2252 results about "Heteroatom" patented technology

A hard carbon negative electrode material as well as a preparation method therefor and a use thereof. The hard carbon negative electrode material comprises a hard carbon base material, heteroatoms and metal monoatoms, wherein the metal monoatoms are doped into the hard carbon base material by means of the heteroatoms, the heteroatoms comprise at least one of N, P or S, and the metal monoatoms are metal monoatoms that can undergo an alloying reaction with sodium. The metal monoatoms are doped into the hard carbon base material by means of covalent (chemical bond) interactions with other heteroatoms, so that the doping of single atoms is achieved, thereby improving the overall capacity and rate capability of a sodium ion battery at normal temperature, and ensuring the capacity retention rate of the sodium ion battery under a low temperature condition.

To provide an onium salt which is used for a chemically amplified resist composition having excellent solvent solubility, high sensitivity, high contrast, and excellent lithographic performances such as exposure latitude and linewidth roughness, in photolithography using high-energy radiation, a chemically amplified resist composition comprising the onium salt as a photoacid generator, and a pattern forming process using the chemically amplified resist composition.SOLUTION: An onium salt having the following formula (1) is provided. [R1-R12 independently represent H, halogen, or a C1-C20 hydrocarbyl group optionally including a heteroatom; one of R13 and R14 represents a substituent having a terminal sulfonic acid anion; the other represents H, halogen, or a C1-C20 hydrocarbyl group optionally including a heteroatom; and Z+ represents an onium cation.]SELECTED DRAWING: None

The invention belongs to the technical field of aqueous zinc ion batteries, and discloses an aqueous zinc ion battery negative electrode coating material and a preparation method and application thereof. Coumarin hydrazide reacts with benzyl isothiocyanate to generate a multi-nitrogen-oxygen-sulfur heteroatom ligand capable of coordinating with zinc ions, and the required aqueous zinc ion battery negative electrode coating material LXB-Zn is further prepared by doping with polyvinylidene fluoride. The synthesized aqueous zinc ion battery negative electrode coating material contains imino groups and heteroatoms S, O and N, can inhibit a hydrogen evolution reaction and provides more active sites, so that dendrites and side reactions are inhibited, and the cycling stability of an aqueous zinc ion battery is effectively improved. In order to solve the problem that an organic coating of a water-based zinc ion battery negative electrode is difficult to prepare, the organic coating of the water-based zinc ion battery negative electrode is prepared by adopting a simple method of adding an adhesive.

The invention discloses a cobalt-loaded covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. The cobalt-loaded covalent organic framework material is prepared by taking a carbonized covalent organic framework as a matrix and cobalt nitrate hexahydrate as a cobalt source, reducing by using a sodium borohydride methanol solution, and introducing transition metal cobalt into the framework through room-temperature impregnation and thermal reduction processes. In the material, active components comprise Co0 and Co < 2 + > which are uniformly distributed on a carrier. Moreover, the metal cobalt is stably loaded in a carbon skeleton through the bonding effect of heteroatoms such as nitrogen and carbon, so that the stability, the catalytic activity and the durability of the metal cobalt are effectively improved, the dissolution risk of the metal cobalt is reduced, the hidden danger of environmental pollution is reduced, and efficient catalytic activity is shown in the aspect of catalyzing and activating peroxymonosulfate to degrade organic pollutants; and good recycling stability is achieved.

The invention provides a heteroatom-doped porous carbon material for carbon dioxide adsorption as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, drying and crushing waste biomass to obtain raw material powder; s2, mixing the raw material powder with an activating agent, and fully grinding to obtain a mixture of the raw material powder and the activating agent powder; s3, dissolving one or more heteroatom sources in hot deionized water to obtain a hot solution, pouring the mixture of the raw materials and the activator powder in the step S2 into the hot solution, and heating and stirring until water is evaporated; s4, performing high-temperature carbonization on the mixture finally obtained in the step S3 in an anoxic environment; and S5, cleaning and drying the product in the step S4 to obtain the heteroatom-doped porous carbon material. The heteroatom-doped porous carbon material disclosed by the invention has a highly developed pore structure, and the porous carbon prepared by taking the waste biomass as a precursor is used as a carbon dioxide adsorbent, so that high-value utilization of waste biomass resources is realized.

The preparation method of the silicon-carbon composite material comprises the following steps: uniformly mixing a carbon source, a pore forming agent and a cross-linking agent, and introducing peroxide gas into a tubular furnace for sintering to obtain porous carbon; uniformly mixing the porous carbon with liquid silane and a surfactant, and transferring the mixture into a high-pressure reaction kettle for reaction to obtain a silicon-carbon precursor; and introducing the obtained material into a carbon source gas containing a heteroatom gas for deposition to obtain the silicon-carbon composite material. The obtained material generates porous carbon with high strength and high pore volume by utilizing the cross-linking agent and the pore-forming agent thereof, so that the expansion is reduced; and the liquid silane has the characteristics of low decomposition temperature, low cost and high safety performance, so that the specific capacity is improved, and the cost is reduced.

The invention provides starch-based hard carbon and a preparation method thereof, a negative electrode plate, a sodium ion battery and electric equipment, and relates to the technical field of new energy. According to the preparation method disclosed by the invention, hydroxyl and hydrogen atoms in the starch are consumed through organic acid esterification, so that a molten state is not formed in the subsequent oxidation crosslinking and carbonization processes, the structure and strength of a carbon skeleton are improved, and functional groups and doped atoms are more easily introduced; in the oxidation cross-linking process, oxygen-containing functional groups mainly containing carbonyl are mainly introduced, and the cross-linking degree is enhanced, so that phosphorus and nitrogen atoms are better doped in subsequent carbonization, a better spherical structure is formed, and the subsequent carbonization yield is further improved. The starch-based hard carbon material prepared by the method has the advantages that the starch-based hard carbon material is mixed with the phosphorus source and the nitrogen source for carbonization, the pore-forming process and the phosphorus-nitrogen atom doping process can be directly completed in the heating process, and open pores are changed into closed pores in the high-temperature and constant-temperature process, so that the prepared starch-based hard carbon material has excellent structure and surface groups and heteroatoms, and the dynamic performance of the starch-based hard carbon material is further optimized.

The invention provides a metal matrix composite microstructure strengthening simulation method and system, and relates to the technical field of composite mechanical property simulation, and the method comprises the following steps: establishing a polycrystalline aluminum matrix atomic model and a spherical silicon nitride particle strengthening phase atomic model unit; embedding the spherical silicon nitride particles into the polycrystalline aluminum matrix according to the target embedding position coordinates, and integrating to generate an atomic scale structure model; according to the method, an embedded atom potential function is adopted to describe interaction among atoms in a polycrystalline aluminum matrix, a Tersoft potential function is adopted to describe covalent bond interaction among atoms in spherical silicon nitride particles, and a Lennard-Jones potential function is adopted to describe interaction among heteroatoms at a Si3N4 / Al interface; based on the interaction potential between atoms, molecular dynamics simulation is adopted for conducting uniaxial stretching simulation on the atomic scale structure model, mechanical property parameters of the particle reinforced metal matrix composite are obtained through calculation, and a visualization method is combined for analyzing the microcosmic strengthening mechanism of the particle reinforced metal matrix composite.

The invention discloses a pyridyl anti-aging agent as well as a synthesis method and application thereof, the anti-aging agent is obtained by taking 5-nitro-N-phenylpyridine-2-amine synthesized by 2-chloro-5-nitropyridine and aniline and iodide synthesized by alcohol and iodine as raw materials, and reacting in the presence of a hydrogen source and a catalyst. The anti-aging agent provided by the invention can effectively slow down the emigration speed of the anti-aging agent in rubber and greatly improve the phenomenon that the appearance of a tire becomes red, has one more N heteroatom than other anti-aging agents in the structure, has good oxidation resistance and flex cracking resistance, and is high in anti-ozone activity, environment-friendly and small in pollution.

The invention discloses a lithium salt doped porous carbon coated graphite composite material for an energy storage battery and a preparation method thereof, the composite material has a core-shell structure, the core is graphite, and the shell is a lithium salt doped porous carbon complex. The preparation method comprises the following steps: uniformly mixing amino resin, a pore-forming agent and a heteroatom compound of the pore-forming agent, curing, activating to obtain porous carbon, adding the porous carbon into an inorganic lithium salt, uniformly mixing, and carrying out spray drying to obtain lithium salt doped porous carbon; the preparation method comprises the following steps: adding lithium salt doped porous carbon into a carboxymethyl cellulose lithium solution, uniformly dispersing, then adding into a graphite material, uniformly dispersing, spray-drying, and carbonizing to obtain the lithium salt doped porous carbon coated graphite composite material. According to the obtained material, the coating layer lithium salt is doped with porous carbon, so that the liquid absorption and retention capacity of the material is improved, the diffusion rate of lithium ions is increased, and the rate capability is improved; meanwhile, the expansion of the composite material in the charging and discharging process is reduced by utilizing the low expansion of the porous carbon, and the cycle performance is improved.

The invention discloses a modified organic silicon resin, a high-temperature-resistant coating and a preparation method thereof, the modified organic silicon resin is prepared by hydrolyzing at least two different siloxane monomers and then carrying out condensation reaction on the hydrolyzed siloxane monomers and at least one boric acid monomer, and the main chain of the organic silicon resin is of a heteroatom doped structure formed by a Si-O bond, a B-O bond and a B-O-Si bond; at 200-250 DEG C, the modified organic-inorganic high-temperature-resistant composite material is subjected to a self-crosslinking reaction. The high-temperature-resistant coating overcomes the defect that the high-temperature-resistant coating in the prior art cannot meet the high-temperature test, and avoids the defects that organic and inorganic high-temperature-resistant coatings crack, the impact resistance and hardness are not matched, the water resistance is poor, and the wear resistance is poor.

The invention discloses a preparation method of metal ion liquid modified co-doped biochar and application of the metal ion liquid modified co-doped biochar in tetracycline removal, and belongs to the technical field of water pollution treatment and adsorption material preparation. The preparation method comprises the following steps: mixing a biochar precursor with a metal ion liquid containing transition metal and a heteroatom source, and carrying out high-temperature carbonization to obtain the metal ion liquid modified co-doped biochar. Multiple modification of the biochar is realized through one-time high-temperature carbonization (transition metal elements and heteroatoms are introduced into a biochar skeleton, abundant surface active sites are provided, and the specific surface area and pore volume of the biochar are improved), so that the adsorption performance of the biochar on tetracycline antibiotics is remarkably improved. The preparation method is simple in process, raw materials are easy to obtain, and the obtained metal ion liquid modified co-doped biochar has excellent adsorption performance on antibiotic pollutants such as tetracycline and is suitable for purification treatment of water polluted by antibiotics.

The invention discloses an antioxidant carbon aerogel composite material and a preparation method thereof. The method comprises the following steps: synthesizing borosilicate modified phenolic resin; preparing boron-silicon modified phenolic fibers by using the boron-silicon modified phenolic resin; preparing a boron-silicon modified phenolic fiber felt by using the boron-silicon modified phenolic fiber; preparing a boron-silicon modified phenolic aerogel composite material by using the boron-silicon modified phenolic resin and the boron-silicon modified phenolic fiber felt; and carbonizing the boron-silicon modified phenolic aerogel composite material to prepare the boron-silicon modified carbon aerogel composite material. The invention also provides the borosilicate modified phenolic aerogel composite material prepared by the method. According to the invention, heteroatom doping modification is carried out on the reinforcement body and the aerogel matrix through a chemical means, so that the purpose of oxidation resistance of the carbon aerogel body is achieved, and a new way is provided for preparation of the high-temperature-resistant carbon-based thermal insulation material.

The invention provides a silicon-based composite material, a preparation method thereof and a negative electrode. The silicon composite material comprises a porous matrix, silicon nanoparticles and heteroatoms, the porous matrix is provided with a three-dimensional cross pore channel with multistage pore diameters, the pore channel contains at least one silicon nanoparticle, the heteroatoms at least partially coat the surfaces of the silicon nanoparticles, and / or the heteroatoms are spaced among the silicon nanoparticles. According to the silicon-based composite material provided by the invention, the porous matrix is adopted as a substrate material to load the silicon nanoparticles and the heteroatoms doped in the silicon nanoparticles, and the silicon nanoparticles are separated and bound by doping the heteroatoms in the silicon nanoparticles, so that the size and distribution of the silicon material in pore channels are controlled; the silicon material is uniformly dispersed in the three-dimensional crossed pore channels of the porous matrix, so that the volume effect of silicon in the charging and discharging process is effectively relieved, the collapse of the composite material structure caused by the expansion of lithium-intercalated silicon is prevented, and the cycling stability of the electrode is improved.

The invention discloses a method for improving the fast charging performance of a silicon-carbon composite material, and the method comprises the following steps: firstly preparing a heteroatom-doped MOF material, then precipitating by a silane cracking method, introducing silane gas and heteroatom gas, and carrying out low-temperature passivation to obtain a silicon-carbon precursor material; the preparation method comprises the following steps: preparing an organic solvent of resin, adding a graphene oxide solution, uniformly dispersing, adding a silicon-carbon precursor, performing spray drying, and introducing hydrogen at 700-1000 DEG C to reduce the obtained material. The obtained material can improve the rate capability and the cycle performance.

The invention provides a hole transport material, a preparation method thereof and a perovskite solar cell. The chemical structural formula of the hole transport material is # imgabs0 #, wherein each A is independently a heteroatom. A thiophene-methoxy triphenylamine group and a thiophene-methylthio triphenylamine group are introduced into an acridine phosphate side chain, and a series of novel hole transport materials are provided. The hole transport material has higher decomposition temperature, better thermal stability and higher hole mobility, thereby being beneficial to hole extraction and transport. The hole transport material has a deep HOMO energy level matched with perovskite, and can be used in a perovskite solar cell without doping any additive, so that the perovskite solar cell has higher photoelectric conversion efficiency, photovoltaic performance and stability, and the material has repeatability.

The invention provides a composite pollution repairing agent as well as a preparation method and application thereof, and belongs to the technical field of environmental functional materials. The composite pollution repairing agent comprises biochar, nano zero-valent iron (nZVI) loaded on the biochar, cyclodextrin and heteroatoms, and at least part of the nZVI is wrapped in the cyclodextrin. According to the prepared composite pollution repairing agent, solid waste resource utilization can be effectively achieved, the removal rate of micro-plastics reaches 90% or above, and the removal rate of heavy metal is 100%. The composite pollution repairing agent has excellent performance and good application prospect, provides a feasible solution for micro-plastic and heavy metal composite pollution treatment, and shows remarkable practical application value.

The present invention relates to a method for the synthesis of a carboxylic diacid, having a 5- or 6-membered heteroaromatic compound optionally comprising an allyl or methylstyrene function, preferably selected from 5- or 6-membered heteroaromatic compounds and comprising at least one heteroatom selected from nitrogen, sulphur and oxygen.

The invention relates to the technical field of batteries, in particular to a negative electrode material, a preparation method thereof and a battery. The negative electrode material comprises a silicon nano material; the metal silicide layer at least partially coats the surface of the silicon nano material; the nitrogen and sulfur doped carbon layer at least partially coats the surface of the metal silicide; and the thickness of the metal silicide layer is greater than that of the nitrogen and sulfur doped carbon layer. According to the negative electrode material, the preparation method thereof and the battery provided by the invention, the coating structure of the negative electrode material is optimized, and the metal silicide / heteroatom doped carbon double-layer coated silicon nano material can be prepared by adopting a synthesis method which is low in energy consumption and capable of constructing a functional multi-layer coating structure, so that the long cycle life and the high-rate fast charging performance can be considered at the same time.

The invention discloses an organic wastewater adsorbent as well as a preparation method and application thereof, and belongs to the technical field of sewage treatment. Comprising the following steps: carrying out nitration reaction on styrene porous microsphere resin, and then carrying out reduction reaction to obtain amino-modified porous microsphere resin; the preparation method comprises the following steps: carrying out polymerization reaction on high-nitrogen-content amino organic small molecules and aldehyde group small molecules under the action of a basic catalyst in an adsorption polymerization manner to generate a nitrogen-doped organic porous polymer, and coating the surface of amino-modified porous microsphere resin with the nitrogen-doped organic porous polymer to obtain the organic wastewater adsorbent. The porous microsphere resin adsorbent with large adsorption capacity and high organic matter removal rate is synthesized by using the carrier advantage of styrene microsphere resin and introducing a porous heteroatom polymer on the microsphere resin. When the adsorbent is used, the adsorbent is directly added into an organic wastewater solution, and the removal rate of bisphenol A, aniline and tetracycline can reach 90% or above.

A novel compound of Chemical Formula 1:wherein in the Chemical Formula 1: n is an integer of 1 to 6; X is O or S; L1 and L2 are each independently a single bond, substituted or unsubstituted C6-60 arylene, or substituted or unsubstituted C2-60 heteroarylene containing at least one heteroatom selected from the group consisting of O, S, Si, P and B; Ar1 is cyano, substituted or unsubstituted C6-60 aryl, or substituted or unsubstituted C2-60 heteroaryl containing at least one heteroatom selected from the group consisting of O, S, Si, P and B; and Ar2 and Ar3 are each independently substituted or unsubstituted C6-60 aryl or substituted or unsubstituted C2-60 heteroaryl containing at least one heteroatom selected from the group consisting of O, S, Si, P and B; and an organic light emitting device including the same.

The invention relates to the technical field of organic materials, and discloses an organic long-afterglow material as well as a preparation method and application thereof. The compounds (I)-VI are rigid aromatic organic compounds containing heteroatoms O, S or N, can be applied to organic long-afterglow materials and serve as guest components of the long-afterglow materials. When a substance containing melamino-formaldehyde resin is used as a main component of the organic long-afterglow material, a cross-linked structure of the organic long-afterglow material can effectively prevent a phosphorescence quenching behavior of water and oxygen on guest molecules; the organic long-afterglow material is long in afterglow luminescence life, good in long-afterglow performance stability, high in phosphorescence quantum yield and high in luminescence efficiency; the polymer film prepared by taking the organic long afterglow material as the raw material can be excited by ultraviolet in sunlight, can generate response under extremely low ultraviolet intensity, and has ultraviolet detection potential.

The invention discloses a preparation method of a heteroatom doped starch-based porous carbon electrode material. The preparation method of the heteroatom doped starch-based porous carbon electrode material sequentially comprises the following steps: mixing starch with an N-methylmorpholine-N-oxide aqueous solution and a doping agent, heating and dissolving, and then melting, blending, extruding and uniformly mixing the dissolved mixture by adopting a double-screw extruder to prepare mixed granules; then pre-carbonizing the mixed granules to prepare pre-carbonized carbon, grinding the pre-carbonized carbon into powder, uniformly mixing the powder with an activating agent aqueous solution, evaporating to dryness, activating and carbonizing the mixture at high temperature, pickling, washing with water, and drying to obtain the heteroatom doped starch-based porous carbon electrode material. The doping agent is one or more of urea, melamine and ammonium polyphosphate. According to the preparation method, heteroatom doping is carried out in a melt blending mode, industrial implementation is easy, raw materials are rich in source and low in cost, and the product has excellent electrochemical performance and good cycle stability.

The invention relates to a sodium ion battery hard carbon material preparation method, which comprises: (S1) uniformly mixing an asphalt substance and a heteroatom-rich organic matter to obtain a mixed precursor I; (S2) carrying out heat treatment on the mixed precursor in an oxidizing atmosphere, cooling, and wrapping the heteroatom-rich organic matter in the asphalt melting process to obtain a mixed precursor II; and (S3) calcining, cooling, grinding, washing and drying the mixed precursor II in an inert atmosphere or a hydrocarbon atmosphere to obtain the amorphous sodium ion battery negative electrode material. The negative electrode material obtained by the preparation method disclosed by the invention has high capacity and high energy density, a carbon material which is low in cost, simple in preparation process, adjustable in disorder degree, high in carbon yield and suitable for large-scale production is provided, and the carbon material is applied to the sodium ion secondary battery as the negative electrode material.

The invention discloses an n-type conductive polymer and a large-scale preparation method thereof, and the method comprises the following steps: mixing a polymeric monomer with anhydride and DMSO, and reacting under the protection of inert gas to obtain the n-type conductive polymer. According to the invention, the anhydride substance and the dimethyl sulfoxide are blended to generate a compound with oxidability in situ, so that low-cost and large-scale preparation of the n-type conductive polymer and other heteroatom substituted analogues / blends is realized. According to the invention, additional use of other oxidants is avoided, and acid anhydrides with relatively low price are adopted, so that the material cost is effectively reduced; meanwhile, due to the volatility of the acid anhydride or the derivative thereof, post-treatment can be simply carried out through vacuum concentration, and the cost required by dialysis purification treatment in the prior art is further reduced. In addition, the n-type conductive polymer provided by the invention has conductivity equivalent to that in the prior art, has good storage stability, and is beneficial to further promotion of industrialization of the n-type conductive polymer.

The invention discloses a preparation method of an oral liver protection composition containing ergothioneine, and relates to the technical field of ergothioneine application. The oral liver protection composition containing the ergothioneine is prepared from the following components in parts by mass: 0.5 to 5 parts of the ergothioneine, 10 to 30 parts of silibinin, 20 to 50 parts of a phospholipid complex, 5 to 15 parts of a liver targeting carrier, 2 to 8 parts of a disintegrating agent, 1 to 5 parts of an adhesive and 2 to 4 parts of an antioxidant. Free radicals are efficiently captured through a polycyclic conjugated pi electron system of the antioxidant, a hydrogen bond network is formed by a heteroatom bridging effect of the antioxidant, a galactose group of the liver targeting carrier and the disintegrating agent, and the stability of the system is synergistically improved; the phospholipid complex is embedded with a hydrophobic drug and a hydrophilic carrier, and the drug is accurately delivered to the liver by combining the specific recognition capability of the liver targeting carrier; the ergothioneine and the silybin form a bidirectional synergistic liver protection mechanism by removing reactive oxygen free radicals and regulating and controlling cell signal channels respectively.

The invention discloses an acid liquid system based on synergistic interaction of a corrosion inhibitor and an iron stabilizer and a preparation method, and relates to the technical field of oilfield chemistry, the acid liquid system comprises the following components by mass: 10%-20% of an acid liquid, 0.5%-3% of a composite corrosion inhibitor, 0.5%-2% of an iron stabilizer, 0.1%-0.5% of a discharge aiding agent, 0.2%-0.8% of an acid thickening agent, and the balance of water; the main component of the composite corrosion inhibitor in the acid liquid system is long-chain alkyl bis-imidazoline-thiadiazole amide hydroxypropyl sulfobetaine, and the composite corrosion inhibitor contains a bis-imidazoline ring and a thiadiazole amide ring, and can form more stable multi-active-site adsorption on the metal surface to form a compact and stable protective film, so that the metal surface corrosion resistance is improved, and the metal surface corrosion resistance is improved. Long carbon chains in molecules can effectively block corrosive media, N, O and S heteroatoms in the molecules are adsorbed on the iron surface through lone pair electrons to inhibit corrosion, the slow-release effect is further enhanced, and therefore the slow-release efficiency is improved by 40% or above.

The invention relates to the technical field of catalytic materials, in particular to a carbon-based monatomic catalyst doped with five non-metallic elements and a preparation method and application of the carbon-based monatomic catalyst doped with the five non-metallic elements. An organic precursor (MOF-coated POSFN-CTP) rich in five non-metallic element heteroatoms is prepared through a simple coprecipitation method at the room temperature; and annealing to obtain the carbon material (POSFNC) doped with five non-metallic elements. On the basis, the POSFNC is further impregnated with a transition metal precursor, annealing is carried out again, and the carbon-based monatomic catalyst doped with five non-metallic elements is successfully synthesized. The carbon-based monatomic catalyst with a hollow porous structure and five non-metallic element heteroatoms uniformly distributed can be constructed through the method, the synthesis process has the advantages of simplicity, convenience, economy and environmental protection, and the ORR activity and stability of the prepared catalyst exceed those of a commercial Pt / C catalyst.

To provide a thickening composition which simultaneously achieves both a refreshing tactile when applied to the skin and a thickening effect and a cosmetic composition containing the same.SOLUTION: There is provided a thickening composition comprising a component (a) and a component (b). The component (a) is a polyamino acid derivative containing a repeating unit represented by the following general formula (1) and the component (b) is a compound having a hydrophobic group. (In the formula, R1 contains at least a hydrocarbon group having 3 to 22 carbon atoms, and R2 contains at least a hydrocarbon group having 1 to 20 carbon atoms which may contain a heteroatom. n and m represent the number of moles of α- or β-polyaspartic acid monomer units A-U and B-U in the molecule, respectively. In the polyamino acid derivative, the bonding form of the monomer unit A-U and the monomer unit B-U may be any of a random form, a blocked form or a tapered form.)SELECTED DRAWING: None

The invention discloses a heteroatom modified intrinsic microporous polymer material, a preparation method and application, and belongs to the technical field of environmental governance, and the preparation method comprises the following steps: (1) preparing nitro-substituted oxygen atom bridged calixarene from cyanuric chloride and nitro-substituted resorcinol in the presence of a basic catalyst; (2) reducing the nitro-substituted oxygen atom bridged calixarene into amino-substituted oxygen atom bridged calixarene; and (3) carrying out a Schiff base polymerization reaction on the amino-substituted oxygen atom bridged calixarene and a polyfunctional aldehyde group under a solvothermal condition to obtain the heteroatom modified intrinsic microporous polymer material. When the adsorbent is used, the adsorbent is directly added into a metal ion solution, the removal rate of dichromate radicals and manganese ions can reach 90% or above, and the adsorbed material can be repeatedly used after being washed by an acidic aqueous solution. And the polymerized material also has high water body stability, and is beneficial to recycling of the material.