3289 results about "O-Phosphoric Acid" patented technology

The invention relates to the technical field of phosphoric acid production control, solves the problem that in the prior art, accurate control over the whole process of phosphoric acid production cannot be achieved, and provides a multivariable model prediction control method and system for the whole process of phosphoric acid production. The method comprises the following steps: acquiring key process data of a plurality of process units in the whole phosphoric acid production process in real time; preprocessing the key process data to obtain real-time standardized data; establishing a soft measurement model according to a pre-collected historical standardized data set; inputting the real-time standardized data into the soft measurement model to obtain a soft measurement predicted value; constructing a multivariable dynamic model according to the historical standardized data set and the soft measurement predicted value; according to the multivariable dynamic model, in combination with a model prediction control algorithm, obtaining target set values of a plurality of preset operation variables; and according to the target set value, realizing control of the whole process of phosphoric acid production. According to the invention, accurate control of the whole process of phosphoric acid production can be realized.

The invention relates to the technical field of catalysts, and discloses a preparation method of a supported catalyst for catalytic cracking oil slurry hydrogenation, and the preparation method comprises the following steps: S1, adding a phosphorus-containing compound into a carrier for modification: putting the carrier, phosphate and phosphoric acid into a round-bottom flask, adding water, and stirring for reaction to obtain a P element modified carrier; s2, dissolving a main active component of the catalyst in deionized water, then slowly adding into the P element modified carrier prepared in the step S1, and reacting to obtain a carrier loaded with the catalyst; and S3, roasting the catalyst-loaded carrier prepared in the step S2 to obtain the supported catalyst. According to the supported catalyst, a phosphorus compound modified carrier is adopted, and Ni-W-Mo or Ni-W active metal components are supported. The acid site of the carrier is optimized by adding the phosphorus element, and the surface acidity and the acid amount of the catalyst are optimized and adjusted by using a preparation process combining a microwave method and a co-impregnation method, so that the thermal stability of the catalyst is improved.

The invention discloses a production method of ferrous dihydrogen phosphate, which comprises the following steps of: changing an iron source of iron-process iron phosphate from traditional iron blocks or iron powder into oxide scale, compounding phosphoric acid and sulfuric acid into mixed acid, and controlling the granularity of the oxide scale and the components and acidity of the mixed acid to solve the problems of dissolution and passivation of the oxide scale. According to the method, iron oxide scale can be better dissolved, the residual problem of ferric ions is solved by reducing excessive iron blocks or iron powder, undissolved impurities such as carbon, silicon and iron are removed by filtering, and finally, the stability problem of a reaction system is solved by adjusting the pH value of the system through industrial phosphoric acid and pure water, so that a ferrous dihydrogen phosphate solution required for producing iron phosphate is obtained. The production cost of an iron source required by iron phosphate is greatly reduced, other impurities are not contained, and mixed acid-containing filtrate and washing water generated in the production process can be recycled through an evaporation device.

The invention discloses a composite water purifying agent based on polyaluminum ferric sulfate. The preparation process comprises the following steps: 1, reacting ferrous sulfate heptahydrate, aluminum sulfate, sodium chlorate, phosphoric acid and the like to prepare a polyaluminum ferric sulfate solution; 2, mixing the modified polyacrylamide solution with the polyaluminum ferric sulfate solution for reaction to obtain a composite system; and step 3, adding acidic ochre soil into the composite system to obtain the composite water purifying agent. The preparation method has the beneficial effects that a modified monomer is prepared through organic synthesis, and the modified monomer is copolymerized with monomers such as acrylamide to prepare modified polyacrylamide; then, the organic polymer is compounded with a polyaluminum ferric sulfate solution and acidic ochre soil, and an inorganic-organic-mineral ternary water purification system is constructed; the composite water purifying agent has the high-efficiency electricity neutralization capability of an inorganic flocculating agent, the bridging flocculation effect of organic macromolecules and the adsorption performance of minerals, and shows excellent flocculation and sedimentation effects and pollutant removal capability.

The preparation method comprises the following steps: S1, preparing a phosphoric acid solution, a hydrogen peroxide solution, a Ti salt, a phosphor salt solution and a ferrite solution; s2, Ti salt and the ferrite solution are mixed, and a titanium iron salt solution is obtained; mixing the phosphoric acid solution and the phosphorus salt solution to obtain a phosphorus source solution; s3, adding the titanium iron salt solution into a reaction kettle, and adding the hydrogen peroxide solution; s4, adding the phosphorus salt solution into the reaction kettle to obtain yellow slurry; s5, after the color of the slurry is heated to be white, white slurry is obtained; s6, carrying out solid-liquid separation on the white slurry to obtain an iron phosphate dihydrate filter cake; and S7, drying and calcining the iron phosphate dihydrate filter cake to obtain the Ti-doped battery-grade anhydrous iron phosphate. The titanium-doped iron phosphate is firstly prepared by a one-step method, the pH value of the reaction system is controlled by controlling the molar ratio of the iron element to all phosphorus elements in total phosphorus, ammonium phosphate and phosphoric acid in the reaction system, and the retention of the Ti element in the finished product and the regulation and control of the iron-phosphorus ratio in a specified range are ensured.

The invention relates to the technical field of polyethylene cables, in particular to a high-strength flame-retardant polyethylene cable and a preparation method thereof.The high-strength flame-retardant polyethylene cable is composed of a copper stranded wire core and a flame-retardant protective layer on the surface of the copper stranded wire core; the flame-retardant protective sleeve is made of a high-strength flame-retardant material; the high-strength flame-retardant material comprises the following components in parts by weight: 80-100 parts of low-density polyethylene, 5-10 parts of a flame retardant, 3-5 parts of a performance additive, 1-1.5 parts of filler, 0.1-0.2 part of a voltage stabilizer, 0.1-0.5 part of an antioxidant, 0.5-1 part of an initiator and 1-5 parts of a lubricant. The amino group on the surface of the silicon dioxide carrier treated by 3-aminopropyltriethoxysilane in the modification additive can be subjected to acid-base interaction with the phosphate group of APP to form chemical bridging; the interface bonding enables the APP and the modification additive to synchronously migrate to the surface of the material during combustion to cooperatively construct a protection layer, so that the problem of protection failure caused by migration rate difference of different flame retardants in a traditional flame-retardant system is solved, and the flame-retardant performance of the cable can be greatly improved.

The invention provides phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar, a preparation method thereof and application of the phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar in formaldehyde adsorption, and belongs to the technical field of biomass resource high-value utilization and air pollution control. The preparation method comprises the following steps: mixing a biomass raw material with a phosphoric acid catalyst, carrying out hydrothermal carbonization reaction, carrying out solid-liquid separation on a reaction product after the reaction is finished, collecting a solid-phase material, drying, mixing with potassium hydroxide, activating, washing and drying the obtained product, and thus obtaining the phosphorus-doped hydrothermal synchronously-activated hierarchical porous green charcoal. Phosphoric acid is introduced in the hydrothermal stage to serve as a structure-directing agent and a doping source, uniform doping of phosphorus and coordinated regulation and control of a pore structure are achieved, a hierarchical pore channel system is formed in the subsequent activation process, and the physical adsorption and chemical fixation capacity of the biochar to formaldehyde molecules is greatly improved.

The invention belongs to the field of hydrometallurgy, and particularly relates to a method for extracting niobium and / or scandium in a phosphoric acid solution system, which is characterized in that the phosphoric acid solution system containing niobium and / or scandium and an extraction organic phase are subjected to auxiliary extraction under a composite field of ultrasonic-magnetic field to obtain a loaded organic phase. Innovative research shows that extraction is carried out under an ultrasonic-magnetic field composite field, the final physicochemical characteristics of niobium-scandium in a phosphoric acid solution can be adapted accidentally, excellent extraction capacity can be obtained accidentally, and especially excellent scandium-niobium separation selectivity can be obtained under a composite phosphoric acid system containing niobium and scandium.

The invention discloses a heat dissipation type anti-corrosion coating and a preparation method thereof, and belongs to the technical field of anti-corrosion coatings. The heat dissipation type anticorrosive paint comprises a component A and a component B, wherein the component A comprises the following components in parts by mass: 100 parts of heat-conducting water-borne epoxy resin, 4-6 parts of graphene, 0.3-0.5 part of an antioxidant, 0.2-0.4 part of a defoaming agent, 0.2-0.4 part of a flatting agent and 10 parts of first deionized water; the component B comprises the following components in parts by mass: 10-20 parts of a curing agent, 40-60 parts of a toughening agent, 4-6 parts of functionalized boron nitride microspheres and 30-50 parts of second deionized water; the heat-conducting water-borne epoxy resin is 1, 5-naphthalene diphenol modified water-borne epoxy resin; the curing agent is an aromatic amine curing agent; the toughening agent is obtained by carrying out copolymerization on acrylamide, N-(4-aminophenyl) acrylamide, 1, 3, 5-triacryloyl-s-triazine and 3-dimethylamino allyl phosphoric acid; the functionalized boron nitride microspheres are boron nitride microspheres modified by 4-aminobenzoic acid.

This invention belongs to the field of wastewater treatment technology, specifically relating to a method for removing metallic impurities from acidic copper-containing etching wastewater at room temperature and pressure. The method includes the following steps: S1, adding an oxidant to the acidic copper-containing etching wastewater to conduct an oxidation-reduction reaction, obtaining a pretreatment solution; S2, adding phosphoric acid or soluble phosphate to the pretreatment solution, adjusting the pH to 1.3-1.7 using a pH adjuster, stirring, and filtering to obtain a purified copper-containing solution. The method provided by this invention achieves high removal rates for Fe, Ni, Zn, Ca, and Mg, while maintaining a high copper ion content. It can recycle and regenerate high-purity copper salt products for application in food, cosmetics, medical, electroplating, and other fields, while also reducing hazardous waste generation, improving economic efficiency, and significantly reducing costs.

The invention relates to a method for treating a waste iron phosphate positive electrode material by a phosphoric acid-hydrogen peroxide method matched with a specific complexing agent. The method comprises the following steps: crushing the positive electrode material of the waste lithium iron phosphate battery, adding the crushed positive electrode material into deionized water, and stirring to prepare slurry; heating the slurry, dropwise adding a phosphoric acid-hydrogen peroxide mixed solution and a complexing agent, adding a NaOH solution to adjust the pH value to 3.5, and filtering to obtain a filtrate and a filter cake; adding a NaOH solution into the filtrate, and adjusting the pH value to 10 to obtain lithium phosphate; performing evaporative crystallization on the filter cake to obtain trisodium phosphate; the complexing agent is prepared by adding pentasodium salt of amino trimethylene phosphonic acid, triallyl citrate, epoxysuccinic acid and DMF (Dimethyl Formamide) into a reaction kettle, mixing, adding ammonia water to adjust the pH value to be 10, and distilling to remove the DMF after the reaction is finished. The precipitation rate of Fe reaches up to 99.99%, the leaching rate of Li reaches up to 99.91%, and efficient separation and recycling of lithium and iron are achieved.

The invention relates to a compound, a preparation method, a hole transport layer material, a photovoltaic device and a photovoltaic module. R1 and R4 are respectively and independently selected from amino and derivatives thereof, hydroxyl and derivatives thereof, methoxyl and derivatives thereof, sulfydryl and derivatives thereof, methylthio and derivatives thereof, thiophene groups and derivatives thereof, phosphate groups and derivatives thereof, carboxylic acid groups and derivatives thereof, and sulfonic acid groups and derivatives thereof; r2 and R3 are independently selected from alkyl, a phosphate group and derivatives thereof, a carboxylic acid group and derivatives thereof, a sulfonic acid group and derivatives thereof, and trimethoxysilyl propyl and derivatives thereof. The material is beneficial to improving the photoelectric conversion efficiency of photovoltaic devices and photovoltaic modules.

The utility model discloses an SF type flotation machine for phosphoric acid beneficiation. The SF type flotation machine comprises a groove body, a power system, a center cylinder, a stirring system and a scraper system. The air distributor is arranged to uniformly distribute the sucked air, so that a large amount of fine bubbles can be formed, and the generation of the bubbles is further facilitated; the slurry on the dispersing cover can be sucked into an upper impeller cavity through the through holes, so that slurry upper circulation is formed; the backward-inclined lower blade and the backward-inclined upper blade are arranged, so that slurry in the tank is subjected to upper and lower double circulation, and the suspension of coarse-grain minerals is facilitated; a large gap between the impeller and the dispersion cover is arranged, and the air suction amount is large. The ore pulp and air are self-sucked, the air suction amount is large, the number of auxiliary devices is small, and operation and maintenance are easy.

The invention relates to the technical field of protective glue, in particular to extreme high and low temperature impact resistant UV (ultraviolet) photocuring electronic protective glue which is prepared from the following raw materials in parts by weight: 30-50 parts of synergistically modified epoxy-urethane acrylate oligomer, 20-35 parts of composite active monomer, 1.5-5 parts of composite photoinitiator and 10-20 parts of core-shell structure inorganic composite filler, 0.6 to 2.2 parts of a silane coupling agent, 0.12 to 1.1 parts of an antioxidant and 0.11 to 1 part of a leveling agent; the preparation method of the synergistically modified epoxy-urethane acrylate oligomer comprises the following steps: reacting resin acid modified epoxy resin with phosphoric acid di (hydroxyethyl acrylate) ester at 80-90 DEG C, and introducing a phosphate group to obtain a phosphate modified epoxy acrylate intermediate; the protection glue unifies rigidity, flexibility and flame retardance on the molecular level through the cooperation of the hybrid oligomer and the core-shell filler, realizes high heat conductivity, strong adhesion and extremely low internal stress, and has extreme temperature impact resistance, long-term damp-heat aging resistance and high-reliability protection performance.

The invention relates to the technical field of phosphoric acid production, in particular to an intelligent optimization management method for phosphoric acid production process parameters. Obtaining adaptive window ranges at different moments according to data change characteristics of the phosphoric acid concentration sequence; obtaining a phosphoric acid production benefit value according to the phosphoric acid concentration in the self-adaptive window range; obtaining a benefit reference value according to the phosphoric acid production benefit value in the historical batch production process; obtaining a benefit comparison value according to the phosphoric acid production benefit value at the current moment and a benefit reference value; judging whether the production process is adjusted according to the benefit contrast value; obtaining a parameter deviation coefficient according to the difference characteristic of the sulfuric acid concentration of the production process corresponding to the benefit reference value and the current production process; and according to the parameter deviation coefficient and the benefit contrast value, obtaining a phosphorite putting amount difference coefficient. According to the parameter deviation coefficient, the phosphorite feeding amount difference coefficient and the benefit contrast value, the sulfuric acid concentration or the phosphorite feeding amount at the current moment is iteratively adjusted, and the quality of the phosphoric acid production process is improved.

The present invention discloses a super-aeration flotation system and its implementation method, belonging to the technical field of wet-process phosphoric acid production. The system comprises a reaction tank, an inclined guide plate arranged on the inner wall of the reaction tank, a dished trough arranged at the bottom of the reaction tank and arranged in a ring shape around its center, a central island formed by a protrusion of the inner ring portion of the dished trough at the bottom of the reaction tank, an aeration mechanism arranged on the central island and connected to the outside through a pipeline, a transmission mechanism installed above the reaction tank, a central transmission rod arranged along the axis of the reaction tank and connected to the output end of the transmission mechanism, a dynamic settler arranged at an upper position in the reaction tank and connected to the central transmission rod, and an overflow port matched with the dynamic settler. By integrating the inclined guide plate, the dished aeration structure and the dynamic settler in the reaction tank, the present invention significantly enhances the super-aeration uniformity, foam separation ability, phosphoric acid purification and liquid vortex intensity in the wet-process phosphoric acid production process, thereby improving reaction efficiency and product quality.

The invention discloses a construction method of a gout compound decoction fingerprint as well as the fingerprint and application thereof, and belongs to the technical field of analysis and detection. The construction method of the fingerprint spectrum comprises the following steps: taking a test solution prepared from the gout compound decoction; the test solution is subjected to HPLC-SPD detection, so that the fingerprint spectrum of the gout compound decoction is obtained, and the HPLC detection conditions are that a C18 chromatographic column is used, a C18 chromatographic column is used, a C18 chromatographic column is used, a C18 chromatographic column is used, and a C18 chromatographic column is used for detecting the fingerprint spectrum of the gout compound decoction. An aqueous solution containing 0.1%-0.2% of phosphoric acid is used as a mobile phase A, and acetonitrile is used as a mobile phase B for gradient elution; the flow velocity is 0.8-1 mL / min, the column temperature is 25 DEG C, the sample injection volume is 5-10 [mu] L, and a diode array detector is 190-400 nm full-wave band scanning. The chemical components in the gout compound decoction are comprehensively and systematically analyzed, and a basis is provided for quality control and in-depth study of a pharmacodynamic material basis.

The invention discloses a method for separating iron and lithium in a lithium iron phosphate iron salt leaching solution and recycling iron phosphate, and belongs to the technical field of waste lithium battery recycling. The method comprises the following steps: constructing a bis (2-ethylhexyl) phosphate and trioctyl decyl tertiary amine mixed extraction system for selective extraction of Fe < 3 + >, adopting phosphoric acid for reverse extraction, recycling phosphoric acid reverse extraction liquid, preparing iron phosphate and the like. According to the method, efficient enrichment of Fe < 3 + > and efficient elution of Fe < 3 + > from a loaded organic phase are realized. The purity of the raffinate Li solution is relatively high, so that the subsequent preparation of battery-grade lithium carbonate is facilitated. The strip liquor can be recycled for multiple times, an iron intermediate is precipitated through pH adjustment, and the FePO4 product can be finally prepared through washing, aging and high-temperature calcination. The method is high in extraction selectivity, recyclable in process and mild in operation condition, has good separation effect and resource utilization efficiency, and is suitable for popularization and application of a Fe / Li separation process in lithium battery recovery.

The invention provides a preparation method of grain size grading iron phosphate and high compaction type lithium iron phosphate. Removing impurities from the titanium dioxide byproduct ferrous sulfate, and filtering to obtain a purified ferrous sulfate base solution; the method comprises the following steps: reacting phosphoric acid with ammonia water to prepare ammonium phosphate solutions with different reaction pH values and phosphorus molar concentrations, respectively mixing the ammonium phosphate solutions with a certain amount of hydrogen peroxide, and sequentially adding an iron source, a first phosphorus salt solution, a second phosphorus salt solution and a third phosphorus salt solution into a tubular reactor for reaction to obtain iron phosphate slurry; and sequentially converting, filtering, washing, drying and calcining the completely reacted slurry to finally prepare the anhydrous iron phosphate. According to the invention, a mode of controlling solution nucleation and growth is adopted, nucleation and growth rates are controlled by preparing phosphorus salt solutions with different concentrations, size grading of precursor particles is directly realized in a synthesis reaction section, and slurry grading uniformity is further realized through aging crystal transformation. Lithium iron phosphate prepared from the iron phosphate precursor has high compaction density.

The present application relates to the technical field of battery materials, and provides iron phosphate having low sulfur content and a high iron-phosphorus ratio, a preparation method therefor, and a use thereof. The preparation method for the iron phosphate having low sulfur content and a high iron-phosphorus ratio comprises: providing amorphous iron phosphate; adding water and phosphoric acid into the amorphous iron phosphate for slurrying treatment, and then heating and aging to obtain an aged slurry; carrying out slurry washing and filter pressing on the aged slurry to obtain a first filter cake; adding water and a first pH regulator into the first filter cake for slurry washing to obtain a first slurry having a pH value range of 3.0-5.0, and carrying out filter pressing on the first slurry to obtain a second filter cake; and rinsing, drying and calcining the second filter cake to obtain iron phosphate having low sulfur content and a high iron-phosphorus ratio. The present application facilitates preparation of iron phosphate having low sulfur content, a high iron-phosphorus ratio, and a large specific surface area. The iron phosphate can be used for preparing lithium iron phosphate having good electrochemical performance, and the lithium iron phosphate can be further used for preparing a positive electrode sheet and a secondary battery having good electrochemical performance.

The invention discloses a phosphogypsum leachate-carbonate rock dynamic corrosion reaction analysis method based on numerical simulation, and aims to research a migration-corrosion coupling mechanism of acid leachate in a carbonate rock fracture network. The method comprises the following steps: firstly, acquiring a two-dimensional image sequence of a rock core sample through CT (Computed Tomography) scanning, carrying out operations such as threshold segmentation, membrane enhancement and a light shading algorithm on an image by utilizing AVIZO software, extracting fracture structure parameters and establishing a high-precision three-dimensional model; then, multiple groups of simplified models with different fracture widths are constructed in COMSOL Multiphysics, a Darcy flow field and a solute concentration field are coupled on the basis of the Darcy law and a dilute matter transfer theory, and the dynamic corrosion effect under the multi-field coupling effect is quantitatively represented by setting hydraulic gradient boundary conditions and chemical reaction kinetic parameters; the dynamic corrosion reaction process of calcium ions, hydrofluoric acid, sulfuric acid and phosphoric acid in the ardealite leachate and carbonate rocks with different crack widths is accurately simulated.

The invention relates to the technical field of wastewater purification, in particular to a phosphorus-containing wastewater treatment system. Comprising a pre-purification unit, a deep purification unit, a membrane concentration unit and a multi-effect evaporation unit which are sequentially connected, the pre-purification unit is used for diluting phosphorus-containing wastewater and filtering impurities; the deep purification unit is used for receiving the wastewater treated by the pre-purification unit and filtering multivalent metal cations, macromolecular substances and divalent salts in the wastewater; the membrane concentration unit is used for receiving the wastewater treated by the deep purification unit and evaporating water at low temperature under vacuum negative pressure and steam heating so as to concentrate phosphoric acid; and the multi-effect evaporation unit is used for receiving the phosphoric acid concentrated by the membrane concentration unit and further evaporating water under steam heating so as to further concentrate the phosphoric acid, so that a phosphoric acid product with the concentration reaching the selling standard is obtained. The method is simple in process and low in operation energy consumption, phosphorus-containing wastewater can be efficiently recycled, pollution to the environment is reduced, and economic benefits are improved through recycling of phosphorus resources.

The invention belongs to the technical field of electrolyte materials, and particularly relates to a pH response biopolymer solid electrolyte as well as a preparation method and application thereof. The pH-responsive degradable biopolymer is taken as a main raw material, and one or more functional groups such as pyridine, sulfonic acid, carboxyl, tertiary amine, phosphoric acid and the like are contained. The organic acid and the organic acid salt are selected to adjust the pH value of a medium around the electrolyte, and the contraction / stretching behavior of a molecular chain is influenced by changing the ionization degree of the electrolyte, so that an interpenetrating polymer network structure is formed. The polar functional group of the biopolymer affects the migration behavior of lithium ions under different pH conditions, so that the migration rate and migration quantity of the lithium ions are increased, and the cycle performance of the battery is improved. The electrolyte is suitable for high-performance energy storage devices such as a lithium ion battery, can effectively improve the battery performance, reduces the environmental pollution, and has relatively strong green and environment-friendly advantages.

The invention discloses an anti-corrosion composite furnace lining material for zircon sand fluidizing chlorination and a preparation method thereof.The anti-corrosion composite furnace lining material comprises a base body layer and an anti-chlorine-seepage protection layer, and the preparation method comprises the steps of base body layer preparation, coating liquid preparation, base body layer surface coating, coating curing, high-temperature firing, chlorine seepage treatment and annealing. According to the method, the specially-made coating liquid is adopted for enhancing the surface of the high-purity corundum furnace lining for the first time, the permeability of the coating liquid to a base body layer is improved by means of matched dissolution-sedimentation of chromium chloride and phosphoric acid, pores are blocked by means of expansion caused by dehydration and oxidation of CrCl3. 6H2O, densification of surface layer Cr2O3, spinel and phosphate and surface layer pore blocking are achieved, the porosity is greatly reduced, and the porosity of the high-purity corundum furnace lining is improved. The chlorine permeability is reduced, and the core problems of high permeability and short service life of the material in a high-temperature chlorine corrosion environment are solved; according to the invention, a chlorination-annealing self-cleaning process is matched to realize deep removal of impurities, so that the product purity of the chlorination process is improved, and the purification cost is reduced.

The invention discloses a preparation method and application of fine-grained melamine phosphate.The preparation method comprises the steps that after melamine, water and a composite surfactant are ultrasonically mixed to be uniform, the ultrasonic power is improved, phosphoric acid is dropwise added, then the ultrasonic power is reduced, a temperature rise reaction is conducted to obtain reaction liquid, and then the fine-grained melamine phosphate is obtained after cooling, filtering, washing and drying are conducted; wherein the composite surfactant is composed of a gemini surfactant and a polymer surfactant according to a mass ratio of (1-20): (5-40). According to the preparation method disclosed by the invention, the composite surfactant and the multi-stage ultrasonic treatment are utilized to cooperate with the mixed materials and react, so that the fine-grained melamine phosphate with the particle size of 1-4.5 microns is prepared, and the preparation method has the advantages of high reaction efficiency, simplicity in operation and the like.

The invention provides a preparation method of a catalyst, the catalyst and a diethyltoluenediamine synthesis method based on the catalyst, and belongs to the technical field of chemical synthesis. After the surface of phosphoric acid modified zeolite is coated with aluminum oxide, a layer of quantum dot intercalation metal layered oxide is coated, the surface is modified by polydopamine, citric acid is coupled, cerium oxide and ruthenium oxide are loaded, and the catalyst is prepared. The prepared catalyst can well improve the conversion rate of toluenediamine, inhibit side reactions, improve the anti-coking capability, reduce the generation of carbon deposits, prevent the agglomeration of catalyst particles, prolong the service life, improve the mechanical strength and thermal stability, reduce the activation energy in the synthesis process of diethyltoluenediamine, make the reaction conditions milder, make the yield higher, and reduce the production cost. And the method can be repeatedly used and has a wide application prospect.

The invention discloses a preparation method of a hydrofining catalyst for petrochemical engineering. The preparation method comprises the following steps: step a, carrier pretreatment: putting an aluminum oxide precursor into a dilute nitric acid solution with the mass fraction of 1-5%, dipping for 2-4 hours, and drying at 120-150 DEG C for 3-6 hours; the comprehensive performance of the catalyst is remarkably improved by modifying the alumina carrier with phosphoric acid and optimizing an active component loading process; a gradient acid center is constructed on the surface of the carrier through phosphoric acid treatment to promote adsorption and dissociation of the sulfur / nitrogen-containing compound; the dispersion degree of the active phase is enhanced and high-temperature sintering is inhibited by a bimetal synergistic loading strategy; the pore structure evolution is effectively controlled by a segmented drying and stepped heating roasting process, a through type mesoporous network is formed, and the macromolecular diffusion efficiency is improved; the obtained catalyst is improved in activity in diesel oil hydrodesulfurization, improved in mechanical strength and prolonged in service life.

The invention discloses an iron-nickel metal magnetic powder core with high stable magnetic conductivity and low loss and a preparation method of the iron-nickel metal magnetic powder core. The iron-nickel metal magnetic powder core is prepared through the steps of preparing iron-nickel alloy powder through gas atomization, screening the particle size, carrying out insulation coating, carrying out compression molding, carrying out heat treatment and carrying out impregnation and spraying. Wherein in the insulating coating process, a passivation solution is adopted to form an insulating layer on the surface of the iron-nickel alloy powder, and the passivation solution comprises 0.1 wt%-0.3 wt% of phosphoric acid, 0.1 wt%-0.6 wt% of sol and the balance deionized water according to the weight part of the iron-nickel alloy powder; and the pH value of the passivation solution is 4-7. According to the technical scheme, the iron-nickel alloy powder is subjected to insulation coating through cooperation of the phosphoric acid, the sol and the coating agent, the magnetic hysteresis loss is effectively reduced, the magnetic conductivity of the iron-nickel magnetic powder core is improved, the quality factor of the iron-nickel magnetic powder core is remarkably improved to 95 or above, and after the obtained high-magnetic-conductivity low-loss iron-nickel magnetic powder core is subjected to long-term high-temperature aging, the magnetic conductivity change rate does not exceed 2%; and the safety and the performance stability are greatly improved in the application of power electronic devices.

The invention relates to the technical field of electric power engineering, in particular to a non-step-in liquid cooling phosphoric acid and all-vanadium liquid flow energy storage power station cooperative control system in butt joint with a 220KV transformer substation. Comprising a hybrid energy storage module, a non-stepping intelligent liquid cooling module, a multi-strategy cooperative control module and a substation deep cooperative interface module. The multi-strategy cooperative control module is used for constructing a multi-stage cooperative control architecture, generating control strategies adapted to different operation scenes by fusing multi-source data, and realizing multi-module cooperative operation optimization; lithium iron phosphate and all-vanadium liquid flow energy storage units are connected in parallel through a direct-current bus, and a short-time high-power response-long-time deep energy storage characteristic complementary system is constructed; through cooperative operation of the hybrid energy storage module, limitation of a single battery type on power or capacity is avoided; a'monitoring-evaluation-response 'totally-closed active safety chain is formed, and the temperature can be kept stable and potential safety hazards can be eliminated without manual intervention in the whole process.

The invention relates to a method for preparing lithium dihydrogen phosphate from a lithium-containing solution by using an extraction-reverse extraction technology, an extraction agent adopted in the method comprises a main extraction agent, a synergistic extraction agent and a diluent, the pKa value of the main extraction agent is 2.2-7, the synergistic extraction agent has a P = O group or a cavity diameter of 0.12-0.15 nm, the water solubility of the synergistic extraction agent is less than or equal to 50 mg / L, and the diluent is a diluent. The synergistic extraction factor R of the extraction agent is more than 100, R = Dmix / (D1 + D2), Dmix is the extraction distribution ratio of the main extraction agent to the lithium when the main extraction agent and the synergistic extraction agent are mixed according to the mass ratio of 1: 1-1: 2, D1 is the extraction distribution ratio of the main extraction agent to the lithium, D2 is the extraction distribution ratio of the synergistic extraction agent to the lithium, and the stripping agent is phosphoric acid. According to the method disclosed by the invention, by selecting the main extraction agent and the synergistic extraction agent, on one hand, lithium monohydrogen phosphate and lithium phosphate impurities cannot be generated by reaction when phosphoric acid is adopted for reverse extraction, and on the other hand, higher separation degree on sodium and potassium can be achieved during extraction, so that high-purity lithium dihydrogen phosphate can be efficiently prepared.