1244 results about "Cerium" patented technology

The invention discloses a neodymium-iron-boron magnet with double main phases and light rare earth diffusion based on asymmetric cerium distribution and a preparation method, and relates to the technical field of neodymium-iron-boron magnets. The method comprises the steps that a diffusion matrix is prepared through a double-main-phase technology, in the double-main-phase technology, the components of a main-phase alloy and an auxiliary-phase alloy are RaCebFe100-a-b-c-dMcBd, R is PrNd alloy or Nd metal, M is at least one of Cu, Al, Zr, Co and Ga, the content of Ce in the main-phase alloy is larger than that of Ce in the auxiliary-phase alloy, then the upper surface and the lower surface of the diffusion matrix are coated with a diffusion source solution, and the diffusion matrix is obtained through heat treatment. Carrying out heat treatment and aging treatment to obtain a neodymium-iron-boron magnet; the diffusion source solution is formed by mixing a diffusion source and a solvent, and the diffusion source is (PrmNdn) aAlbCucZrdCoeMgf. The neodymium-iron-boron magnet obtained through the method has high residual magnetism and high coercive force at the same time, the diffusion efficiency of the diffusion source is high, and the rare earth utilization rate is increased.

The invention discloses a high-oxygen-storage zirconium solid solution material and a preparation method, and belongs to the technical field of rare earth catalytic materials, and the method comprises the following steps: precursor preparation, ultrasonic dispersion, double-gradient precipitation, ultrasonic aging, solid-liquid separation, three-section roasting and furnace cooling. Through the synergistic effect of double-gradient precipitation and ultrasonic aging, coarse grains and non-uniform particle size distribution are avoided, and the material is not prone to abnormal growth of the grains and structural collapse in long-term high-temperature service. Meanwhile, according to the gradient roasting process, through step-by-step regulation and control of crystal densification and crystal lattice reconstruction, separation of a fluorite phase and a pyrochlore phase easily occurring in traditional low-temperature single-section roasting is reduced, a stable crystal phase structure is maintained, it is ensured that the material can still keep sufficient active surface and pore channel structures under the working conditions of high temperature and thermal shock alternation, and the performance of the material is improved. The oxygen storage capacity and the long-term durability of the catalyst carrier are obviously improved.

The invention provides a cerium oxide photo-thermal synergistic catalytic material loaded with a metal promoter as well as a preparation method and application of the cerium oxide photo-thermal synergistic catalytic material. The cerium oxide photo-thermal synergistic catalytic material loaded with the metal promoter comprises a cerium oxide nanocrystal and the metal promoter loaded on the surface of the cerium oxide nanocrystal, the exposed crystal face of the cerium oxide nanocrystal comprises a {111} crystal face, and the area of the {111} crystal face accounts for more than 50% of the total area of the outer surface of the crystal face; the mass fraction of the metal cocatalyst is 0.1-2wt% of the mass of the cerium oxide. The catalytic material provided by the invention takes cerium oxide with a {111} crystal face as an exposed special crystal face as a carrier, photons can be captured and charges can be separated more efficiently, and phonons further promote deep trap state charge release. Meanwhile, the metal additive is added and cooperates with cerium oxide with exposed special crystal faces for catalysis, so that the catalytic effect is remarkably improved, and efficient catalytic combustion of methane is achieved under the mild condition.

The invention discloses a synthesis method of a hydrazine dicarboxylate modified cerium dioxide abrasive, and belongs to the technical field of precise polishing materials. The method comprises the following steps: taking cerous nitrate as a raw material, and preparing a cerous carbonate precursor through an ammonium carbonate precipitation reaction; and grinding and calcining the obtained precursor and hydrazine dicarboxylate to obtain the CeO2 grinding material with the surface rich in oxygen vacancies. And Ce < 4 + > can be partially reduced into Ce < 3 + > by reducing fragments generated by decomposition of the hydrazine dicarboxylate in the calcining process, so that an oxygen vacancy structure is formed through induction, and the chemical activity and the reaction rate of the abrasive are improved. The obtained grinding material shows excellent performance in chemical mechanical polishing (CMP) of K9 glass, the material removal rate (MRR) is increased by about 3.6 times compared with that of unmodified CeO2, the surface roughness (Ra) is reduced to about 0.16 nm or below, and grinding material particles are good in dispersity and less in agglomeration. The used hydrazine dicarboxylate is stable, low in toxicity and mild in reaction, and the particle size can be prevented from excessively growing while the high oxygen vacancy concentration is kept.

The invention provides a low-cost high-specific-surface-area cerium-aluminum composite oxide, a preparation method and application thereof, and relates to the technical field of catalysts, the preparation method comprises the following steps: step S1, adding 10-40% of cerium salt, 50-90% of aluminum salt and 0-10% of lanthanum source or zirconium source into deionized water, stirring and mixing, filtering, and washing to be neutral to obtain a cerium-containing solution; step S2, impregnating an alumina carrier in the cerium-containing solution prepared in the step S1, and standing to enable the cerium-containing solution to be impregnated on the alumina carrier, so as to obtain impregnated slurry; and S3, drying the dipping slurry, and then roasting in an inert atmosphere to obtain the cerium-aluminum composite oxide. The stable cerium-aluminum composite material is formed by doping one of lanthanum and zirconium with different masses into aluminum oxide or cerium oxide, the problem that the adsorption capacity of a traditional ammonia trapping method is limited is effectively solved, and the adsorption capacity of the material to ammonia is remarkably improved.

The invention relates to the technical field of metal material hot working, and discloses a hot-rolled coiled plate production process which comprises the following steps: preparing a reaction type protective agent, the high-temperature-resistant coating is prepared from the following raw materials in parts by weight: 20 to 40 parts of tetraethoxysilane, 5 to 15 parts of triethyl phosphate, 1 to 5 parts of triethyl borate, 0.5 to 2.0 parts of cerous nitrate (III) hexahydrate, 0.1 to 1.0 part of lithium acetate and 0.01 to 0.05 part of vanadyl acetylacetonate (IV). Coating the surface of a hot-rolled plate blank with the protective agent; the coated plate blank is heated in a heating furnace, so that the protective agent forms a molten-state protective layer in situ; carrying out hot rolling on the plate blank with the molten protective layer; and cooling and coiling the hot-rolled steel strip. In the whole heating and hot rolling process, the molten protective layer isolates the contact between the steel and the oxidizing atmosphere, so that the generation of oxide scales is fundamentally inhibited, the production process is simplified, and the metal yield is increased.

The invention discloses a coating with in-situ plugging and active protection functions as well as a preparation method and application thereof, and belongs to the technical field of metal material surface treatment. An innovative electrolyte design scheme is provided, the commercial 5083 aluminum alloy is subjected to micro-arc oxidation in a phosphate system containing specific cerium salt and a complexing agent, film layer growth and in-situ chemical blocking of micropores are completed in one step, the process is simple, and the obtained coating has excellent blocking firmness and corrosion resistance, has an active protection function and is suitable for large-scale industrial production. And a new solution is provided for improving the durability of the 5083 aluminum alloy in a harsh marine environment.

The invention relates to the technical field of chemical catalysts, in particular to a cerium-based solid solution loaded iron-based oxygen vacancy enhanced low-temperature ammonia synthesis catalyst. The heterovalent ions are doped in CeO2 crystal lattices to introduce strain and defects, so that the oxygen vacancy formation energy and concentration are greatly improved. Experiments show that the oxygen vacancy concentration (delta) of the Ce0. 8Zr0. 2O2-delta carrier disclosed by the invention can reach 0.12, which is 3-5 times that of pure CeO2. Under the conditions of 250 DEG C and 5 MPa, the ammonia synthesis rate reaches 120 [mu] mol / g / h, which is more than 20 times that of a traditional molten iron catalyst; under the conditions of 350 DEG C and 10 MPa, the ammonia synthesis rate exceeds 1000 [mu] mol / g / h and is close to the level of a noble metal ruthenium-based catalyst. As the working temperature is reduced by 100-150 DEG C, the reaction heat consumption is reduced by more than 30%, and the overall energy consumption is reduced by 25-40%.

The invention discloses a preparation method of a rare earth element doped nickel-based selenide nano-material and application of the rare earth element doped nickel-based selenide nano-material in electro-catalysis water full-hydrolysis reaction. According to the method, nickel salt, cerium salt, selenium dioxide and potassium chloride are prepared into electrolyte, and the electrolyte is subjected to electro-deposition on a foamed nickel substrate to obtain Ce-doped Ni0.85Se nanoparticles growing on foamed nickel. The crystal structure and electron distribution of Ni0.85Se are optimized by doping trace rare earth element cerium, so that the HER and OER performances of the Ni0.85Se are greatly improved. The prepared catalyst is self-supporting closely-packed nanoparticles, the formed amorphous structure is easy to expose more active sites, the catalyst has good electrocatalytic hydrogen evolution and oxygen evolution performance under alkaline conditions, the overpotential in electrocatalysis of nickel-based selenide is greatly reduced, and the electrocatalytic performance of nickel-based selenide is improved. And excellent electro-catalytic activity is shown in electro-catalytic water full hydrolysis. And the self-supporting electrode is not easy to fall off due to generation of bubbles in the reaction process, so that the working stability of the catalyst is improved.

The method comprises the following steps: weighing an oxide precursor of metal indium, an oxide precursor of metal M, an ammonium salt and a lithium salt according to a chemical formula of indium-based halide, fully mixing, and calcining in an inert atmosphere to obtain the indium-based halide solid electrolyte. Forming an indium-based halide solid electrolyte through a solid-phase reaction; wherein M is selected from at least one of magnesium, calcium, strontium, barium, aluminum, gallium, indium, bismuth, scandium, yttrium, zinc, germanium, tin, lanthanum, cerium, samarium, gadolinium, holmium, erbium and ytterbium. The method can greatly simplify the synthesis process, reduce the raw material cost and realize industrial batch preparation.

The invention relates to the technical field of metal material manufacturing, and discloses a manufacturing process of a super-strong wear-resistant tire protection chain, which comprises the following steps of: forming a chain link blank by adopting high-silicon high-manganese bainite steel through hot rolling and hot die forging; the core of the method is an integrated heat treatment step, specifically, surface functionalization co-permeation of copper and cerium elements is synchronously carried out in the austenitizing stage, then bainite isothermal quenching is carried out, and a composite structure of bainite and stable retained austenite is obtained in a matrix; the process further comprises the steps that a special high-toughness welding wire is adopted for welding, and local tempering treatment is conducted on a welding seam; by means of the scheme, the chain link is endowed with excellent obdurability and fatigue resistance through the phase transformation induced plasticity effect of the base body, the abrasion resistance is remarkably improved through the surface functionalization co-cementation layer, and the reliability of a joint area is ensured through accurate welding and postweld treatment. The technical problems that wear resistance and toughness of a traditional protection chain are difficult to consider at the same time, and a welding joint is prone to failure are systematically solved.

The present invention relates to an ammonia decomposition catalyst and a manufacturing method thereof, and more particularly to an ammonia decomposition catalyst containing alumina (Al2O3), cerium (Ce), lanthanum (La), ruthenium (Ru) and potassium (K).

This invention relates to the field of special agents for treating air pollution, specifically to a rare earth water-based environmentally friendly urea crystal remover for vehicles and its preparation method. The raw materials for preparing the rare earth water-based environmentally friendly urea crystal remover for vehicles, by weight, include: 0.005-0.2 parts rare earth-based catalyst, 3-10 parts surfactant, 1-3 parts dispersant, 5-10 parts stabilizer, and 80-100 parts deionized water; wherein the rare earth-based catalyst includes at least a cerium-based catalyst. The urea crystal remover provided by this invention has excellent performance, effectively removing urea crystals, and the cerium emission concentration is far below the requirements of the EURO 7 draft (EURO 7 does not require cerium). NOx conversion rate is significantly improved, making it more suitable for vehicles using high-sulfur fuels, and greatly benefiting the control of air pollution from mobile sources. It is also environmentally safe and environmentally friendly.

The invention discloses a high-aluminum wear-resistant ceramic grinding ball and a preparation method thereof. The grinding ball comprises the following raw materials in percentage by weight: 85%-95% of aluminum oxide, 2%-10% of silicon dioxide, 1%-3% of calcium carbonate, 0.2%-0.5% of magnesium carbonate, 0.03%-0.05% of titanium dioxide, 0.01%-0.03% of sodium oxide and 1%-5% of modified zirconium dioxide. The preparation method of the modified zirconium dioxide comprises the following steps: adding hydrogen peroxide into a mixed solution of soluble cerium salt and soluble zirconium salt to obtain a reaction system; adding the reaction system into an alkaline solution for reaction, and collecting an insoluble substance after the reaction is finished; and calcining the insoluble substance to obtain the modified zirconium dioxide. The ceramic ball is simple in formula, rich in raw materials, low in price and low in production cost, the operation stability of the ceramic ball is improved, and the service life is prolonged.

The invention belongs to the technical field of electrochemistry, and particularly provides a lanthanum-cerium double-doped sodium ferric sulfate positive electrode material and a preparation method thereof. The material is composed of a matrix and a carbon coating layer coating the matrix, the matrix has a chemical expression of Na6Fe4-x-yLaxCey (SO4) 7, x is greater than or equal to 0.01 and less than or equal to 0.1, and y is greater than or equal to 0.01 and less than or equal to 0.1. The material is prepared through spray drying and high-temperature sintering treatment in sequence, the particle morphology is regular, and the particle size distribution is uniform; the electronic conductivity and Na < + > diffusion rate of the material are remarkably improved by rare earth doping, so that the material has more excellent low-temperature cycle performance, sodium storage performance and the like.

The invention relates to an ultrasonic vibration assisted large-width copper plate strip continuous extrusion short-process technology, and belongs to the technical field of metal processing. A copper raw material is subjected to mechanical cleaning and then ultrasonic cleaning, and the surface cleanliness of the raw material is guaranteed; the cleaned copper raw materials are fed into continuous extrusion equipment, and ultrasonic vibration is adopted for assisting continuous extrusion; after the extruded copper plate strip is cooled, spraying a suspension containing cerium (IV)-sodium dodecyl benzene sulfonate-pyrrolidone nano aluminum oxide additive on the surface of the copper plate strip, and drying; straightening by using a multi-roll straightening machine to obtain a large-width copper plate strip; the cerium (IV)-sodium dodecyl benzene sulfonate-pyrrolidone nanometer aluminum oxide auxiliary agent is prepared from nanometer aluminum oxide, DMF (Dimethyl Formamide), sodium dodecyl benzene sulfonate, N-vinyl pyrrolidone, ammonium persulfate and cerous sulfate (IV); the copper plate strip prepared by the invention has relatively high density, relatively high tensile strength and ductility, and the mechanical property of the copper plate strip is remarkably improved.

The invention discloses a preparation process of a rare earth precipitation resistant electrophoretic coating for an automobile body. The preparation process comprises the following steps: S1, preparing a stable solution; s2, preparing a rare earth chelating solution; adding lanthanum lactate into the stable solution for multiple times, and adding ammonium ceric sulfate for multiple times after the lanthanum lactate is completely dissolved; s3, preparing a resin base solution; s4, preparing mixed slurry; s5, adding a solvent and an auxiliary agent; a five-membered ring chelate with thermodynamic stability is formed by carboxyl, hydroxyl and rare earth elements in sodium citrate, rare earth ions can be tightly wrapped through strong coordination bonds, namely, empty orbits of the rare earth ions and lone pair electrons of a chelating agent form coordination bonds, so that the rare earth ions cannot be dissociated in a system, and the rare earth ions are prevented from being dissociated in the system. And a path of generating hydroxide precipitates by free rare earth ions is thoroughly blocked, so that rare earth elements are effectively ensured to be uniformly distributed in the electrophoretic paint, and the surface of a raw material treated by a subsequent electrophoresis process is more uniform.

The application discloses a preformed methane reforming catalyst and a preparation method thereof. The catalyst comprises a nickel-active alumina first functional component, a cerium oxide nanocluster second functional component and an alumina inert phase. The preparation method comprises preforming an inert phase pretreatment, hydrothermal treatment, calcination and reduction. The preformed inert phase after pretreatment is used as a carrier, which greatly improves the catalyst strength, pertinently weakens the metal-carrier interaction, avoids bed layer temperature drop and carbon deposition caused by local high strength reaction, and improves the operation stability. The first functional component with a layered structure and the second functional component rich in oxygen vacancies further improve the catalyst activity and stability, and the performance indicators are overall superior to those of the existing catalyst products. The preparation method is simple and easy to implement, has no special requirements on equipment, and is conducive to the popularization and application in the fields of methane steam reforming and methane dry reforming.

The invention discloses zwitterion co-doped CeO2 abrasive particles and a preparation method and application thereof.The preparation method includes the steps that a cerium source and a soluble carbonate precipitator are subjected to an aging reaction to obtain a cerium-based precursor, and the cerium-based precursor, fused salt, metal ions and a fluorinating agent are mixed and then roasted to obtain the zwitterion co-doped CeO2 abrasive particles; the synthesis method is simple, the size is controllable, the particle size distribution is uniform, and the spherical-like zwitterion co-doped CeO2 abrasive particles are obtained; the co-doped CeO2 abrasive particles have excellent photo-assisted chemical mechanical polishing performance; when the polishing solution prepared from the sphere-like co-doped CeO2 abrasive particles synthesized by the method is used for processing the surface of quartz glass, the material removal rate reaches 988.69 nm / min, and a high material removal rate is obtained due to the fact that the co-doped CeO2 abrasive particles synthesized by the two-step method shorten the forbidden bandwidth and have high chemical activity, so that the material removal rate is favorably improved.

The hydrogen transmission pipeline steel comprises the following chemical components in percentage by mass: 0.020%-0.045% of C, 0.11%-0.19% of Si, 1.45%-1.65% of Mn, less than or equal to 0.0010% of S, less than or equal to 0.008% of P, 0.015%-0.045% of Al, 0.040%-0.060% of Nb, 0.020%-0.035% of Ti, 0.30%-0.50% of Cr, 0.0040%-0.0080% of RE, less than or equal to 0.004% of N, less than or equal to 0.0015% of O, less than or equal to 0.0001% of H and the balance of Fe and other inevitable impurities, the conditions that the carbon equivalent Ceq = C + Mn / 6 + (Cr) / 5 is less than or equal to 0.35%, the Nb / Ti = the rare earth element is selected from at least one of lanthanum, cerium and neodymium. The invention aims to solve the technical problems that the existing hydrogen transmission pipeline steel is easy to generate hydrogen embrittlement, short in fatigue life and high in production cost in a high-pressure hydrogen environment, and meets the core requirements of hydrogen energy long-distance transmission pipeline engineering on high strength, high hydrogen embrittlement resistance, high fatigue performance and low cost of materials.

The invention discloses a preparation method and application of a multimode luminescent cesium yttrium chloride lead-free perovskite luminescent material. In the specific synthesis process, firstly, precursor materials-cesium carbonate, yttrium carbonate and cerium acetate are dissolved in a mixed solution of glacial acetic acid and hydrochloric acid, and a precursor solution is obtained; then dissolving a certain amount of antimony acetate with acetonitrile to form an anti-solvent solution; and finally, adding the precursor solution into the anti-solvent solution to obtain the Sb / Ce double-doped cesium yttrium chloride lead-free perovskite luminescent material. During application, the Cs3YCl6 Sb and the Cs3YCl6 Sb / Ce luminescent materials are combined for use to form a pattern, and protected information can be decrypted through a specific excitation wavelength. According to the invention, the cesium yttrium chloride lead-free perovskite luminescent material capable of realizing multimode luminescence can be prepared in a short time.

The invention belongs to the technical field of EBSD sample preparation of heterogeneous materials, and particularly relates to an EBSD sample preparation method of an Al7075 / Al6061 bimetal composite cast ingot. According to the method, mechanical grinding and polishing and argon ion polishing are combined for EBSD sample preparation, during mechanical grinding and polishing, aluminum oxide polishing paste is selected for rough polishing, aluminum oxide or chromium oxide polishing paste is selected for fine polishing, and finally cerium oxide polishing paste is selected for fine polishing, so that crystal lattices with complete and distortionless sample surface layers are obtained as far as possible, and the defects such as trailing are reduced to the maximum extent; the optimal surface characteristics are provided for subsequent argon ion polishing, and meanwhile, the calibration rate of an Al7075 / Al6061 bimetal composite cast ingot EBSD sample prepared through the method is not lower than 90% in combination with the optimal argon ion polishing process parameters.

The invention discloses a low-corrosion halogen-free soldering flux for aluminum-based part brazing and a preparation method of the low-corrosion halogen-free soldering flux, and belongs to the technical field of halogen-free welding materials.The low-corrosion halogen-free soldering flux comprises, by mass, 4-6 parts of oxalic acid, 1-2 parts of triethanolamine, 0.8-1.5 parts of Tween-80, 4-6 parts of polyvinylpyrrolidone, 0.3-1 part of compound nano cerium oxide, 0.5-1.5 parts of chitosan oligomer and the balance deionized water. And the welding spot oxidation resistance and the interface self-repairing capability are further improved. Through the synergistic effect of four mechanisms of complexing, oxidation prevention, wetting and film forming, the flux achieves efficient film removal, excellent wetting, no corrosion residue and stable film forming protection, is high in shear strength, low in welding spot porosity and clean in surface after welding, and is suitable for electronic packaging, heat exchanger manufacturing and high-reliability aluminum welding occasions.

A preparation method for high-nitrogen austenitic stainless steel. The high-nitrogen austenitic stainless steel comprises the following chemical components in percentages by weight: carbon: ≤0.02%; silicon: 0.4-0.8%; manganese: 10.2-12.5%; chromium: 24.5-26.5%; nickel: 13.5-16.5%; molybdenum: 3.2-4.8%; nitrogen: 0.75-0.95%; phosphorus: ≤0.03%; sulfur: ≤0.0025%; vanadium: 0.016-0.022%; niobium: 0.026-0.034%; copper: 0.2-0.35%; aluminum: 0.01-0.02%; cerium: 0.015-0.025%; and the balance of iron and inevitable impurities. The preparation method comprises the steps of raw material charging, vacuum melting, refining, nitrogen-added alloying, deoxidation and desulfurization, casting, electroslag remelting, and secondary casting. The preparation is implemented by using the processes of smelting in a pressurized induction furnace and electroslag remelting under a protective atmosphere; and nitrogen is added by using a method in which a nitrogen alloy and pressurized nitrogen permeation are combined.

The invention discloses a rare-earth-based soil remediation catalyst as well as a preparation method and application thereof. The catalyst takes a composite oxide of micron-sized aluminum oxide and titanium dioxide as a carrier, a nano-fiber composite oxide of cerium oxide and copper oxide as an active component and a nano-particle composite oxide of iron oxide and manganese dioxide as a cocatalyst; on the basis of the mass of the carrier, the mass percentage of the active component is 5-10%, and the mass percentage of the cocatalyst is 3-6%. The catalyst synthesized through the method has the advantages of being good in soil compatibility, high in catalytic efficiency and the like, and the target of low-energy-consumption remediation of organic pollutant soil can be achieved.

The invention discloses a preparation method of a low-iridium-content catalyst for PEM electrolyzed water anode oxygen evolution, and belongs to the field of PEM electrolyzed water. The method comprises the following steps: (1) dissolving a manganese salt, potassium permanganate and a cerium salt in water, adding an acid, adjusting the pH value to 3-7, uniformly stirring, and aging to form a uniform suspension; then transferring into a reaction kettle, and carrying out hydrothermal reaction; roasting by using a muffle furnace to obtain a cerium-manganese-based metal oxide carrier; (2) adding iridium salt into deionized water, stirring, and carrying out ultrasonic dispersion to obtain an iridium-containing precursor solution; and adding the iridium-containing precursor solution into the cerium-manganese-based metal oxide carrier suspension, stirring and mixing, then carrying out ball milling treatment, washing and drying to obtain the supported low-iridium-content catalyst, namely the low-iridium-content catalyst for PEM electrolytic water anode oxygen evolution. The use amount of Ir is reduced, more active sites of Ir are exposed, and the performance of the catalyst is improved.

The invention relates to the technical field of biomedical materials, in particular to a preparation method of TPP-mediated mitochondrial-targeted cerium-doped antioxidant carbon quantum dots, which comprises the following steps: mixing citric acid, urea and cerium salt serving as raw materials, and reacting by adopting a hydrothermal method to synthesize the cerium-doped carbon quantum dots; then triphenylphosphine is grafted to the surface of the cerium-doped carbon quantum dot through an amide method, separation and purification are carried out after the reaction is completed, the target carbon quantum dot is obtained, and the cerium element in the cerium salt is used for endowing the carbon quantum dot with an anti-oxidation function. The carbon quantum dots prepared by the method are accurate in mitochondria targeting and strong in oxidation resistance, the preparation process is simple, convenient, environment-friendly and large-scale, and the product is uniform in particle size, stable in fluorescence, good in biocompatibility and wide in application prospect in the field of biomedicine.

The invention discloses a sulfur-resistant non-noble metal catalyst for removing carbon monoxide and a preparation method thereof. The preparation method comprises the following steps: step 1, dissolving aluminum oxide, cerium-containing metal salt and a precipitator in a solvent, fully mixing, and dispersing to obtain a colloidal dispersion system; a hydrothermal product is obtained after the hydrothermal reaction, and solid powder A is obtained after the hydrothermal product is roasted; step 2, dropwise adding a copper-containing metal salt solution into the solid powder A under a ball-milling condition to obtain a turbid liquid; carrying out heat preservation roasting to obtain solid powder B; 3, roasting the molybdenum-containing metal salt, and performing thermal decomposition to obtain solid powder C; and 4, adding the solid powder C obtained in the step 3 into the turbid liquid of the solid powder B, dispersing, and roasting to obtain the required catalyst. The obtained catalyst is stable in overall structure and can still keep good catalytic performance in a sulfur-containing environment.

The invention discloses a copper-doped cerium oxide antifouling agent and a preparation method and application thereof.The antifouling agent takes cerium oxide as a main body material, copper is introduced for doping, Cu < 2 + > partially replaces Ce < 4 + > to enter crystal lattices, charge imbalance is caused, more oxygen vacancies are induced to be generated, meanwhile, reduction conversion from Ce < 4 + > to Ce < 3 + > is promoted, and formation of the oxygen vacancies is further stabilized. The oxygen vacancies obviously enhance the surface catalytic activity of the material, H2O2 and Br <-> in seawater can be efficiently catalyzed to generate hypobromous acid (HOBr) with a bactericidal effect, the function of natural halogenated peroxidase is simulated, and long-acting and environment-friendly biological antifouling is realized. The antifouling agent provided by the invention can be synthesized by adopting a hydrothermal method, is simple and convenient in process, is suitable for large-scale preparation, is suitable for various marine environment antifouling scenes such as hulls, marine engineering equipment and underwater sensors, and has a good application prospect.

The invention discloses a cerium-zirconium-based high-entropy oxide as well as a preparation method and application thereof. According to the cerium-zirconium-based high-entropy oxide, cerium and zirconium serve as main bodies, and meanwhile rare earth elements (lanthanum, praseodymium, neodymium and samarium) and transition metal elements (manganese, iron, cobalt, nickel, copper and zinc) are introduced to form a high-entropy solid solution with the equal molar ratio and containing 3-8 kinds of metal. In the cerium-zirconium-based high-entropy oxide, the cerium element and the zirconium element respectively account for 20%-40% of the total amount, and the other elements are respectively 10%-30% in an equimolar ratio. The cerium-zirconium-based high-entropy oxide catalyst prepared by the invention has excellent oxygen storage and release capacity and CO oxidation capacity, and the CO complete conversion temperature is 181 DEG C. The method adopts a simple coprecipitation process, is mild in condition and low in cost, and is suitable for large-scale application in the field of tail gas purification.