4165 results about "Zirconium" patented technology

The invention discloses a matte glaze and a preparation method thereof. The matte glaze comprises the following components by weight: 1-5 parts of zinc oxide, 5-15 parts of barium carbonate, 0-15 parts of zirconium silicate, 10-25 parts of potassium feldspar, 10-20 parts of kaolin, 5-15 parts of calcite, 5-15 parts of calcined talcum powder, 20-35 parts of a matte frit and 0.5-1 part of an additive. Specifically, the matte frit comprises the following components by weight: 30-50 parts of SiO2, 15-20 parts of Al2O3, 0.01-0.5 part of Fe2O3, 3-10 parts of CaO, 0.5-5 parts of MgO, 1-5 parts of K2O, 3-10 parts of Na2O, 3-10 parts of ZnO, 0.1-1 part of B2O3 and 10-25 parts of BaO. By introducing the matte frit, the melting temperature of the formula is lowered, the firing range of the formula isbroadened, and the glaze texture achieves a fine matte effect.

The invention relates to the technical field of welding wire preparation, in particular to a nickel-based alloy flux-cored wire for 9Ni steel welding and a preparation method of the nickel-based alloy flux-cored wire. A nickel-based alloy flux-cored wire for 9Ni steel welding comprises a flux core, and the flux core comprises, by weight, 26%-34% of titanium dioxide, 3%-5% of ferrozirconium, 8%-12% of ferrotitanium, 1%-3% of rare earth ferrosilicon, 15%-20% of tungsten powder, 1%-2% of polytetrafluoroethylene and the balance pretreated mixed powder. The nickel-based alloy flux-cored wire for 9Ni steel welding has the advantages that low-melting-point eutectic is not prone to being formed, the hot crack sensitivity is reduced, the nickel-based alloy flux-cored wire is suitable for welding of restrained large structures, the deoxidation and denitrification capacity is enhanced, and the pore sensitivity is reduced.

The invention discloses a raw material of a near-zero shrinkage silicon-based ceramic core and a preparation method thereof, the raw material of the ceramic core comprises refractory material powder, zirconium silicate powder and metal zirconium powder, and the refractory material powder, the zirconium silicate powder and the metal zirconium powder are mixed according to the proportion to form the raw material of the ceramic core; ceramic core raw materials are added into liquid paraffin to form ceramic core slurry, the ceramic core slurry is used for obtaining a ceramic core biscuit through a hot-pressing injection molding method, and the ceramic core biscuit is subjected to powder burying sintering to obtain the ceramic core. Volume shrinkage generated in the sintering process of the ceramic core is made up through in-situ synthesis oxidation expansion of the metal zirconium powder, meanwhile, shrinkage of the ceramic core can be made up through generated zirconium dioxide due to the phase change effect, near-zero shrinkage of the silicon-based ceramic core in the sintering process is achieved under the dual effects of in-situ oxidation and the phase change effect, and the silicon-based ceramic core has the good sintering performance. Meanwhile, the generated zirconium dioxide improves the room-temperature bending strength and the high-temperature bending strength of the ceramic core.

Provided are a lithium manganese iron phosphate material and a preparation method therefor, a positive electrode sheet, and a lithium ion battery. The lithium manganese iron phosphate material comprises a core and a coating layer that coats the surface of the core. The chemical formula of the material of the core is LiaMnbFecMdPO4, wherein M comprises at least one element among magnesium, calcium, strontium, cobalt, titanium, zirconium, molybdenum, vanadium, niobium, nickel, scandium, chromium, copper, zinc, beryllium, lanthanum and aluminum. The coating layer is formed by sintering a carbon source, and the carbon coating layer comprises graphitized carbon.

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The present application relates to nuclear fuel claddings, and more particularly to zirconium alloy tubes with a ceramic covering. A first coating layer is applied to the ceramic covering. A second coating layer is over the first coating layer. The first coating layer includes Nb. The second coating layer includes Cr.

The invention discloses an enamel ceramic glaze tile with a metal spot bionic effect and a preparation method thereof, and relates to the technical field of ceramics. The enamel porcelain glaze tile comprises a bottom blank, a metal ground glaze layer and a semi-opaque cover glaze layer, the metal ground glaze layer is prepared from a first ground glaze formula or a second ground glaze formula, and the first ground glaze formula comprises, by mass, potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and manganese dioxide; the formula of the second ground glaze comprises the following components in percentage by mass: potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and chromic oxide; the semi-opaque surface glaze layer is prepared from the following raw materials in percentage by mass: albite, calcite, talc, burnt soil, zircon powder, oriental zirconium, calcined zinc oxide, black clay powder and calcined aluminum oxide. Through a double-layer glaze structure and a black mud powder glaze breaking mechanism, the stereoscopic visual effect that metal spots are randomly generated on an opacifying substrate is achieved, and meanwhile the Moh's hardness of the ceramic tile is improved.

The invention relates to the field of aluminum materials, and provides an automobile corrosion-resistant aluminum material and a preparation method thereof.The automobile corrosion-resistant aluminum material is prepared from cerium oxide loaded aluminum oxide nanorods, scandium / boron nitride nanotubes, zirconium powder, magnesium powder, copper powder, manganese powder, silicon carbide nanoparticles, TiB2 nanoparticles, aluminum powder and stearic acid. Wherein the cerium oxide loaded aluminum oxide nanorod is composed of an aluminum oxide nanorod and cerium oxide nanoparticles loaded on the surface of the aluminum oxide nanorod, and the scandium / boron nitride nanotube is composed of a boron nitride nanotube and a scandium nanolayer uniformly coated on the surface of the boron nitride nanotube. The material is prepared through mechanical ball milling, cold isostatic pressing forming, vacuum sintering and aging treatment, and finally the aluminum-based composite material containing the Al3Sc nano precipitated phase and the boron nitride nanotube reinforced phase is formed. And an Al3Sc precipitated phase and an aluminum matrix form a coherent interface, so that the strength, the corrosion resistance and the wear resistance of the material are improved. Through nanostructure optimization, high performance of the aluminum alloy is achieved, and the aluminum alloy is suitable for the fields of automobiles, aerospace and the like.

The invention provides a polysilazane green special refractory ceramic coating and a preparation method thereof, and belongs to the field of ceramic coatings. The ternary core material composed of titanium carbide, zirconium boride and silicon nitride provides high hardness, oxidation resistance, thermal shock resistance and excellent thermal stability; the silicon dioxide-aluminum oxide composite shell layer remarkably improves the oxidation resistance and reliability of the coating through the synergistic oxidation resistance and crack self-repairing function; the multi-metal oxygen cluster network endows the coating with excellent electrical conductivity, thermal conductivity and corrosion resistance; the intercalated montmorillonite enhances the crack resistance and oxidation resistance through a layered structure and embedded active ions; and the boron nitride coated vanadium carbide particles provide lubricity, oxidation resistance and wear resistance. Through collaborative optimization of multiple components, the comprehensive performance of the coating is comprehensively improved in the aspects of oxidation resistance, thermal conductivity, interface stability, high-temperature performance, mechanical performance and the like, so that the coating shows excellent long-term stability and functionality in an extreme environment.

The invention discloses a special phosphorus removal agent for deep phosphorus removal and a preparation method and application thereof, and relates to the field of phosphorus removal agents and preparation methods thereof.The phosphorus removal agent is prepared from a porous precursor, an activating agent and a dispersing agent, and the porous precursor comprises at least one of aluminum oxide, iron oxide, calcium oxide and magnesium oxide; the activating agent comprises at least one of lanthanum salt, cerium salt, zircon salt, magnesium salt and ferric salt. By optimizing the composition of the porous precursor and activating treatment, the phosphorus adsorption capacity is remarkably improved, the phosphorus removal agent also plays a role in micro-flocculation in the process of mixed adsorption with sewage, a wet adding mode is adopted, the adding amount can be flexibly adjusted according to the phosphorus concentration condition of inlet water and outlet water, and the phosphorus removal efficiency is improved. The phosphorus removal agent can reduce the total phosphorus concentration in tail water of a sewage treatment plant to 0.5 mg / L or below.

The invention provides a fluorine-containing aromatic acid ligand modified zirconium metal oxide nano-cluster photoresist material as well as a preparation method and application thereof. The preparation method of the fluorine-containing aromatic acid ligand modified zirconium metal oxide nano-cluster photoresist material comprises the following steps: mixing a Zr6O4 (OH) 4 (MAA) 12 solution and a fluorine-containing aromatic acid ligand compound solution, and carrying out reaction, rotary evaporation and drying to obtain the fluorine-containing aromatic acid ligand modified zirconium metal oxide nano-cluster photoresist material. The preparation method is simple, cheap and easily available in raw materials, low in cost and suitable for industrial production. The fluorine-containing aromatic acid ligand modified zirconium metal oxide nano-cluster photoresist material can be suitable for ultraviolet lithography, electron beam lithography and extreme ultraviolet lithography, and the formed photoetched pattern has the advantages of low line edge roughness, high resolution and the like, and has wide application prospects.

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

The invention relates to the technical field of rare earth metal electrolysis cathode protection coatings, in particular to a high-temperature-corrosion-resistant yttrium-stabilized zirconia gradient coating on the surface of a tungsten cathode. A metallurgically bonded strong bonding bottom layer is constructed on a tungsten substrate through surface pretreatment and reactive sintering, then an atmosphere plasma technology is adopted to spray a creep-resistant gradient layer with continuous components to buffer thermal stress, and finally a sol-gel technology is utilized to construct an extremely compact corrosion-resistant surface layer in a superposition mode. The high-temperature-corrosion-resistant yttrium-stabilized zirconia gradient coating is constructed through a multi-scale and multi-mechanism synergistic effect, the problems that a tungsten cathode coating is insufficient in binding force and poor in thermal shock resistance are fundamentally solved, molten salt permeation can be blocked, and the service life of a tungsten cathode in a severe environment is remarkably prolonged.

The invention discloses an electrochemical sensor constructed based on a composite material and a preparation method and application thereof.The electrochemical sensor comprises a screen-printed electrode, the surface of the reaction end of a working electrode of the screen-printed electrode is loaded with a zirconium-based metal organic framework composite material, the composite material comprises UiO-66, and the surface of the composite material is modified with a polydopamine coating. The preparation method comprises the following steps: preparing the zirconium-based metal organic framework composite material and fixing the composite material on the working electrode of the screen-printed electrode. According to the invention, the zirconium-based metal organic framework composite material with many adsorption sites, good dispersibility, good conductivity and good hydrophilicity is used as a functional material, so that the sensor has the advantages of simple operation, low cost, rapid response, strong anti-interference capability, wide detection linear range, high detection sensitivity, long service life and the like, and can be widely used for detecting Mn < 2 + >, Mn < 2 + >, Mn < 2 + >, Mn < 2 + > and Mn < 2 + > in a water body. The method can realize rapid and accurate detection of Mn < 2 + > in a water body, and is high in use value and good in application prospect.

The invention discloses a halloysite / zirconium phosphate nano composite material, a preparation method thereof and application of the halloysite / zirconium phosphate nano composite material in heavy metal adsorption, and belongs to the technical field of materials. The halloysite / zirconium phosphate nano composite material is formed by growing nano zirconium phosphate particles on the inner wall of a halloysite nanotube, and the preparation process of the halloysite / zirconium phosphate nano composite material comprises the following steps: dispersing the halloysite nanotube in a solvent, adding a zirconium salt solution, carrying out ultrasonic treatment to obtain a halloysite-zirconium ion dispersion liquid, carrying out circulating vacuum treatment on the halloysite-zirconium ion dispersion liquid, and carrying out vacuum drying to obtain the halloysite / zirconium phosphate nano composite material. And carrying out solid-liquid separation, putting the obtained solid into phosphoric acid or a phosphate solution to carry out phosphating reaction, and washing and drying the obtained product to obtain the product. Zirconium phosphate nanoparticles in the composite material are small in size, uniform in distribution and good in loading stability, show high adsorption activity on heavy metal ions, can be widely applied to adsorption of the heavy metal ions in a solution system, are good in stability and can be repeatedly used for multiple times.

The invention provides a samarium / europium / gadolinium-containing zirconium hydride block as well as a preparation method and application thereof, and relates to the technical field of radiation shielding materials. The zirconium hydride block containing samarium / europium / gadolinium comprises the following elements in percentage by mass: 95% < = Zr < = 99.5%, 0% < = Gd < = 5%, 0% < = Sm < = 5%, 0% < = Eu < = 5% and 0% lt. Gd + Sm + Eu < = 5%. The preparation method comprises the following steps: respectively hydrogenating sponge zirconium, metal gadolinium, metal europium and metal samarium to respectively obtain corresponding hydride powder; weighing zirconium hydride powder, gadolinium hydride powder, europium hydride powder and samarium hydride powder according to a required proportion, and uniformly mixing under a protective atmosphere; and carrying out pressure sintering on the mixed powder, and carrying out secondary hydrogenation to obtain the zirconium hydride block containing samarium / europium / gadolinium. According to the invention, the absorption of the material to low-energy-segment neutrons can be obviously improved; and the preparation of the zirconium hydride block containing samarium / europium / gadolinium and the accurate regulation and control of doped elements are realized.

The invention relates to the technical field of biodiesel hydrogenation catalysts, and particularly discloses a hydrogenation catalyst of organic bentonite loaded cerium-zirconium solid solution and nickel-molybdenum phosphide as well as a preparation method and application of the hydrogenation catalyst. The hydrogenation catalyst with the organic bentonite loaded with the cerium-zirconium solid solution and the nickel-molybdenum phosphide comprises an organic bentonite carrier, the cerium-zirconium solid solution and the nickel-molybdenum phosphide, the loading capacity of the cerium-zirconium solid solution on the organic bentonite carrier is 2-2.5 wt%; the cerium-zirconium solid solution comprises cerium dioxide and zirconium dioxide; the loading capacity of the nickel molybdenum phosphide on the organic bentonite carrier is 10-15 wt%; and the nickel molybdenum phosphide is Ni2Mo3P. The organobentonite carrier provides an acid site and promotes deoxidation path optimization, the layered structure of the organobentonite carrier can limit the cerium-zirconium solid solution and the nickel-molybdenum phosphide, and organic groups are also embedded into the layered structure, so that the organic compatibility of the organobentonite carrier to biodiesel is improved, and the catalytic efficiency is improved. The cerium-zirconium solid solution provides oxygen vacancies, promotes hydrogenation / deoxidation, and improves the thermal stability and sintering resistance of the catalyst.

The invention discloses a hydrogen embrittlement-resistant high-strength titanium alloy and a preparation method thereof. The hydrogen embrittlement-resistant high-strength titanium alloy comprises the following components in percentage by mass: 5.5%-6.5% of aluminum, 3.5%-4.5% of tin, 3.2%-3.8% of zirconium, 0.4%-0.6% of molybdenum, 0.7%-1.2% of tungsten, 0.25%-0.35% of niobium, 0.4%-0.6% of silicon, 0.8%-1.2% of yttrium, 0.03%-0.08% of carbon and the balance of titanium and inevitable impurities. The hydrogen embrittlement-resistant high-strength titanium alloy is prepared through the following steps that after cogging treatment is carried out on a smelted as-cast alloy blank, forging and heat treatment are carried out. The titanium alloy has no hydrogen embrittlement phenomenon after hydrogen charging stretching, the strength and hydrogen embrittlement resistance of the material are both considered, the Rm after hydrogen charging can reach 1180 MPa and is higher than that before hydrogen charging, and the ductility after hydrogen charging can reach 11.3% and is equivalent to that before hydrogen charging.

The invention relates to the technical field of aluminum alloy materials, in particular to a high-temperature-resistant and high-strength aluminum alloy material and a preparation method thereof. The problems that an existing aluminum alloy material is insufficient in mechanical property and poor in high temperature resistance are solved. A plurality of strengthening elements with synergistic effects, including copper, magnesium, scandium, zirconium, nickel, manganese and titanium, are introduced into an aluminum alloy matrix, meanwhile, multiple layers of graphene nanosheets are added for step-by-step smelting, and under argon protection, hexachloroethane refining and lithium salt complexing agent grain refinement are performed to prepare a smelted alloy; and by combining the multi-stage refined smelting, the staged heat treatment process, the three-stage aging treatment and the surface modification process, the microstructure is optimized, and meanwhile the surface performance is improved. According to the prepared aluminum alloy material, through multi-element cooperation and multi-process optimization, the mechanical property, the high temperature resistance and the surface oxidation resistance of aluminum alloy are remarkably improved, and the aluminum alloy material is suitable for the field of aerospace.

The invention relates to the technical field of ceramic substrates, and provides a low-dielectric-constant multilayer ceramic substrate and a preparation method thereof. The low-dielectric-constant multilayer ceramic substrate comprises the following components in parts by weight: 100 parts of aluminum oxide, 4-8 parts of a sintering aid, 8-16 parts of silicate, 3-6 parts of copper oxide, 3-5 parts of a dispersing agent, 6-12 parts of a binder and 70 parts of a solvent, the silicate comprises magnesium aluminum silicate and zirconium silicate in a weight ratio of (1.5-9): 1. According to the technical scheme, the problem that the bending strength of the multi-layer ceramic substrate is poor in the prior art is solved.

The invention provides a positive electrode material, a positive electrode plate, a secondary battery and an electronic device, the positive electrode material comprises lithium manganese iron phosphate, the positive electrode material comprises a first element and a second element, the first element comprises at least one of a magnesium element, a nickel element, a cobalt element or a zinc element, and the second element comprises at least one of a titanium element or a zirconium element; the mass ratio of the first element to the second element is 1 to 20. The positive electrode material meets the characteristics, the dynamic performance and the cycle performance of the positive electrode material can be improved, and meanwhile, the positive electrode material has relatively high capacity.

The invention discloses a radiation refrigeration coating with high refractive index contrast, and belongs to the technical field of radiation refrigeration coatings. The radiation refrigeration coating with high refractive index contrast comprises the following raw materials: hollow microspheres, a high refractive index pigment, a film-forming substance, a solvent and an auxiliary agent. The coating process of the radiation refrigeration coating film comprises two coating steps: firstly, coating an inner layer coating film on the surface of a base material by using the radiation refrigeration coating with rutile type titanium dioxide as a high-refractive-index pigment as a raw material; and coating the surface of the inner-layer coating film with an outer-layer coating film by using the radiation refrigeration coating with high-refractive-index pigment being zirconium dioxide and / or zirconium silicate as a raw material. According to the invention, a closed and independent bubble structure is introduced into the coating by adopting the hollow microspheres, and the preferable high-refractive-index pigment is matched, so that the refractive index difference value between adjacent components in a coating film is increased, and the sunlight reflectivity of the coating film is remarkably enhanced, thereby realizing excellent radiation refrigeration performance under strong sunlight irradiation.

A method of fixating carbon dioxide to a substituted cyclic carbonate includes a reaction of an epoxide and carbon dioxide in the presence of a zirconium-containing metal-organic framework to form the substituted cyclic carbonate. The zirconium-containing metal-organic framework is a UiO-66-based metal-organic framework including an aminomethylbenzoic acid. The zirconium-containing metal-organic framework catalyzes the formation of the substituted cyclic carbonate in a range of 40 to 97 percent yield.

The invention discloses a high-oxygen-storage zirconium solid solution material and a preparation method, and belongs to the technical field of rare earth catalytic materials, and the method comprises the following steps: precursor preparation, ultrasonic dispersion, double-gradient precipitation, ultrasonic aging, solid-liquid separation, three-section roasting and furnace cooling. Through the synergistic effect of double-gradient precipitation and ultrasonic aging, coarse grains and non-uniform particle size distribution are avoided, and the material is not prone to abnormal growth of the grains and structural collapse in long-term high-temperature service. Meanwhile, according to the gradient roasting process, through step-by-step regulation and control of crystal densification and crystal lattice reconstruction, separation of a fluorite phase and a pyrochlore phase easily occurring in traditional low-temperature single-section roasting is reduced, a stable crystal phase structure is maintained, it is ensured that the material can still keep sufficient active surface and pore channel structures under the working conditions of high temperature and thermal shock alternation, and the performance of the material is improved. The oxygen storage capacity and the long-term durability of the catalyst carrier are obviously improved.

The invention relates to the technical field of metal wires, in particular to a low-voltage aluminum wire and a preparation method thereof, the sectional area of the wire is 35 square millimeters, the wire comprises an aluminum alloy conductor and an insulating layer, the aluminum alloy conductor comprises the following chemical components: 0.7-0.9% of magnesium, 0.4-0.6% of silicon, 0.15-0.25% of copper, 0.08-0.12% of zirconium, 0.05-0.09% of scandium, 0.03-0.07% of silver, 0.01-0.03% of erbium, 0.02-0.04% of vanadium and the balance of aluminum, and the microstructure of the aluminum alloy conductor is in gradient distribution. The center is ultra-fine grains, a transition region contains a nano precipitated phase, the surface layer is of a high-density dislocation and nano precipitated phase synergistic reinforcement structure, the insulating layer is of a double-layer composite structure, the inner layer is a crosslinked polyethylene modified layer, the outer layer is an ethylene-tetrafluoroethylene copolymer modified layer, the electric conductivity is improved to 58% IACS or above, and the tensile strength is improved to 280 MPa or above.

The invention discloses a niobium-zirconium alloy and nickel-based alloy vacuum brazing process and a part, and belongs to the technical field of vacuum brazing. According to the process, a vacuum brazing furnace is adopted for brazing, and BNi-2 brazing filler metal is used; the process comprises the following steps that S1, a welding assembly structure formed by a niobium-zirconium alloy part and a nickel-based alloy part is assembled, and BNi-2 brazing filler metal is arranged at the matching position of the welding assembly structure; s2, staged heating is carried out on the welding assembly structure under the preset vacuum degree of the vacuum brazing furnace, and the staged heating comprises a foreign matter removing heating stage, a brazing filler metal solid diffusion heating stage and a brazing filler metal melting wetting heating stage which are sequentially carried out; and S3, staged cooling is conducted on the welded assembly structure after welding is completed, the staged cooling comprises a furnace cooling stage and a gas quenching cooling stage which are conducted in sequence, according to the scheme, defect control over the niobium-zirconium alloy and nickel-based alloy welding joint can be effectively achieved, and the strength and sealing performance of the welding joint are guaranteed.

The invention discloses a nuclear zirconium alloy cladding high-temperature oxidation resistant composite coating and a preparation method thereof, and belongs to the technical field of nuclear zirconium alloy coatings. According to the preparation method disclosed by the invention, through component gradient structure design, Cr ion pretreatment activation, deposition of a pure Cr inner coating, deposition of a Cr70Al30 intermediate coating and deposition of a Cr50Al50 outer coating are sequentially carried out on the surface of a nuclear zirconium alloy cladding, and the Cr-Cr70Al30-Cr50Al50 composite coating zirconium alloy cladding with a three-layer structure is obtained. According to the method, outward migration of the Al element is effectively limited while the excellent anti-oxidation characteristics of the Cr and Al elements are fully utilized, the coating has the excellent high-temperature oxidation performance, and the requirement for the service performance of the surface coating of the zirconium alloy cladding at the extremely high temperature is met.

The invention relates to the technical field of batteries, and discloses a high-compaction ferric sodium pyrophosphate positive electrode material and a preparation method thereof.The chemical formula of the positive electrode material is Na4Fe2.9VxTiyZrz (PO4) 2P2O7, 0.001 < = x < = 0.01, 0.002 < = y < = 0.01, and 0.001 < = z < = 0.01. The preparation method comprises the following steps that a sodium source, an iron source, a phosphorus source, a carbon source, a vanadium source, a titanium source and a zirconium source are weighed and mixed to be uniform, and a mixture is obtained; carrying out primary sanding treatment to obtain first sanding slurry, carrying out spray drying, and carrying out primary sintering treatment to obtain a pre-sintered material; adding a proper amount of carbon source into the pre-sintered material, and carrying out secondary sanding treatment to obtain a second ground material; and carrying out spray drying on the second grinding material, and carrying out secondary sintering treatment to obtain the positive electrode material. The high-compaction ferric sodium pyrophosphate positive electrode material provided by the invention has high compaction density and excellent rate capability and cycle performance, and can be used for preparing a sodium ion battery with high compaction density, high capacity and good rate capability and cycle performance.

The invention discloses a high-temperature-irradiation-resistant zirconium alloy and a manufacturing method and a workpiece thereof, and belongs to the field of zirconium alloys. Wherein the zirconium alloy resistant to high temperature irradiation comprises the following components in percentage by weight: not less than 96% of Zr, 0.61%-1.4% of Sn, 0.41%-1.4% of Nb, 0.1%-0.5% of Fe, 0.11%-0.2% of O and 0.001%-0.3% of Cr; and from 0.015% to 0.03% of Si and / or from 0.001% to 0.06% of Ge; wherein Sn + Nb + O is greater than or equal to 1.5%, Fe / Cr is greater than or equal to 1.5%, Si + Ge is greater than or equal to 0.015%, and (Sn + Nb + O) / (Fe + Cr + Si + Ge) = 1.5-25.0. The alloy has good mechanical properties, corrosion resistance, creep resistance and radiation growth resistance, and is suitable for manufacturing of pressurized water reactor core structural members.

The invention relates to a preparation method of niobium-zirconium alloy spherical powder. The method comprises the following process steps: proportioning and mixing materials, pressing and sintering, smelting, hydrogenating and crushing, and spheroidizing. Aiming at the problems of high oxygen and nitrogen content, over-wide powder size distribution range, low powder yield and the like of the existing niobium-zirconium alloy spherical powder, the invention provides the preparation method of the niobium-zirconium alloy spherical powder, and the preparation method is used for preparing the niobium-zirconium alloy spherical powder of which the components, the size distribution, the yield and the sphericity rate meet the requirements of a laser melting bed additive manufacturing process. And technical support is provided for application and expansion of the niobium-zirconium alloy additive manufacturing technology in the fields of aerospace, chemical industry, nuclear power, military industry and the like.