68 results about "Chemical hydrides" patented technology

An apparatus, system, and method are disclosed for generating a gas. One or more liquid permeable pouches each define a cavity that contains a solid anhydrous reactant, such as a chemical hydride. A reaction chamber made of a heat, chemical and / or pressure resistant material receives the one or more pouches from a pouch feeder that transfers the one or more pouches into the reaction chamber successively at a feed rate. One or more liquid sources inject a liquid reactant into the reaction chamber so that the liquid reactant contacts a portion of the one or more pouches. The one or more liquid sources inject the liquid reactant at an injection rate that corresponds to the feed rate. A gas outlet releases a gas, such as hydrogen, oxygen, ammonia, borazine, nitrogen, or a hydrocarbon, that is produced by a reaction between the solid reactant and the liquid reactant.

A system is disclosed for hydrogen generation based on hydrolysis of solid chemical hydrides with the capability of controlled startup and stop characteristics wherein regulation of acid concentration, acid feed rate, or a combination of both control the rate of hydrogen generation. The system comprises a first chamber for storing a solid chemical hydride and a second chamber for storing an acidic reagent. The solid chemical hydride is a solid metal borohydride having the general formula MBH4, where M is selected from the group consisting of alkali metal cations, alkaline earth metal cations, aluminum cation, zinc cation, and ammonium cation. The acidic reagent may comprise inorganic acids such as the mineral acids hydrochloric acid, sulfuric acid, and phosphoric acid, and organic acids such as acetic acid, formic acid, maleic acid, citric acid, and tartaric acid, or mixtures thereof.

An apparatus, system, and method are disclosed to generate electric power from a chemical hydride. A fuel cartridge produces hydrogen by reacting a liquid with a chemical hydride. A fuel cell stack generates electric power using an oxygen source and the produced hydrogen. An electric power storage device is coupled with the fuel cell stack. The electric power storage device stores and supplies electric power. One or more liquid sources inject the liquid into the fuel cartridge at a variable rate. A controller calculates a liquid injection rate for the one or more liquid sources based on power demands of an electric load.

A hydrogen generation and storage method for producing and storing hydrogen at a home or business site that enables refueling hydrogen to a personal vehicle at a convenient location. The method comprises (a) operating a solar energy conversion subsystem to capture and convert solar radiation into both electrical energy and thermal energy; (b) operating a fuel cell electrolyzer that uses the converted electrical energy and thermal energy to split water into hydrogen and oxygen wherein the fuel cell electrolyzer operates at a temperature between 80° C. and 300° C.; and (c) operating a hydrogen storage means to store the generated hydrogen. The hydrogen storage means preferably comprises (1) a hydrogen storage container comprising a metal hydride, chemical hydride, or other solid or liquid phase material as a storage medium to capture and store the generated hydrogen; and (2) control means to regulate the uptake of hydrogen in the storage container.

Hydrogen storage fuel compositions comprising a mixture of at least one chemical hydride compound and at least one compound, polymer, or salt that acts as a water surrogate source, and methods for thermally initiated hydrogen generation from fuel compositions, are disclosed. The water surrogate source / chemical hydride compositions are preferably solids, and may be powders, caplets, tablets, pellets or granules, for example. The water surrogate source / chemical hydride compositions may comprise alternating layers of the chemical hydride and of the water surrogate source.

Hydrogen generators and power module systems that use solid chemical hydrides and acidic reagents for hydrogen storage and generation on demand are disclosed. The generators incorporate mechanisms for controlling the contact between solid chemical hydride and acidic reagents to control the rate of hydrogen generation and characteristics of the reaction products, including bulk density. The preferred systems of the present invention combine functions of fuel reagent storage, reaction chamber, and gas-liquid separation into a minimum number of components to reduce the balance of plant of hydrogen generation systems.

A method and apparatus for forming a chemical hydride is described and which includes a pseudo-plasma-electrolysis reactor which is operable to receive a solution capable of forming a chemical hydride and which further includes a cathode and a movable anode, and wherein the anode is moved into and out of fluidic, ohmic electrical contact with the solution capable of forming a chemical hydride and which further, when energized produces an oxygen plasma which facilitates the formation of a chemical hydride in the solution.

The present disclosure generally relates to an on-demand hydrogen gas generation device, suitable for use in a fuel cell, which utilizes water electrolysis, and more particularly galvanic cell corrosion, and / or a chemical hydride reaction, to produce hydrogen gas. The present disclosure additionally relates to such a device that comprises a switching mechanism that has an electrical current passing therethrough and that repeatedly and reversibly moves between a first position and a second position when exposed to pressure differential resulting from hydrogen gas generation, in order to (1) alter the rate at which hydrogen gas is generated, such that hydrogen gas is generated on an as-needed basis for a fuel cell connected thereto, and / or (2) ensure a substantially constant flow of hydrogen gas is released therefrom. The present disclosure additionally or alternatively relates to such an on-demand hydrogen gas generation device that comprises a gas management system designed to maximize the release or evolution of hydrogen gas, and in particular dry hydrogen gas, therefrom once it has been formed, thus maximizing hydrogen gas output. The present disclosure is still further directed to a fuel cell comprising such an on-demand hydrogen gas generation device, and in particular a fuel cell designed for small-scale applications.

A system is disclosed to generate electric power from a chemical hydride. A fuel cartridge produces hydrogen by reacting a liquid with a chemical hydride. A fuel cell stack generates electric power using an oxygen source and the produced hydrogen. An electric power storage device is coupled with the fuel cell stack. The electric power storage device stores and supplies electric power. One or more liquid sources inject the liquid into the fuel cartridge at a variable rate. A controller calculates a liquid injection rate for the one or more liquid sources based on power demands of an electric load.

The present invention discloses a method and system for charging a metal hydride bed, wherein the metal hydride bed contains a hydrogen storage material. The metal hydride bed is charged using a chemical hydride slurry having a metal hydride, a stabilizing agent and water. As the slurry contacts the metal hydride bed, a catalyst in the metal hydride bed promotes a reaction between the metal hydride of the slurry and water. The reaction produces atomic hydrogen and byproducts. At least a portion of the atomic hydrogen is absorbed by the hydrogen storage material and the remaining atomic hydrogen is disposed from the system or used as fuel in a hydrogen fueled apparatus, such as a fuel cell.

A chemical hydride liquid reactant distribution mixture is provided. The mixture includes a fuel mixture having at least one hydride and at least one activating agent. The invention further includes a liquid-distributing agent (LDA), a form-stabilizing agent, and at least one anti-caking agent. The liquid reactant distribution mixture reduces caking and precipitation while promoting liquid reactant distribution, where the chemical hydride liquid reactant distribution mixture generates hydrogen via hydrolysis.

The present disclosure generally relates to an on-demand hydrogen gas generation device, suitable for use in a fuel cell, which utilizes water electrolysis, and more particularly galvanic cell corrosion, and / or a chemical hydride reaction, to produce hydrogen gas. The present disclosure additionally relates to such a device that comprises a switching mechanism that has an electrical current passing therethrough and that repeatedly and reversibly moves between a first position and a second position when exposed to pressure differential resulting from hydrogen gas generation, in order to (1) alter the rate at which hydrogen gas is generated, such that hydrogen gas is generated on an as-needed basis for a fuel cell connected thereto, and / or (2) ensure a substantially constant flow of hydrogen gas is released therefrom. The present disclosure additionally or alternatively relates to such an on-demand hydrogen gas generation device that comprises a gas management system designed to maximize the release or evolution of hydrogen gas, and in particular dry hydrogen gas, therefrom once it has been formed, thus maximizing hydrogen gas output. The present disclosure is still further directed to a fuel cell comprising such an on-demand hydrogen gas generation device, and in particular a fuel cell designed for small-scale applications.

A preferred embodiment of the present invention is a hydrogen gas storage and supply method, comprising (a) providing a dry, solid-state hydrogen fuel source comprising a solid metal hydride or chemical hydride and a reaction-controlling agent in a solid state, wherein the hydride and the reaction-controlling agent are mixed at a desired proportion; and (b) delivering a desired amount of a liquid reactant to contact and react with a desired amount of the solid-state fuel source to produce hydrogen gas continuously or intermittently on demand, responsive to the needs of a fuel cell.

The present disclosure generally relates to an on-demand hydrogen gas generation device, suitable for use in a fuel cell, which utilizes water electrolysis, and more particularly galvanic cell corrosion, and / or a chemical hydride reaction, to produce hydrogen gas. The present disclosure additionally relates to such a device that comprises a switching mechanism that has an electrical current passing therethrough and that repeatedly and reversibly moves between a first position and a second position when exposed to pressure differential resulting from hydrogen gas generation, in order to (1) alter the rate at which hydrogen gas is generated, such that hydrogen gas is generated on an as-needed basis for a fuel cell connected thereto, and / or (2) ensure a substantially constant flow of hydrogen gas is released therefrom. The present disclosure additionally or alternatively relates to such an on-demand hydrogen gas generation device that comprises a gas management system designed to maximize the release or evolution of hydrogen gas, and in particular dry hydrogen gas, therefrom once it has been formed, thus maximizing hydrogen gas output. The present disclosure is still further directed to a fuel cell comprising such an on-demand hydrogen gas generation device, and in particular a fuel cell designed for small-scale applications.

The invention relates to a hydrogen storage and production technology, in particular to a device and a method for chemical hydride catalytic-hydrolysis hydrogen production suitable for an onboard hydrogen source. The hydrogen production device mainly comprises a catalytic reaction chamber provided with a heat exchanger, a gas-liquid separator, a fuel pump and a controlling unit, and the hydrogen production method is used for controlling the contact and the separation between liquid fuel and catalyst to achieve the purpose of prompt hydrogen production as required. Since the heat exchanger is additionally arranged at the periphery or inside the catalytic reaction chamber, the heat from hydrolysis reaction is effectively utilized, the initial temperature of the liquid fuel is remarkably improved, the hydrogen-production rate of the device, the fuel conversion ratio and the system energy efficiency are greatly improved; and in addition, due to the design of the controlling unit, the continuous automatic adjustment of the delivery rate of the liquid fuel is realized, the stable hydrogen pressure of the system is ensured, and the hydrogen-storage density of the device is improved when the hydrogen supply demand at the hydrogen use terminal is responded in real time. The provided device for prompting hydrogen production can provide the onboard hydrogen source for hydrogen fuel-cell vehicles and various military and civil portable power supplies.

A method of producing hydrogen is disclosed and which includes providing a first composition; providing a second composition; reacting the first and second compositions together to produce a chemical hydride; providing a liquid and reacting the chemical hydride with the liquid in a manner to produce a high pressure hydrogen gas and a byproduct which includes the first composition; and reusing the first composition formed as a byproduct in a subsequent chemical reaction to form additional chemical hydride.

An apparatus is disclosed to generate hydrogen. A liquid permeable material with one or more cavities contains a solid anhydrous chemical hydride and an anhydrous activating agent. A housing that is heat and pressure resistant houses the liquid permeable material, and a liquid. One or more liquid sources inject the liquid into the housing such that the liquid contacts at least a portion of the liquid permeable material. A gas outlet port releases hydrogen gas produced by a reaction comprising the solid anhydrous chemical hydride, the anhydrous activating agent, and the liquid. A hydrogen output regulator controls the amount of hydrogen gas that the gas outlet port releases.

A chemical hydride hydrogen generation system and an energy system incorporating the same are provided. The hydrogen generation system has: a storage means for storing a chemical hydride solution; a reactor containing a catalyst; and a pump for supplying the chemical hydride solution from the storage means to the reactor so that the chemical hydride solution reacts to generate hydrogen in the presence of the catalyst. The hydrogen is supplied to a fuel cell stack. Additionally, a heat transfer circuit is provided including a heat transfer fluid that is circulated through the cooling channels of the fuel cell stack to effect heating thereof on startup, and cooling once the operating temperature is reached.

A chemical hydride hydrogen generation system and an energy system incorporating the same are provided. The hydrogen generation system comprises: a storage tank for storing a chemical hydride solution; a reactor containing a catalyst; a pump for supplying the chemical hydride solution from the said storage means to the reactor so that the chemical hydride solution reacts to generate hydrogen in the presence of the catalyst; and a second supply line for continuously supplying the solvent of the solution to the chemical hydride solution during the reaction. The energy system comprises the hydrogen generation system, a fuel cell for generating electricity and water from hydrogen and an oxidant, and a separator for recovering the water generated in the fuel cell and supplying the water to the chemical hydride solution during the reaction.

A hydrogen generator having a hydrogen generating reaction between a chemical hydride and vapor from a liquid having a freezing point below 0° C. The liquid is selected from alcohols such as ethanol and methanol used pure or diluted with distilled water, and distilled water that has had a non-reactive salt such as calcium chloride or magnesium chloride dissolved therein.

A method of producing a high pressure gas is disclosed and which includes providing a container; supplying the container with a liquid such as water; increasing the pressure of the liquid within the container; supplying a reactant composition such as a chemical hydride to the liquid under pressure in the container and which chemically reacts with the liquid to produce a resulting high pressure gas such as hydrogen at a pressure of greater than about 100 pounds per square inch of pressure; and drawing the resulting high pressure gas from the container.

A disposable, compact, and efficient storage apparatus (10) contains a fuel source (24) and water for supplying hydrogen fuel (36) to a micro-fuel cell. The storage apparatus comprises a housing defining a fuel source chamber (14) and a plurality of water chambers (12), and one or more polymer crystals (22) containing water positioned within each of the water chambers (12). The fuel source (24), such as a chemical hydride mixed with a catalyst, is positioned within the fuel source chamber (14), wherein the water in each of the water chambers (12) is selectively allowed to migrate to the fuel source chamber (14) to contact the solid fuel, thereby producing the hydrogen fuel (36) at a desired flow rate and temperature. A conduit (32) supplies the hydrogen fuel (36) produced within the housing to the fuel cell (38).

This invention relates to the chemical hydrogen storage material system comprising alkali metals and alkaline-earth metals borohydrides, and the hydrolyzation of the same for producing hydrogen, and the equipment therefore. The chemical hydride hydrogen storage material system consists of: chemical hydrides, water, catalyst and the carrier. This inventive hydrogen generator consists of: raw material storage unit, water tank, mixer, pump, reactor, accumulator and collector. The hydride powder and water are mixed in the mixer, and then in the reactor equipped with catalyst, the hydrolyzation takes place and producing hydrogen. In this hydrogen storage material contains no stabilizer, so reducing the cost and increasing hydrogen production property. This invention has also advantages of: fast responsive time, fast hydrogen supply rate, automatically regulating hydrogen production process based on the requirement of terminal unit, so it is the useful technique and equipment for vehicle carried hydrogen storage and mobile electric power supply.

A hydrogen generator having a hydrogen generating reaction between a chemical hydride and vapor from a liquid having a freezing point below 0° C. The liquid is selected from alcohols such as ethanol and methanol used pure or diluted with distilled water, and distilled water that has had a non-reactive salt such as calcium chloride or magnesium chloride dissolved therein.

Provided is a method for producing hydrogen aimed at storage and transportation, by which hydrogen for storage and transportation that is necessary for smoothly performing an organic chemical hydride method can be industrially produced efficiently at low cost. The method is a method for producing hydrogen aimed at storage and transportation in an organic chemical hydride method, in which: the hydrogenation process of an aromatic compound uses, as a hydrogen source for the reaction of the aromatic compound, a reaction gas is produced by a reforming reaction and adjusted a hydrogen concentration from 30 to 70 vol % by a shift reaction; and a hydrogenated aromatic compound is separated from a reaction mixture obtained in the hydrogenation process, which is followed by purification.

This invention relates to a valve assembly for metal hydride hydrogen storage (MHHS) or chemical hydride hydrogen storage (CHHS) devices. The valve assembly comprises a body with an inlet connector for connecting to the MHHS or CHHS device, an outlet connector for connecting to an external device, a cavity in the body that is in gas communication with the inlet and outlet connectors, and a shut-off valve in the cavity that can be moved between an opened position that permits gas flow between the inlet and outlet connectors, and a closed position that denies said gas flow. The outlet connector has a first valve therein that is biased to remain closed when external pressure thereon is less than or equal to ambient pressure, thereby impeding at least atmospheric gas backflow into the cavity. The outlet connector can also have a second, one-way valve that permits gas flow out of the valve assembly only, as well as a bypass mechanism including a gas passage coupled to the cavity and upstream of the first and second valves, through which gas can be transmitted to the canister during charging.

A method of producing a chemical hydride is described and which includes selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of a hydrocarbon; and reacting the composition with the source of the hydrocarbon to generate a chemical hydride.

Apparatus for generating hydrogen gas are provided herein. In some embodiments, an apparatus for generating hydrogen gas may include a first chamber; a first mixture comprising a chemical hydride and a catalyst disposed within the first chamber; a second chamber coupled to the first chamber; a connector; a third chamber coupled by the connector to the second chamber, wherein the third chamber is fluidly coupled to the first chamber; a sealing element coupled to at least one of the second chamber or the third chamber; an outlet fluidly coupled to the first chamber; and a resilient member disposed within the third chamber and configured to control the flow of water into the first chamber via movement of the resilient member in response to hydrogen gas pressure within the apparatus.

A system is disclosed for hydrogen generation based on the hydrolysis of solid chemical hydrides with the capability of controlled startup and stop characteristics wherein regulation of acid concentration, acid feed rate, or a combination of both control the rate of hydrogen generation. The system comprises a first chamber for storing a solid chemical hydride and a second chamber for storing an acidic reagent. The solid chemical hydride is a solid metal borohydride having the general formula MBH4, where M is selected from the group consisting of alkali metal cations, alkaline earth metal cations, aluminum cation, zinc cation, and ammonium cation. The acidic reagent may comprise inorganic acids such as the mineral acids hydrochloric acid, sulfuric acid, and phosphoric acid, and organic acids such as acetic acid, formic acid, maleic acid, citric acid, and tartaric acid, or mixtures thereof.