1168 results about "Hydride" patented technology

The invention relates to the technical field of hydrogen preparation, and provides a hydrogen storage device based on a solid hydrogen storage material and a hydrogen production method thereof.The device comprises a fuel tank internally provided with a reaction cavity used for containing an aluminum hydride material and mixed powder; the heater is arranged on the outer side of the fuel tank; the first end of the water recycling assembly is communicated with the reaction cavity, and the second end of the water recycling assembly is communicated with the fuel cell system so as to recycle water generated by the fuel cell system to the reaction cavity; the first end of the hydrogen discharging assembly is communicated with the reaction cavity, and the second end is communicated with a fuel cell system. According to the hydrogen storage device provided by the invention, through the application of the high-specific-energy solid hydrogen storage material aluminum hydride which can be stored at normal pressure and release hydrogen at a relatively low temperature, the thermal decomposition process of the metal hydride in the fuel tank and the coupling reaction process of the metal hydride and water are optimized, and the hydrogen is produced by utilizing the hydrolysis reaction of the aluminum hydride thermal decomposition reactant simple substance aluminum and the water; meanwhile, thermal decomposition of aluminum hydride is promoted through heat released by hydrolysis reaction, hydrogen release is coupled, and effective utilization of heat is achieved.

The invention relates to the technical field of solid electrolyte, and discloses a double-layer solid electrolyte membrane, a preparation method thereof and an all-solid-state battery. The double-layer solid-state electrolyte membrane comprises a first solid-state electrolyte layer and a second solid-state electrolyte layer which are overlapped with each other, the first solid-state electrolyte layer comprises hydride solid-state electrolyte, and the second solid-state electrolyte layer comprises halide solid-state electrolyte; the hydride solid electrolyte comprises Li < 7-a > P (BH4) S < 6-a > and / or Li < 7-a-b > P (BH4) S < 6-a-b > X , a < = 2, 0lt; blt; 2. The interface between the double-layer solid-state electrolyte membrane and the positive electrode and the interface between the double-layer solid-state electrolyte membrane and the negative electrode have good interface stability, and the interface side reaction between the two solid-state electrolyte layers is less, so that the solid-state battery has high coulombic efficiency and cycling stability.

The present invention relates to a metal hydride hydrogen storage container which is easy to disassemble and can effectively exchange heat, and relates to the technical field of hydrogen storage containers, and in particular to a metal hydride hydrogen storage container which is easy to disassemble and can effectively exchange heat. The present invention comprises: a hydrogen storage alloy tank, a sleeve, a flange and a hydrogen valve; the hydrogen storage alloy tank is installed in the sleeve, and the flange is sealed and connected by a rubber gasket and flange bolts and nuts; a hydrogen valve is installed at the center of the flange; and the interior of the hydrogen storage alloy tank is filled with hydrogen storage alloy powder. The technical solution of the present invention solves the problems in the prior art that the hydrogen storage alloy generates stress on the inner wall of the container due to lattice expansion during the hydrogen absorption process, causing the container to deform and affecting the service life of the container; the hydrogen storage alloy has poor long-term cycle stability and needs to be frequently replaced; the hydrogen storage alloy has poor thermal conductivity and the hydrogen storage device needs to transfer heat to the outside world.

A heat pipe cooled nuclear reactor core (“reactor core”) includes an array of fuel, an array of primary heat rejection heat pipes, and an array of moderator cooling heat pipes or thermosiphons. Each moderator cooling heat pipe in the array of moderator cooling heat pipes is surrounded by metal hydride moderator materials, slowing neutrons from a fission energy range to a lower energy range in the reactor core.

The invention relates to a hydrogen storage pellet enabling the production of compact, modular, safe and energy-efficient hydrogen reservoirs. The pellet according to the invention comprises a peripheral ring (4) having an outer diameter of expanded natural graphite (ENG) of a determined height, surrounding a wafer of a metal hydride (5) in the form of compacted powder.

The invention relates to the technical field of hydrogen storage, and discloses a metal hydride hydrogen storage system and a hydrogen absorption and desorption method. The metal hydride hydrogen storage system comprises n hydrogen storage units which are connected in series, and n is 3-20 and is a positive integer; the adjacent hydrogen storage units are connected through a detachable connecting unit, an open hole is formed in the detachable connecting unit, and the open hole is used for circulation of hydrogen; the hydrogen storage unit comprises a tank body, the tank body is filled with a hydrogen storage bed layer, and the hydrogen storage bed layer is used for hydrogen absorption / hydrogen desorption and heat conduction. According to the hydrogen storage system, the hydrogen storage volume can be flexibly controlled, hydrogen storage material filling is simpler, the heat transfer efficiency can be improved, and the hydrogen absorption and desorption rate can be better controlled.

The invention belongs to the technical field of hydrogen production, and particularly relates to a double-tank metal hydride hydrogen purification device which comprises a first tank body, a second tank body, a primary exhaust pipe, a gas communicating pipe, a first liquid passing bathroom, a second liquid passing bathroom, a circulating liquid bath chamber and a liquid communicating pipe. A first perforated pipe and a first metal hydride are arranged in the first tank body; and a second perforated pipe and a second metal hydride are arranged in the second tank body. The primary exhaust pipe is communicated with the first perforated pipe, and the gas communication pipe is communicated with the primary exhaust pipe and the second perforated pipe. And the first tank body and the second tank body are coated with the first liquid passing bathroom and the second liquid passing bathroom respectively. And the first liquid passing bathroom, the circulating liquid bath chamber, the second liquid passing bathroom and the liquid communicating pipe are communicated in sequence to form a liquid pipeline. Through the design of the circulating liquid bath chamber and the liquid communicating pipe, the hydrogen absorption and heat release process and the hydrogen desorption and heat absorption process are mutually compensated, the heat utilization efficiency is improved, the external heating and cooling requirements are reduced, and the energy consumption in the hydrogen purification process is reduced.

A curable composition for preparing a compressible silicone foam includes an alkenyl-containing component including an alkenyl-diterminated polyorganosiloxane, an alkenyl-substituted MQ polyorganosiloxane, and an alkenyl-substituted copolyorganosiloxane, and a hydride-containing component comprising a hydride-substituted polyorganosiloxane. The curable composition includes a cure catalyst; a filler composition; and a blowing agent. Compressible foams made from the curable composition and methods of making compressible foams from the curable composition are also disclosed.

The invention relates to the technical field of powder metallurgy materials, and discloses rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and a preparation method thereof.The die steel is prepared from 4Cr5MoSiV1 pre-alloyed powder, rare earth hydride, boron carbide and porous amorphous carbon powder loaded with a nickel catalyst. The preparation method comprises the steps of material mixing, sheath packaging, graded dynamic reaction thermal devolatilization, hot isostatic pressing densification and heat treatment, in the graded dynamic reaction thermal devolatilization, active hydrogen generated by decomposition of rare earth hydride is used for reducing oxide on the surface of powder, and nickel catalyzed carbon powder is used for capturing water vapor at low temperature to generate CO to be discharged. An oxide film on the surface of the powder is thoroughly removed through in-situ chemical reaction, original particle boundaries are eliminated, meanwhile, a nano strengthening phase with high thermal stability is generated in situ, and the high-temperature strength, impact toughness and tissue compactness of the die steel are remarkably improved.

The invention relates to the technical field of hydrogen storage, and provides a double-storage and double-release system based on hydrogen storage and phase change heat storage and a heat regulation and control method thereof.The double-storage and double-release system comprises a metal hydride hydrogen storage unit, a phase change heat storage unit and a heat regulation unit; a hydrogen storage heat conduction pipe is arranged in the metal hydride hydrogen storage unit, a heat storage heat conduction pipe is arranged in the phase change heat storage unit, and temperature sensors are arranged on the metal hydride hydrogen storage unit and the phase change heat storage unit. A heat exchange fluid medium is placed in the heat adjusting unit, and the heat adjusting unit is communicated with an inlet and an outlet of the hydrogen storage heat conduction pipe and an inlet and an outlet of the heat storage heat conduction pipe through a heat exchange medium conveying pipeline to form a closed pipeline. An electromagnetic valve is arranged on the heat exchange medium conveying pipeline, and the opening degree of the electromagnetic valve is adjusted according to the temperature detected by the temperature sensor so as to regulate and control the flow of the heat exchange fluid medium. The efficiency of thermal management in the hydrogen storage and release process is remarkably improved, and the applicability of the hydrogen storage and release device in different scenes is further enhanced.

The invention relates to the technical field of hydrogen energy solid hydrogen storage, and discloses a metal hydride hydrogen storage tank and a circulating hydrogen charging and discharging method.The metal hydride hydrogen storage tank comprises a tank body, the top end of the tank body is communicated with a gas inlet pipe, and the bottom end of the gas inlet pipe extends into the tank body and is rotationally provided with a connecting pipe through a rotating connector; a plurality of circular heat dissipation fins are fixedly connected between the inner walls of the tank body, the bottom end of the connecting pipe penetrates through the heat dissipation fins to be rotationally connected with the bottom end of the tank body, and a plurality of air holes are formed in the surface of each heat dissipation fin; four telescopic rods are fixedly connected to the top wall of the interior of the tank body, the hydrogen storage tank drives the transmission assembly to drive the connecting pipe and the stirring plate to rotate through movement of the piston, metal hydride is prevented from caking, hydrogen is dispersed more evenly through inclined air outlet holes, and the hydrogen storage efficiency is improved; the circular heat dissipation fins are provided with air holes, so that heat dissipation is achieved, and circulation of hydrogen is not blocked.

The invention discloses a preparation method of niobium-tungsten alloy spherical powder and a 3D printing method of the niobium-tungsten alloy spherical powder, and belongs to the technical field of refractory metal material preparation.The preparation method comprises the steps that niobium, tungsten, molybdenum and zirconium refractory metal raw materials are smelted to obtain cast ingots with uniform components, and hydride powder is formed after hydrotreating and mechanical crushing; spherical powder is prepared by adopting a plasma spheroidizing technology, then dehydrogenation is performed for 1-3 hours at the temperature of 450-750 DEG C, magnesium powder is added, treatment is performed for 2-5 hours in an inert atmosphere at the temperature of 800-1100 DEG C, and finally the low-oxygen niobium-tungsten alloy spherical powder with the oxygen content lower than 120 ppm is obtained. Compared with a traditional process, the spheroidizing treatment is innovatively carried out before the dehydrogenation and oxygen reduction process, the deoxidation efficiency is improved through the relatively small specific surface area of spherical powder, and oxygen content control is achieved in combination with magnesium powder heat treatment. The problems of high oxygen content and low powder yield in a traditional process are solved, and material support is provided for high-performance niobium-tungsten alloy components in the fields of aerospace, nuclear power and the like.

The magnesium-based metal hydride hydrogen storage system with the energy recovery function comprises an energy recovery device and a hydrogen storage tank, a first heat exchange pipe is installed in the energy recovery device, and the energy recovery device is filled with phase change heat storage materials; the hydrogen storage tank is filled with a magnesium-based hydrogen storage material, a second heat exchange pipe is arranged in the hydrogen storage tank, and heat conduction oil is filled in the second heat exchange pipe; an oil outlet of the second heat exchange pipe is connected with an oil inlet of the heating module through a first pipe set, an oil outlet of the heating module is connected with an oil inlet of the second heat exchange pipe through a second pipe set, and a circulating pump is installed on the second pipe set. The first pipe group is connected with an oil inlet of the first heat exchange pipe through a first branch pipe; the second pipe set is connected with an oil outlet of the first heat exchange pipe through a second branch pipe. By arranging the energy recovery device, energy released in the hydrogen absorption process can be recovered, energy is provided in the hydrogen desorption process, energy-saving and efficient hydrogen storage are achieved, and the operation stability of the hydrogen storage system is guaranteed.

A dehydrogenation reaction device includes a chemical hydride storage unit including a chemical hydride storage tank, a reaction unit including an acid aqueous solution storage tank, and a dehydrogenation reactor configured to generate hydrogen by reacting a chemical hydride with an acid aqueous solution, and a hydrogen storage unit including a hydrogen storage tank configured to store the hydrogen produced in the dehydrogenation reactor. The dehydrogenation reactor includes a body portion made of a metal and a reinforcement portion surrounding the outer surface of the body portion and including fiber reinforced plastic (FRP).

The invention provides an ammonia synthesis method with high activity under mild conditions, ammonia is synthesized through photo-thermal catalysis, a photo-thermal catalyst is a transition metal composite metal hydride, the metal hydride is an alkali metal hydride or an alkaline earth metal hydride and has high catalytic activity, and a high ammonia synthesis rate can be obtained. When the transition metal composite metal hydride is loaded on the carrier, the ammonia synthesis rate can be further improved, and the catalyst has a good application prospect.

The invention relates to the technical field of hydrogen storage materials, and discloses a polymer-doped aluminum hydride hydrogen storage material and a preparation method thereof, comprising a composite hydrogen storage material, wherein the composite hydrogen storage material is composed of a light metal hydride and a polymer, wherein the light metal hydride comprises at least one of LiH, MgH2 or AlH3, and the polymer comprises at least one of PMMA, ABS or PVP, wherein the mass ratio of the light metal hydride to the polymer is 1:0.1-100, and the composite hydrogen storage material is composed of AlH3 and PMMA, and the composition expression of the composite hydrogen storage material is AlH 3 + x wt.%PMMA, where x represents the mass fraction of PMMA in the composite hydrogen storage material, and 1

The invention belongs to the technical field of compound synthesis, and particularly relates to a synthesis method of AEA-AEA. Triethylene glycol is adopted as a starting material, in the first step, p-toluenesulfonate with high leaving property is formed through TsCl, then nucleophilic substitution is performed, and a product 2 is obtained; the preparation method comprises the following steps: preparing a product 3, oxidizing by adopting TEMPO capable of being industrially produced, removing Pht through quantitative hydrazine hydrate to obtain a product 4, esterifying and extracting to obtain a product 5, acylating through the product 3 to obtain amide, washing, extracting and pulping to obtain an esterified product 6; and finally, quantitatively removing Pht, hydrolyzing and pulping to obtain a pure product. According to the method, complex operation steps of using metal hydride and alkylating column passing are avoided, process production can be realized, and the product yield and purity are relatively high.

The invention relates to the technical field of polycrystalline silicon production, in particular to a metal modified adsorbent as well as a preparation method and application thereof in circulating hydrogen purification. The metal modified adsorbent is obtained by introducing a copper-containing active component, an auxiliary metal component, an oxidation auxiliary component and an ionic liquid on an adsorption carrier, and the number of metal aggregates with the size being 20 nm or above on the metal modified adsorbent is 2.3 * 10 < 6 > / mm < 2 > or below. The composite material has rich surface active sites, metal species on the surface are high in stability and not prone to loss, and the composite material has excellent adsorption performance and long service life, can have extremely high adsorption-oxidation efficiency on phosphorus hydride especially when being applied to the circulating hydrogen purification process in polycrystalline silicon production, and is easy to operate and low in energy consumption.

The invention belongs to the technical field of catalysts, and particularly relates to a ruthenium-based supported catalyst as well as a preparation method and application thereof. The ruthenium-based supported catalyst provided by the invention comprises a composite carrier and ruthenium supported on the composite carrier, the composite carrier is one or more of a perovskite type metal oxide and an alkali metal oxide, an alkali metal hydroxide, an alkaline earth metal oxide and an alkaline earth metal hydroxide which are dispersed on the surface of the perovskite type metal oxide; the preparation method of the composite carrier comprises the following steps: mixing a perovskite type oxide with an alkali metal hydride and / or an alkaline earth metal hydride, and carrying out first calcination; soaking the first calcined product in a solvent to obtain a composite carrier; the perovskite type oxide comprises one or two of MgTiO3 (magnesium titanate), SrTiO5 (strontium titanate), BaTiO3 (barium titanate) and CaTiO3 (calcium titanate); the solvent comprises an alcohol solvent and / or water. The catalyst provided by the invention can catalyze an ammonia synthesis reaction under a relatively low pressure.

The invention discloses a multilayer nanostructure metal hydride and a preparation method thereof.The preparation method comprises the steps that transition metal ion salt and a carbon material are added into a polar solvent to be mixed, heating and stirring are conducted to obtain solid powder, and the solid powder is subjected to a hydrogen thermal reduction reaction to obtain a functionalized carbon material; a metal hydride raw material and a functionalized carbon material are added into an organic solvent, ultrasonic treatment and mixing are carried out, a mixed solution is obtained, and the metal hydride raw material is a mixture of an alkyl metal Mg compound or an alkyl metal Li compound and a borane compound; and in a hydrogen atmosphere, carrying out solvothermal reaction on the mixed solution, and then centrifuging, washing, filtering and drying to obtain the multilayer nanostructure metal hydride. The multilayer nano-structure metal hydride prepared by the preparation method has relatively high hydrogen absorption and hydrogen storage capacity.

The invention discloses a method for improving the quality of a laser cladding refractory high-entropy alloy coating, and belongs to the technical field of alloy coatings. The refractory high-entropy alloy coating is composed of WMoTaNb and hydride of Ti or V, the refractory high-entropy alloy coating is a single BCC phase, and the refractory high-entropy alloy coating is prepared through coaxial powder feeding laser cladding. The laser cladding refractory high-entropy alloy coating prepared through an introduction method (solid solution strengthening and in-situ deoxidation) has excellent wear resistance and high-temperature oxidation resistance, the quality and performance of the refractory high-entropy alloy coating are improved through additional powder, and the microhardness of the section of the refractory high-entropy alloy coating reaches up to 674.52 HV0. 2. The coating can be applied to the fields of aerospace, nuclear reactors and the like.

The invention relates to a metal hydride solid hydrogen storage device, in particular to a detachable metal hydride solid hydrogen storage device which comprises a shell, a flange and a blind flange, a hydrogen conveying pipe and the flange are welded to the shell, the hydrogen conveying pipe serves as a hydrogen flow channel, a U-shaped heat exchange pipe and a temperature measuring protective sleeve are welded to the blind flange, and the U-shaped heat exchange pipe serves as the temperature measuring protective sleeve. Hydrogen is absorbed by introducing a hydrogen cylinder into a pipeline system through a pressure reducing valve and then entering a metal hydride solid hydrogen storage device through a hydrogen conveying pipe, so that a first-stage hydrogen absorption process can be completed; a reversible chemical reaction in the hydrogen absorption process is carried out in the forward direction to generate a large amount of heat, if the heat is not discharged in time, the further hydrogen absorption process of the hydrogen storage material can be influenced, at the moment, a certain flow of cooling water is introduced into the upper U-shaped heat exchange pipe by controlling a water path, and the heat generated in the hydrogen storage material is conducted to the wall of the heat exchange pipe through the aluminum annular fins on the heat exchange pipe; and the water is timely taken away by cooling water through convective heat exchange.

A metal hydride compressor (1) for compressing hydrogen gas from a state of lower pressure to a state of higher pressure comprises a first pressure vessel (2), said first pressure vessel (2) containing a first metal alloy capable of absorbing hydrogen gas at a first pressure (p1) in an absorption mode of the first pressure vessel (2) to form a first metal hydride. The first metal hydride is capable of desorbing hydrogen gas at a second pressure (p2), higher than the first pressure (p1), in a desorption mode of the first pressure vessel (2) to release hydrogen gas. The metal hydride compressor (1) further comprises a piping system (3) comprising a first inlet line (4) connected to an inlet (5) of the first pressure vessel (2) for receiving hydrogen gas into the first pressure vessel (20), and a first outlet line (6) connected to an outlet (7) of the first pressure vessel (2) for discharging hydrogen gas from the first pressure vessel (2). The piping system (3) further comprises a first cooling loop (8) that is adapted to cool the first metal alloy in the first pressure vessel (2) when hydrogen gas is absorbed at the first pressure (p1) by the first metal alloy to form a first metal hydride. The first cooling loop (8) comprises a first heat exchanger (9). The piping system (3) further comprises a first heating loop (10) that is adapted to heat the first metal hydride in the first pressure vessel (2) when hydrogen gas is desorbed from the first metal hydride at the second pressure (p2), the first heating loop (10) comprising a second heat exchanger (11). The first cooling loop (8) and the first heating loop (10) each comprise a blower (12) to circulate hydrogen gas through the first cooling loop (8) and the first heating loop (10). The first cooling loop (8) is fluidically connectable to the outlet (7) and to the inlet (5) of the first pressure vessel (2) during the absorption mode such that hydrogen gas being discharged from the outlet (7) of the first pressure vessel (2) via the first outlet line (6) of the first pressure vessel (2) is cooled via the first heat exchanger (9) and is then supplied to the inlet (5) of the first pressure vessel (2) via the first inlet line (4) to cool the first metal alloy as the first metal hydride is formed. The first heating loop (10) is fluidically connectable to the outlet (7) and to the inlet (5) of the first pressure vessel (2) during the desorption mode such that hydrogen gas being discharged from the outlet (7) of the first pressure vessel (2) via the first outlet line (6) is heated via the second heat exchanger (11) and is then supplied to the inlet (5) of the first pressure vessel (2) to heat the first metal hydride as hydrogen gas is desorbed. The piping system (3) further comprises a plurality of first switching valves (13) adapted to either connect the first cooling loop (8) or the first heating loop (10) to the outlet (7) and the inlet (5) of the first pressure vessel (2). The piping system (3) further comprises a supply line (16) adapted to fluidically connect a hydrogen source with the first inlet line(4), wherein the supply line (16) comprises a check valve (17) adapted to prevent a backflow of the hydrogen gas towards the hydrogen source and adapted to let through hydrogen gas towards the inlet (5) of the first pressure vessel (2) at a pressure of at most the first pressure (p1). The piping system (3) further comprises a first discharge line (18) fluidically connected to the first outlet line (6) and comprising a first overflow valve (19) adapted to discharge hydrogen gas having a pressure of at least the second pressure (p2).

The present application provides a solid-state hydrogen storage material and a preparation method and application thereof. Specifically, the preparation method comprises the following steps: (1) ball-milling a magnesium-based alloy powder, a light metal hydride, a nano-carbon material, a composite catalyst powder and an interface modifier to obtain a mixed powder; and (2) sintering the mixed powder under vacuum at 200-350 DEG C for 2-5 hours to obtain a sintered body, wherein: the magnesium-based alloy powder is a Mg-Mn-Al alloy powder; the light metal hydride is a mixture of LiAlH4 and NaBH4; the nano-carbon material is selected from one or more of graphene and carbon nanotubes; the composite catalyst powder is a mixture of TiO2, Fe3O4, CeO2 and La2O3; and the interface modifier is selected from one or more of a silane coupling agent and a titanate coupling agent. The solid-state hydrogen storage material has high hydrogen storage capacity, fast hydrogen absorption and desorption rate and good cycle stability.

Hydrogen storage system for passive discharge of hydrogen gas without employing heater, comprising a plurality of hydrogen storage tanks each containing at least one metal hydride (MH) storage material, a hydrogen gas flow circuit connected to the storage tanks and a control system including pressure sensors (P) and temperature sensors (T) arranged for measuring the pressure and temperature in each storage tank, the gas flow circuit comprising valves (V, V1, . . . Vn) coupling said plurality of storage tanks to an inlet, respectively an outlet of the hydrogen storage system, whereby the inlet and outlet may be common or may be separate. At least a first material storage tank comprises a first metal hydride (MH1) of a first composition and at least a second material storage tank comprises a second metal hydride (MH2) of a second composition.

The invention provides a feeding control method and device for an arsenic hydride reaction kettle, equipment and a storage medium, and belongs to the technical field of arsenic hydride reaction, and the method comprises the following steps: determining an initial feeding mode of raw materials at the initial reaction stage based on the volume of the reaction kettle and an expected reaction molar ratio; the raw materials comprise zinc arsenide and dilute sulphuric acid; the desired reaction molar ratio is the desired molar ratio between zinc arsenide and dilute sulphuric acid; in response to the situation that the pressure change rate in the reaction kettle is smaller than a preset change rate value, the initial feeding mode is switched into a constant-speed feeding mode of raw materials in the middle stage of reaction; in response to the condition that the generation rate of the arsenic hydride is lower than a preset generation rate value, switching the constant-speed feeding mode into a final feeding mode of raw materials at the end of the reaction; according to the arsenic hydride reaction kettle feeding control method and device, the equipment and the storage medium provided by the invention, the feeding opportunity and the feeding speed of the reaction kettle can be accurately grasped.

A device for compressing a medium is equipped with a compressor unit (2) for compressing a drive medium and with a pressure intensifier (13) operatively connected to the compressor unit, in which a drive piston (15) driven by the drive medium and a high-pressure piston (18a, 18b) cooperating with the drive piston (15) for compressing the medium to be compressed is arranged. According to the invention, hydrogen is used as the drive medium, and the compressor unit (2) comprises a hydrogen storage system (3a, 3b) which has a pressure vessel (4a, 4b) equipped with a metal hydride storage medium (7a, 7b) with at least one supply line (5a, 5b, 6a, 6b) for supplying and / or removing hydrogen into or from the pressure vessel (4a, 4b) and a heating device (8a, 8b) for heating the metal hydride storage medium (7a, 7b) in the pressure vessel (4a, 4b).

The invention provides a method for growing an aluminum nitride thick film through a hydride vapor phase epitaxy method, and belongs to the technical field of third-generation semiconductor material preparation. According to the method, an aluminum source area in HVPE equipment is improved, supply of a multi-partition independent control aluminum source is provided, a periodic etching control strategy of an HCl gas channel is introduced, and a nested collaborative epitaxy method of outer-layer aluminum source rotation and inner-layer growth cycle embedded etching is formed. The problems of aluminum source degradation, nozzle blockage and stress accumulation in existing HVPE growth can be effectively solved, and long-time continuous operation of epitaxial AlN of the HVPE equipment is achieved; interruption and replacement operations caused by degradation of the aluminum source in long-time growth are avoided; nozzle area deposition is effectively removed, and the flow field stability is maintained; the stress is dynamically released, the crack occurrence rate is reduced, the film layer integrity is improved, and the method is suitable for HVPE equipment transformation and upgrading.

The invention discloses a high-temperature solid hydrogen storage and SOEC coupling hydrogen production and storage integrated system and method. The system comprises a water supply device, and the end of the water supply device is connected with a suction device; one end of the recovery device is connected with the suction device, and the other end is connected with a reaction device; the SOEC electrolytic reactor is connected with the reaction device, the SOEC electrolytic reactor comprises an anode end and a cathode end, and the anode end is connected with the recovery device; one end of the air delivery device is mounted between the reaction device and the SOEC electrolytic reactor, and the other end of the air delivery device is connected with a hydrogen high-temperature heat recovery device; the first end of the hydrogen medium-temperature heat recoverer is connected with the hydrogen high-temperature heat recovery device, the second end of the hydrogen medium-temperature heat recoverer is connected with the reaction device, the third end of the hydrogen medium-temperature heat recoverer is connected with a condenser, the fourth end of the hydrogen medium-temperature heat recoverer is connected with a dryer, and the condenser is connected with the dryer. Medium-temperature and high-temperature heat energy released in the hydrogen storage process of the high-temperature metal hydride is recycled through the heat recycling device and used for producing high-temperature superheated steam needed by SOEC electrolysis, and the good heat and mass synergistic effect is achieved on the whole.

The invention provides an alkyne selective hydrogenation catalyst with high activity and high selectivity and a preparation method thereof. The catalyst is a compound of metallic nickel and alkali metal hydride and is marked as nickel-alkali metal hydride, high catalytic reaction activity and high olefin selectivity can be both considered by regulating and controlling the proportion of the nickel elementary substance and the alkali metal hydride, and compared with the metallic nickel and the alkali metal hydride as the catalyst, the catalyst has the advantages that the catalytic activity is high; the catalytic activity and the olefin selectivity are greatly improved. The nickel-alkali metal hydride catalyst is suitable for alkyne selective hydrogenation reaction in a high-temperature and high-pressure fixed bed gas phase reaction system, is also suitable for alkyne selective hydrogenation reaction in a high-temperature and high-pressure reaction kettle liquid-solid phase reaction system, and has a good application prospect.