2645 results about "Cerium" patented technology

The invention discloses a low-cost high-cerium neodymium iron boron diffusion magnet and a preparation method and application thereof, and relates to the technical field of rare earth permanent magnet materials. Comprising the steps that a neodymium iron boron alloy casting piece Ce30 with the Ce content being 10 wt% and a neodymium iron boron alloy casting piece Ce50 with the Ce content being 15 wt% are prepared through burdening and smelting, after the Ce30 and Ce50 neodymium iron boron alloy casting pieces are evenly mixed, hydrogen decrepitation, jet milling, oriented pressing, cold isostatic pressing and vacuum sintering are sequentially carried out, and a high-cerium sintered neodymium iron boron matrix is obtained; carrying out grain boundary diffusion on the high-cerium sintered neodymium-iron-boron matrix to obtain a high-cerium neodymium-iron-boron diffused magnet; the performance of the blank prepared through the method is close to the N40 mark, the performance of the magnetic sheet after diffusion reaches the 38MT mark, the magnetic performance is kept at the high level, the Ce content is high, efficient utilization of the high-abundance element cerium is achieved, the production cost of the rare earth permanent magnet material is greatly reduced, industrial batch production can be achieved, and balanced utilization of rare earth resources is promoted.

The invention relates to the technical field of smashing, and discloses a cerium oxide airflow smashing device and a production technology.The cerium oxide airflow smashing device comprises a base, four supporting legs arranged at equal angles are arranged on the base, a first tank is connected to the supporting legs, and an air injection mechanism used for spraying high-pressure airflow and driving materials to collide with one another to be smashed is installed in the first tank; a feeding pipeline positioned above the air injection mechanism is mounted on the first tank body; the inner wall of the first tank body is provided with four cooling assemblies which are arranged at equal angles, the upper port of the first tank body is connected with a second tank body through a flange, the second tank body is provided with a grading mechanism and a discharging pipeline corresponding to the grading mechanism, and the upper port of the second tank body is provided with a top cover; according to the device, efficient production is achieved through multi-dimensional innovation, a double-layer S-shaped cooling flow channel dissipates heat quickly, and high-temperature agglomeration of materials is avoided so as to guarantee stable physicochemical properties; and the four groups of opposed nozzles form a vortex field, so that the particle size refining rate of the material is more than 90%, and the energy consumption is reduced by 35%.

The invention relates to the technical field of aluminum alloys, in particular to a high-fluidity corrosion-resistant aluminum alloy material for laser cladding as well as preparation and application of the high-fluidity corrosion-resistant aluminum alloy material. The material comprises the following components in percentage by mass: 3.12%-5.34% of nickel, 4.24%-6.76% of molybdenum, 6.54%-8.12% of cobalt, 10.45%-14.49% of silicon, 5.65%-8.45% of a functional additive, 1.25%-2.45% of cerium oxide, 3.46%-7.42% of yttrium oxide, 3.45%-7.58% of lanthanum oxide and the balance of aluminum, the functional additive is titanium carbide doped with Ti < 3 + >. The aluminum alloy material has high flowability during laser cladding and is well combined with a matrix, and related properties such as wear resistance, high temperature resistance, corrosion resistance and oxidation resistance of a coating formed by the aluminum alloy material are sufficiently uniform due to the high flowability of the aluminum alloy material.

The invention belongs to the technical field of adsorbent preparation, and relates to a preparation method of a series of M-TCBB metal organic framework materials and application of the M-TCBB metal organic framework materials to adsorption of sulfur dioxide and ammonia gas. The preparation method comprises the following steps: dispersing [9, 9 '-dicarbazole]-3, 3', 6, 6 '-tetracarboxylic acid (H4TCBB) serving as an organic ligand and any one or more of yttrium salt, zirconium salt, hafnium salt, cerium salt and thorium salt in a solution according to a certain mass ratio, and carrying out solvothermal reaction at 100-120 DEG C; and after the reaction is finished, centrifuging to take a precipitate, washing and drying to obtain a series of M-TCBB metal organic framework materials. The series of M-TCBB metal organic framework materials prepared by the invention have relatively good adsorption acting force on sulfur dioxide and ammonia gas, and are high in adsorption cycle stability; under a humid condition, capture of sulfur dioxide and ammonia gas shows a humidity enhancement characteristic, namely, water vapor promotes enhancement of the adsorption capacity of sulfur dioxide and ammonia gas.

The invention discloses a neodymium-iron-boron magnet with double main phases and light rare earth diffusion based on asymmetric cerium distribution and a preparation method, and relates to the technical field of neodymium-iron-boron magnets. The method comprises the steps that a diffusion matrix is prepared through a double-main-phase technology, in the double-main-phase technology, the components of a main-phase alloy and an auxiliary-phase alloy are RaCebFe100-a-b-c-dMcBd, R is PrNd alloy or Nd metal, M is at least one of Cu, Al, Zr, Co and Ga, the content of Ce in the main-phase alloy is larger than that of Ce in the auxiliary-phase alloy, then the upper surface and the lower surface of the diffusion matrix are coated with a diffusion source solution, and the diffusion matrix is obtained through heat treatment. Carrying out heat treatment and aging treatment to obtain a neodymium-iron-boron magnet; the diffusion source solution is formed by mixing a diffusion source and a solvent, and the diffusion source is (PrmNdn) aAlbCucZrdCoeMgf. The neodymium-iron-boron magnet obtained through the method has high residual magnetism and high coercive force at the same time, the diffusion efficiency of the diffusion source is high, and the rare earth utilization rate is increased.

The invention relates to cerium oxide-based polishing powder and a preparation method thereof, a polishing solution and application, the cerium oxide-based polishing powder comprises porous secondary particles assembled by a plurality of primary crystal grains, the primary crystal grain aperture is 2-30 nm, the pore volume is 0.10-0.50 cm < 3 > / g, the specific surface area is 10-80 m < 2 > / g, and the content of surface trivalent cerium accounts for 10-40% of the total surface cerium content. The microstructure of the cerium oxide-based polishing powder is porous cerium oxide-based particles assembled by nano primary particles, and the self-assembly structure enables the cerium oxide-based polishing powder to have higher specific surface area while having higher surface trivalent cerium content, so that higher polishing rate can be obtained; due to the submicron particle size, the dispersity of the polishing slurry is improved; the Young modulus of the polishing powder is reduced due to the porous structure, so that the polishing powder is not easy to break in the polishing process, the surface precision of a polished workpiece is improved, and the service life of the polishing powder is prolonged. Therefore, the cerium oxide-based polishing powder provided by the invention has excellent polishing rate and polishing precision at the same time, and has relatively long service life.

The present invention discloses a medium-high performance neodymium iron boron and a preparation method thereof. Through the master-slave phase double alloy process, the master phase alloy is cerium iron boron with a low total rare earth content, and the slave phase is a neodymium iron boron alloy with a high total rare earth content, avoiding the entry of light rare earths in the master phase into the grain boundaries, while the surplus rare earths in the slave phase enter the grain boundaries and are recombined into rare earth-rich phases. The prepared magnet is processed into a thin magnetic sheet, and a low-melting-point HReM alloy is magnetron sputtered, realizing low-temperature grain boundary diffusion. This alloy improves the grain boundary wettability and also improves the fluidity of the rare earth-rich phase, enabling the cerium-containing neodymium iron boron master and slave phase grains to be quickly isolated during grain boundary diffusion. The low-temperature diffusion avoids the replacement of the diffused heavy rare earths by praseodymium, neodymium, and cerium elements, inhibits the exchange coupling between cerium iron boron grains, and makes the heavy rare earths free in the grain boundaries or interact with the rare earth-rich phase to form a core-shell structure on the surface layer of the master phase grains, enabling the rare earth-rich phase to be continuously and uniformly distributed, effectively enhancing the effectiveness of the grain boundary diffusion of heavy rare earth elements in improving the intrinsic coercivity of the cerium-containing magnet.

The invention discloses lanthanum-cerium mixed rare earth corrosion-resistant twisted steel with yield strength of 400MPa. The lanthanum-cerium mixed rare earth corrosion-resistant twisted steel comprises the following elements: 0.10 to 0.20 percent of C, 0.25 to 0.80 percent of Si, 0.90 to 1.60 percent of Mn, 0.020 to 0.045 percent of V, 0.003 to 0.010 percent of Ti, less than or equal to 0.010 percent of P, less than or equal to 0.010 percent of S, 0.25 to 0.65 percent of Ni, 0.25 to 0.70 percent of Cr, 0.10 to 0.18 percent of RE, less than or equal to 0.20 percent of Cu, less than or equal to 0.004 percent of O, less than or equal to 0.006 percent of N and the balance of Fe and inevitable impurities. The invention further discloses a production method of the lanthanum-cerium mixed rare earth corrosion-resistant twisted steel with the yield strength being 400 MPa. The production method comprises the working procedures of converter smelting, argon blowing refining, LF furnace refining, continuous casting and rolling, and the lanthanum-cerium mixed rare earth reinforced alloy cored wire and the silicon-calcium wire are fed into molten steel in the argon blowing refining process. The components, inclusions and mechanical properties of the produced 400 MPa-grade lanthanum-cerium mixed rare earth steel bar completely meet the technical requirements of the steel bar, the quality control requirement is met, and the 400 MPa-grade lanthanum-cerium mixed rare earth steel bar has the advantages of being high in strength, high in plasticity, resistant to corrosion and the like. The service life of the steel is prolonged, coating and galvanization are avoided, the burden of environmental protection is relieved, and reasonable application of resources is facilitated.

The invention discloses a low-smoke flame-retardant cable outer layer material, and a preparation method of key components and a high-entropy alloy nano material comprises the following steps: grinding cerous nitrate, ferric nitrate, manganous nitrate, sodium hexahydroxyplatinate and copper nitrate into particles according to a ratio of 2: 1: 1: 1: 1; then adding 10-20 times by mass of a 32% tannic acid solution and 5-8 times by mass of a 10% glutaraldehyde solution, carrying out an oil bath at 65-70 DEG C for a reaction for 4-8 h, then carrying out overnight vacuum freeze drying to obtain mixed powder, placing the mixed powder in a crucible of a muffle furnace, then calcining the mixed powder at 1000-1200 DEG C under the protection of nitrogen flow for 4-10 h, and finally cooling the calcined mixed powder to room temperature. And cooling. The prepared outer layer material for the cable overcomes the defects that a conventional cable easily releases a large amount of toxic smoke during combustion, is poor in flame retardant property and contains halogen to pollute the environment.

The invention relates to the technical field of welding, in particular to a lead-free solder composition and a preparation method thereof. The composition comprises brazing filler metal and a brazing flux, wherein the brazing filler metal comprises 55 to 65 parts of copper, 30 to 40 parts of zinc, 0.5 to 1 part of silver, 0.1 to 1 part of tin, 0.1 to 0.5 part of nickel, 0.02 to 0.15 part of lanthanum, 0.03 to 0.15 part of cerium and 0.05 to 0.2 part of indium; the brazing flux comprises 18-22 parts of borax, 13-17 parts of boric acid, 25-32 parts of a potassium fluoride and potassium fluoborate compound, 3-5 parts of calcium fluoride, 12-16 parts of aluminum oxide and 8-11 parts of magnesium oxide. The lead-free solder composition does not contain toxic lead elements, pollution to the environment and the ecological system is little, the wettability, corrosion resistance, strength, stability and the like of the lead-free solder composition are improved, and the welding quality is comprehensively improved. According to the preparation method, uniform distribution and accurate control of the brazing filler metal and the brazing flux are guaranteed, stability and consistency of product quality are guaranteed, and the preparation method is easy and convenient to operate and suitable for mass production.

The invention provides a method for synthesizing octahedral nano cerium oxide with a high Ce < 3 + > ratio and a chemical mechanical polishing solution, the polishing solution takes the synthesized octahedral cerium oxide as a grinding material, and the octahedral cerium oxide is prepared by the following specific steps: dissolving a certain amount of organic ligand and cerous nitrate in deionized water; controlling the ratio of the organic ligand to cerous nitrate to water to be (0.01-0.5): 1: (100-300), and stirring for 1-2 hours in a nitrogen atmosphere; dropwise adding a certain amount of alkali liquor into the solution at a certain speed in a nitrogen atmosphere, carrying out hydrothermal treatment on the mixture, controlling the reaction temperature to be 80-150 DEG C and the synthesis time to be 6-8 hours, centrifuging, drying and calcining the mixture after the reaction, calcining at the calcining temperature to be 400-600 DEG C and calcining for 4-8 hours, thereby obtaining the catalyst. The particle size of the octahedral nano cerium oxide is about 30-50nm, and the Ce < 3 + > ratio of the octahedral nano cerium oxide is high. The polishing solution taking the octahedral nano cerium oxide prepared by the method as the abrasive material has good dispersity and stability, high polishing rate and low surface roughness, and has wide popularization and application values.

The invention discloses a high-oxygen-storage zirconium solid solution material and a preparation method, and belongs to the technical field of rare earth catalytic materials, and the method comprises the following steps: precursor preparation, ultrasonic dispersion, double-gradient precipitation, ultrasonic aging, solid-liquid separation, three-section roasting and furnace cooling. Through the synergistic effect of double-gradient precipitation and ultrasonic aging, coarse grains and non-uniform particle size distribution are avoided, and the material is not prone to abnormal growth of the grains and structural collapse in long-term high-temperature service. Meanwhile, according to the gradient roasting process, through step-by-step regulation and control of crystal densification and crystal lattice reconstruction, separation of a fluorite phase and a pyrochlore phase easily occurring in traditional low-temperature single-section roasting is reduced, a stable crystal phase structure is maintained, it is ensured that the material can still keep sufficient active surface and pore channel structures under the working conditions of high temperature and thermal shock alternation, and the performance of the material is improved. The oxygen storage capacity and the long-term durability of the catalyst carrier are obviously improved.

The invention provides multi-element alloy silver-free copper-based brazing filler metal and a preparation method thereof.The brazing filler metal comprises, by mass, 30%-40% of zinc, 4%-11% of manganese, 1%-4% of tin, 0.2%-0.6% of silicon, 0.2%-1% of rare earth elements and the balance copper, the rare earth elements comprise cerium, praseodymium and rhenium, and the mass ratio of cerium to praseodymium to rhenium is (0.8-1.2): (0.8-1.2): (0.6-1.0). According to the multi-element alloy silver-free copper-based brazing filler metal, the performance of a brazed joint is improved, the strength, toughness, fatigue resistance and the like of the joint are improved, and the reliability and stability of connection under various working conditions are ensured.

The invention belongs to the technical field of stainless steel surface treatment, and particularly relates to a stainless steel passivation solution and a preparation method thereof. The water-based cutting fluid is prepared from the following raw materials: cerium salt, copper sulfate, citric acid, sodium dihydrogen phosphate, ammonium molybdate, sodium tungstate, aminated-silane modified SiO2 nanoparticles, polyethylene glycol, L-ascorbic acid, polyaspartic acid, an anti-settling agent, a surfactant and the balance of deionized water. According to the invention, a three-dimensional network skeleton is constructed by using aminated-epoxy group silane modified SiO2 nanoparticles, so that the problem of weak interface bonding force of a traditional passivation layer is solved; according to the formula, the proportion of biodegradable components such as citric acid and polyaspartic acid is extremely high, cerate adopts a low-toxicity rare earth compound, molybdenum / tungsten elements are fixed in a stable oxide form, the dosage of EDTA is remarkably reduced through a compounding technology, residual ions are adsorbed in combination with a three-dimensional network, and the balance of environment friendliness and long-acting corrosion resistance is achieved.

The present invention relates to the technical field of tungsten alloy materials, and in particular to a tungsten alloy wire, and a preparation method therefor and a use thereof. The tungsten alloy is composed of the following elements in percentage by mass: 0.45-0.9 wt% of L, 0.05-0.2 wt% of oxygen, and the balance being tungsten and inevitable impurities, wherein L is one or more of lanthanum, cerium, praseodymium, neodymium, gadolinium, and samarium, the wire has a wire diameter of 20-60 μm, in the wire, L or compounds of L exist in the axial direction of the wire in a linear shape, and the average width D of L or the compounds of L in the radial direction is less than or equal to 5 nm. The element L is controlled to be doped between the tungsten base materials in a linear shape, and the average width D of L in the radial direction to be less than or equal to 5 nm, so that cracks and wire breakage caused by second-phase particles in the subsequent pressure machining process are greatly reduced, thereby guaranteeing the mechanical strength of the tungsten alloy wire, and thus the wire has a tensile strength of 5000 MPa or above under a wire diameter of 20-60 μm, and the machining performance of the tungsten alloy wire is enhanced.

The invention provides a uric acid detection material Ce-UiO-66-X based on cerium-based UiO-66 as well as a preparation method and application of the uric acid detection material Ce-UiO-66-X, and belongs to the technical field of uric acid detection. The uric acid detection material Ce-UiO-66-X is prepared on the basis of a cerium-based metal organic framework material, and Ce-UiO-66-X can convert uric acid into allantoin and generate hydrogen peroxide at the same time. In the presence of hydrogen peroxide, Ce-UiO-66-X can be changed from white to orange, rapid quantitative analysis of uric acid concentration is carried out, one-step colorimetric rapid detection analysis of uric acid can be realized without participation of natural urate oxidase, peroxidase and a color developing agent, and the detection time is only 3 minutes. Moreover, a green and efficient uric acid detection material Ce-UiO-66-X water phase synthesis strategy is developed by using a carboxylic acid regulator, a material basis is provided for constructing a novel enzyme-free uric acid rapid detection method, and the method is safe and environmentally friendly.

The invention relates to the field of photoelectrocatalysis, and provides a preparation method and application of a cerium-based double-layer composite material coated with indium zinc sulfide, and the preparation method comprises the following steps: dispersing Ce (IV)-MOF in DMF and methanol, adding a hydroxyl-containing organic ligand, carrying out room temperature ultrasonic treatment to obtain modified MOF, dispersing the modified MOF in water and glycerin, adding a zinc salt and an indium salt, stirring, adding thioacetamide, stirring, filtering, washing, and drying to obtain the cerium-based double-layer composite material coated with indium zinc sulfide. And heating to obtain the product indium zinc sulfide coated cerium-based double-layer composite material. According to the invention, an ultrasonic-assisted MOF ligand exchange technology is utilized, so that an MOF regular octahedral framework structure is well maintained; the ZnIn2S4 material is compounded through in-situ growth of ZnIn2S4, the compounding synthesis temperature and a solution system are optimized, a ZnIn2S4 double-layer coating structure is obtained, and the yield and dispersity of ZnIn2S4 are improved. And the prepared ZnIn2S4 / MOF composite material has excellent reaction efficiency and stability of photoelectrocatalytic hydrogen production.

The invention relates to the technical field of metal materials, and discloses a light high-strength zinc alloy and a preparation method and application thereof.The zinc alloy takes aluminum and magnesium as main alloy elements, scandium-yttrium pre-alloying components, cerium-lanthanum composite rare earth and a nano TiB2 particle reinforced phase are introduced, and grain refinement and interface strengthening are achieved through the synergistic effect of multiple components; the preparation method comprises the key processes of pre-alloy smelting, dynamic magnetic field assisted die casting, gradient aging treatment and the like, and the defects of melt oxidation and solidification are effectively controlled. The zinc alloy has low density, high specific strength, corrosion resistance and excellent surface treatment adaptability, is suitable for manufacturing of precise metal fasteners such as belt buckles, belt buckles and shoe buckles, can remarkably improve the anti-fatigue performance and appearance quality of products, meanwhile, reduces processing energy consumption and material loss, and meets the market requirements of light-weight and high-end hardware fittings.

The invention provides a cerium oxide photo-thermal synergistic catalytic material loaded with a metal promoter as well as a preparation method and application of the cerium oxide photo-thermal synergistic catalytic material. The cerium oxide photo-thermal synergistic catalytic material loaded with the metal promoter comprises a cerium oxide nanocrystal and the metal promoter loaded on the surface of the cerium oxide nanocrystal, the exposed crystal face of the cerium oxide nanocrystal comprises a {111} crystal face, and the area of the {111} crystal face accounts for more than 50% of the total area of the outer surface of the crystal face; the mass fraction of the metal cocatalyst is 0.1-2wt% of the mass of the cerium oxide. The catalytic material provided by the invention takes cerium oxide with a {111} crystal face as an exposed special crystal face as a carrier, photons can be captured and charges can be separated more efficiently, and phonons further promote deep trap state charge release. Meanwhile, the metal additive is added and cooperates with cerium oxide with exposed special crystal faces for catalysis, so that the catalytic effect is remarkably improved, and efficient catalytic combustion of methane is achieved under the mild condition.

The present invention belongs to the field of material preparation, and discloses a preparation method and application of a composite material of Pd, cerium oxide and silicon dioxide with a controllable hierarchical catalytic structure. Cerium oxide rich in oxygen vacancies is used as a carrier, and Pd species are loaded by impregnation, and then dispersed on the surface of acidic silicon dioxide with a high specific surface area. Finally, a Pd / CeO2 / SiO2 material with a controllable hierarchical catalytic structure is prepared by high-temperature calcination and reduction, and is used to catalyze the hydrogenation conversion reaction of furfural. The preparation method of the present invention is simple, green and environmentally friendly, highly active, stable, cheap and easy to obtain, and can efficiently catalyze the hydrogenation conversion of furfural, and has good industrial application prospects.

The invention provides a cerium oxide-loaded mesoporous carbon sphere material and a preparation method and application thereof, and belongs to the technical field of cerium oxide composite material preparation, and the preparation method comprises the following steps: carrying out a hydrothermal reaction on cerium salt under the action of an alkaline mesoporous carbon sphere aqueous solution to obtain a mixed solution; the mass fraction of the mesoporous carbon spheres in the mixed solution is 1-4 wt%, and the concentration of the cerium salt is 0.04-0.06 mol / L; and carrying out centrifugal washing on the obtained mixed solution, and carrying out vacuum drying to obtain the cerium oxide loaded mesoporous carbon sphere material. The mesoporous carbon sphere has a large specific surface area and a uniform pore structure, the pore structure of the mesoporous carbon sphere is very close to the diameter of the short rod type CeO, and the short rod type CeO can be embedded into the pore of the mesoporous carbon sphere due to the size matching, so that tight physical contact is formed; meanwhile, hydroxyl groups on the surfaces of the carbon spheres and oxygen vacancies on the surfaces of the CeO particles can form stable covalent bonds, so that the bonding strength of the cerium oxide-loaded mesoporous carbon spheres is improved, and the service life of the cerium oxide-loaded mesoporous carbon spheres is prolonged.

The invention discloses a synthesis method of a hydrazine dicarboxylate modified cerium dioxide abrasive, and belongs to the technical field of precise polishing materials. The method comprises the following steps: taking cerous nitrate as a raw material, and preparing a cerous carbonate precursor through an ammonium carbonate precipitation reaction; and grinding and calcining the obtained precursor and hydrazine dicarboxylate to obtain the CeO2 grinding material with the surface rich in oxygen vacancies. And Ce < 4 + > can be partially reduced into Ce < 3 + > by reducing fragments generated by decomposition of the hydrazine dicarboxylate in the calcining process, so that an oxygen vacancy structure is formed through induction, and the chemical activity and the reaction rate of the abrasive are improved. The obtained grinding material shows excellent performance in chemical mechanical polishing (CMP) of K9 glass, the material removal rate (MRR) is increased by about 3.6 times compared with that of unmodified CeO2, the surface roughness (Ra) is reduced to about 0.16 nm or below, and grinding material particles are good in dispersity and less in agglomeration. The used hydrazine dicarboxylate is stable, low in toxicity and mild in reaction, and the particle size can be prevented from excessively growing while the high oxygen vacancy concentration is kept.

The invention discloses a blue-and-white glaze and a preparation method and application thereof, and belongs to the technical field of inorganic non-metallic materials (ceramics), the blue-and-white glaze comprises quartz, feldspar, limestone, plant ash and other basic raw materials, zinc oxide, aluminum oxide, lanthanum oxide, cerium oxide and other rare earth elements, and a modified organic additive is introduced. Compared with the prior art, the blue-and-white glaze shows excellent stability in the drying and firing process, the phenomena of cracking and glaze stripping are effectively reduced, the friction coefficient after firing is low, the breaking strength and the breaking modulus are high, the glossiness and transparency of a glaze surface are remarkably improved, and the blue-and-white glaze has important application value.

The invention provides a low-cost high-specific-surface-area cerium-aluminum composite oxide, a preparation method and application thereof, and relates to the technical field of catalysts, the preparation method comprises the following steps: step S1, adding 10-40% of cerium salt, 50-90% of aluminum salt and 0-10% of lanthanum source or zirconium source into deionized water, stirring and mixing, filtering, and washing to be neutral to obtain a cerium-containing solution; step S2, impregnating an alumina carrier in the cerium-containing solution prepared in the step S1, and standing to enable the cerium-containing solution to be impregnated on the alumina carrier, so as to obtain impregnated slurry; and S3, drying the dipping slurry, and then roasting in an inert atmosphere to obtain the cerium-aluminum composite oxide. The stable cerium-aluminum composite material is formed by doping one of lanthanum and zirconium with different masses into aluminum oxide or cerium oxide, the problem that the adsorption capacity of a traditional ammonia trapping method is limited is effectively solved, and the adsorption capacity of the material to ammonia is remarkably improved.

The invention belongs to the technical field of new materials, and discloses a method for preparing indium cerium oxide powder based on an electrochemical method, which comprises the following steps: by taking indium cerium alloy as an anode and an inert electrode as a cathode, carrying out electrolytic reaction in an alkaline electrolyte to generate an indium cerium hydroxide precipitate; the hydroxide precipitate is pyrolyzed after being washed, and indium cerium oxide powder is generated. According to the method, an electrolytic method is adopted for preparing mud of indium cerium hydroxide, the grain size of the mud is very small, in the precipitation reaction, the indium cerium hydroxide is evenly mixed, then pyrolysis is conducted, and the indium cerium oxide powder with good uniformity can be obtained. Meanwhile, the invention further provides the cerium indium oxide powder, the target material and the transparent conductive oxide film which are prepared on the basis of the method.

The invention relates to the technical field of copper alloys, in particular to a high-conductivity wear-resistant copper alloy and a preparation method and application thereof. A high-conductivity wear-resistant copper alloy comprises, by mass, 3-6% of nickel, 2-5% of tin, 1-3% of zinc, 0.1-0.5% of a rare earth element, 0.8-1.2% of a carbon nanotube-copper intermediate alloy and the balance copper, the rare earth element is one of cerium and lanthanum, the conductivity of the high-conductivity wear-resistant copper alloy is larger than or equal to 94% IACS, and the Vickers hardness of the high-conductivity wear-resistant copper alloy is larger than or equal to 120 HV. By regulating and controlling the mass ratio of nickel (Ni) to tin (Sn), adding the rare earth element and the carbon nanotube-copper intermediate alloy and accurately controlling the preparation process, the conductivity, wear resistance and mechanical property of the copper alloy material are remarkably improved, and the copper alloy material has wide application prospects in the fields of power transmission, high-speed transportation, ocean engineering and the like.

The invention relates to the technical field of metal material hot working, and discloses a hot-rolled coiled plate production process which comprises the following steps: preparing a reaction type protective agent, the high-temperature-resistant coating is prepared from the following raw materials in parts by weight: 20 to 40 parts of tetraethoxysilane, 5 to 15 parts of triethyl phosphate, 1 to 5 parts of triethyl borate, 0.5 to 2.0 parts of cerous nitrate (III) hexahydrate, 0.1 to 1.0 part of lithium acetate and 0.01 to 0.05 part of vanadyl acetylacetonate (IV). Coating the surface of a hot-rolled plate blank with the protective agent; the coated plate blank is heated in a heating furnace, so that the protective agent forms a molten-state protective layer in situ; carrying out hot rolling on the plate blank with the molten protective layer; and cooling and coiling the hot-rolled steel strip. In the whole heating and hot rolling process, the molten protective layer isolates the contact between the steel and the oxidizing atmosphere, so that the generation of oxide scales is fundamentally inhibited, the production process is simplified, and the metal yield is increased.

The invention discloses a coating with in-situ plugging and active protection functions as well as a preparation method and application thereof, and belongs to the technical field of metal material surface treatment. An innovative electrolyte design scheme is provided, the commercial 5083 aluminum alloy is subjected to micro-arc oxidation in a phosphate system containing specific cerium salt and a complexing agent, film layer growth and in-situ chemical blocking of micropores are completed in one step, the process is simple, and the obtained coating has excellent blocking firmness and corrosion resistance, has an active protection function and is suitable for large-scale industrial production. And a new solution is provided for improving the durability of the 5083 aluminum alloy in a harsh marine environment.

The invention relates to the technical field of explosion suppression, in particular to a composite powder explosion suppressant and a design method and a preparation method thereof. The composite powder explosion suppressant is prepared from the following components in parts by mass: 20 to 25 parts of aluminum oxide, 10 to 20 parts of magnesium oxide, 20 to 30 parts of silicon dioxide, 1 to 3 parts of cerium oxide, 10 to 15 parts of potassium bicarbonate, 10 to 15 parts of sodium bicarbonate, 3 to 8 parts of gas-phase hydrophobic white carbon black and 2 to 6 parts of talcum powder. The composite powder explosion suppressant disclosed by the invention is high in explosion suppression efficiency; the metal oxide component screened through quantum chemistry calculation has good explosion suppression performance, and all the components in the composite powder explosion suppressant have a synergistic effect, so that hydrogen explosion can be effectively inhibited.

The invention belongs to the technical field of neodymium iron boron rare earth permanent magnets, and relates to a cerium-containing neodymium iron boron magnet with high coercivity and high stability and a preparation method thereof. According to the preparation method, the cerium-containing copper auxiliary alloy and the neodymium iron boron magnetic powder are ingeniously combined, the whole preparation process is optimized, and remarkable technical progress and economic benefits are achieved. Firstly, in the aspect of magnetic performance, Ce in a specific proportion is added into the cerium-containing copper auxiliary alloy, the cerium-containing copper auxiliary alloy is used, the coercive force of a magnet is effectively improved, high residual magnetism is kept to a certain degree, and introduction of Cu is beneficial to refining of grains and improvement of a grain boundary phase structure; therefore, the reverse magnetization resistance in the magnet is enhanced, and the magnet can maintain stable performance in a wider temperature range.