173 results about "Terbium" patented technology

A light-emitting device including an organometallic compound having a metal such as is platinum (Pt), palladium (Pd), copper (Cu), silver (Ag), gold (Au), rhodium (Rh), ruthenium (Ru), osmium (Os), titanium (Ti), zirconium (Zr), hafnium (Hf), europium (Eu), terbium (Tb), or thulium (Tm) is provided. The light-emitting device may include a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and comprising an emission layer. The light-emitting device may be included in an electronic apparatus.

The invention discloses a rare earth metal polymer with multiple stimulation responsiveness and a preparation method thereof, two monomers SP and VTPY are mixed with methyl methacrylate (MMA) according to a certain proportion, a polymer skeleton Poly (VTPY-co-SP-co-MMA) is prepared through a free radical polymerization reaction, the polymer and Tb (Com) 3.2 H2O are further subjected to a coordination reaction according to a specific proportion, and the rare earth metal polymer with multiple stimulation responsiveness is obtained. The Poly-Tb (Coum) 3 with the stimuli-responsive discoloration characteristic is prepared by the aid of the method. The rare earth metal polymer with methyl methacrylate as a framework and rare earth terbium ions and spiropyran monomers as double emission centers is synthesized, has multiple stimulation response characteristics, provides a brand new strategy and possibility for development of rare earth-based multifunctional intelligent materials, and has wide application prospects. An innovative solution is provided for development of a thermal enhanced rare earth luminescent material, the thermosensitive fluorescence response performance of the material is greatly improved, and a new thought is provided for design of an intelligent temperature response type rare earth luminescent material.

A sensor comprising one or more metal oxides as sensor material is used to detect pathogen-derived VOCs, such as those released from an infected wound. The metal oxides can comprise one or more metal elements selected from aluminum, antimony, bismuth, boron, cerium, chromium, cobalt, copper, gold, indium, iridium, iron, lanthanum, lead, manganese, molybdenum, nickel, niobium, osmium, palladium, platinum, rhodium, ruthenium, selenium, silicon, silver, tantalum, tellurium, terbium, tin, titanium, tungsten, vanadium, ytterbium, yttrium, zinc, and zirconium. The sensor device can have one or more sensors that detect and record various VOCs indicative of the presence of pathogens, which are associated with mortality and / or infection.

The invention discloses a method for improving performance of rare earth permanent magnet sintered neodymium iron boron grain boundary diffusion, and belongs to the technical field of rare earth permanent magnet materials. The method comprises the steps that a low-melting-point metal layer and a diffusion layer containing heavy rare earth elements are sequentially formed on the surface of a clean sintered neodymium-iron-boron magnet, and then vacuum diffusion heat treatment and tempering treatment are conducted. Wherein the low-melting-point metal layer comprises at least one of copper, aluminum, gallium and tin or an alloy of the copper, the aluminum, the gallium and the tin; the heavy rare earth element comprises at least one of dysprosium, terbium, holmium and gadolinium. The low-melting-point metal layer is preferentially diffused and wets the grain boundary in the heat treatment process, heavy rare earth elements are promoted to be deeply and uniformly diffused towards the interior of the magnet along the grain boundary, so that a heavy rare earth-rich shell layer is formed outside main phase grains of the magnet, and the intrinsic coercive force is improved; meanwhile, the low-melting-point metal forms a strengthening phase at the grain boundary, the brittleness of the magnet after diffusion is improved, the surface corrosion phenomenon is restrained, and collaborative optimization of the comprehensive performance of the magnet is achieved.

The invention provides a method for manufacturing a terbium-dysprosium-iron giant magnetostrictive alloy based on three-dimensional photocuring molding, which comprises the following steps of: firstly, preparing three-dimensional photocuring molding slurry, adopting photosensitive resin as a matrix, and matching with a metal organic chelating agent containing terbium-dysprosium-iron giant magnetostrictive alloy component to enhance the uniform distribution of metal powder so as to ensure the printing precision and the material stability; secondly, the resin and the chelating agent are removed through heat treatment degreasing, the degreasing process is controlled by controlling the heating rate, and structural collapse is avoided; decarburization is carried out in a low-oxygen atmosphere, so that the purity of the alloy is improved, and the structural integrity before sintering is ensured; then reduction treatment is performed to improve the structural stability and purity; and finally, high-temperature sintering is carried out under the assistance of a magnetic field, grain orientation and magnetic domain arrangement are optimized, and the magnetostrictive effect and the force-magnetic energy conversion efficiency are improved. According to the method, three-dimensional light curing forming and magnetic field auxiliary heat treatment are combined, and the risk of structural damage in the printing process of the terbium dysprosium iron giant magnetostrictive alloy is practically and effectively avoided.

The invention provides a sintered neodymium-iron-boron magnet and a preparation method thereof. The sintered neodymium-iron-boron magnet comprises a neodymium-iron-boron sintered body and a heavy rare earth layer, wherein the heavy rare earth layer comprises heavy rare earth and an oxide; part or all of the surface of the neodymium-iron-boron sintered body is covered by the heavy rare earth layer, and heavy rare earth is distributed in an area, at least 3.5 mm deep from the surface, of the neodymium-iron-boron sintered body covered by the heavy rare earth layer; the oxide is one or more of aluminum oxide, silicon oxide, calcium oxide, magnesium oxide, zirconium oxide, copper oxide and zinc oxide, and the heavy rare earth is one or more of dysprosium, terbium, holmium and gadolinium. At least one part of the surface of the neodymium-iron-boron sintered body is covered with the heavy rare earth layer containing the oxide, when the heavy rare earth is diffused at a high temperature, the heavy rare earth enters the neodymium-iron-boron sintered body, the oxide is high in melting point, relatively thick and left on the surface of the neodymium-iron-boron sintered body, the effect of a spacer is achieved, magnet adhesion can be effectively prevented when the heavy rare earth is diffused, and the service life of the magnet is prolonged. And the preparation of the magnet is more convenient, and industrial application is realized.

The invention discloses a neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and a preparation method thereof, and relates to the technical field of neodymium-iron-boron magnet preparation, and the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet comprises the following preparation raw materials: 170-175 kg of PrNd (praseodymium-neodymium alloy), 25-30 kg of BFe (iron white copper), 1-5 kg of Co (cobalt), 0.1-2 kg of Cu (copper), 1-5 kg of Zr (zirconium), 0.1-1 kg of Ga (gallium) and 380-420 kg of Fe (iron). According to the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and the preparation method thereof, the 54H sintered neodymium-iron-boron magnet is prepared through a double-alloy technology with neodymium, iron and gallium as auxiliary alloy without adding dysprosium, terbium and other scarce type heavy rare earth elements, and performance optimization and cost optimization of the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet are achieved.

The invention relates to a lanthanide oxide electrochemiluminescence aptamer sensor with dual signal amplification for detecting acetamiprid as well as a preparation method and application of the lanthanide oxide electrochemiluminescence aptamer sensor. According to the sensor, terbium-doped europium oxide (Eu2O3: Tb < 3 + >) modified by gold nanoparticles (Au NPs) is used as a luminous body, and the electrochemical luminescence performance can be remarkably improved through multiple mechanisms: on one hand, the Au NPs can effectively promote generation of more sulfate free radicals; on the other hand, the surface defect passivation effect and the efficient synergistic effect of energy transfer jointly achieve effective amplification of signals. In addition, the wool ball-shaped Ag NPs is used as a plasma resonance signal amplification source, so that the ECL intensity of the sensor is further enhanced. The prepared electrochemical luminescence sensor with the dual signal amplification effect is used for detecting acetamiprid (ACE), has a wide linear range and a low detection limit, and has a wide application prospect in detection of acetamiprid residues in a water environment.

The invention relates to the technical field of architectural ceramics, in particular to golden yellow metal dry granular glaze and a preparation method and application thereof.The preparation method comprises the following steps that A, under the inert atmosphere, copper simple substances, aluminum simple substances, zinc simple substances, tin simple substances, chromium simple substances and terbium simple substances are completely molten, and copper alloy liquid drops are obtained after liquid breaking; cooling the copper alloy liquid drops in a natural environment to obtain copper alloy dry particles; b, uniformly mixing kaolin, quartz, calcite, dolomite, barium carbonate and zinc oxide, calcining, quenching with water, grinding and sieving to obtain a crystalline frit; and C, uniformly mixing the copper alloy dry granules, the crystalline frit and the suspending agent to obtain the golden yellow metal dry granular glaze. The preparation method of the golden yellow metal dry granular glaze is high in operability, and on the premise that the golden yellow metal texture effect is uniform, the golden yellow metal dry granular glaze can have the excellent golden yellow metal texture effect, transparency and antifouling performance at the same time and also has high abrasion resistance and hardness.

The invention belongs to the field of lubricants, and relates to a composite solid lubricant for a sprocket shaft group and a preparation method thereof. The composite solid lubricant for the sprocket shaft group is prepared from the following raw materials in percentage by weight: 2-15% of graphite fluoride, 1-4% of terbium-thulium co-doped molybdenum disulfide, 1-3% of organic graphene, 0.07-0.4% of tin powder, 1-11% of polyethylene glycol, 1-7% of a thickening agent and the balance of basic lubricating oil. According to the preparation method, molybdenum disulfide is co-doped with rare earth thulium and terbium, thulium and terbium ions are embedded into molybdenum disulfide layers or replace molybdenum sites through electrostatic adsorption in the hydrothermal reaction process, the layered structure is more compact, oxygenolysis of molybdenum disulfide at high temperature is effectively inhibited, and better oxidation resistance is achieved. The talcum powder is introduced to modify the lithium-based soap, and zinc ions are adopted to modify the talcum powder, so that the dispersibility of the talcum powder is improved, and the thermal stability, wear resistance and water resistance of the lubricant are improved after the talcum powder is compounded with the lithium-based soap.

A method for producing a coated chromium-containing component includes providing a coating mixture of a solvent and a source of praseodymium and / or a source of terbium, contacting the surface of the component with the coating mixture, optionally drying, and heating the component in an oxidising atmosphere at a temperature of 450° C. or higher. Examples include coated components for a device, and electrochemical devices with coated components, the components having a surface coating including at least one layer that includes a praseodymium material and / or terbium material. The method produces coatings that reduce chromium evaporation and are useful as barriers on a chromium-containing components.

The present invention relates to the field of magnetic functional materials. The present invention discloses a use of a rare earth fluoride single crystal in magnetic refrigeration, a magnetic refrigeration method and a magnetic refrigeration device. A magnetocaloric material of the series is lithium rare earth fluoride, with the chemical formula of LiREF4, wherein RE is one or more of rare earth elements gadolinium, terbium, dysprosium, holmium, erbium, thulium and ytterbium. A magnetocaloric material single crystal of the series has extremely strong magnetic anisotropy. By applying a varying magnetic field of 0-20 kOe along the easy magnetization axis direction of the magnetocaloric material, LiGdF4, LiTbF4, LiHoF4, LiDyF4, LiErF4, LiYbF4 and LiTmF4 obtained isothermal magnetic entropy changes of 50.35 J·kg−1·K−1, 21.12 J·kg−1·K−1, 24.98 J·kg−1·K−1, 24.45 J·kg−1·K−1, 21.95 J·kg−1·K−1, 14.7 J·kg−1·K−1 and 0.692 J·kg−1·K−1, respectively, at 1.8K, 4K, 4K, 1.8K, 1.8K, 1.8K, and 18K. Wherein, the thermal conductivity of LiTbF4 and LiErF4 reaches 50 W·K−1·m−1 at 25K.

The invention relates to the technical field of tungsten alloy materials, in particular to a tungsten alloy wire and a preparation method and application thereof.The tungsten alloy wire is composed of, by mass, 0.4-1.1 wt% of L, 0.001-0.01 wt% of X, 0.001-0.25 wt% of Z and the balance tungsten and inevitable impurities; wherein L is one or more than two of lanthanum, cerium, praseodymium, neodymium, gadolinium and erbium; x is one or more than two of lutetium, europium, ytterbium, dysprosium, holmium, terbium and samarium; the Z comprises oxygen; the wire rod has a wire diameter of 20-60 [mu] m, the wire rod contains a linear L or L compound in the axial direction, and the average radial width D of the L or L compound is less than or equal to 5 nm. According to the tungsten alloy wire, the linear element L is doped between the tungsten matrixes, the radial average width of L is controlled to be smaller than or equal to 5 nm, the wire diameter of the wire can range from 20 micrometers to 60 micrometers, the tensile strength of 5000 MPa or above can be achieved under the wire diameter of 60 micrometers, and the machining performance of the tungsten alloy wire is enhanced.

The invention is suitable for the technical field of heat treatment, and provides a metal deep ion nitriding heat treatment process which comprises the following steps: (a) preparing a quantum dot catalyst layer; (b) acoustic resonance plasma treatment; (c) magnetic field enhanced diffusion; (d) carrying out grain boundary passivation treatment; according to the preparation method, Fe3O4 (at) Gd quantum dots are deposited on a nanocrystallization surface, an electron conduction channel is provided by utilizing a Fe3O4 carrier, N2 molecules are captured by Gd < 3 + > through physical adsorption, unpaired electrons are injected into a pi orbit of the N2 molecules, so that N is equivalent to N bond energy is reduced, and the layer permeation time is shortened; the plasma sheath oscillation frequency is matched with the inherent frequency of the workpiece, acoustic resonance is excited, and the plasma penetration depth is increased; plasma forms a standing wave field on the surface of a workpiece, and the uniformity deviation of an infiltrated layer is reduced. The strong magnetic field perpendicular to the electric field is applied, so that electrons do spiral motion, the collision ionization probability is increased, and the deep nitrogen concentration is improved; through reaction of terbium steam and grain boundary impurities, a brittleness source is eliminated, and the impact toughness is improved.

The inventors have developed technology to improve the generation of daughter isotopes for clinical treatments. The technology includes systems and methods for using a liquid target to deliver parent isotopes to a reactor for neutron bombardment and subsequently separating desired daughter isotopes from the liquid target. According to an aspect of the technology described herein, a method of obtaining desired daughter isotopes comprises pumping a liquid target solution comprising a parent isotope through a fluid path that includes a first portion that passes through a fission reactor, a second portion that passes through a pump, and a third portion that passes through an isotope capture device.

The invention discloses a preparation method of an Eu-Tb-In-MOF material based on a dual fluorescence emission source type, and the preparation method specifically comprises the following steps: under a closed condition, uniformly mixing terbium nitrate hexahydrate, europium nitrate hexahydrate, indium nitrate pentahydrate, an organic ligand, N, N-dimethylformamide and acetonitrile, then adjusting the pH value of a mixed solution, and carrying out solvothermal reaction, washing, filtering and drying to obtain the Eu-Tb-In-MOF material. The invention also discloses an application of the Eu-Tb-In-MOF material in identification of heavy metal ions Cr in a water environment. The Cr (VI) ions in the water environment are detected through fluorescence quenching sensing, excellent high selectivity is shown, and interference of other single and mixed anions and cations in the water environment can be resisted.

The invention relates to a novel functional material for X-ray protection, in particular to a liquid metal flexible shielding material and a preparation method and application thereof. The material comprises liquid metal and solid metal, the liquid metal serves as a solvent to be filled in gaps of the solid metal, the liquid metal is gallium, gallium indium, gallium indium tin, gallium indium tin zinc or mercury, and the solid metal is selected from one or more of indium, tin, gold, platinum, iridium, zirconium, niobium, molybdenum, ruthenium, osmium, rhenium, rhodium, tungsten, antimony, palladium, tantalum, hafnium, lutetium, lead, ytterbium, thulium, bismuth, silver, erbium, holmium, dysprosium, terbium, gadolinium, samarium, neodymium, lanthanum, praseodymium, cerium and europium. On the basis of compounding of the liquid metal solvent and the solid metal solute based on the liquid metal combinatology, the liquid metal and the solid metal are jointly used for protecting X-ray radiation, the comprehensive performance of X-ray protection is improved, and meanwhile the variety and number range of selectable metal elements is widened.

The present invention proposes a method for manufacturing a TbDFe supermagnetic alloy based on stereolithography. The method first prepares a stereolithography slurry using a photosensitive resin as a matrix. A metal-organic chelating agent containing TbDFe supermagnetic alloy components is added to enhance the uniform distribution of the metal powder, ensuring printing accuracy and material stability. Next, degreasing is performed to remove the resin and chelating agent through heat treatment. The degreasing process is controlled by controlling the heating rate to avoid structural collapse. Decarburization is then performed in a low-oxygen atmosphere to improve the purity of the alloy and ensure structural integrity before sintering. A reduction treatment is then performed to improve structural stability and purity. Finally, high-temperature sintering is performed under the assistance of a magnetic field to optimize grain orientation and magnetic domain arrangement, thereby enhancing the magnetostrictive effect and force-to-magnetic energy conversion efficiency. This method combines stereolithography with magnetic field-assisted heat treatment, effectively avoiding the risk of structural damage during the printing of TbDFe supermagnetic alloy.

To provide a multilayer ceramic capacitor having an excellent characteristic of a reliability variation and a manufacturing method of them.SOLUTION: A multilayer ceramic capacitor according to an embodiment, contains: a capacitor body containing a dielectric layer and an internal electrode layer; and an external electrode that is arranged to an outside of the capacitor body. The dielectric layer contains a plurality of dielectric crystal grains, each dielectric crystal grain contains a core part and a shell part surrounding at least one part of the core part, and the shell part contains: a main component of a barium titanate system containing barium (Ba) and titanium (Ti); and a rare earth element (R) containing dysprosium (Dy), terbium (Tb), yttrium (Y), La (lanthanum), or a combination of them. A R / Ba atom ratio variation coefficient (CV) obtained by a formula 1 in the shell part and a R / Ti atom ratio variation coefficient (CV) exceeds 0 and is less than 0.19.SELECTED DRAWING: Figure 4

The invention provides a nano rare earth oxide as well as a preparation process and application thereof, and relates to the technical field of nano materials. The nano rare earth oxide is prepared from the following raw materials: rare earth ions, chitosan-hexadecyl trimethyl ammonium bromide, tea saponin, nano cellulose and a hydroxyapatite nano rod; the rare earth ions are selected from at least one of cerium ions Ce < 3 + >, yttrium ions Y < 3 + >, samarium ions Sm < 3 + >, terbium ions Tb < 3 + >, lanthanum ions La < 3 + >, praseodymium ions Pr < 3 + > and neodymium ions Nd < 3 + >. The prepared nano rare earth oxide can be used as an independent antibacterial agent, can also be used as a functional filler to be compounded with a polymer, and has application potential in the fields of medical instrument coatings, food packaging and the like.

The invention relates to a polycrystalline fused product of formula (Sc2O3)yAx(ZrO2 + HfO2)1-x-y, with 0.030 ≤ y ≤ 0.150, and 0.000 ≤ x ≤ 0.070, and x ≤ y, A denoting an additive selected from Y2O3, Al2O3, CeO2, Yb2O3, Gd2O3, MnO, Bi2O3, La2O3, Pr2O3, Nd2O5, Sm2O3, Eu2O3, Tb4O7, Ta2O5, Nb2O5 and mixtures thereof, ZrO2 + HfO2 + Sc2O3 + A representing more than 98% of the mass of the fused product, MnO expressing the total content of manganese oxides expressed in the form MnO, Pr2O3 expressing the total content of praseodymium oxides expressed in the form Pr2O3, Nd2O5 expressing the total content of neodymium oxides expressed in the form Nd2O5, Tb4O7 expressing the total content of terbium oxides expressed as Tb4O7, Ta2O5 expressing the total content of tantalum oxides expressed as Ta2O5, and Nb2O5 expressing the total content of niobium oxides expressed as Nb2O5.

The invention discloses a multicolor stress luminescent material for handwriting anti-counterfeiting and a preparation method thereof, the chemical general formula is Lu3-xAl2Ga3O12: xTb < 3 + >, 0.25% < = x < = 3.0%; the crystal structure is an Ia-3d cubic system, and the active ion is Tb < 3 + >. The preparation method comprises the following steps: weighing a lutetium-containing compound raw material, an aluminum-containing compound raw material, a gallium-containing compound raw material and a terbium-containing compound raw material, grinding and uniformly mixing to obtain a mixture, presintering, heating and calcining, cooling to room temperature, and grinding to obtain the terbium ion-doped multicolor stress luminescent material. The terbium ion-doped multicolor stress luminescent material disclosed by the invention has good stress luminescence self-recovery performance, shows different responses of energy level transition to stress in a visible light range, and is adjustable in color. The material has a low-threshold excitation characteristic, can provide multicolor stress luminescence response, and meets multicolor anti-counterfeiting requirements under different stress conditions.

The invention relates to preparation and application of a ruthenium-functionalized terbium-based metal organic framework fluorescence sensing material for uric acid detection. The preparation method comprises the following steps: S1, selecting raw materials; s2, dissolving pyrazinetetracarboxylic acid in secondary water, and stirring; s3, adding the solution obtained in S2 into a methanol solution of terbium nitrate, and stirring; s4, adding the solution obtained in S3 into a KOH solution, and stirring; s5, aging, alternately washing with distilled water and ethanol, centrifugally collecting white precipitate, and drying to obtain a white rare earth metal organic framework material; s6, dispersing the sample in an ethanol solution of Ru (bpy) 3 < 2 + >, and stirring; and S7, washing the solution obtained in the step S6 with ethanol, performing centrifugal separation to obtain a precipitate, and drying to obtain the ruthenium-functionalized terbium-based metal organic framework material. And S8, detecting uric acid in urine by using the obtained ruthenium functionalized terbium-based metal organic framework material. The ruthenium-functionalized terbium-based metal organic framework can be used as a ratio type fluorescent probe, and uric acid in urine can be identified and detected more sensitively and accurately.

The present invention relates to the field of luminescent materials, and discloses a layered scandium hydroxide composite material with luminescent properties, a preparation method thereof, and an application thereof. It conforms to the chemical general formula RE 2‑a Sc a (OH)5DS b X 1‑b ·nH2O; wherein, 1.85 ≤ a ≤ 1.9; 0.7 < b < 0.9; RE is any one of terbium or europium; X is any one of 4-biphenylacetate or terephthalate. The Tb 0.1 Sc 1.9 (OH)5DS 0.8 BPA 0.2 ·H2O colloid of the present invention can rapidly detect Fe 3+ in real time, and the operation is simple. The colloids of Tb 0.1 Sc 1.9 (OH)5DS 0.8 TA 0.2 ·H2O and Eu 0.14 Sc 1.86 (OH)5DS 0.8 TA 0.2 ·H2O achieve color change by adjusting the volume ratio of the two, and the operation is simple and rapid prototyping, providing a new idea for the preparation of luminescent hydrogels.

The present invention provides a high quantum yield rare earth terbium cluster compound with thiacalixarene as a ligand, a preparation method and an application thereof. The chemical formula of the rare earth terbium cluster compound is: [(CH3)2NH2][Tb9(TC4A)2(μ3-O)8(μ4-O)2(H2O) 24 The rare earth terbium cluster compound is constructed with H4TC4A as a ligand and Tb(CH3COO)3·6H2O as a metal source. The rare earth terbium cluster compound provided by the present invention has good photoluminescence properties, good solubility in methanol and high fluorescence quantum yield, and can be widely used in technical fields such as light detection.

The inventors have developed technology to improve the generation of daughter isotopes for clinical treatments. The technology includes systems and methods for using a liquid target to deliver parent isotopes to a reactor for neutron bombardment and subsequently separating desired daughter isotopes from the liquid target. According to an aspect of the technology described herein, a method of obtaining desired daughter isotopes comprises pumping a liquid target solution comprising a parent isotope through a fluid path that includes a first portion that passes through a fission reactor, a second portion that passes through a pump, and a third portion that passes through an isotope capture device.

To provide a rare earth aluminate fluorescent body capable of constituting a wavelength conversion member having a high luminous efficiency and a method for producing the same.SOLUTION: A rare earth aluminate fluorescent body includes: a first element M1 including at least one selected from the group consisting of yttrium, lanthanum, lutetium, gadolinium, and terbium; cerium; aluminum; and an oxygen element, and may optionally include a second element M2 including at least one selected from gallium and scandium, where a total mole number of the first element M1 and cerium is 2.9 or more and 3.1 or less, and a total mole number of aluminum and the second element M2 is 4.5 or more and 5.5 or less when a mole number of the oxygen element is 12. The rare earth aluminate fluorescent body has a ratio of a reflectance of 280 nm to a reflectance of 380 nm of 0.33 or higher and 0.76 or lower.SELECTED DRAWING: Figure 3

The invention discloses a diffusion source and a diffusion method for improving the coercive force of a sintered neodymium-iron-boron magnet, and the diffusion source comprises the following components in atomic ratio: more than 80 at.% of heavy rare earth elements, 10-19 at.% of low-melting-point metal elements, not more than 0.2 at.% of high-melting-point metal elements, and not more than 1 at.% of magnetic elements, wherein the heavy rare earth element is at least one of dysprosium and terbium; the low-melting-point metal is at least one of aluminum, copper, gallium, tin and zinc; the high-melting-point metal is at least one of zirconium, vanadium, tungsten, niobium, titanium and manganese; the magnetic element is at least one of iron, cobalt and nickel. The diffusion effect of the diffusion source is remarkably improved by optimally designing the components, the adhesion mode and the diffusion process of the alloy diffusion source, and the diffusion source is mainly used for improving the coercive force of the sintered neodymium-iron-boron magnet through grain boundary diffusion and is particularly suitable for improving the coercive force of the sintered neodymium-iron-boron magnet with the thickness larger than 10 mm through grain boundary diffusion.

The invention discloses a high-strength and high-toughness ADC12 cast aluminum alloy and a preparation method thereof, and belongs to the technical field of aluminum alloy preparation. The ADC12 cast aluminum alloy comprises the following chemical components in percentage by weight: 9.6%-12.0% of Si, less than or equal to 1.3% of Fe, 1.5%-2.5% of Cu, less than or equal to 0.5% of Mn, less than or equal to 0.3% of Mg, less than or equal to 0.5% of Ni, less than or equal to 1.0% of Zn, less than or equal to 0.2% of Sn, 0.1%-0.3% of Tb and the balance of aluminum and inevitable impurity elements. According to the ADC12 cast aluminum alloy, the content of a copper element is reduced, and meanwhile, a trace amount of rare earth terbium element is added to refine a structure, so that the strength and the toughness are improved, and the strength reduction caused by the reduction of the copper element is made up. Meanwhile, artificial aging treatment is provided, and the strength is further improved by separating out a secondary strengthening phase, so that the ADC12 material which is low in cost, high in strength and high in toughness is developed, and the high-strength requirement under the extreme condition is met.

The invention discloses a sensor material based on a lanthanide metal organic framework as well as a preparation method and application thereof, and belongs to the technical field of white spirit detection. The sensor material based on the lanthanide metal organic framework is a composite material formed by adding lanthanide metal terbium or europium into the metal organic framework for modification, and is an Eu-MOF (at) Eu-MOF material, a Tb-MOF (at) Tb-MOF material or an Eu-MOF (at) Tb-MOF material. A fluorescent sensing array with 11 sensing channels is constructed by taking Eu-MOF (at) Eu-MOF, Tb-MOF (at) Tb-MOF or Eu-MOF (at) Tb-MOF material as a probe, so that the organic substances and the Luzhou-flavor liquor are detected, and the fluorescent sensing array has the advantages of high sensitivity, short detection time, short response time, good portability and the like, and is very suitable for rapid detection of the Luzhou-flavor liquor.