The invention discloses a preparation method of a self-assembled
cellulose diaphragm, a membrane prepared by the self-assembled
cellulose diaphragm and application of the self-assembled
cellulose diaphragm. The preparation method comprises the following steps: mixing a
solvent solution containing cellulose and
zinc salt with a
solvent solution containing a
microporous material, ultrasonically crushing, and forming a membrane to obtain the self-assembled cellulose diaphragm, the cellulose is selected from cellulose nanofibers and / or cellulose nanowires; after the cellulose and the
microporous material are uniformly dispersed in the solution, a film-forming base solution of the self-assembled diaphragm can be formed without adding any binder in the film-forming process, and the self-assembled diaphragm has a good film-forming effect. The composite diaphragm provides an effective channel, promotes the transmission of
zinc ions in the battery, has smaller
internal resistance than a traditional diaphragm, has high
electrolyte preservation rate, is smaller than the traditional diaphragm in thickness, and can improve the
energy density and cycle performance of the battery. The preparation process of the diaphragm is simple, the reaction condition is mild, the preparation period is short, and the diaphragm is suitable for large-scale industrial production and commercial application.