549 results about "Hydride" patented technology

The invention relates to the technical field of powder metallurgy materials, and discloses rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and a preparation method thereof.The die steel is prepared from 4Cr5MoSiV1 pre-alloyed powder, rare earth hydride, boron carbide and porous amorphous carbon powder loaded with a nickel catalyst. The preparation method comprises the steps of material mixing, sheath packaging, graded dynamic reaction thermal devolatilization, hot isostatic pressing densification and heat treatment, in the graded dynamic reaction thermal devolatilization, active hydrogen generated by decomposition of rare earth hydride is used for reducing oxide on the surface of powder, and nickel catalyzed carbon powder is used for capturing water vapor at low temperature to generate CO to be discharged. An oxide film on the surface of the powder is thoroughly removed through in-situ chemical reaction, original particle boundaries are eliminated, meanwhile, a nano strengthening phase with high thermal stability is generated in situ, and the high-temperature strength, impact toughness and tissue compactness of the die steel are remarkably improved.

The invention relates to the technical field of hydrogen energy solid hydrogen storage, and discloses a metal hydride hydrogen storage tank and a circulating hydrogen charging and discharging method.The metal hydride hydrogen storage tank comprises a tank body, the top end of the tank body is communicated with a gas inlet pipe, and the bottom end of the gas inlet pipe extends into the tank body and is rotationally provided with a connecting pipe through a rotating connector; a plurality of circular heat dissipation fins are fixedly connected between the inner walls of the tank body, the bottom end of the connecting pipe penetrates through the heat dissipation fins to be rotationally connected with the bottom end of the tank body, and a plurality of air holes are formed in the surface of each heat dissipation fin; four telescopic rods are fixedly connected to the top wall of the interior of the tank body, the hydrogen storage tank drives the transmission assembly to drive the connecting pipe and the stirring plate to rotate through movement of the piston, metal hydride is prevented from caking, hydrogen is dispersed more evenly through inclined air outlet holes, and the hydrogen storage efficiency is improved; the circular heat dissipation fins are provided with air holes, so that heat dissipation is achieved, and circulation of hydrogen is not blocked.

The invention discloses a preparation method of niobium-tungsten alloy spherical powder and a 3D printing method of the niobium-tungsten alloy spherical powder, and belongs to the technical field of refractory metal material preparation.The preparation method comprises the steps that niobium, tungsten, molybdenum and zirconium refractory metal raw materials are smelted to obtain cast ingots with uniform components, and hydride powder is formed after hydrotreating and mechanical crushing; spherical powder is prepared by adopting a plasma spheroidizing technology, then dehydrogenation is performed for 1-3 hours at the temperature of 450-750 DEG C, magnesium powder is added, treatment is performed for 2-5 hours in an inert atmosphere at the temperature of 800-1100 DEG C, and finally the low-oxygen niobium-tungsten alloy spherical powder with the oxygen content lower than 120 ppm is obtained. Compared with a traditional process, the spheroidizing treatment is innovatively carried out before the dehydrogenation and oxygen reduction process, the deoxidation efficiency is improved through the relatively small specific surface area of spherical powder, and oxygen content control is achieved in combination with magnesium powder heat treatment. The problems of high oxygen content and low powder yield in a traditional process are solved, and material support is provided for high-performance niobium-tungsten alloy components in the fields of aerospace, nuclear power and the like.

The present application provides a solid-state hydrogen storage material and a preparation method and application thereof. Specifically, the preparation method comprises the following steps: (1) ball-milling a magnesium-based alloy powder, a light metal hydride, a nano-carbon material, a composite catalyst powder and an interface modifier to obtain a mixed powder; and (2) sintering the mixed powder under vacuum at 200-350 DEG C for 2-5 hours to obtain a sintered body, wherein: the magnesium-based alloy powder is a Mg-Mn-Al alloy powder; the light metal hydride is a mixture of LiAlH4 and NaBH4; the nano-carbon material is selected from one or more of graphene and carbon nanotubes; the composite catalyst powder is a mixture of TiO2, Fe3O4, CeO2 and La2O3; and the interface modifier is selected from one or more of a silane coupling agent and a titanate coupling agent. The solid-state hydrogen storage material has high hydrogen storage capacity, fast hydrogen absorption and desorption rate and good cycle stability.

The invention provides a feeding control method and device for an arsenic hydride reaction kettle, equipment and a storage medium, and belongs to the technical field of arsenic hydride reaction, and the method comprises the following steps: determining an initial feeding mode of raw materials at the initial reaction stage based on the volume of the reaction kettle and an expected reaction molar ratio; the raw materials comprise zinc arsenide and dilute sulphuric acid; the desired reaction molar ratio is the desired molar ratio between zinc arsenide and dilute sulphuric acid; in response to the situation that the pressure change rate in the reaction kettle is smaller than a preset change rate value, the initial feeding mode is switched into a constant-speed feeding mode of raw materials in the middle stage of reaction; in response to the condition that the generation rate of the arsenic hydride is lower than a preset generation rate value, switching the constant-speed feeding mode into a final feeding mode of raw materials at the end of the reaction; according to the arsenic hydride reaction kettle feeding control method and device, the equipment and the storage medium provided by the invention, the feeding opportunity and the feeding speed of the reaction kettle can be accurately grasped.

A device for compressing a medium is equipped with a compressor unit (2) for compressing a drive medium and with a pressure intensifier (13) operatively connected to the compressor unit, in which a drive piston (15) driven by the drive medium and a high-pressure piston (18a, 18b) cooperating with the drive piston (15) for compressing the medium to be compressed is arranged. According to the invention, hydrogen is used as the drive medium, and the compressor unit (2) comprises a hydrogen storage system (3a, 3b) which has a pressure vessel (4a, 4b) equipped with a metal hydride storage medium (7a, 7b) with at least one supply line (5a, 5b, 6a, 6b) for supplying and / or removing hydrogen into or from the pressure vessel (4a, 4b) and a heating device (8a, 8b) for heating the metal hydride storage medium (7a, 7b) in the pressure vessel (4a, 4b).

The invention provides a method for growing an aluminum nitride thick film through a hydride vapor phase epitaxy method, and belongs to the technical field of third-generation semiconductor material preparation. According to the method, an aluminum source area in HVPE equipment is improved, supply of a multi-partition independent control aluminum source is provided, a periodic etching control strategy of an HCl gas channel is introduced, and a nested collaborative epitaxy method of outer-layer aluminum source rotation and inner-layer growth cycle embedded etching is formed. The problems of aluminum source degradation, nozzle blockage and stress accumulation in existing HVPE growth can be effectively solved, and long-time continuous operation of epitaxial AlN of the HVPE equipment is achieved; interruption and replacement operations caused by degradation of the aluminum source in long-time growth are avoided; nozzle area deposition is effectively removed, and the flow field stability is maintained; the stress is dynamically released, the crack occurrence rate is reduced, the film layer integrity is improved, and the method is suitable for HVPE equipment transformation and upgrading.

The invention relates to the technical field of ferrous metallurgy and solid waste treatment, in particular to an efficient utilization production process of iron-containing ore powder and slag powder, which comprises the following steps: preheating the iron-containing ore powder ground by a grinder by a preheater, and feeding the iron-containing ore powder into a reduction furnace; a fan provides aerodynamic force, high-temperature gas obtained after air is preheated by a hot-blast stove and hydrocarbon such as pulverized coal sprayed from a pulverized coal feeding port are combusted, and generated reducing gas such as CO and H2 enters a reduction furnace through an annular exhaust outlet of a hearth and is subjected to a reduction reaction with iron-containing ore powder entering the reduction furnace and the high-temperature gas such as CO and H2 at high temperature; and reducing into metal iron powder and slag. Iron ore powder does not need to be made into prefabricated lump ores such as pellets and sinter, and dependence of a blast furnace on metallurgical coking coal is avoided; iron ore powder can be directly used for producing metal iron powder, water is saved, and the risk that high-temperature molten iron explodes when encountering water is eliminated; green hydrogen can be used as a reducing agent, and the method is a preferable scheme in the ferrous metallurgy industry.

The embodiment of the invention discloses a composite shielding plate and a preparation method thereof, and the composite shielding plate comprises a cladding which is provided with an accommodation space, and the accommodation space is in a vacuum state; the shielding material is arranged in the accommodating space; wherein the shielding material comprises a neutron moderation base material, and the cladding is made of a boron-containing metal material; or the shielding material comprises a neutron moderation base material and a neutron absorption base material, the cladding is made of a metal material, the neutron moderation base material comprises rare earth hydride, and the neutron absorption base material comprises boron-containing ceramic. The composite shielding plate provided by the embodiment of the invention not only comprises the neutron moderation base material which is high in hydrogen content and excellent in temperature resistance so as to effectively moderate fast neutrons, but also is combined with the neutron absorption base material containing boron atoms so as to efficiently absorb thermal neutrons, so that the complete neutron moderation-absorption integrated shielding performance of the composite shielding plate is realized; and stable shielding performance can be provided at the temperature of 300-1000 DEG C.

The invention belongs to the technical field of heat storage, and provides a paired metal hydride storage tank heat storage system and method for solar power generation. Wherein the paired metal hydride storage tank heat storage system is respectively communicated with the solar concentrating system and the electric power system through a heat exchange medium pipeline; the paired metal hydride storage tank heat storage system is configured in a multi-stage tandem mode, and at least two stages of heat storage systems are sequentially arranged in the flowing direction of heat exchange fluid in the heat output process. Under the operation requirement higher than the threshold load, all levels of heat storage systems are in an activated state, heat exchange fluid flows through each level of system according to a preset path, and heat released by each level of heat storage system is absorbed step by step; and under the condition that the load is lower than the threshold value for operation or the set working condition requirement, at least one stage of heat storage system bypass directly obtains the needed heat from other stages of heat storage systems.

The invention discloses a self-adaptive fixing structure for a nickel-hydrogen battery, and belongs to the technical field of batteries. The upper clamping mechanism is fixed at the top end of the inner wall of the shell; the lower clamping mechanism is fixed at the bottom end of the inner wall of the shell; the plurality of battery pieces are stacked and fixed between the upper clamping mechanism and the lower clamping mechanism; and the spring penetrates through the plurality of battery pieces and is detachably connected between the upper clamping mechanism and the lower clamping mechanism. According to the battery fixing structure, the spring is arranged between the telescopic upper clamping mechanism and the telescopic lower clamping mechanism, and battery pieces can be stacked between the upper clamping mechanism and the lower clamping mechanism according to actual requirements, so that the battery capacity is adjusted, the adaptive capacity of the battery fixing structure is improved, and meanwhile, certain buffering and damping effects are considered.

The invention provides a method for growing a (310) oriented beta-Ga2O3 single crystal thick film on a sapphire substrate. The method comprises the following steps: cleaning the sapphire substrate and then carrying out annealing treatment; and with hydrogen chloride gas, gallium metal and oxygen as reaction sources, epitaxially growing a (310) oriented beta-Ga2O3 single crystal thick film on the treated sapphire substrate by using a hydride vapor phase epitaxy method. According to the method for growing the (310) oriented beta-Ga2O3 single crystal thick film on the sapphire substrate, the process is simple, operation is easy, controllability is high, the obtained (310) oriented beta-Ga2O3 single crystal thick film is smooth in surface, compact and uniform in thickness, the crystallinity of the single crystal film layer is high, and the growth requirement of a single crystal epitaxial film layer of tens of micrometers can be met; in addition, the method provided by the invention can realize large-batch and large-scale production of the (310) oriented beta-Ga2O3 single crystal thick film, and meets the device preparation requirements.

The invention discloses a preparation method of an R-T-B rare earth permanent magnet, and the method comprises the following steps: 1, coating with a coating: coating an S1 region on the surface of a permanent magnet substrate with a first coating to obtain a first coating region S1, and coating an S2 region on the surface of the permanent magnet substrate with a second coating to obtain a second coating region S2; the first coating area S1 is smaller than or equal to S, the second coating area S2 is smaller than or equal to S, S is the magnet surface area where the coating face is located, and the first coating and the second coating are composed of one or more components of pure metal containing Dy and / or Tb, hydride, fluoride and oxide; and 2, carrying out grain boundary diffusion treatment on the magnet obtained in the step 1, and carrying out aging treatment after cooling to obtain the R-T-B rare earth permanent magnet. The method has the advantages that diffusion of heavy rare earth in a grain main phase can be reduced, the use amount of the heavy rare earth is reduced, and the coercive force of a selected area can be further enhanced.

A method of producing a chemical hydride is described and which includes selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of a hydrocarbon; and reacting the composition with the source of the hydrocarbon to generate a chemical hydride.

The invention discloses a solid hydrogen storage and fuel cell energy coupling system and method, and belongs to the technical field of fuel cells, the system comprises a solid hydrogen storage module, a combustion cell, a hydrogen storage pipeline, a hydrogen delivery pipeline and a circulation pipeline, the hydrogen storage pipeline is used for inputting hydrogen into the solid hydrogen storage module, the hydrogen conveying pipeline is used for conveying hydrogen output by the solid hydrogen storage module to the fuel cell; the solid hydrogen storage module comprises a plurality of reactors, each reactor is of a double-layer structure composed of a first cavity and a second cavity, the first cavity is filled with a metal hydride bed and a heat exchange pipe penetrating through the metal hydride bed, and first heat exchange fins distributed in the metal hydride bed are installed on the heat exchange pipe; a phase-change material and spiral second heat exchange fins distributed in the phase-change material are arranged in the second cavity; each heat exchange pipe is connected into a circulating pipeline penetrating through the fuel cell, and a circulating medium circularly flowing in the circulating pipeline transfers heat generated by power generation of the fuel cell into the metal hydride bed to promote hydrogen release.

The invention discloses a hydrogen energy production and production-and-use distributed energy supply system, which relates to the technical field of new energy, and comprises a hydrogen production module which comprises a proton exchange membrane electrolytic tank, an alkaline electrolytic tank and a solid oxide electrolytic tank and runs through a three-mode collaborative architecture, in combination with a light-electricity-heat synergistic catalysis device and a wastewater or industrial tail gas coupling hydrogen production device, the hydrogen storage and safety management module comprises a metal hydride hydrogen storage unit, a metal organic framework material hydrogen storage unit and a liquid organic hydrogen storage unit. According to the invention, multi-source, high-efficiency and low-cost hydrogen production is realized through the hydrogen production module with a three-mode collaborative architecture in combination with light-electricity-heat collaborative catalysis and wastewater / industrial tail gas coupling hydrogen production, and meanwhile, a solid oxide fuel cell and micro gas turbine combined cycle, a hydrogen combustion turbine direct drive and a multi-type energy storage unit in the energy supply module realize multi-source, high-efficiency and low-cost hydrogen production. And in cooperation with waste heat-cold energy gradient utilization, the energy conversion efficiency and the comprehensive energy utilization rate are greatly improved.

The invention provides metal-hydrogen modified porous carbon and a preparation method thereof, a silicon-carbon composite material and a preparation method thereof, and a battery, and the preparation method of the metal-hydrogen modified porous carbon comprises the following steps: mixing an aldehyde compound, a phenolic compound, a metal source and a catalyst, and carrying out heating treatment to prepare modified phenolic resin; carrying out carbonization treatment on the modified phenolic resin to prepare metal-doped porous carbon; mixing the metal-doped porous carbon with a metal hydride reducing agent, and performing reduction treatment to prepare metal-hydrogen modified porous carbon; wherein the mass ratio of metal elements to phenolic compounds in the metal source is (2-5): 100. A proper amount of metal-hydrogen bonds are introduced into the inner surface of a porous carbon pore structure; when the porous carbon is subsequently subjected to silicon deposition, low-temperature, uniform and confined deposition of nano silicon in a porous carbon matrix is facilitated, and the silicon-carbon composite material with low expansion rate and excellent electrochemical performance is prepared.

The invention discloses a slurry hydrogen storage fuel cell system, which comprises: a hydrogen storage slurry circulation module for storing and circulating a slurry hydrogen storage material; the slurry hydrogen storage material comprises organic liquid and metal hydride; the fuel cell adopts a liquid metal anode; the fuel cell comprises an anode inlet and an anode outlet; a separator for separating the anode discharge; the metal hydride powder feeder is used for supplementing metal hydride powder to the hydrogen storage slurry circulating module; wherein the slurry hydrogen storage material reacts on a liquid metal anode interface to generate electric energy and form organic liquid vapor; and the organic liquid vapor is discharged into the separator from the anode outlet, is separated, is conveyed into the hydrogen storage slurry circulating module, and is mixed with the metal hydride powder from the metal hydride powder feeder to form a slurry hydrogen storage material. According to the invention, direct power generation of the slurry hydrogen storage material on the fuel cell anode interface is realized, and the power density of the system is greatly improved.

To provide an active metal brazing material which can suppress variation in joining.SOLUTION: An active metal brazing material contains one or two kinds of Ti component particles, CuSn alloy particles and CuIn alloy particles, wherein the Ti component particles are composed of one or more kinds of Ti particles and Ti hydride particles, the CuSn alloy particles are composed of Cu and Sn, when the total of Cu and Sn is 100 pts.mass, Cu is 30 pts.mass or more and 80 pts.mass or less, and Sn is 20 pts.mass or more and 70 pts.mass or less, the CuIn alloy particles are composed of Cu and In, and when the total of Cu and In is 100 pts.mass, Cu is 30 pts.mass or more and 80 pts.mass or less, and In is 20 pts.mass or more and 70 pts.mass or less.SELECTED DRAWING: Figure 1

The invention discloses a rare earth hydride doped single-phase refractory high-entropy alloy coating and a preparation method, and belongs to the technical field of alloy coatings. According to the method, rare earth hydride is mainly used as a doping agent and is combined with a cladding material to purify a molten pool and refine grains to optimize the structure and performance of the coating, so that the quality of the single-phase refractory high-entropy alloy coating is improved. The preparation method comprises the steps of matrix pretreatment, preparation of rare earth hydride and refractory high-entropy alloy mixed powder, preparation of the refractory high-entropy alloy coating through laser cladding and the like, and cracks and defects of the coating are remarkably reduced. A series of embodiments verify that the quality of the single-phase refractory high-entropy alloy coating can be effectively improved, and the application prospects of the single-phase refractory high-entropy alloy coating in the fields of aviation, spaceflight, weapons and the like are widened.

The invention discloses a hydrogen storage reactor based on synergistic heat management of a phase change material and a spiral heat exchange tube. The hydrogen storage reactor comprises an outer cylinder, a middle cylinder, an inner cylinder, a sealing cover and the spiral heat exchange tube. The outer cylinder, the middle cylinder and the inner cylinder divide the hydrogen storage reactor into three layers from inside to outside, and the inner layer and the outer layer are filled with phase change materials; the spiral heat exchange tube is arranged on the middle layer, and metal hydride is filled around the spiral heat exchange tube; in the hydrogen storage process, hydrogen flows into the middle layer of the reactor from an inlet in the center of the top end of the reactor and reacts with metal hydride; heat exchange fluid flows into the spiral heat exchange tube from a top inlet of the reactor, absorbs heat generated by reaction and flows out from a bottom outlet of the reactor; the phase change materials filled in the inner layer and the outer layer absorb heat generated by reaction and store the heat. The spiral heat exchange pipe is adopted for accelerating heat exchange, and the hydrogen storage and release rate is increased; the phase change material can store part of heat generated by the hydrogen storage reaction and release the heat during hydrogen release, the interlayer type arrangement can increase the heat exchange area, and the heat storage and release efficiency is improved.

The invention discloses a method for preparing a carbon-coated lithium titanate negative electrode material by a one-step solid phase method, and belongs to the technical field of lithium ion battery materials. The method comprises the following steps: uniformly mixing and dispersing carbon-containing lithium salt, titanium salt and metal hydride to obtain a solid mixture; and roasting the obtained solid mixture in a protective atmosphere to obtain the carbon-coated lithium titanate negative electrode material. According to the preparation method, a certain amount of metal hydride is added into the reaction raw materials, a high-temperature solid-phase method is used, and carbon in the carbon-containing lithium source is reduced by the metal hydride to serve as a carbon source, so that the carbon-coated lithium titanate negative electrode material can be directly synthesized in one step, additional carbon sources and technological processes are not needed, and the preparation technology is greatly simplified.

The present invention discloses a rapid detection method for sodium polydisulfide (PDPS). The method comprises preparing a buffer solution and an Elma color developer; preparing multiple sets of sodium polydisulfide (PDPS) solutions of different concentrations; pretreating the sodium polydisulfide (PDPS) solutions with an excess of a boron hydride compound as a reducing agent to reduce the sodium polydisulfide to a thiol-containing compound; and removing the excess reducing agent. An absorbance test is performed to establish a standard curve for the concentration and absorbance of the brightener, and the concentration of the sodium polydisulfide (PDPS) in the electrolyte to be tested is measured using the established standard curve. The method uses a boron hydride compound as a reducing agent and utilizes ultraviolet-visible spectroscopy to rapidly detect the content of the brightener, sodium polydisulfide (PDPS). The method is convenient and simple to operate, provides highly accurate test data, and is applicable to the detection of electroplating bath additives in various systems.

The utility model provides a heat digestion reduction system for liquid chromatography and atomic fluorescence is used together, including heat digestion device, cooling device, sucking pump, gas -liquid separator, digestion agent container and reducing agent container. Heat digestion device includes digestion pipeline and heating device, and heating device is used for heating digestion pipeline. Cooling device includes heat dissipation board and cooling pipeline, and heat dissipation board installs on cooling pipeline and is used for heat dissipation to cooling pipeline. The utility model discloses compared with prior art in ultraviolet lamp digestion, and the higher stability of digestion efficiency is not needed to consider the risk of ultraviolet lamp breakage, and heating temperature will also reduce the memory effect in pipeline, improve hydride generation efficiency. Through setting up cooling device to the mixed liquid of measuring in pipeline after completing heating digestion is cooled, make the aerosol that generates because of heating digestion quick liquefaction, effectively reduce the system pressure in pipeline, avoid the risk of pipeline burst.

A curable composition for preparing a compressible silicone foam comprises: an alkenyl group-containing component comprising an alkenyl double-terminated polyorganosiloxane, an alkenyl substituted MQ polyorganosiloxane, and an alkenyl substituted copolymerized organosiloxane; and a hydrogen radical-containing component, wherein the hydrogen radical-containing component comprises a hydrogen radical-substituted polyorganosiloxane. The curable composition includes a curing catalyst; a filler composition; and a blowing agent. A compressible foam made from the curable composition and a method of making a compressible foam from the curable composition are also disclosed.

The invention belongs to the technical field of waste resource utilization, and particularly relates to a method for preparing crude arsenic by recycling arsenic-containing hydrogen gas. The method comprises the following steps: in an oxygen-isolated environment, introducing arsenic hydride-containing gas into a sulfuric acid aqueous solution with the mass fraction of 70%-98%, carrying out an oxidation-reduction reaction to obtain slurry containing crude arsenic, and carrying out solid-liquid separation to obtain a crude arsenic product. According to the method, the arsenic hydride gas can be directly converted into the arsenic elementary substance, so that the recovery of arsenic in the arsenic-containing material is realized. Concentrated sulfuric acid can fully oxidize arsenic hydride in a specific concentration range, and the arsenic hydride is prevented from being excessively oxidized into arsenic trioxide. Compared with other acidic or oxidizing solutions, the method has the advantages that the crude arsenic product with the purity larger than or equal to 95% can be directly obtained under the normal-temperature and normal-pressure conditions, the generated by-product dilute sulphuric acid can be circularly used for absorbing arsenic hydride again or used for leaching materials such as zinc arsenate-containing smoke dust to generate new arsenic hydride-containing gas, and therefore a closed-loop circulation process is formed; and efficient resource recovery and environment-friendly treatment are realized. The method is short in technological process, low in equipment requirement and small in energy consumption, the crude arsenic can be used as a precursor for preparing the high-purity arsenic, and a feasible scheme is provided for safety treatment and resource utilization of arsenic hydride in the industrial processes of metallurgy, wet refining and the like.

The invention relates to preparation and application of a metal hydride serving as a lithium ion battery negative electrode material. The lithium ion battery negative electrode material is obtained by mixing Ti3C2 and MgH2 serving as raw materials and then carrying out dehydrogenation-hydrogenation treatment. Compared with the prior art, the lithium ion negative electrode material provided by the invention is simple in preparation method, and the obtained product is high in purity, uniform in size distribution and good in electrochemical performance, and can be further applied to the fields of battery materials, supercapacitors and the like.

The invention discloses a vortex channel hydrogen storage reactor of a fluid streaming gradual change hydrogen storage tank unit, and belongs to the field of chemical reactor design. The whole reactor is a cylindrical shell, a heat exchange fluid inlet is formed in the center of the upper side of the shell, a hydrogen inlet is formed in a left end shell cover, and a heat exchange fluid outlet is formed in a right end shell cover; the heat exchange fluid channel is in a vortex shape, the multiple hydrogen storage tank units are sequentially arranged in the center of a flow channel of the vortex channel, and the diameter of the hydrogen storage tank is evenly reduced from the shell to the center position. Hydrogen enters the bed layer through a hydrogen pipe in the hydrogen storage tank and reacts with the metal hydride; meanwhile, the heat exchange fluid in the vortex channel flows around the hydrogen storage tank unit in the axial direction for heat exchange and then flows out through an outlet; the hydrogen storage tank has the advantages of excellent heat and mass transfer performance, uniform bed temperature of the hydrogen storage tank, small pressure-bearing stress of the tank body, synchronous reaction process of each hydrogen storage tank, high reliability and long service life, and is suitable for hydrogenation / dehydrogenation reaction of metal hydride with high hydrogen storage capacity requirement and larger reaction heat effect.

The application discloses an alkali metal hydride, a preparation method and application, and at least comprises the following steps: under a non-active atmosphere, ball milling raw materials containing alkali metal, an organic solvent and hydrogen to obtain the alkali metal hydride. The alkali metal hydride disclosed by the application has uniform particle size and wide application prospects in the fields of hydrogen storage, heat storage and catalytic synthesis; the preparation method is simple, suitable for large-scale and low-cost amplification, and has good development prospects and practical application value.

The invention discloses a preparation method of mesophase pitch regulated and controlled by plasma-assisted directional bromination and catalytic debromination, and belongs to the technical field of high-value utilization of heavy oil and preparation of advanced carbon materials. The method comprises the following steps: (1) by taking aromatic hydrocarbon-rich heavy oil as a raw material, carrying out low-temperature plasma-assisted liquid-phase bromination reaction, and directionally introducing bromine atoms on an aromatic ring as activation and orientation sites, so as to construct bromination modified linear precursor asphalt; (2) carrying out supported metal hydride catalytic debromination-directional polycondensation reaction to synchronously realize total removal of bromine atoms, linear coupling between aromatic rings and improvement of molecular planarity, so as to prepare pre-mesophase pitch; and (3) carrying out heat treatment in a strong and uniform magnetic field, and enabling the liquid crystal state molecules to be highly and orderly arranged along the direction of the magnetic field by virtue of the orientation effect of the magnetic field on the pi electron cloud, so as to finally form the spinnable mesophase pitch with a wide-area streamline structure. The method realizes full-chain accurate regulation and control from molecular structure design to macroscopic orientation, and the prepared mesophase pitch has the characteristics of high anisotropic content (greater than 98%), moderate softening point (260-300 DEG C), highly ordered molecular arrangement and low quinoline insoluble content (less than 0.1%). The process is novel, and a brand new path is provided for preparing the high-performance mesophase pitch.