oleophobic film layer is prepared on the surface. The method provided by the invention ensures that the system has stable dispersibility and migration responsiveness, realizes spontaneous construction of an oleophobic structure, improves the interface specificity of a film layer, and improves the hydrophobicity and fingerprint pollution resistance of the surface of the steel plate, so that the colored coating has both decoration and functionality, and is suitable for being used in the field of steel plates. The double requirements on appearance stability and anti-pollution performance in practical application are met.

The invention provides a color-coated steel plate with heat-insulating, antibacterial and super-hydrophobic functions, which comprises a metal substrate, and a chemical conversion layer and a primer layer which are sequentially arranged on at least one surface of the metal substrate, and a composite functional finish paint layer is arranged on the primer layer; the composite functional finish paint layer comprises film-forming resin, a near-infrared reflection composite pigment, a dual-mode antibacterial agent and fluorinated nano silicon dioxide; the finishing coat layer in the color-coated steel plate has heat-insulating and antibacterial capabilities and a super-hydrophobic self-cleaning function at the same time; the invention also provides a preparation method of the color-coated steel plate, which comprises the following steps: carrying out surface pretreatment on the metal substrate to form the chemical conversion layer; coating the chemical conversion layer with a primer and carrying out first curing to form a primer layer; the primer layer is coated with finish paint coating, then multi-temperature-zone gradient curing is conducted, and a composite functional finish paint layer is formed; according to the preparation method, a multi-temperature-zone gradient curing process is adopted, the temperature of different curing stages is controlled, and a stable functional structure is constructed.

The invention provides a construction method and system of a non-reciprocal emission / absorption device with a Fizeau dragging effect. The construction method comprises the following steps: selecting a metal substrate, a dielectric grating and a two-dimensional material; applying a bias voltage in the x-axis direction to the two-dimensional material layer to generate a Fizeau dragging effect; the bias voltage is adjusted under TM polarization, so that the electron drift speed is close to the Fermi speed, asymmetric surface plasmon resonance is excited, and unequal emissivity and absorptivity are achieved; an adjustable singular point is generated in an angle-frequency space by adjusting the filling ratio of the grating, so that the numbers of spectral formants of emissivity and absorptivity near the singular point are different, and the wavelength integral nonreciprocity intensity is improved. The non-reciprocal heat radiation characteristic can be realized through voltage regulation and control without an external magnetic field.

The present invention relates to a precursor for the production of an alloy used as a catalyst. The precursor comprises a metallic substrate, a layered structure comprising binders, metallic particles, and at least one metal oxide, metal phosphide, and / or metal sulfide, wherein the layered structure is arranged on the metallic substrate.

The application provides a micron-thick graphite film and a growth method thereof. A substance with high carbon content is dispersed in an organic solvent and coated on a metal foil, and after drying, a carbon film / metal foil is obtained; or the substance with high carbon content is made into a sheet and placed on a metal foil, and a carbon film / metal foil is obtained; in a protective atmosphere, a current is applied to the sample, the carbon film / metal foil is heated by using the Joule effect of the current, and the power supply is stopped, so that a micron-thick graphite film is obtained on the surface of the metal foil. The graphite film is prepared by using the dissolution-precipitation of carbon in the metal substrate in the process of high-temperature-low-temperature temperature change. Since the metal substrate has an epitaxial relationship with the graphite lattice, the graphite film with AB stacking can be directly precipitated, so that the graphitization of carbon can be realized at a lower temperature. The reaction system is radiated and heated by using the Joule heating characteristic of the current, the heating efficiency is effectively improved, the temperature is raised from room temperature to the growth temperature in a few seconds, the influence of the side reaction is reduced, and the raw material utilization rate is improved.

The invention discloses metal material surface treatment equipment and a surface treatment method. The surface treatment method comprises the following steps: performing surface pretreatment on a metal matrix to form an activated matrix with target surface roughness; metal ceramic powder is directionally deposited on the surface of the activated substrate through a spraying system, and a porous substrate layer with uniform micropore channels is generated; depositing a gradient functional coating on the porous substrate layer, and dynamically adjusting the mixing proportion and the spraying angle of spraying powder to sequentially form a bottom layer bonding interface, a transition strengthening layer and a surface layer protection layer; the gradient functional coating is subjected to laser remelting treatment, and a coating interface is scanned through a multi-beam laser array, so that metallurgical bonding is achieved between the surface protection layer and the transition strengthening layer, and between the transition strengthening layer and the bottom bonding interface; in a single treatment process, multiple protection performances of high temperature resistance, corrosion resistance and fatigue resistance are synergistically improved, so that the problem of interface stripping caused by thermal expansion mismatch of a protective coating and a matrix is solved.

The invention discloses a water-based metal anticorrosive paint and a preparation method thereof, and belongs to the technical field of water-based paints. The hyperbranched polyphosphate and the water-based alkyd resin can be subjected to a cross-linking reaction to form a compact network structure, the hyperbranched polyphosphate and a metal interface also have good bonding performance, the adhesiveness of a coating is improved, the water-based alkyd resin has good flexibility, the integrity of the coating is kept, and the water-based alkyd resin has good adhesion to the metal interface. Corrosion media are prevented from permeating, and the purpose of protecting metal for a long time is achieved; by adding the glass flakes, a complex and zigzag path can be formed in the coating, corrosion media are further prevented from permeating into metal, and therefore the corrosion resistance of the coating is improved; the organosilane-modified nano cerium oxide particles can be directionally distributed in the coating, oxygen diffusion is blocked, a rare earth conversion film can be formed on the surface of a metal base material, and a stable passivation layer is generated through hydrolysis, so that electrochemical corrosion is inhibited.

The invention discloses a corrosion-resistant high-entropy alloy surfacing layer for the surface of marine structural steel and a preparation method of the corrosion-resistant high-entropy alloy surfacing layer, and belongs to the technical field of structural steel. The preparation method comprises the following steps: (1) Co powder, Cr powder, Fe powder, Ni powder and Mo powder are mixed and then subjected to ball milling, and CoCrFeNiMo powder is obtained; (2) the metal matrix plate to be treated is subjected to alkali washing and then subjected to surface sand blasting roughening treatment till rough silver gray metal luster appears on the surface; and (3) a CoCrFeNiMo powder material serves as a raw material, plasma arc powder surfacing is conducted on the surface of the metal matrix plate subjected to sand blasting roughening, and the corrosion-resistant high-entropy alloy surfacing layer is obtained. The high-entropy alloy surfacing layer is high in bonding strength with a matrix, high in density, extremely low in porosity, excellent in corrosion resistance and capable of spontaneously resisting seawater corrosion, a passive film has high stability and pitting corrosion resistance, and the whole surfacing layer has good comprehensive corrosion resistance.

The invention relates to the technical field of tool surface functional coatings, in particular to a wear self-monitoring superhard wear-resistant gradient reinforced coating and a preparation method thereof.The coating comprises a metal substrate, a high-entropy wear-resistant layer, a color layer and a transition layer, and the outer layer is a top high-entropy wear-resistant layer; the high-entropy wear-resistant layer is composed of Ti / Al / Zr / Si / Mo-N, and the hardness gradient of the high-entropy wear-resistant layer is 35-55 GPa; the color layer is of an AlTiN / Si (Ti) double-layer structure and has a multicolor structural color, and the hardness of the color layer is 20-35 GPa; the transition layer is a component gradient system. The preparation method adopts multi-target magnetron sputtering, and comprises the steps of substrate pretreatment, layered deposition (wear-resistant layer / color layer / transition layer), top layer deposition and vacuum cooling. By means of the design, the problems that an existing coating lacks self-monitoring, the hardness gradient is narrow, and interlayer stripping is prone to occurring are solved, abrasion visual monitoring is achieved, super-hard abrasion resistance and high binding force (larger than or equal to 85 N) are achieved, different cutting working conditions are adapted, and the service life of a cutter is greatly prolonged.

The invention discloses a special-shaped surface processing method for a GPU main body structural member. The method comprises the steps of generating a three-dimensional special-shaped surface model with an electromagnetic shielding function and a thermal radiation enhancement characteristic based on environment simulation data of a target application scene; a metal additive manufacturing process is adopted, a metal matrix is formed layer by layer according to a three-dimensional special-shaped surface model, a multi-stage fractal microstructure is formed on the surface of the metal matrix through an electrochemical micromachining process, and a gradient refractive index photonic crystal layer and a periodic nano-particle layer are sequentially deposited on the surface of the multi-stage fractal microstructure. Forming a composite functional layer with a super-hydrophobic surface and high infrared emissivity; and based on the hydrophobic angle and thermal radiation performance data detected in real time, processing parameters are adjusted through a feedback control system, iterative optimization is performed on the morphology of the composite functional layer, a high-performance surface with electromagnetic shielding, efficient heat dissipation and super-hydrophobic characteristics is formed, the reliability of the GPU structural part is integrally improved, and the service life of the GPU structural part is integrally prolonged.