1877 results about "Reference electrode" patented technology

The invention belongs to the technical field of medical electronic equipment, and discloses a control system for alternative electrical stimulation of idiopathic tremor, and the system comprises a signal collection module which is used for obtaining tremor motion data of a patient in real time; the signal processing module is used for analyzing tremor frequency, amplitude and phase characteristics; the dynamic parameter generation module is used for generating an alternate stimulation mode according to the tremor characteristics; and the electrode array module comprises at least two stimulating electrodes and a reference electrode. The invention provides a non-invasive and dynamically optimized alternate electrical stimulation control system which is used for inhibiting hand tremor of an idiopathic tremor patient, regulation and control of a tremor network can be enhanced by alternately stimulating different peripheral nerves, the curative effect can be improved through closed-loop feedback optimization parameters, long-acting and safe tremor inhibition is achieved, and the treatment effect is improved. The problems of insufficient curative effect, nerve adaptability, surgical risk and the like in the prior art are solved.

The invention relates to a flow battery charge state detection device and method, and is applied to the technical field of flow batteries. Compared with the prior art, the reference detection cavity connected with the bipolar plate is formed, the reference electrolyte can be replaced and supplemented without arranging a reference electrolyte storage tank, the adaptability of the detection device is improved, and the reference detection cavity corresponds to the positive electrolyte detection cavity and / or the negative electrolyte detection cavity, so that the detection efficiency is improved. A reference electrode is arranged in a reference detection cavity, the potential deviation of a reference electrolyte can be detected and calibrated in real time, and a calibration voltage value of the reference detection cavity is obtained, so that the potential of a positive electrode electrolyte relative to the reference electrode, the potential of a negative electrode electrolyte relative to the reference electrode and the calibration voltage value are used for calibrating the potential deviation of the reference electrolyte. The concentration of each valence ion is calculated on line through a multi-parameter empirical formula, and the charge state of the flow battery is obtained in real time through the concentration of each valence ion, so that the detection error is reduced, the detection sensitivity is improved, and the real-time monitoring precision of the charge state is improved.

The invention discloses an all-solid-state calibration-free ion concentration detection method. The method comprises the following steps: constructing a plurality of traditional three-electrode detection systems; in each traditional three-electrode detection system, current and impedance signals are synchronously acquired through a step potential electrochemical spectrum and an electrochemical impedance spectrum, and interface kinetic parameters are analyzed; on the basis of a traditional three-electrode detection system, an original reference electrode is removed, a counter electrode is reserved, all glassy carbon electrodes with gradient membrane volumes are connected in series one by one to obtain a new three-electrode detection system, the new three-electrode detection system is immersed in a to-be-detected solution, a preset potential is applied, and through transient current response in combination with calibrated kinetic parameters, the gradient membrane volumes of the glassy carbon electrodes are detected. And performing inversion to obtain the ion concentration of the to-be-detected solution. According to the method, automatic calibration is realized by analyzing interface process kinetic parameters of different-volume film ion selective electrodes and calculating the slope to generate a built-in standard curve. According to the method, interface process parameters are obtained through transient current, and dependence of a traditional detection system on the stable potential of a reference electrode is eliminated.

The invention discloses an immunosensor for detecting cytokine interferon gamma through electrochemiluminescence as well as a preparation method and application of the immunosensor. The immunosensor comprises a three-electrode system consisting of an immunoelectrode, a reference electrode and a counter electrode, the immunoelectrode is a VMSF modified electrode confined to cerium dioxide nano enzyme and platinum nano particles, and is obtained by covalently immobilizing an IFN-gamma antibody and closing a non-specific site; when the immunosensor is used for detection, a solution containing luminol is used as an electrolyte. The CeO2 and the PtNPs which are confined in the nano channel show a remarkable synergistic catalysis effect. Compared with direct modification on a plate electrode, CeO2-PtNPs has higher catalytic activity and stability. The sensor provided by the invention is used for INF-gamma detection, has the advantages of high sensitivity, low detection limit and wide detection range, does not need complex pretreatment and separation processes during detection, reduces the detection cost, is simple to operate, and is suitable for large-scale application.

The invention belongs to the technical field of metal surface treatment, and relates to a preparation method of a metal surface lattice passivation corrosion-resistant film, which comprises the following steps of: polishing and cleaning a metal surface, constructing a three-electrode system, and applying cathode voltage to the metal to carry out surface modification treatment so as to realize metal surface lattice reconstruction, thereby obtaining the metal surface lattice passivation corrosion-resistant film. A compact adsorption layer of corrosion inhibition molecules is formed; the three-electrode system comprises metal as a working electrode, a platinum sheet as an auxiliary electrode and silver / silver chloride or saturated calomel as a reference electrode. According to the method, metal surface lattice reconstruction is achieved through cathode voltage treatment, the technical thought of traditional anodic oxidation is subverted, the passive film forms a regular lattice structure, defects in the film are greatly reduced, permeation of a corrosion medium is effectively blocked, and the corrosion resistance of metal is remarkably improved.

The invention provides a flow battery energy storage power station full life cycle health degree assessment management method. The method comprises the following steps: constructing an initial health reference library, collecting electrochemical parameters through a reference electrode, collecting electrolyte physical parameters and environmental parameters through a sensor, synchronously recording operation and maintenance data, and carrying out time-space synchronization processing; introducing a hierarchical fusion assessment mechanism, assessing data integrity and constructing an attention mechanism model, calculating a dynamic weight according to a parameter relative change rate and a health degree correlation coefficient, generating a weighted feature vector, and predicting a short-term health degree index by adopting a bidirectional long-short-term memory network Bi-LSTM; a particle filter (PF) algorithm is introduced to be combined with a physical parameter drift distance to correct a long-term health degree index, and then a real-time health degree index is output through fuzzy comprehensive evaluation. The method can achieve the linkage evaluation of the health state in the operation period and the full life cycle trend, corrects the long-term SOH through the PF algorithm in combination with the physical parameter drift distance, and reduces the error of long-term prediction.

The invention discloses an electrocatalytic oxidation method for highly selectively converting 5-hydroxymethylfurfural into 2, 5-furandicarboxylic acid by using a cobalt-nickel bimetallic catalyst, and belongs to the technical field of electrochemistry. Firstly, foamed nickel is pretreated; secondly, preparing a cobalt-nickel mixed solution, synthesizing the catalyst by adopting a solvothermal method, and characterizing the catalyst; and thirdly, preparing a three-electrode system by taking the cobalt-nickel catalyst as a working electrode, a spiral platinum wire electrode as a counter electrode, a Hg / HgO electrode as a reference electrode, an alkaline solution as an electrolyte and a Nafion 117 proton membrane as a diaphragm to realize conversion. And finally, testing the stability and cyclicity of the cobalt-nickel catalyst. Under the same potential, the material has the highest current density, the maximum electrochemical active area and the optimal charge transfer rate; the self-degradation of HMF can be effectively inhibited, the electrocatalytic oxidation has lower initial potential than the oxygen evolution reaction, and the electrode cycle stability is good; the method is simple in process, mild in condition and beneficial to industrial production.

The invention discloses a micro-structure electrode flexible electrochemical sensor which comprises a flexible electrode substrate with a hemispherical array and three surface electrodes (a working electrode, a counter electrode and a reference electrode). The working electrode comprises a protruding metal array and a through hole array, protruding metal corresponds to the hemisphere array of the substrate, and the through hole array penetrates through the substrate. According to the sensor, the reaction area is increased through the three-dimensional structure, electron transfer is promoted, oxygen supply is guaranteed through the through hole array, the mechanical stability is enhanced through the flexible substrate and the structural design, and the sensor is suitable for wearable equipment.

A gas sensor includes a sensor element including an element body, a measurement pump cell being configured to pump out oxygen from surroundings of an inner measurement electrode to surroundings of an outer measurement electrode, and a measurement voltage detection sensor cell that detects a measurement voltage between a reference electrode and the inner measurement electrode, and a pump cell controller that executes a normal time measurement pump control process of pumping out oxygen in the measurement chamber during a normal operation time of the sensor element so that the measurement voltage reaches a normal time target value, and executes a start-up time measurement pump control process of pumping out oxygen in the measurement chamber at a start-up time of the sensor element earlier than the normal operation time so that the measurement voltage reaches a start-up time target value higher than the normal time target value.

The present invention discloses a high-precision foundation pit retaining wall leakage potential measurement system and method. An electrode matrix, an electric field establishment module, a reference electrode, a multi-channel electrical signal parallel measurement device and a data processing terminal are respectively arranged in the foundation pit. The outer side of the non-polarized electrode of the electrode matrix is ​​filled with bentonite slurry. The bentonite slurry can infiltrate the contact part between the non-polarized electrode and the foundation pit soil to change the properties of the soil, thereby controlling the contact potential between the electrode matrix and the soil and reducing the measurement error. At the same time, the non-polarized electrode and the reference electrode of the electrode matrix are respectively provided with an ion concentration meter and a temperature sensor. The data processing terminal can correct the potential difference according to the electrode temperature and ion concentration of the non-polarized electrode and the reference electrode temperature and reference ion concentration of the reference electrode to calibrate the electrode extreme difference caused by temperature and ion concentration, thereby obtaining the true potential difference of the foundation pit, thereby effectively improving the measurement accuracy and improving the accuracy and reliability of the foundation pit leakage detection results.

The invention provides a flexible electrochemical sensor, a preparation method and application. The flexible electrochemical sensor comprises a flexible substrate, three electrodes, a conductive strip, an external wire and a multi-cavity polypyrrole film, the three electrodes comprise a working electrode, a reference electrode and an auxiliary electrode and are printed on the flexible substrate; the conductive strip is connected with the three electrodes, the conductive strip is packaged through an insulating tape, and only working areas of the three electrodes are exposed; the external wire is pasted on the conductive strip through conductive silver adhesive. The multi-cavity polypyrrole film is modified on the surface of the working electrode. The technical problems that existing equipment is insufficient in portability, cannot meet the requirements of on-site rapid screening and real-time analysis of large-batch samples, and is difficult to realize on-site mobile detection are solved. The invention provides a feasible technical means for portable, mobile and on-site rapid detection of high-harm heavy metal ions such as Hg < 2 + > and Cd < 2 + >, and the method is simple to operate and extremely low in cost.

The invention provides an electrode for monitoring active oxygen substances of tumor cells in real time, a detection system and a preparation method of the electrode. According to the electrode, an electrode array is constructed on a glass substrate through an MEMS technology, the electrode comprises a working electrode, a reference electrode and a counter electrode, the surface of the working electrode is modified with an AuNPs / ZIF-8 ZIF-67 nano-enzyme material so as to enhance the detection sensitivity of reactive oxygen species (ROS), and the detection system comprises the electrode, a PDMS cavity and an electrochemical detection device. The cell culture chamber is fixed on the electrode through plasma bonding and is provided with a through hole to be matched with the Transwell cell culture chamber, so that ROS released by incubated tumor cells can be directly diffused to the surface of the electrode, and efficient detection is realized. By optimizing the electrode modification material and the system structure, the detection sensitivity and stability are improved, and the sensor has real-time monitoring capability and is suitable for biomedical research and anti-cancer drug screening.

The application discloses an electrochemiluminescence immunosensor for detecting interleukin-1 beta and a preparation method and application thereof, and comprises a three-electrode system of a working electrode, a reference electrode and a counter electrode; the working electrode is a modified electrode of CoAl layered double hydroxide, is loaded with platinum nanoparticles after being etched by alkali, and is obtained by fixing interleukin-1 beta antibodies and blocking non-specific sites; and a solution containing luminol is used as an electrolyte during detection of the immunosensor. The working electrode of the immunosensor takes oxygen-rich vacancy CoAl layered double hydroxide as a substrate, combines with platinum nanoparticles to realize EMSI effect, significantly enhances the electrochemiluminescence signal of a luminol-dissolved oxygen system, realizes quantitative detection of IL-1 beta by combining with specific antigen-antibody recognition, and has the characteristics of strong anti-interference ability, fast detection speed and good stability.

The invention belongs to the technical field of metal material and coating performance detection, and particularly relates to a high-pressure hydrogen permeation testing device and method.The testing device comprises a gas phase system and an electrochemical testing system, and the gas phase system comprises a high-pressure kettle, a hydrogen cylinder, a nitrogen cylinder and a vacuum treatment device; the autoclave is sealed and communicated with the hydrogen cylinder, the nitrogen cylinder and the vacuum treatment device; a first test port is formed in the upper part of the autoclave; the electrochemical testing system comprises an electrochemical workstation and an electrolytic tank; the electrolytic tank is connected to the upper part of the autoclave; the electrolytic tank is provided with a reference electrode and an auxiliary electrode, the lower part of the electrolytic tank is provided with a second test port, and the first test port and the second test port are connected with closed rubber rings and jointly clamp a sample to be tested through the closed rubber rings; the electrochemical workstation is electrically connected with the auxiliary electrode, the reference electrode and the to-be-tested sample, so that the service condition of the to-be-tested sample can be accurately simulated, the hydrogen permeation process in the actual working condition can be more truly reflected, and the accuracy of a hydrogen permeation test experiment is improved.

The present disclosure provides a sensing assembly for sensing a property of a fluid sample comprising at least one working electrode provided in the primary fluid channel configured to sense a property of a fluid sample in the primary fluid channel; a secondary fluid channel adjacent to and fluidly connected to the primary fluid channel along the primary flow path; and a reference electrode element provided in the secondary fluid channel. The secondary fluid channel is arranged as a branch from the primary fluid channel so as to limit the flow of fluid sample from the primary fluid channel to the reference electrode element. Alternatively or additionally, a method comprises determining a property of a sample comprising providing such a sensing assembly.

This disclosure relates to magnetic microgel beads, and in particular to magnetic microgel beads for biofunctionalization and methods of making and uses thereof, for example, in biosensing assays. In an embodiment, a magnetic microparticle comprising a magnetic nanoparticle encapsulated by a polymer hydrogel. In another embodiment, an assay for detecting the presence of a target analyte in a sample comprising a) the magnetic microparticle disclosed herein, wherein the biorecognition agent further comprises a reporter moiety; b) an electrochemical chip comprising a working electrode, a counter electrode and a reference electrode; and c) a capture probe functionalized on the working electrode; wherein binding of the biorecognition agent to the target analyte results in production of an electrochemical, electroluminescent or photoelectrochemical signal.

An antenna includes: a first substrate and a second substrate. The first substrate includes: a first dielectric substrate, a first reference electrode layer, a first radiation part, and a feeder group. The first dielectric substrate includes a main substrate and a side substrate, the feeder group includes at least one feeder, in each of which, each feeder is electrically connected to one first radiation part, and different feeders are electrically connected to different first radiation parts. The second substrate includes: a second dielectric substrate, a second reference electrode layer, and a feed structure. The feed structure corresponds to the feeder group, and for corresponding feed structure and feeder group, each first feed port in the feed structure is electrically connected to one feeder in the feeder group through a first connection via which runs through at least the side substrate, the second reference electrode layer, and the second dielectric substrate.

The invention relates to the technical field of fuel cell membrane electrode voltage distribution testing, in particular to a fuel cell membrane electrode voltage distribution testing method and system, and the method comprises the steps: arranging a potential sensor array, and synchronously collecting an original voltage vector through the potential sensor array in the loading operation process of a fuel cell; a reference electrode is arranged in the non-reaction area, a stable reference signal is applied to the reference electrode, and a feedback signal of the reference electrode is collected after preset stable time is delayed; carrying out difference calculation on the feedback signal and the stable reference signal to obtain a system measurement drift distance; and performing joint calibration on the original voltage vector according to the system measurement drift amount and the spatial continuity constraint of the membrane electrode voltage distribution to obtain the voltage distribution vector of the fuel cell membrane electrode. And the authenticity and reliability of the voltage distribution data in the long-period test process of the fuel cell are ensured by continuously compensating the drift of the measurement precision.

Provided is a potentiostat-based electrochemical sensor detection device. The device comprises: a digital-to-analog converter (DAC) configured to receive a digital signal from a waveform generator and digital logic and output an analog signal corresponding to a reference voltage; a control amplifier (CA) configured to receive the analog signal corresponding to the reference voltage and apply the reference voltage to a reference electrode (RE); a gain-boosting current mirror configured to copy a sensor current of an electrochemical sensor and output a copied sensor current; a transimpedance amplifier configured to convert the copied sensor current into a voltage signal; a low-pass filter configured to block a high-frequency band signal component of the voltage signal; and an analog-to-digital converter (ADC) configured to perform digital signal processing on a signal having passed through the low-pass filter, wherein at least one of the gain-boosting current mirror and the transimpedance amplifier employs a dynamic element matching (DEM) technique using a plurality of choppers and a plurality of DEM clock signals.

The invention relates to an electroencephalogram signal multi-source physiological artifact real-time removal method and system based on a self-adaptive hybrid model. The types of artifacts such as electro-oculogram, myoelectricity and the like are dynamically identified through fusion preprocessing, time-frequency domain feature rapid extraction and a lightweight online classifier; an intelligent hybrid processing engine is innovatively constructed, and an optimal denoising strategy is adaptively selected according to an artifact type: an improved regression model is adopted for ocular artifacts, adaptive wavelet threshold or ICA component elimination is adopted for myoelectric artifacts, and component separation is performed on hybrid artifacts in combination with sparse representation and variational mode decomposition; and parameters are optimized online through a real-time feedback mechanism. According to the method, additional hardware reference electrodes are not needed, high-precision artifact removal is achieved under millisecond-level delay, the electroencephalogram signal quality is remarkably improved, and the method is suitable for scenes with strict requirements for real-time performance and robustness such as brain-computer interfaces and nerve disease auxiliary diagnosis.

An object is to provide a micro-analysis chip in which a satisfactory area of contact between a specimen and an ion-selective membrane and an adequate amount of the specimen that reacts with the ion-selective membrane can be secured, and which is excellent both in measurement sensitivity and in ion selectivity. In order to achieve the object, a micro-analysis chip as described below is provided. That is, provided is a micro-analysis chip including a channel region which is surrounded by a channel wall provided inside a porous substrate. The channel region includes a first channel chamber containing a reference electrode, a second channel chamber containing a working electrode. The working electrode is covered with an ion-selective membrane containing an ingredient that has ion selectivity. The ion-selective membrane has an exposed surface serving as a dispensing section to which a specimen is dispensed.

The application discloses an antenna and electronic equipment, and relates to the technical field of antennas. The antenna comprises a first substrate and a second substrate which are arranged in a stack; the first substrate comprises a radiation component, a first feed line and a second feed line which are electrically connected to the radiation component; the second substrate comprises: a second dielectric substrate having a third surface and a fourth surface; a second reference electrode layer arranged on the third surface side; a first feed structure and a second feed structure both arranged on the fourth surface side, and a second feed port of the first feed structure is electrically connected to the first feed line, and a fourth feed port of the second feed structure is electrically connected to the second feed line; a first connecting via and a second connecting via which penetrate through the second dielectric substrate and the second reference electrode layer, and the first connecting via is in communication with the first feed port, and the second connecting via is in communication with the third feed port. Through the scheme of the application, the first feed structure and the second feed structure are prevented from crossing lines, and the welding of the radio frequency line is facilitated.

The invention discloses a reference electrode, and relates to the technical field of batteries. The reference electrode comprises a conductive assembly and a diaphragm assembly, the conductive assembly comprises an exposed conductor section and an insulating section, the exposed conductor section is wrapped in the diaphragm assembly, a coating is arranged on one side, facing the exposed conductor section, of the diaphragm assembly, and a metal lithium layer is plated on the surface of the exposed conductor section. Through the structure, the service life and the voltage stability of the reference electrode can be remarkably improved, so that the accuracy and the reliability of battery test data are guaranteed.

The present disclosure is related to a bimetallic monatomic nano-enzyme electrochemical sensor, and a preparation method therefor and an application thereof. The bimetallic monatomic nano-enzyme electrochemical sensor comprises a working electrode, a counter electrode, a reference electrode and an electric signal control device; the working electrode is formed by coating a gallium-copper bimetallic monatomic nano-enzyme and a conductive carbon paste on a flexible carrier; and according to the present disclosure, the electrochemical sensor is constructed by loading a catalytic material of the gallium-copper bimetallic monatomic nano-enzyme on an electrode substrate material, which is used for detecting a volatile amine content in fresh meat, so as to detect a freshness of fresh meat.

The application discloses a preparation method of a high-density and high-stability conductive polymer film based on electrochemical polymerization, and comprises the following steps: using an oxidant solution and a BFDO monomer solution to pretreat a formed foil to obtain a working electrode, then immersing the working electrode and a reference electrode into an electrolyte to perform electrochemical oxidation polymerization, and obtaining the high-density and high-stability conductive polymer film based on electrochemical polymerization. The pretreated formed foil containing N-type conductive polymer PBFDO is prepared by using a chemical in-situ polymerization method on the formed foil, and when the pretreated formed foil is applied in the field of capacitors, the conductivity and electron transport capacity of the capacitor can be improved, and the stability problem caused by the coupling of positive and negative charges in the traditional capacitor is greatly improved.

Techniques for determining microbiological corrosion include flowing a mixed-phase wellbore fluid from at least one tank into a volume of a reactor tank of a microbiological corrosion reactor; controlling a multi-channel potentiostat coupled to a three-electrode cell assembly positioned in the volume, the three-electrode cell assembly including a working electrode, a counter electrode, and a reference electrode, where each of the working electrode, the counter electrode, and the reference electrode is positioned in the volume to contact the mixed-phase wellbore fluid; based on controlling the multi-channel potentiostat, activating the working electrode in the mixed-phase wellbore fluid in the volume; and determining, based on activating the working electrode, a corrosion rate of at least one of the working electrode or a target coupon positioned within the mixed-phase wellbore fluid in the volume.

The invention discloses a miniaturized low-profile flexible ocean galvanic couple type pH sensor and a preparation method thereof, and aims to solve the problems of large profile thickness and insufficient reliability of the conventional flexible pH sensor. A working electrode system and a reference electrode system in the miniaturized low-profile flexible ocean galvanic couple pH sensor are arranged on a flexible polyimide substrate, and the working electrode system comprises an iridium oxide working electrode, a first metal conduction circuit layer and a first metal bonding pad; the iridium oxide working electrode is connected with the first metal bonding pad through the first metal conduction circuit layer, the reference electrode system comprises a reference electrode, a second metal conduction circuit layer and a second metal bonding pad, and the reference electrode is connected with the second metal bonding pad through the second metal conduction circuit layer. The pH response performance is remarkably improved by utilizing the nanocrystalline iridium oxide sensing layer, the sensitivity reaches 72.76 mV / pH, and 16.84 s quick response is realized in a 3m / s high-flow-speed marine environment.

The invention discloses a hexachlorophenol electrochemical sensor built based on NiFe-coated C / MoO3 and a preparation method and application thereof.The hexachlorophenol electrochemical sensor comprises a working electrode, an auxiliary electrode and a reference electrode, the working electrode is a NiFe-coated C / MoO3 modified electrode and is composed of a glassy carbon electrode and a NiFe-coated C / MoO3 composite material modified on the glassy carbon electrode, the auxiliary electrode is a NiFe-coated C / MoO3 modified electrode, and the reference electrode is a NiFe-coated C / MoO3 modified electrode. The NiFe (at) C / MoO3 composite material comprises a NiFe (at) C framework and MoO3 loaded on the NiFe (at) C framework, and the NiFe (at) C framework is formed by embedding NiFe bimetal nanoparticles into a porous carbon framework. The preparation method comprises the steps of synthesis of MoO3, synthesis of NiFe C, preparation of the modified electrode and preparation of the electrochemical sensor. The hexachlorophenol electrochemical sensor disclosed by the invention can be used for direct electrochemical detection without derivatization, and is high in selectivity, portable at low cost, ultrahigh in sensitivity and good in application prospect.

The invention discloses a seawater chemical oxygen demand determination method based on bias voltage photoelectric oxidation, and relates to the technical field of water quality monitoring. The method comprises the following steps: collecting seawater and performing pretreatment to obtain a seawater sample; adding supporting electrolyte into the seawater sample to obtain an electrolytic water sample; the method comprises the following steps: injecting an electrolysis water sample into a photoelectrochemical reaction tank, applying bias voltage to a working electrode by taking Ag / AgCl as a reference electrode, and turning on a light source with a specific wavelength for irradiation; carrying out an oxidation reaction in the photoelectrochemical reaction tank, and after the oxidation reaction of the organic matter is complete, obtaining a steady-state photocurrent with a stable current signal; according to a preset steady-state light current-COD concentration curve, a COD measured value is obtained, the COD standard concentration value is corrected according to the water temperature and the salinity, and a COD corrected value is obtained. An adjustable tiny external bias voltage is introduced to cooperate with light source irradiation, so that rapid, accurate and high-anti-interference measurement of COD in seawater is realized.

An ion sensor is disclosed that includes an ion selective electrode including a first internal solid layer including a first insertion material, and a first ion conductive ceramic, an ion selective membrane provided on the first internal solid layer, a reference electrode including a second internal solid layer including a second insertion material, and a second ion conductive ceramic, an ionic liquid containing membrane provided on the second internal solid layer, and an insulator on which the ion selective electrode and the reference electrode are arranged.