1751 results about "Heteroatom" patented technology

The invention discloses a cobalt-loaded covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. The cobalt-loaded covalent organic framework material is prepared by taking a carbonized covalent organic framework as a matrix and cobalt nitrate hexahydrate as a cobalt source, reducing by using a sodium borohydride methanol solution, and introducing transition metal cobalt into the framework through room-temperature impregnation and thermal reduction processes. In the material, active components comprise Co0 and Co < 2 + > which are uniformly distributed on a carrier. Moreover, the metal cobalt is stably loaded in a carbon skeleton through the bonding effect of heteroatoms such as nitrogen and carbon, so that the stability, the catalytic activity and the durability of the metal cobalt are effectively improved, the dissolution risk of the metal cobalt is reduced, the hidden danger of environmental pollution is reduced, and efficient catalytic activity is shown in the aspect of catalyzing and activating peroxymonosulfate to degrade organic pollutants; and good recycling stability is achieved.

The invention provides a heteroatom-doped porous carbon material for carbon dioxide adsorption as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, drying and crushing waste biomass to obtain raw material powder; s2, mixing the raw material powder with an activating agent, and fully grinding to obtain a mixture of the raw material powder and the activating agent powder; s3, dissolving one or more heteroatom sources in hot deionized water to obtain a hot solution, pouring the mixture of the raw materials and the activator powder in the step S2 into the hot solution, and heating and stirring until water is evaporated; s4, performing high-temperature carbonization on the mixture finally obtained in the step S3 in an anoxic environment; and S5, cleaning and drying the product in the step S4 to obtain the heteroatom-doped porous carbon material. The heteroatom-doped porous carbon material disclosed by the invention has a highly developed pore structure, and the porous carbon prepared by taking the waste biomass as a precursor is used as a carbon dioxide adsorbent, so that high-value utilization of waste biomass resources is realized.

The invention provides a metal matrix composite microstructure strengthening simulation method and system, and relates to the technical field of composite mechanical property simulation, and the method comprises the following steps: establishing a polycrystalline aluminum matrix atomic model and a spherical silicon nitride particle strengthening phase atomic model unit; embedding the spherical silicon nitride particles into the polycrystalline aluminum matrix according to the target embedding position coordinates, and integrating to generate an atomic scale structure model; according to the method, an embedded atom potential function is adopted to describe interaction among atoms in a polycrystalline aluminum matrix, a Tersoft potential function is adopted to describe covalent bond interaction among atoms in spherical silicon nitride particles, and a Lennard-Jones potential function is adopted to describe interaction among heteroatoms at a Si3N4 / Al interface; based on the interaction potential between atoms, molecular dynamics simulation is adopted for conducting uniaxial stretching simulation on the atomic scale structure model, mechanical property parameters of the particle reinforced metal matrix composite are obtained through calculation, and a visualization method is combined for analyzing the microcosmic strengthening mechanism of the particle reinforced metal matrix composite.

The invention discloses a modified organic silicon resin, a high-temperature-resistant coating and a preparation method thereof, the modified organic silicon resin is prepared by hydrolyzing at least two different siloxane monomers and then carrying out condensation reaction on the hydrolyzed siloxane monomers and at least one boric acid monomer, and the main chain of the organic silicon resin is of a heteroatom doped structure formed by a Si-O bond, a B-O bond and a B-O-Si bond; at 200-250 DEG C, the modified organic-inorganic high-temperature-resistant composite material is subjected to a self-crosslinking reaction. The high-temperature-resistant coating overcomes the defect that the high-temperature-resistant coating in the prior art cannot meet the high-temperature test, and avoids the defects that organic and inorganic high-temperature-resistant coatings crack, the impact resistance and hardness are not matched, the water resistance is poor, and the wear resistance is poor.

The invention discloses a preparation method of metal ion liquid modified co-doped biochar and application of the metal ion liquid modified co-doped biochar in tetracycline removal, and belongs to the technical field of water pollution treatment and adsorption material preparation. The preparation method comprises the following steps: mixing a biochar precursor with a metal ion liquid containing transition metal and a heteroatom source, and carrying out high-temperature carbonization to obtain the metal ion liquid modified co-doped biochar. Multiple modification of the biochar is realized through one-time high-temperature carbonization (transition metal elements and heteroatoms are introduced into a biochar skeleton, abundant surface active sites are provided, and the specific surface area and pore volume of the biochar are improved), so that the adsorption performance of the biochar on tetracycline antibiotics is remarkably improved. The preparation method is simple in process, raw materials are easy to obtain, and the obtained metal ion liquid modified co-doped biochar has excellent adsorption performance on antibiotic pollutants such as tetracycline and is suitable for purification treatment of water polluted by antibiotics.

The invention provides a composite pollution repairing agent as well as a preparation method and application thereof, and belongs to the technical field of environmental functional materials. The composite pollution repairing agent comprises biochar, nano zero-valent iron (nZVI) loaded on the biochar, cyclodextrin and heteroatoms, and at least part of the nZVI is wrapped in the cyclodextrin. According to the prepared composite pollution repairing agent, solid waste resource utilization can be effectively achieved, the removal rate of micro-plastics reaches 90% or above, and the removal rate of heavy metal is 100%. The composite pollution repairing agent has excellent performance and good application prospect, provides a feasible solution for micro-plastic and heavy metal composite pollution treatment, and shows remarkable practical application value.

The present invention relates to a method for the synthesis of a carboxylic diacid, having a 5- or 6-membered heteroaromatic compound optionally comprising an allyl or methylstyrene function, preferably selected from 5- or 6-membered heteroaromatic compounds and comprising at least one heteroatom selected from nitrogen, sulphur and oxygen.

The invention relates to the technical field of batteries, in particular to a negative electrode material, a preparation method thereof and a battery. The negative electrode material comprises a silicon nano material; the metal silicide layer at least partially coats the surface of the silicon nano material; the nitrogen and sulfur doped carbon layer at least partially coats the surface of the metal silicide; and the thickness of the metal silicide layer is greater than that of the nitrogen and sulfur doped carbon layer. According to the negative electrode material, the preparation method thereof and the battery provided by the invention, the coating structure of the negative electrode material is optimized, and the metal silicide / heteroatom doped carbon double-layer coated silicon nano material can be prepared by adopting a synthesis method which is low in energy consumption and capable of constructing a functional multi-layer coating structure, so that the long cycle life and the high-rate fast charging performance can be considered at the same time.

The invention discloses an organic wastewater adsorbent as well as a preparation method and application thereof, and belongs to the technical field of sewage treatment. Comprising the following steps: carrying out nitration reaction on styrene porous microsphere resin, and then carrying out reduction reaction to obtain amino-modified porous microsphere resin; the preparation method comprises the following steps: carrying out polymerization reaction on high-nitrogen-content amino organic small molecules and aldehyde group small molecules under the action of a basic catalyst in an adsorption polymerization manner to generate a nitrogen-doped organic porous polymer, and coating the surface of amino-modified porous microsphere resin with the nitrogen-doped organic porous polymer to obtain the organic wastewater adsorbent. The porous microsphere resin adsorbent with large adsorption capacity and high organic matter removal rate is synthesized by using the carrier advantage of styrene microsphere resin and introducing a porous heteroatom polymer on the microsphere resin. When the adsorbent is used, the adsorbent is directly added into an organic wastewater solution, and the removal rate of bisphenol A, aniline and tetracycline can reach 90% or above.

The invention relates to a sodium ion battery hard carbon material preparation method, which comprises: (S1) uniformly mixing an asphalt substance and a heteroatom-rich organic matter to obtain a mixed precursor I; (S2) carrying out heat treatment on the mixed precursor in an oxidizing atmosphere, cooling, and wrapping the heteroatom-rich organic matter in the asphalt melting process to obtain a mixed precursor II; and (S3) calcining, cooling, grinding, washing and drying the mixed precursor II in an inert atmosphere or a hydrocarbon atmosphere to obtain the amorphous sodium ion battery negative electrode material. The negative electrode material obtained by the preparation method disclosed by the invention has high capacity and high energy density, a carbon material which is low in cost, simple in preparation process, adjustable in disorder degree, high in carbon yield and suitable for large-scale production is provided, and the carbon material is applied to the sodium ion secondary battery as the negative electrode material.

The invention discloses a preparation method of an oral liver protection composition containing ergothioneine, and relates to the technical field of ergothioneine application. The oral liver protection composition containing the ergothioneine is prepared from the following components in parts by mass: 0.5 to 5 parts of the ergothioneine, 10 to 30 parts of silibinin, 20 to 50 parts of a phospholipid complex, 5 to 15 parts of a liver targeting carrier, 2 to 8 parts of a disintegrating agent, 1 to 5 parts of an adhesive and 2 to 4 parts of an antioxidant. Free radicals are efficiently captured through a polycyclic conjugated pi electron system of the antioxidant, a hydrogen bond network is formed by a heteroatom bridging effect of the antioxidant, a galactose group of the liver targeting carrier and the disintegrating agent, and the stability of the system is synergistically improved; the phospholipid complex is embedded with a hydrophobic drug and a hydrophilic carrier, and the drug is accurately delivered to the liver by combining the specific recognition capability of the liver targeting carrier; the ergothioneine and the silybin form a bidirectional synergistic liver protection mechanism by removing reactive oxygen free radicals and regulating and controlling cell signal channels respectively.

The invention discloses an acid liquid system based on synergistic interaction of a corrosion inhibitor and an iron stabilizer and a preparation method, and relates to the technical field of oilfield chemistry, the acid liquid system comprises the following components by mass: 10%-20% of an acid liquid, 0.5%-3% of a composite corrosion inhibitor, 0.5%-2% of an iron stabilizer, 0.1%-0.5% of a discharge aiding agent, 0.2%-0.8% of an acid thickening agent, and the balance of water; the main component of the composite corrosion inhibitor in the acid liquid system is long-chain alkyl bis-imidazoline-thiadiazole amide hydroxypropyl sulfobetaine, and the composite corrosion inhibitor contains a bis-imidazoline ring and a thiadiazole amide ring, and can form more stable multi-active-site adsorption on the metal surface to form a compact and stable protective film, so that the metal surface corrosion resistance is improved, and the metal surface corrosion resistance is improved. Long carbon chains in molecules can effectively block corrosive media, N, O and S heteroatoms in the molecules are adsorbed on the iron surface through lone pair electrons to inhibit corrosion, the slow-release effect is further enhanced, and therefore the slow-release efficiency is improved by 40% or above.

The invention relates to the technical field of catalytic materials, in particular to a carbon-based monatomic catalyst doped with five non-metallic elements and a preparation method and application of the carbon-based monatomic catalyst doped with the five non-metallic elements. An organic precursor (MOF-coated POSFN-CTP) rich in five non-metallic element heteroatoms is prepared through a simple coprecipitation method at the room temperature; and annealing to obtain the carbon material (POSFNC) doped with five non-metallic elements. On the basis, the POSFNC is further impregnated with a transition metal precursor, annealing is carried out again, and the carbon-based monatomic catalyst doped with five non-metallic elements is successfully synthesized. The carbon-based monatomic catalyst with a hollow porous structure and five non-metallic element heteroatoms uniformly distributed can be constructed through the method, the synthesis process has the advantages of simplicity, convenience, economy and environmental protection, and the ORR activity and stability of the prepared catalyst exceed those of a commercial Pt / C catalyst.

The invention discloses a heteroatom modified intrinsic microporous polymer material, a preparation method and application, and belongs to the technical field of environmental governance, and the preparation method comprises the following steps: (1) preparing nitro-substituted oxygen atom bridged calixarene from cyanuric chloride and nitro-substituted resorcinol in the presence of a basic catalyst; (2) reducing the nitro-substituted oxygen atom bridged calixarene into amino-substituted oxygen atom bridged calixarene; and (3) carrying out a Schiff base polymerization reaction on the amino-substituted oxygen atom bridged calixarene and a polyfunctional aldehyde group under a solvothermal condition to obtain the heteroatom modified intrinsic microporous polymer material. When the adsorbent is used, the adsorbent is directly added into a metal ion solution, the removal rate of dichromate radicals and manganese ions can reach 90% or above, and the adsorbed material can be repeatedly used after being washed by an acidic aqueous solution. And the polymerized material also has high water body stability, and is beneficial to recycling of the material.

The invention provides a ZIF-derived Co-P catalyst and a preparation method thereof. The catalyst can be used for synthesizing dimethyl carbonate through oxidative carbonylation of methanol. The ZIF-derived Co-P catalyst disclosed by the invention is prepared by roasting a precursor P-doped Zn / Co-ZIF intermediate. Compared with a traditional cobalt-based catalyst, the Co-P catalyst prepared through roasting treatment modification can regulate and control the variety and coordination number of heteroatoms, improve the interaction between metal and a carrier and effectively anchor metal atoms, and meanwhile P atoms can serve as second active sites to assist in improving the adsorption and activation capacity of reactants and intermediate species. In addition, the ZIF generates a hierarchical pore structure in the roasting treatment process, so that the mass transfer and diffusion processes of reactants and products are effectively promoted. According to the Co-P catalyst disclosed by the invention, the methanol oxidative carbonylation reaction activity is remarkably improved, and the catalyst has high stability.

The invention relates to a negative pole piece and a preparation method and application thereof.The negative pole piece comprises a current collector and a negative active layer arranged on at least one face of the current collector in the thickness direction, the negative active layer comprises a first active layer, a second active layer and a third active layer, the first active layer is attached to the surface of the current collector, and the second active layer is attached to the surface of the current collector; the second active layer is arranged on the surface, far away from the current collector, of the first active layer, and the third active layer is arranged on the surface, far away from the first active layer, of the second active layer; the first active layer comprises carbon-coated secondary particle graphite, the second active layer comprises heteroatom-doped hard carbon, and the third active layer comprises porous carbon nanofibers. According to the lithium ion battery, the multiple active layers containing different active materials are arranged on the surface of the current collector, and meanwhile, the thickness of each active layer is regulated and the preparation process is optimized, so that the lithium ion battery containing the negative pole piece has high energy density, quick charge capacity and excellent cycle life.

The invention discloses a porous carbon-coated graphite composite material for an energy storage battery and a preparation method of the porous carbon-coated graphite composite material. The porous carbon-coated graphite composite material consists of inner core graphite and lithium heteroatom-doped porous carbon coated on the surface of the inner core graphite, the preparation method comprises the following steps: preparing an organic template agent solution, adding resin and an amino organic lithium compound, uniformly mixing, adding a hydrogen peroxide oxidizing agent, reacting, filtering, and activating at high temperature to obtain lithium-doped porous carbon; the preparation method comprises the following steps: adding lithium-doped porous carbon into an organic solvent, then adding graphite and an organic aluminum-based compound, uniformly dispersing, dropwise adding an amino solution, carrying out chemical reaction at the temperature of 50-120 DEG C, filtering, and carrying out vacuum drying and high-temperature carbonization on obtained filter residues to obtain the lithium-doped porous carbon composite material. The cycle performance and the storage performance of the graphite can be improved.

The invention belongs to the technical field of organic electroluminescent materials, and provides an iridium-containing heterocyclic phosphorescent doping material and an organic electroluminescent device.The doping material has a compound general formula shown in the formula I. Quinoline and a naphthalene ring are connected through silane or germane, and a silicon or germanium six-membered heterocyclic structure is formed. And reacting with iridium metal and a diketone monomer to obtain the iridium metal heterocyclic phosphorescent organic light-emitting material. The heteroatom silicon or germanium in the material can adjust molecular orbital HOMO and LUMO energy levels, and the polarity effect of heteroatoms promotes electron migration, reduces interface potential barriers and electron injection barriers, reduces carrier injection loss and improves carrier mobility, so that driving voltage is reduced, and the external quantum efficiency of a device is improved. In addition, the silicon or germanium heterocyclic ring has better rigidity, so that the overall stability of the structure is enhanced, and the rigid structure can prolong the service life of the device.

The invention relates to a compound of formula (I) wherein X is selected from the group consisting of-O-(CH2) n-wherein n is 0 to 4, R1 and R2 are independently selected from the group consisting of C11-C25 alkyl groups, SP is a spacer, in particular selected from the group consisting of saturated C4-C8 alkyl groups, unsaturated C4-C8 alkyl groups and substituted or unsubstituted C6 aromatic compounds, in particular substituted C6 aromatic compounds are alkyl substituted C6 aromatic compounds, Y is a heteroatom, n is 0 to 4, and R1 and R2 are independently selected from the group consisting of C11-C25 alkyl groups, SP is a spacer, in particular selected from the group consisting of saturated C4-C8 alkyl groups, unsaturated C4-C8 alkyl groups, and substituted or unsubstituted C6 aromatic compounds, in particular substituted C6 aromatic compounds are alkyl substituted C6 aromatic compounds. L is a peptide synthesis linker, in particular selected from the group consisting of-O-and-NH-, L is a peptide synthesis linker, and m is 0 or 1, in particular m is 1.

Flash Joule heating (FJH) for production of one-dimensional (1D) carbon and / or boron nitride nanomaterials, and 1D materials integrated with 0D, 1D, 2D, and 3D nanomaterials, composites, nanostructures, networks, and mixtures thereof. Such materials produced by FJH include 1D carbon and hybrid nanomaterials, boron nitride nanotubes (BNNTs), turbostratic boron-carbon-nitrogen (BCN), doped (substituted) graphene, and heteroatom doped (substituted) re-flashed graphene.

The invention provides a preparation method for preparing porous carbon based on an aerogel method, the porous carbon and application of the porous carbon, and belongs to the technical field of porous carbon material preparation. The preparation method comprises the following steps: mixing polyhydroxy phenol, aromatic aldehyde, acrylamide, graphene oxide and lithium salt according to a mass ratio of 100: (50-200): (5-30): (1-5): (1-5), carrying out hydrothermal reaction at 100-200 DEG C for 1-6 hours, and freeze-drying at-40 DEG C to obtain a hydrogel precursor; and carbonizing the precursor in organic heteroatom gas at 500-800 DEG C, mixing the intermediate with alkali according to the ratio of 100: (100-500), activating at 900-1100 DEG C, pickling and drying to obtain the porous carbon. The conductivity of the product is improved by means of graphene, lithium salt and heteroatoms, and the aerogel method obtains large aperture, has the characteristics of low impedance, high first efficiency and small charge-discharge expansion, and can be efficiently applied to silicon-carbon materials.

The purpose of the present invention is to provide a photoelectric conversion element that shows excellent photoelectric conversion characteristics and has low variation.　A photoelectric conversion element 10 according to one mode of the present invention has a structure in which a first electrode 12, a hole transport layer 13, a photoelectric conversion layer 14, an electron transport layer 15, and a second electrode 16 are layered in that order. The photoelectric conversion layer 14 includes a perovskite compound. The hole transport layer 13 includes an insulating compound and a monomolecular hole transport material. The hole transport material includes a compound represented by the chemical formula (I). (I): Ar1–(L1–X1)n. In the chemical formula (I), Ar 1 is a structure that includes an aromatic ring, atoms that constitute the aromatic ring may include heteroatoms, and Ar1 may have a substituent other than –L1–X1. n is an integer 1 or greater, and if n is 2 or greater, the structures represented by –L1–X1 may be mutually identical or different. L1 is a divalent linking group linking Ar1 and X1 or is a single bond. X1 is a group capable of chemical bonding or hydrogen bonding with a p-type metallic oxide semiconductor.

The invention provides N-O doped flower-like porous carbon microspheres as well as a preparation method and application thereof, and belongs to the technical field of electromagnetic wave absorbing materials. According to the invention, microspheres are coated by using a simple soap-free emulsion polymerization method, a complex multi-layer heterogeneous interface structure is realized, N and O atoms are introduced, and heteroatom doping is realized so as to improve the wave-absorbing performance; a unique flower-shaped structure is grown on the surface of the microsphere through a self-assembly process, and an exquisite flower-shaped porous carbon microsphere can be obtained through carbonization, so that an ingenious structure beneficial to multiple reflection and scattering generation is realized. Under the conditions that the mass ratio of the flower-like porous carbon microspheres to the paraffin is 1: 5 and the matching thickness is 2.5-3mm, the minimum reflection loss of the flower-like porous carbon microspheres is-40.8 to-48.0 dB, the optimal effective absorption bandwidth is 4.40 GHz, and the flower-like porous carbon microspheres have excellent electromagnetic wave absorption performance.

The invention discloses a preparation method of nitrogen-doped hierarchical pore hollow carbon spheres, and relates to the technical field of electrochemical desalination, the preparation method comprises the following steps: carrying out polycondensation on melamine and formaldehyde in the presence of PVP to form a spherical template; resorcinol and HMTA form a phenolic resin coating layer on the surface of the template; calcining at high temperature to realize decomposition and carbonization of the template, and introducing double bonds through a silane coupling agent; introducing a phosphoryl chloride group through free radical polymerization; finally, grafting a sulfonic acid group through nucleophilic substitution to obtain a final product. The nitrogen-doped hollow carbon spheres with a hierarchical pore structure are prepared through a hollowing strategy and surface modification, and N, P and S ternary heteroatom synergy is realized through introduction of a phosphoryl chloride group and a sulfonic acid group, so that the material has high specific surface area, optimized pore structure and strong ion exchange capacity; the composite material shows excellent ion adsorption performance and cycling stability, and has a good application prospect in the field of capacitive deionization.

The invention belongs to the field of fuel cells, and particularly relates to an electrode material for a fuel cell and a preparation method thereof, and the preparation method comprises the following steps: preparing polyimide containing amino POSS (Polyhedral Oligomeric Silsesquioxane); carrying out primary pyrolysis, and sequentially carrying out acid etching, cleaning and drying on a product to obtain primary carbonized polyimide; and grinding the primary carbonized polyimide, performing pyrolysis again, and sequentially performing acid etching, cleaning and drying on the product to obtain the electrode material for the fuel cell. The electrode material has a good graphite structure and a rich pore structure, so that ions and electrons can be quickly transferred in pores while the good conductivity of the material can be ensured; meanwhile, introduction of non-metal nitrogen heteroatoms can increase active sites, the electrochemical activity of the material is remarkably improved, and the material is suitable for being used as an electrode material of a fuel cell.

The invention discloses an electrolyte based on a fluorine-containing polynitrile compound and a high-voltage supercapacitor, and belongs to the field of energy storage materials. The electrolyte comprises a fluorine-containing polynitrile compound, an organic solvent and electrolyte salt; the structure of the fluorine polynitrile compound is as follows: Fm-A-(CN) n, wherein A is C1-C10 alkyl, C6-C14 aryl or a heteroatom-containing linking group, m is greater than or equal to 1, and n is greater than or equal to 2. By introducing the Fm-A-(CN) n structure compound and utilizing the synergistic effect of fluorine atoms and cyano groups, a stable interfacial film is formed on the surface of an electrode, so that the working voltage of the electrolyte is increased to 3-3.2 V. The capacitance decay rate of the electrolyte in the range of 60-80 DEG C is lt; the method is suitable for the fields of vehicle-mounted energy storage, power grid frequency modulation and the like.

To provide a modified polyisocyanate having high adhesive property to a non-ferrous metal and applicable to a one-coat coating material.SOLUTION: A modified polyisocyanate is a reaction product which has as the raw material, components containing an alkoxysilane (a1) having a primary amino group, an unsaturated carboxylic acid alkyl ester (a2) or a saturated carboxylic acid alkyl ester (a3), and a polyisocyanate (a4). The unsaturated carboxylic acid alkyl ester (a2) is at least one kind selected from the group consisting of a branched alkyl ester (a2-1) of an unsaturated dicarboxylic acid, and a branched alkyl ester (a2-2) which may contain a hetero atom of an unsaturated monocarboxylic acid or has a cyclic structure. A production method of the modified polyisocyanate, and a coating containing the same are also provided.SELECTED DRAWING: None

The invention belongs to the technical field of rubber auxiliaries and rubber tracks, and particularly relates to a coupling agent composition for inhibiting rubber appearance flooding and application of the coupling agent composition in the rubber tracks. The coupling agent composition comprises the following components in percentage by weight: 15%-30% of coupling agent, 1%-15% of metal chloride and 70%-85% of clay mineral. Different from a microcapsule technology only aiming at anti-aging agent migration, the coupling agent composition disclosed by the invention can effectively capture various types of color-flooding source substances including carbon black residues, anti-aging agents, antioxidants and the like by starting from common characteristics (containing unsaturated bonds, heteroatoms and aromatic structures) of color-flooding small molecules and through the synergistic effect of the coupling agent and metal ions, so that the color-flooding source substances can be effectively captured. And the method has wide applicability. In addition, a composite system composed of the clay, the coupling agent and the metal chloride can improve the bonding strength of the rubber and a track framework material, and is suitable for being applied to a heavy-load rubber track.

Disclosed are biodegradable polyesters. Methods for their production and adhesives prepared therefrom. The polyesters comprise a plurality of adducts of two dicarboxylates or anhydrides with a compound having at least two fused ring heterocycles containing a heteroatom and a hydroxyl group pendant from each ring, the adducts are linked by the residues of one or more diols of alkylene diols or polyoxyalkylene diols and a plurality of one or more aliphatic diols containing a pendant carboxylate group. Ester groups are formed by reaction of the hydroxyl groups of the fused ring compounds and the diols with the carboxylate groups of the dicarboxylates and the composition contains pendant carboxylate groups, wherein the composition contains two dicarboxylates, a first dicarboxylate or an anhydride containing between the carboxylate or carboxyl groups a C1-8 hydrocarbylene group and a second dicarboxylate containing between the carboxylate groups a C9-60 hydrocarbylene group.

The invention discloses a hydrogen energy fuel cell catalyst carrier based on a graphene graft polymer, which is characterized in that two-dimensional graphene is used as a substrate, the surface of the two-dimensional graphene is modified with an oxygen-containing functional group, and a functional polymer branch chain containing nitrogen, sulfur or phosphorus heteroatoms is covalently grafted to form a local three-dimensional network winding structure; the carrier is loaded with platinum, palladium, ruthenium and other metal or alloy nanoparticles, the particle size is 2-8 nm, the loading capacity is 10%-40%, and the particles are anchored to polymer functional sites or reduced in situ to a graphene defect area through coordination. A polymer branch chain has pH responsiveness and can adjust the local proton transmission efficiency; the grafting density is 3-15 grafting points per 100 carbon atoms, so that high dispersion and stable anchoring of metal particles are effectively realized; the specific surface area of the carrier is 400-800m < 2 > / g, the electrochemical active area is not less than 80m < 2 > / g, and the activity retention rate is greater than 80% after 5000 circles of accelerated durability tests. The activity, the stability and the proton conduction performance of the catalyst are remarkably improved, and the catalyst is suitable for high-performance fuel cells.