2183 results about "Redox" patented technology

Embodiments described herein relate generally to electrochemical cells including a selectively permeable membrane and systems and methods for manufacturing the same. In some embodiments, the selectively permeable membrane can include a solid-state electrolyte material. In some embodiments, electrochemical cells can include a cathode disposed on a cathode current collector, an anode disposed on an anode current collector, and the selectively permeable membrane disposed therebetween. In some embodiments, the cathode and / or anode can include a slurry of an active material and a conductive material in a liquid electrolyte. In some embodiments, a catholyte can be different from an anolyte. In some embodiments, the catholyte can be optimized to improve the redox electrochemistry of the cathode and the anolyte can be optimized to improve the redox electrochemistry of the anode. In some embodiments, the selectively permeable membrane can be configured to isolate the catholyte from the anolyte.

The invention relates to the technical field of optical sensing, in particular to a copper-carbon quantum dot nano-enzyme and a preparation method and application thereof. Poria cocos and Cu < 2 + > are taken as raw materials, and the copper-carbon quantum dots with excellent peroxidase activity are prepared by adopting a one-pot hydrothermal method and can be used for sensitively, accurately and selectively detecting glyphosate. Cu < 2 + > is combined with oxygen-rich and nitrogen-rich components in poria cocos to generate an oxidation-reduction reaction, CuCDs with Cu < 2 + > / Cu < + > are obtained, Cu < 2 + > doping changes electron cloud distribution of the CDs, the electron transmission capability of the CuCDs is enhanced, and Cu < 2 + > and the CDs have a synergistic effect to generate three ROS (. OH,. O2 <-> and < 1 > O2), so that excellent peroxidase activity is exerted. The glyphosate is chelated with hydroxyl, amino, carbonyl, carboxyl and Cu on the surface of the CuCDs to occupy active sites, so that the active sites are poisoned, the peroxidase activity of the CuCDs is selectively inhibited, and a powerful choice is provided for simply, quickly, sensitively and selectively detecting the glyphosate.

The invention provides a titanium-doped high-nickel ternary positive electrode material and a preparation method thereof. The titanium-doped high-nickel ternary positive electrode material comprises a high-nickel ternary positive electrode material and a titanium-doped element, and the content of the titanium-doped element accounts for 0.5-5wt% of the titanium-doped high-nickel ternary positive electrode material. The preparation method comprises the following steps: preparing a nickel-cobalt-manganese hydroxide precursor; uniformly mixing the nickel-cobalt-manganese hydroxide precursor with a lithium source, sintering and cooling to obtain a high-nickel ternary positive electrode material; and mixing and sintering the high-nickel ternary positive electrode material and a reducing titanium source to obtain the titanium-doped high-nickel ternary positive electrode material. Reducing titanium is used for modifying the high-nickel ternary material, more stable Ni < 2 + > is enriched on the surface of the material through an oxidation-reduction reaction to serve as a protective layer, corrosion of electrolyte to the material is reduced, and the surface stability of the material is improved; the titanium element can enter material crystal lattices more easily compared with a common doping method; the lattice structure strength of the material is improved through a relatively strong Ti-O bond, and excellent cycling stability and rate capability are obtained.

The invention belongs to the technical field of solar cell materials, and particularly relates to silver-coated copper powder and a preparation method thereof. A preparation method of silver-coated copper powder comprises the following steps that copper powder subjected to surface activation through an acid-base solution and a complexing agent are dissolved in water, and copper powder turbid liquid is obtained; dropwise adding a silver source solution into the copper powder turbid liquid to carry out a replacement reaction, and adjusting the pH value of the solution after the reaction to obtain a silver-coated copper powder precursor turbid liquid; and dropwise adding a reducing agent solution into the silver-coated copper powder precursor turbid liquid, then dropwise adding a silver source solution, carrying out oxidation-reduction reaction, carrying out solid-liquid separation, washing, and drying to obtain the silver-coated copper powder. According to the preparation method provided by the invention, in the chemical oxidation reduction process, the silver-coated copper powder with different silver layer distribution structures, compact silver coating structure and better performance is obtained by regulating and controlling the dropping sequence and dropping rate of the reducing agent solution and the silver source solution.

The invention provides a redox imidazole covalent organic framework material as well as a preparation method and application thereof, belongs to the technical field of material preparation and photocatalytic preparation of hydrogen peroxide, and aims to solve the technical problem of low activity of a current covalent organic framework in preparation of hydrogen peroxide. The preparation method of the imidazole-connected redox type imidazole covalent organic framework material comprises the following steps: respectively reacting a reactant 2, 7-di-tert-butylpyrene-4, 5, 9, 10-tetraketone monomer with 4, 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ' The preparation method comprises the following steps: mixing 4, 4 '-(pyridine-2, 4, 6-triyl) tribenzaldehyde and a tri (4-formylphenyl) amine monomer, adding a solvent and a catalyst, uniformly stirring, and reacting to obtain the redox type imidazole covalent organic framework material after the reaction is finished. The application comprises the following steps: adding the covalent organic framework, oxygen and the sacrificial agent into water, and reacting under the irradiation of visible light. The preparation method is green, environment-friendly, simple and easy to implement, the prepared material has good thermal stability, and efficient visible light photocatalysis preparation of hydrogen peroxide can be achieved; meanwhile, the catalyst can be recycled and has good photocatalytic stability.

The present application relates to the field of wastewater treatment, and provides a treatment system and method for electroless nickel-plating waste liquid. The treatment system comprises a decomplexing pretreatment system; an oxidation-decomplexing system comprising a redox reactor and a decomplexing reactor which are connected in sequence, wherein an oxidizing agent in the redox reactor is oxygen, and an oxidizing agent in the decomplexing reactor is hydrogen peroxide; a chemical precipitation system comprising a neutralization reaction tank and a sedimentation tank which are connected in sequence, wherein the sedimentation tank is equipped with a filter system; and an evaporation crystallization system comprising an evaporation device, a crystallization device, and a separation device which are arranged in sequence. In the treatment system and method for electroless nickel-plating waste liquid, a two-stage oxidation method is employed to achieve oxidation and decomplexing of the waste liquid; in addition, combining chemical precipitation treatment and evaporation crystallization treatment not only reduces the waste liquid treatment cost but also avoids the introduction of other impurities, and allows for the separation of nickel salts and phosphate salts, so that the operation is easy and convenient, the treatment cost is low, the nickel removal rate is high, and resource utilization of nickel is facilitated.

The present invention is directed to a fission product extraction system operable to capture and extract fission products from a flow of irradiated fueled molten salt of a molten salt reactor. The example extraction systems described herein utilize electroless deposition to chemically plate fission products onto a metallic structure. The metallic structure may be partially coated with a reducing agent, such as beryllium to provide an electron source for the fission products. The metallic structure may be a component of an extraction system designed to facilitate submersion of the metallic structure into the flow of molten salt. The extraction system may also be designed to facilitate removal of the metallic structure without requiring a shut down or slowdown of the reactor system.

Described are aqueous rechargeable hydrogen batteries operating in the full pH range (e.g., pH: −1 to 15) with potential for electrical grid storage. The pH-universal hydrogen batteries operate with different redox chemistry on the cathodes and reversible hydrogen evolution / oxidation reactions (HER / HOR) on the anode. The reactions can be catalyzed by a highly active ruthenium-based electrocatalyst. The ruthenium-based catalysts exhibit comparable specific activity and superior long-term stability of HER / HOR to that of state-of-the-art Pt / C electrocatalyst in the full pH range. New chemistries for aqueous rechargeable hydrogen batteries are also provided.

The invention discloses a high-capacity positive electrode electrolyte for all-vanadium liquid flow batteries, wherein the electrolyte contains a solid energy storage material with a concentration of 0.02-1 g / mL, and the main component is a targeted redox solid energy storage material containing ammonia-rich iron / copper ferrocyanide, which reacts with a positive electrode redox medium VO in a supporting electrolyte containing ammonium ions. 2+ / VO2 + With similar equilibrium potential, reversible redox reaction can occur to continue the charge and discharge process. The high-capacity all-vanadium liquid flow battery positive electrode electrolyte disclosed in the present invention uses low-cost solid energy storage materials as the main energy storage medium, so when using a lower positive electrode redox medium VO 2+ / VO2 + High capacity and energy can be achieved at low concentrations, and pentavalent vanadium VO2 + The concentration can enhance the temperature adaptability of the all-vanadium liquid flow battery system while reducing the electrolyte cost.

The invention discloses a P450 mutant and application thereof in synthesis of calcifediol, and belongs to the technical field of bioengineering. According to the present invention, the P450 enzyme mutant enzyme is constructed, and the single plasmid three-enzyme co-expression system of the redox partner and the cofactor cycle enzyme is constructed, such that the sufficient electron transport chain is provided for the P450 enzyme, and the calcifediol can be efficiently synthesized under the mild condition by using the vitamin D3 as the substrate; the conversion rate of calcifediol can reach 63.1%, and the conversion rate of the reaction is greatly improved. By adopting the method disclosed by the invention, the catalytic efficiency of the catalyst is improved, and the reaction cost is reduced.

The present disclosure provides an enzyme electrode that is advantageous from the viewpoint of causing a redox to occur which involves a target substance without replenishing an enzyme. An enzyme electrode (1a) according to the present disclosure is provided with: a conductive base material (10); an enzyme (21b); a metal organic structure (21a); and a fixing agent (22). The enzyme (21b) catalyzes the redox in which the target substance is involved. The fixing agent (22) fixes the enzyme (21b) and the metal organic structure (21a) to the base material (10).

The present invention relates to novel lignin-derived compounds and compositions comprising the same and their use as redox flow battery electrolytes. The invention further provides a method for preparing said compounds and compositions as well as a redox flow battery comprising said compounds and compositions. Additionally, an assembly for carrying out the inventive method is provided.

A method for measuring chromium content in a laterite nickel ore, comprising the following steps: S1, adding in sequence nitric acid, phosphoric acid, perchloric acid, and sulfuric acid to a laterite nickel ore sample to be measured, and mixing evenly to obtain a mixed solution A; S2, when the amount of nitric acid is not 0, heating the mixed solution A to remove water and nitric acid, and then raising the temperature to remove perchloric acid, to obtain a mixed solution C; when the amount of nitric acid is 0, heating the mixed solution A directly to remove water and perchloric acid, to obtain a mixed solution C; S3, cooling the mixed solution C, adding water to dilute, boiling again to dissolve salts, cooling, filtering, and diluting for use, and recording as a mixed solution D; and S4, testing the mixed solution D by ICP to calculate the chromium content in the laterite nickel ore. By using nitric acid, phosphoric acid, perchloric acid, and sulfuric acid to perform redox reaction and combining the same with ICP to perform testing, the problems of few process sample testing and analysis methods, long detection time, and complicated procedures in the hydrometallurgy of laterite nickel ore are solved.

The invention discloses a doped material based on a hexagonal boron nitride / titanium dioxide heterojunction and a preparation method thereof. According to the material, a heterojunction is formed by hexagonal boron nitride and titanium dioxide, and the light absorption performance, the carrier mobility and the photocatalytic efficiency are optimized by doping a nitrogen element, an iron element and a fluorine element; wherein the doped nitrogen element can reduce a band gap by introducing a defect energy level, and broaden a light absorption range to a visible light region and an infrared light region; the doped iron element can promote carrier separation by introducing an intermediate energy level; the doped fluorine element can inhibit carrier recombination by reducing surface defects. The light absorption efficiency of the material in the ultraviolet light range can be improved by constructing the layered # imgabs0 # heterojunction composite material, and the migration rate of electrons and holes can be improved by doping the N element, the Fe element and the F element in the # imgabs1 #, so that the oxidation-reduction reaction is promoted, and reference significance is provided for further improving the application effect of a photocatalyst in sewage treatment.

The invention discloses a novel photocatalyst for producing hydrogen from organic matter wastewater and a preparation method of the novel photocatalyst, and relates to the technical field of photocatalysis. The photocatalyst disclosed by the invention is combined with oxidation-reduction capability, and can effectively degrade and produce hydrogen under the irradiation of sunlight. Through combination of quaternized porous tungsten oxide and vanadate radicals, silver vanadate load growth is promoted, the sunlight utilization rate is increased, and the electron-hole recombination rate is reduced. Reduced graphene oxide is used for pretreatment, active groups are introduced, the reduced graphene oxide is compounded with tungsten oxide / silver vanadate, the binding force is enhanced through heat treatment, photo-induced electron-hole pair compounding is inhibited through the conductivity, and the visible light catalytic performance is improved. The adsorption effect of porous tungsten trioxide and reduced graphene oxide can accelerate the degradation of organic matters. By optimizing the proportion of silver vanadate, tungsten oxide and reduced graphene oxide, the visible light response and charge separation efficiency are enhanced, the degradation and hydrogen production performance is improved, and light corrosion is reduced.

The disclosure is directed to blended anode materials including at least two types of electrochemically active components possessing different redox potentials. The anode design renders improved chemical and structural stability to that of the conventional single-phase graphite anode particularly at high and / or low electrochemical potentials.

The invention discloses preparation and application of an organic-inorganic interface layer modified zinc negative electrode. The preparation method comprises the following steps: firstly, dispersing organic polymer polylactic acid and zinc sulfide powder into tetrahydrofuran, then coating the surface of zinc foil with the dispersed solution, and drying a solvent at 70 DEG C, so as to prepare the zinc negative electrode modified by an organic-inorganic interface layer. According to the interface layer, zinc ion deposition is regulated and controlled, and the problem of zinc dendrite growth is solved. In addition, the polylactic acid-zinc sulfide composite coating can effectively improve the redox kinetics of zinc ions and improve the coulombic efficiency of the zinc negative electrode. Due to the good ionic conductivity, the interface modification layer can improve diffusion of zinc ions, and the polarization influence caused by the concentration gradient of the zinc ions is relieved. Therefore, the prepared polylactic acid-zinc sulfide composite interface layer modified zinc negative electrode symmetric battery has more excellent cycling stability, the half battery has more stable coulombic efficiency, and the assembled total battery has more prominent capacity retention rate.

The invention belongs to the technical field of zinc battery electrolyte, and discloses application of pyridine hydrochloride as an electrolyte additive in stabilizing a zinc negative electrode and realizing four-electron transfer of a zinc-iodine secondary battery. The hydrochloride containing the pyridine structure is used as an electrolyte additive, molecules of the pyridine structure are adsorbed on the surface of the zinc negative electrode to form a shielding layer, the deposition / stripping reversibility of the zinc negative electrode is improved, stabilization of the zinc negative electrode can be achieved, and the problems of zinc dendritic crystal, corrosion and hydrogen evolution are solved. Meanwhile, molecules with pyridine structures can activate and stabilize I- / I0 / I < + > four-electron redox reaction, inhibit I < + > hydrolysis side reaction and improve the energy density and cycling stability of the zinc-iodine battery. The problem of poor electrochemical deposition / stripping reversibility of a zinc negative electrode and the problem of poor stability of positive valence I < + > species of an iodine positive electrode of a four-electron transfer reaction are solved. The electrolyte containing the additive is low in cost, simple in method, easy to produce and high in practical value.

A method for recovering heavy metals and soluble chlorine salts from fly ash generated by incineration of domestic waste. The method comprises the following steps: first, mixing fly ash with water and an acid, performing a leaching reaction when a pH value is controlled, improving the leaching efficiency of lead and zinc by means of air agitation, and measuring dissolved oxygen or redox potential to determine a leaching reaction endpoint; second, using a vulcanizing agent to recover leached heavy metals, and adjusting and monitoring the pH value of a leachate so as to control the adding amount of the vulcanizing agent; third, adding an alkali to adjust the pH value of the leachate so as to precipitate impurities such as aluminum and iron, and using an excessive amount of the vulcanizing agent to further remove heavy metals; and finally, adding an oxidizing agent and an iron salt coagulant into the leachate from which the heavy metals and impurities are removed, so as to remove divalent sulfur and arsenic, wherein the finally purified leachate can be used for recovering soluble chlorine salts. The method has a simple and efficient process, can significantly increase the recovery rate of heavy metals, and recovers heavy metals in the form of metal sulfides, thus facilitating subsequent separation treatment. The treated fly ash can be used as a raw material of cement, thus achieving efficient utilization of resources.

According to the method, phosphomolybdic acid, copper chloride and ferric chloride serve as precursors, copper and iron-containing phosphomolybdic acid nano-enzyme (Cu, Fe-PMs) with peroxidase-like activity is synthesized through a microwave method, under the acidic condition, on one hand, the surface of Cu and Fe-PMs carries negative charges, high affinity is generated between Cu and Fe-PMs and a substrate TMB with positive charges, and on the other hand, the surface of Cu and Fe-PMs has negative charges; on the other hand, Cu / Fe / Mo three-metal redox couple accelerates the regeneration of Fe < 2 + > and plays an important role in the activity of peroxidase, and meanwhile, due to the introduction of sodium dehydroacetate, Cu and Fe in Cu and Fe-PMs and pyranoid ring and keto O in sodium dehydroacetate interact through coordinate bonds to cause electron interaction, so that the peroxidase-like activity of Cu and Fe-PMs is enhanced, and the peroxidase-like activity of Cu and Fe-PMs is improved. And the Fenton reaction is enhanced through transfer of electrons among the sodium dehydroacetate, the Cu and the Fe-PMs. When Cu and Fe-PMs oxidize TMB and H2O2, sodium dehydroacetate enhances the absorbance of the system, and on the basis, a novel colorimetric rapid detection method of sodium dehydroacetate is established.

Thermo-electrochemical generator cells in general supply energy in the thermal gradient; no energy is available when the temperature is consistent. The aim of the invention is to overcome this disadvantage. To achieve this aim, a metallization mixture is used, by means of which it is possible for the first time to provide electrodes which have long-term stability, specify a current direction for one of the redox reactions via a stable overvoltage, and make energy available when the heat is consistent. A metallization method and a thermo-electrochemical generator cell according to the method can be produced and provided especially cost-effectively using rancid, natural oils as the raw material and starting material for the metallization mixture and using cost-effective, technically pure chemicals. As a result, it is possible for the first time to directly industrially utilize non-directional waste heat in the range of 10-70°C on an industrial scale using a cell (1) according to figure 1, comprising: electrode (2), first main surface (12), second main surface (14), electrolyte layer (4), second electrode (3), first main surface (13) and second main surface (15).

The invention discloses a functionalized carbon quantum dot modified all-vanadium redox flow battery electrolyte. The functionalized carbon quantum dot has a large specific surface area and a carboxyl functional group on the surface; the electrolyte of the flow battery is a dilute sulfuric acid solution of vanadium; the main evaluation indexes of the electrochemical performance are the cycle efficiency, the capacity retention ratio and the battery performance of the electrolyte; the invention aims to discuss the catalytic action of the surface functional groups of the functionalized carbon quantum dots on the oxidation-reduction reaction of vanadium ions in the electrolyte of the all-vanadium redox flow battery by using the functionalized carbon quantum dots as an additive of the electrolyte. Meanwhile, the influence of the concentration and doping of the carbon quantum dots on the electrochemical performance of the electrolyte of the all-vanadium redox flow battery is researched, so that the working efficiency and the overall performance of the battery are improved, the characteristics of the electrolyte are improved, and the energy consumption of the battery is reduced.

The invention provides a preparation method of a vanadium electrolyte for an all-vanadium redox flow battery, the vanadium electrolyte and application. The method comprises the following steps: (1) dissolving concentrated sulfuric acid in water to obtain a sulfuric acid solution with a preset concentration, then adding vanadium pentoxide into the sulfuric acid solution, and reacting to obtain a first vanadium solution; (2) the temperature of the first vanadium solution is kept to be the preset temperature, low-valence vanadium oxide is added into the first vanadium solution for reaction, water or hydrochloric acid is supplemented in the reaction process, a second vanadium solution is obtained, and the low-valence vanadium oxide is vanadium oxide with the valence of 3-3.5; and (3) filtering the second vanadium solution to obtain the vanadium electrolyte. The method provided by the invention can save energy consumption, reduce cost and improve dissolution efficiency.

The utility model discloses a coupled biomass chemical looping combustion system which comprises an air reactor, a cyclone separator, a return feeder and a fuel reactor, the air reactor is communicated with the return feeder through the cyclone separator, the air reactor is configured to complete an oxidation reaction based on the received oxygen carrier and air, the generated oxidation-state oxygen carrier is conveyed to the cyclone separator under the driving of flue gas, and the corresponding oxidation-state oxygen carrier is conveyed to the return feeder through the cyclone separator; the return feeder is respectively communicated with the air reactor and the fuel reactor through a material conveying pipe, the input oxidation-state oxygen carrier is input into the air reactor and / or the fuel reactor by the return feeder, and the fuel reactor completes an oxidation-reduction reaction based on the received oxidation-state oxygen carrier and biomass fuel; the fuel reactor is used for inputting the reduced oxygen carrier into the air reactor through a return pipe; and the exhaust port of the fuel reactor is provided with a carbon dioxide trapping device so as to complete trapping of discharged carbon dioxide.

The invention provides a circuit deposition method and device, and relates to the field of electronic circuit manufacturing, and the method comprises the following steps: preparing a deposition solution; deploying a dripping path of the deposition solution on a sample to be processed according to a preset circuit pattern; and dropwise adding the deposition solution on the sample along a dropwise adding path, and irradiating a dropwise adding region by using laser, so that an oxidation-reduction reaction occurs on the sample, thereby forming a line. The method is based on a laser-induced liquid phase deposition technology, a deposition solution containing metal ions is dropwise added to a sample to be processed according to a preset circuit pattern, laser is further used for irradiating a dropwise adding area, and a needed pattern circuit is formed along with movement of a laser irradiation position. The deposition device applying the method is simple in operation step and does not need post-treatment, and a simplified and environment-friendly solution is provided for the circuit manufacturing industry.

The present invention provides a glass sheet having soda-lime-silica glass composition with a high visible light transmittance (LtC) of at least 89% with a dominant wavelength (DW) from about 490 to 505 nanometers and purity (Pe) of no more than 1% for control thickness of 5.66 mm and methods of making the same. The glass composition comprising a low iron raw material, a total iron oxide (Fe2O3) of 0.02 to 0.06 wt. %, ferrous (FeO) from 0.006 to 0.02 wt. %, redox (FeO / Fe2O3) from about 0.30 to 0.55, Cr2O3 from about 0.3 to 10 ppm, TiO2 from about 50 to 500 ppm, SnO2 from about 10 to 500 ppm, and a critical amount from about 0.10 to 0.25 wt. % of SO3. The low content of iron oxide is achieved by the partial substitution of regular raw materials by low iron raw materials, with a complete substitution of regular dolomite by a low iron dolomite with a maximum content of 0.020 wt. % Fe2O3.

This invention belongs to the field of wastewater treatment technology, specifically relating to a method for removing metallic impurities from acidic copper-containing etching wastewater at room temperature and pressure. The method includes the following steps: S1, adding an oxidant to the acidic copper-containing etching wastewater to conduct an oxidation-reduction reaction, obtaining a pretreatment solution; S2, adding phosphoric acid or soluble phosphate to the pretreatment solution, adjusting the pH to 1.3-1.7 using a pH adjuster, stirring, and filtering to obtain a purified copper-containing solution. The method provided by this invention achieves high removal rates for Fe, Ni, Zn, Ca, and Mg, while maintaining a high copper ion content. It can recycle and regenerate high-purity copper salt products for application in food, cosmetics, medical, electroplating, and other fields, while also reducing hazardous waste generation, improving economic efficiency, and significantly reducing costs.

The invention discloses a microbial electrochemical efficient preparation method and application of metal nanoparticles, the metal nanoparticles are prepared and synthesized by regulating the redox metabolism behavior of microorganisms through positive / negative constant potential, and the microorganisms are electroactive microorganisms domesticated and cultured by activated sludge or single bacteria; the metal nanoparticles are in a solid state of a metal simple substance, are formed on the surface of an electroactive biological membrane, and are generated by electroactive microorganisms through extracellular electron transfer dissolved-state metal salt reduction. The palladium or silver and other metal nanoparticles prepared by the method are uniformly distributed on the surface of the electroactive biological membrane, the particle size is 1-10nm, the electroactive biological membrane-metal nanoparticle complex has extremely strong reducibility, and the electroactive biological membrane-metal nanoparticle complex is used for treating a non-biodegradable organic pollutant (4-chlorophenol), so that compared with a non-electroactive biological membrane and a treatment group without metal ions, the electroactive biological membrane-metal nanoparticle complex has the advantages that the biodegradability is greatly improved; the degradation effect is the best.

The invention relates to the technical field of sewage treatment, in particular to a wastewater recycling method which comprises the following steps: cyanide breaking: in an alkaline environment, adding an oxidizing agent to oxidize wastewater; first monitoring: monitoring the oxidation reduction potential and the free cyanide concentration in real time, and adjusting the adding proportion of sodium hypochlorite based on the ORP dynamic range and the cyanide concentration attenuation rate; precipitation: adding hydroxide, and carrying out heavy metal precipitation; second monitoring: acquiring component information in the sewage, and adding sodium hydroxide and sodium sulfide in a gradient compensation manner after triggering judgment; membrane treatment: performing filtration and degradation treatment through a biological membrane; 3, monitoring: dynamically adjusting the aeration intensity and the backwashing period according to the coupling relationship between the pressure difference slope and the sludge concentration; and 4, monitoring: calculating a process capability index, judging whether the process capability index is smaller than a third threshold value, and if so, adjusting the sodium sulfide dosage in the precipitation stage. The method has the effect of reducing resource waste in the wastewater treatment process.

The invention relates to the technical field of preparation of an electrolyte for a vanadium redox flow battery, in particular to a reduction method of an alkaline vanadium-containing solution during short-process preparation of a vanadium electrolyte. The reduction method comprises the following steps: (1) adding a reducing agent sodium sulfite into an alkaline vanadium-containing solution and dissolving; and (2) acid is added into the solution obtained after dissolving in the step (1), the pH is adjusted, a reduction reaction is conducted, and vanadium is reduced to be tetravalent. The method provided by the invention effectively solves the problem of vanadium loss caused by precipitation generated in the sequential operation process of acidification and reduction of the alkaline vanadium-containing solution in the prior art, and meanwhile, the method provided by the invention is easy for engineering implementation.