2448 results about "Chemical stability" patented technology

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.

The invention provides a novel polynorbornene anion exchange ionomer containing a polar functional group as well as a preparation method and application of the novel polynorbornene anion exchange ionomer. The polynorbornene has excellent thermal stability and chemical stability. Meanwhile, the AEI main chain of the polynorbornene has no aryl group, so that the adsorption influence caused by the aryl group is avoided. The synthesized addition polynorbornene AEI in the form of quaternary ammonium salt can be dissolved in a low-boiling-point solvent, and it is ensured that a membrane electrode can be prepared through a solvent casting method. Besides the solubility of the AEI, the addition polynorbornene-based AEI in the form of quaternary ammonium salt is modified by utilizing a thiol-ene click reaction, an anion exchange ionomer containing a polar functional group can be prepared, the interaction between the AEI and an electrolytic catalyst is improved, the reaction is simple and easy to operate, the universality is high, and the method is suitable for industrial production. And the current density in the AEMWE system containing the AEI can be effectively improved.

The invention relates to the technical field of all-solid-state batteries, in particular to a halide sulfide double-layer coated positive electrode material and a preparation method and application thereof. The halide sulfide double-layer coated positive electrode material comprises a positive electrode material substrate, and a halide electrolyte coating layer and a sulfide electrolyte coating layer which sequentially coat the positive electrode material substrate. The halide electrolyte coating layer is located in the middle layer, compatibility with a positive electrode interface can be achieved by means of high oxidation resistance of the halide electrolyte coating layer, and the problem of the positive electrode interface occurring in sulfide electrolyte oxygenolysis is solved. The sulfide electrolyte coating layer is located on the outermost layer, air stability is excellent, processing in a dry environment can be met, and the problems that halide electrolyte is poor in chemical stability, cannot be processed and manufactured in an external environment and is high in density are solved. The halide sulfide double-layer coated positive electrode material has high interface stability and good chemical stability.

The invention discloses a high-weather-resistance bismuth vanadate coating and a preparation method thereof, and belongs to the technical field of inorganic pigment modification. The high-weather-resistance bismuth vanadate coating comprises bismuth vanadate matrix particles, and the surfaces of the bismuth vanadate matrix particles are sequentially coated with an amorphous aluminum oxide layer, a cerium oxide layer and a fluorinated silicon oxide layer. The amorphous aluminum oxide layer is formed in an atomic layer deposition mode; the cerium oxide layer is formed by hydrothermal treatment of a cerium source. The preparation technology has accurate and controllable technological parameters, is suitable for industrial production, can replace the traditional toxic pigment containing lead and cadmium, and meets the requirements of environmental regulations. The bismuth vanadate coating has excellent weather resistance and chemical stability, the service life of a product can be prolonged, the maintenance cost is reduced, and a reliable solution is provided for development of high-performance environment-friendly pigments.

The invention discloses a compound with anti-tumor activity. The compound has a chemical structural formula as shown in a formula (I). The compound belongs to a novel tetracyclic triterpenoid natural product, has good fat solubility and chemical stability, and can be conveniently extracted from the rhizome of a herbal medicine Polygala fallax Hemsl. And prepared into an oral or injection form. The invention also provides a preparation method and application of the compound. The compound provided by the invention can obviously inhibit the growth of mouse lung cancer and reduce the volume and weight of tumor, and can be used for treating tumor diseases.

The invention relates to the technical field of three-step fine polishing methods for 19nm wafer regeneration, discloses a fine polishing method named'three-step fine polishing method for 19nm wafer regeneration ', and aims to solve the technical contradiction between macroscopic planarization and microscopic surface integrity of regenerated wafers in advanced process nodes. The method is characterized by comprising a first fine polishing step, a second fine polishing step and a third fine polishing step, and in each step, gradient decreasing polishing pad hardness, abrasive particle size and concentration, polishing pressure and pH value are adopted; and an on-line process monitoring and self-adaptive feedback control subsystem is used for assistance. By adopting the technical scheme, defects can be efficiently removed, damage can be repaired step by step, the wafer surface with ultralow defect density and excellent chemical stability is obtained, the requirements of the manufacturing process of 19nm and more advanced semiconductors are met, and the yield is increased.

The invention discloses a preparation method and application of monolithic BiVO4 photocatalytic foamed ceramic. The method comprises the following steps: 1) preparing composite slurry containing BiVO4 powder, an organic additive and a reinforced phase; (2) uniformly attaching the composite slurry to the organic foam skeleton by adopting an impregnation method; 3) performing drying and heat treatment to remove organic components; and 4) performing high-temperature sintering to form the three-dimensional communicated porous structure. Through the structure-function integrated design, the problems that a traditional powder catalyst is difficult to recover, the activity of an immobilized catalyst is low and a supported catalyst is easy to fall off are solved. The obtained product is high in porosity, the compressive strength is larger than or equal to 0.1 MPa, the specific surface area is larger than or equal to 0.1 m < 2 > / g, visible light can be efficiently utilized for degrading emerging organic pollutants in water, and the degradation rate reaches 20-99%. The material has no nano-particle leakage risk, has excellent mechanical strength, chemical stability and engineering applicability, and provides a feasible scheme for large-scale application of a photocatalytic water treatment technology.

The invention provides a compound containing a silicon group and an organic electroluminescent device thereof, and particularly relates to the technical field of organic electroluminescent materials. When the compound containing the silicon group is used as a covering layer material, the glass transition temperature is high, the thermal stability and the chemical stability are good, the light transmittance of a device can be improved, aging of the device is delayed, and therefore the service life of the device is effectively prolonged; and the compound has weak metal adsorption capacity, and can effectively inhibit the deposition of a metal electrode material on the surface of a nucleation inhibition layer when being applied to the nucleation inhibition layer, thereby improving the performance of the device. In conclusion, the silicon group-containing compound provided by the invention can be widely applied to the fields of panel display and the like, and has a good development prospect.

The invention discloses a method for preparing high-purity nickel acetate from crude nickel carbonate in the technical field of nickel compound purification, which comprises the following steps: mixing the crude nickel carbonate with deionized water to obtain a suspension, and adding glacial acetic acid to react to obtain a nickel acetate solution; then a specially-made hierarchical-pore titanium silicalite molecular sieve loaded bimetallic nanocluster material is added for purification treatment, the material is obtained through precise preparation, the method comprises the steps of carrier modification, bimetallic loading, hydrophobic modification, activation balance and the like, and the material has excellent impurity adsorption capacity and chemical stability; carrying out concentration crystallization and solid-liquid separation on the purified solution to obtain wet nickel acetate crystals; the mother liquor is subjected to adsorption treatment again, crystals in the mother liquor are recycled, and finally all the crystals are combined and dried to obtain a high-purity nickel acetate product. The process is simple and efficient, the purity of the prepared nickel acetate exceeds 98.5%, the content of each impurity is superior to the industrial standard, and the mother liquor can be recycled, is environment-friendly and is suitable for industrial production.

The invention discloses a self-assembled monomolecular material based on pyrene-carbazole diphosphate and a preparation method and application thereof, and belongs to the technical field of perovskite solar cells. According to the material, two carbazole units and a pyrene core are in conjugate connection to form a large conjugate plane structure, and the material has the following advantages: 1) a rigid molecular skeleton and an expanded conjugate system significantly improve thermal stability and chemical stability; 2) the conjugate plane of pyrene enhances intermolecular pi-pi accumulation, and promotes hole extraction and transmission; and 3) energy level matching is accurately regulated and controlled, a compact interface layer is formed, and electron-hole recombination is inhibited. When the hole transport layer is applied to the trans-perovskite solar cell, the photoelectric conversion efficiency and the long-term stability can be improved at the same time, and the hole transport layer has a good industrialization prospect.

The invention discloses a hydrophobic micro-nano flexible thin film structure and a characterization method, relates to the technical field of thin film structure characterization, and aims to solve the problems of poor supporting performance of a flexible thin film and inaccurate standard data acquisition. Different acceleration voltages and currents are set for the coarse thinning stage and the fine thinning stage, fine removal of materials can be achieved, the accuracy of the thinning thickness is guaranteed, the thickness, the surface fluctuation amplitude and the microstructure feature size of a thin film in a measured image are measured with the help of a scale tool, and the measurement accuracy is improved. The morphological characteristics of the hydrophobic micro-nano flexible film can be converted into accurate data, rigid support is provided for the film by utilizing high hardness, high chemical stability and good thermal conductivity of tungsten, the upper side and the lower side of a target area are milled, hole digging is conducted on surrounding materials to form a preliminary sheet contour, then U-shaped milling and back-splashing material cleaning are conducted, and the thin film is obtained. The sample form is effectively controlled, and damage of processing stress to the sample structure is reduced.

The invention relates to an automatic magnesium oxide coating analysis system and method, and belongs to the technical field of coating quality analysis. The method comprises the following steps: acquiring attributes of a magnesium oxide coating, an infrared spectrum and environment temperature and humidity data, and constructing a multi-source feature set; analyzing the distribution dispersion and local enrichment risk of free water based on a dynamic migration model, and analyzing the bonding weakening degree and dissociation risk of bound water based on a chemical stable state model; respectively generating free water treatment process parameters for inhibiting structural damage and combined water treatment process parameters for preventing performance degradation according to the abnormal analysis result and the coating attribute; by performing coupling influence analysis on the two types of process parameters, the balance requirements of the structural integrity and chemical stability of the coating are coordinated, an optimized process scheme is generated, and cooperative regulation is realized. According to the method, accurate identification, independent analysis and cooperative control of the free water and the bound water are realized, and the accuracy, reliability and quality consistency of coating water treatment are improved.

The invention discloses a preparation method and application of a composite PVDF-HFP and polylysine nanofiber diaphragm, and belongs to the technical field of lithium batteries. The composite material is prepared by blending polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) and polylysine and then carrying out an electrostatic spinning process. The PVDF-HFP is utilized to provide excellent mechanical strength and chemical stability, rich polar amino functional groups in a polylysine molecular chain are utilized to improve the lyophilic property of the membrane, and anions in an electrolyte are fixed through an intermolecular acting force, so that the transference number of lithium ions is increased, and the lithium ions are induced to be uniformly deposited. The nanofiber membrane combines the characteristics of PVDF-HFP and polylysine, has high porosity, good thermal stability and excellent interface compatibility, can effectively inhibit the growth of lithium dendrites and prevent the diaphragm from being punctured, and can significantly prolong the cycle life and improve the safety performance of the lithium metal battery when being applied to the lithium metal battery.

The invention relates to a preparation method of a high-lithium-affinity vinylene covalent organic framework material serving as a lithium metal negative electrode interface protective layer. The method comprises the following steps: firstly, by utilizing a simple hydrothermal synthesis method, taking 1, 3, 5-trimethyl-2, 4, 6-triazine (TMT) and 2, 2-bipyridine-5, 5-diformaldehyde (BPY) as monomers, and carrying out Aldol condensation reaction to synthesize a covalent organic framework material connected by a vinylene bond, which is named as viCOF-bpy; the electrochemical performance of the material is verified by modifying the surface of a copper pole piece with the viCOF-bpy material and then assembling a battery. The lithium-loving group on the material skeleton can promote the migration of lithium ions, and the vinylidene has very strong chemical stability, so that the electrochemical performance of the lithium metal battery can be effectively improved.

The invention relates to a long-life room-temperature phosphorescent material and a preparation method and application thereof.According to the phosphorescent material, epoxy resin is doped with an epoxy prepolymer containing a fluorine-containing chain segment to serve as a host matrix, F-pi and pi-pi non-covalent synergistic interaction is formed between the host matrix and aromatic fluorescent guest molecules, the energy level difference of the excited state is adjusted, and the phosphorescent material is obtained. Intersystem crossing (ISC) and radiative transition rates are optimized, so that the phosphorescence lifetime and environmental adaptability are improved; a fluorine-containing chain segment introduced into a polymer system can be enriched on the surface of a material to form a needle-shaped structure, so that the surface energy of the material is remarkably reduced, the antifouling property is excellent, and additional functions of lyophobicity, transparency, chemical stability and the like are also realized while ultra-long room-temperature phosphorescence is realized; and cooperative enhancement and multifunctional integration of optical performance and surface performance are realized.

The invention relates to a PVB (polyvinyl butyral) composite film as well as a preparation method and application thereof. The PVB composite film is prepared from the following raw materials in parts by weight: 100 parts of PVB resin, 1-10 parts of nano praseodymium oxide, 1-10 parts of a dispersing agent, 0.01-1 part of a coupling agent and 20-50 parts of a plasticizer. The nano praseodymium oxide is added into the PVB resin, and the infrared absorption band of the PVB composite film is optimized by utilizing the infrared absorption performance, chemical stability and heat-resistant stability of the nano praseodymium oxide, so that infrared radiation can be efficiently blocked, and the excellent heat insulation effect and long-term use stability of the PVB composite film are realized. Furthermore, the nano praseodymium oxide is modified by a coupling agent, so that the dispersion uniformity of the nano praseodymium oxide in the PVB resin and the interface bonding force of the nano praseodymium oxide and the PVB resin are improved, the light transmittance loss of the PVB composite film is reduced, and the mechanical property and the heat insulation property of the composite film are improved.

The invention provides a silicon-based material and a preparation method thereof, a negative pole piece and a solid-state battery. The silicon-based material comprises an inner core and a surface coating layer, the inner core comprises a silicon-based negative electrode material, the surface coating layer is a carbon fluoride layer, the carbon fluoride layer internally comprises Li-M, LiF and LiX, M represents a metal element and is selected from at least one of Ag, Mg, Zn and Al, and X represents a non-metal element and is selected from at least one of N, S and P. The silicon-based negative electrode material is used as a core, the surface of the silicon-based negative electrode material is coated with the carbon fluoride layer, and the Li-M alloy / LiF / LiX composite lithium compound is introduced into the carbon fluoride layer, so that triple effects of ion-electron double-conduction network construction, interface chemical stabilization and mechanical buffer enhancement are achieved; and the chemical stability of an interface between the silicon negative electrode and sulfide solid electrolyte is improved while the rate capability of the negative electrode is improved and the expansion and shrinkage of the silicon negative electrode are relieved, and the cycling stability is improved.

The invention provides a setter plate for sintering a powder metallurgy product and a preparation method of the setter plate, and belongs to the technical field of setter plates. The refractory material is prepared from the following raw materials in parts by weight: 20-40 parts of fused zirconium mullite, 20-40 parts of modified sintered corundum, 30-50 parts of alumina micro powder, 0.5-1 part of yttrium oxide / alumina-carbon nanotube hollow microsphere powder, 0.5-1 part of zinc oxide micro powder and 5-10 parts of a binder. The setter plate for sintering the powder metallurgy product has the advantages of good heat insulation, high temperature resistance, thermal shock resistance and chemical stability, good mechanical properties, good hardness and good wear resistance, the problems of cracking, deformation and the like caused by thermal shock are reduced, the service life of the setter plate is prolonged, and the setter plate has a wide application prospect.

The invention relates to an insulating material, in particular to a voltage-breakdown-resistant high-insulation EPDM material and application thereof, and the voltage-breakdown-resistant high-insulation EPDM material comprises the following components: modified silicone rubber, 4, 4 '-thiobis (6-tert-butyl o-cresol), a composite filler, a cross-linking agent, 4-isopropoxybenzoic acid and an EPDM matrix; according to the voltage-breakdown-resistant high-insulation EPDM material disclosed by the invention, the comprehensive performance of the material is greatly improved and the application field of the EPDM material is widened through the matching of all the components and the specific dosage ratio of the components. The modified silicone rubber is introduced, the modified silicone rubber is obtained by modifying vinyl-containing perfluoropolyether-b-polysiloxane, in the vinyl-containing perfluoropolyether-b-polysiloxane, a perfluoropolyether chain segment has extremely low surface energy and good chemical stability, and a polysiloxane chain segment endows the vinyl-containing perfluoropolyether-b-polysiloxane with excellent flexibility and electrical insulating property.

The invention belongs to the field of chemical engineering, and relates to a preparation method of a high-chroma bismuth vanadate pigment for a coating, which comprises the following steps: mixing a titanium-based ion sieve with an acidic vanadium leachate, filtering after the reaction is completed to obtain a first filtrate, adding mercaptoacetic acid into the first filtrate, and filtering after the reaction is completed to obtain a second filtrate; preparing a bismuth salt solution containing yttrium ions and zirconium ions, mixing the bismuth salt solution with the second filtrate, adjusting the pH value to be in linear gradient change from acidity to neutrality, heating to a first temperature at a set heating rate, aging, centrifuging and drying to obtain a precursor; and calcining the precursor at a second temperature to obtain the bismuth vanadate pigment. According to the method, the acid vanadium leaching solution is used as a raw material, and the bismuth vanadate pigment with high chromaticity and chemical stability is obtained while the production cost is reduced through an innovative ion sieve purification technology and lattice stabilization doping, so that the method has obvious economic benefits.

The present invention provides an organic phosphonic acid betaine and a preparation method thereof, specifically an ammonium phosphonic acid betaine containing a glycidyl group. The organic phosphonic acid betaine can be used as a functional monomer for free radical grafting modification of the surface of a polymer material such as polyolefin, or can be mixed with acrylate, acrylonitrile or other olefin monomers for copolymerization to prepare an amphoteric ionomer. The organic phosphonic acid betaine can also be used for ring-opening grafting modification of polymer materials such as starch, cellulose, polyurethane, and polyamide containing amino or hydroxyl groups in their structures. At the same time, the phosphonic acid betaine imparts functional effects such as zwitterionization, hydrophilicity, antibacterial properties, and antifouling properties to the obtained polymer material. The organic phosphonic acid betaine also has high chemical stability in acidic and alkaline water environments.

The invention belongs to the technical field of electrochemical energy storage, and discloses a flow battery composite membrane material and a preparation method thereof, and the preparation method comprises the following steps: spraying a ZIF-8 metal organic framework solution to the positive electrode side of a microporous diaphragm, and drying to obtain the flow battery composite membrane material. According to the zinc-bromine flow battery and the preparation method thereof, ZIF-8 acts on the positive electrode side of the microporous diaphragm, ZIF-8 shows good chemical stability in an acidic electrolyte environment of the zinc-bromine flow battery and is not easily oxidized and degraded by bromine, and a stable framework ensures that a screening pore channel is kept complete in long-term operation and continuously plays a role in resisting bromine, so that the corrosion of a zinc negative electrode and the loss of bromine active substances are reduced, and the service life of the zinc-bromine flow battery is prolonged. The problems of low bromine permeation and bromine reaction rate on the positive electrode side of the zinc-bromine flow battery and the like can be effectively solved, and the coulombic efficiency and the voltage efficiency can be remarkably improved, so that the microporous diaphragm with excellent comprehensive performance is obtained.

The invention discloses a fullerene pyrrolidine derivative as well as a preparation method and application thereof, and relates to the field of photoelectric functional materials. The structural general formula of the fullerene pyrrolidine derivative is # imgabs0, and fullerene, amino acids with different carbon chain lengths and aromatic aldehyde are subjected to Prato reaction to generate the fullerene pyrrolidine derivative. The fullerene pyrrolidine derivative provided by the invention is used as an electron transport layer material, can significantly improve the performance of a photoelectric device, has excellent chemical stability and environmental adaptability, and greatly enhances the stability of the device. In addition, the preparation method of the fullerene pyrrolidine derivative is simple, convenient and efficient, the operation condition is mild, and the manufacturing cost of a device is reduced.

The invention relates to a photoetching ordered microcosmic fixed abrasive polishing pad and a preparation method thereof. Compared with the prior art, the method has the advantages that the to-be-photoetched surface of the substrate is photoetched according to the photoetched pattern, so that the plurality of microscopic grinding columns are orderly distributed and formed on the grinding material base according to the preset distribution and arrangement mode, the distribution shape, direction and position of the microscopic grinding columns on the grinding material base are kept unchanged, and regular distribution and uniform distribution can be presented; the distribution and the size of the micro grinding columns can be adjusted according to the photoetching pattern to meet different polishing requirements, then the micro grinding columns of the substrate are compositely filled with the filling body to keep the stability of the micro grinding columns, and the polishing pad can be suitable for the micro level to meet the requirement of the manufacturing procedure below 5nm, so that the production efficiency is improved, and the production cost is reduced. The microcosmic grinding columns are formed through photoetching to replace traditional grinding particles, the chemical stability of the polishing pad during polishing is improved, the removal rate is increased, the surface roughness is reduced, and the polishing effect of the polishing pad on a polishing product is improved.

The invention relates to an acylhydrazone bond-connected covalent organic framework material, in particular to an acylhydrazone bond-connected covalent organic framework material as well as a preparation method and application thereof, and aims to overcome the defects of various materials for adsorbing Pd (II) in one aspect or the defects of poor stability and durability in high-acidity and high-radioactivity environments. Or the adsorption selectivity on Pd (II) is not strong. As an emerging crystalline organic porous polymer, the covalent organic framework is mainly formed by connecting pure organic structural units through dynamic covalent bonds, has the advantages of permanent high porosity, low density, high chemical stability, high thermal stability and the like, and is expected to realize Pd (II) adsorption in strong acid and ray irradiation environments.

The invention belongs to the technical field of kitchen ware coatings, and discloses a preparation method of a wear-resistant coating based on nano structure optimization, through a specific ratio of nano silicon carbide, titanium dioxide, boron nitride and silver, four particles form a complementary and synergistic functional system-silicon carbide provides a hardness basis, boron nitride optimizes the antifriction performance by means of a layered structure, and the wear-resistant coating is prepared. Titanium dioxide enhances the chemical stability; by matching with a composite dispersion process of high-energy ball milling and ultrasonic treatment, particle aggregation is broken, so that the coating forms a uniform and compact nano-structure, the structure can effectively disperse friction stress, the wear resistance is remarkably improved, and the service life of the kitchen ware in a high-frequency cooking friction environment is greatly prolonged; a kitchen ware substrate is subjected to 80-mesh white corundum sand blasting to form a rough surface, then impurities are removed through ultrasonic cleaning, and a good interface condition is created for coating adhesion; and a subsequent stepped vacuum curing process promotes chemical bonding of the nanoparticles and the polyimide resin, and the binding force of the interior of the coating and the binding force of the coating and the substrate are enhanced.

The invention discloses a natural component composition for conditioning skin micro-ecology, a preparation method of the natural component composition and application of the natural component composition in skin care products for children. The composition comprises a synergistic combination of a sphingomonas fermentation product extract, a haematococcus pluvialis extract rich in astaxanthin, an abelmoschus esculentus fruit extract rich in polysaccharides, and a yeast / zinc fermentation product. The present invention provides improvements in astaxanthin in terms of chemical stability and transdermal permeability. The composition aims to enhance the immature skin barrier, provide a good effect, and support the healthy development of skin microecology, thereby solving the unique physiological needs of children's skin. The invention also describes a preparation method of the composition and application of the composition in cosmetics for children and dermatological products.

The invention discloses a battery diaphragm as well as a preparation method and application thereof. The battery diaphragm comprises a base membrane and a composite coating formed on at least one side surface of the base membrane, the composite coating comprises a composite inorganic material, and the composite inorganic material comprises a porous layered bimetallic oxide and MOFs particles grown on the surface of the porous layered bimetallic oxide in situ. According to the invention, a composite coating is formed on the surface of the base film by using a composite inorganic material, and the unique pore structure and the layered structure of the porous layered bimetallic oxide LDO provide more liquid storage and retention spaces. The MOFs have good thermal stability, good chemical stability and a unique pore structure, so that the MOFs are endowed with relatively good ion conduction capability, heat resistance and stability. The synthesized MOFs particles grow in situ on the surface of the porous bimetal oxide, so that the bonding force between the particles is improved, and the particles are easier to transfer to the surface of a pole piece after being in contact with the pole piece and hot-pressed, thereby improving the safety of the battery.

The invention belongs to the technical field of biochar, and provides nitrogen-doped graded porous biochar as well as a preparation method and application thereof. The preparation method comprises the following steps: performing hydrothermal reaction on coconut shell biomass powder and urea to obtain nitrogen-doped biomass powder, and mixing the nitrogen-doped biomass powder with an activating agent for carbonization; the activating agent comprises potassium hydroxide and potassium nitrate. The agricultural waste coconut shells are prepared into the porous biochar, the raw material sources are wide, the production cost is low, the porous biochar is environmentally friendly, and the preparation method has the advantage of being high in yield which is 2.85 times that of a traditional alkali activation method; the nitrogen-doped graded porous biochar has the characteristics of excellent graded porous structure, strong chemical stability, high nitrogen content and high specific surface area, the adsorption capacity of gaseous iodine is effectively improved, the adsorption capacity of 6000 mg / g or above can still be kept after five times of adsorption, and the nitrogen-doped graded porous biochar has relatively good iodine retention capacity.

The invention belongs to the technical field of lining oil pipes, and particularly relates to a lining oil pipe and a preparation method thereof. The lining oil pipe is prepared from the following raw materials in parts by mass: 70-90 parts of ultra-high molecular weight polyethylene, 8-13 parts of high-density polyethylene, 7-12 parts of modified carbon nanotubes, 2-5 parts of reinforcing filler, 3-6 parts of a compatilizer, 0.1-0.3 part of a calcium-zinc composite stabilizer and 0.05-0.2 part of a lubricant. The prepared lining oil pipe has excellent tensile strength, toughness, chemical stability and the like.