4868 results about "Surface modification" patented technology

The invention relates to a self-cleaning nano coating material and a preparation process thereof, and belongs to the technical field of functional coatings. The coating material is prepared from nano silicon dioxide, nano aluminum oxide, graphene nanosheets, nitrogen-doped titanium dioxide, fluorinated silane, polyurethane, polydimethylsiloxane, a microcapsule repairing system, ethanol and deionized water according to a specific proportion through a multi-layer composite structure. The preparation process comprises the steps of base material surface pretreatment, reinforced particle surface modification, base material dissolution, functional additive introduction and multi-layer coating preparation. Through bottom layer enhancement, middle layer flexible buffering and surface layer functional design, excellent mechanical strength, wide-spectrum photocatalytic performance, self-repairing capacity and environmental adaptability are achieved. The problems that in the prior art, a self-cleaning coating is insufficient in mechanical performance, low in photocatalytic efficiency, lack of a self-repairing function and poor in weather resistance are solved, the service life of the coating is remarkably prolonged, and the functional stability of the coating is remarkably improved.

The invention discloses spherical aluminum oxide and a silicone rubber heat conduction composite material thereof, and belongs to the technical field of functional polymer materials. The spherical aluminum oxide is subjected to surface modification through an amphiphilic fluorosilicone heat conduction interface synergist; comprising the following raw materials in parts by weight: 100-200 parts of vinyl silicone oil, 1-6 parts of side hydrogen-containing silicone oil, 1-6 parts of end hydrogen-containing silicone oil, 0.2-2 parts of a platinum catalyst, 0.01-0.1 part of an inhibitor and 2500-6000 parts of amphiphilic fluorine-silicon heat-conducting interface synergistic spherical aluminum oxide powder. Through surface modification of spherical aluminum oxide, the prepared silicone rubber heat-conducting composite material realizes synergistic gain of heat conduction, insulation and flexibility, and can meet the requirements of multiple fields such as power battery pack heat dissipation gaskets, high-frequency circuit packaging and wearable equipment.

The invention relates to the technical field of laser surface modification, and discloses a water turbine laser cladding process parameter intelligent optimization system and method, and the system comprises a data preparation and preprocessing module which is used for obtaining and preprocessing water turbine laser cladding process parameters and corresponding cladding layer quality index data; a physical information guided multi-task prediction network construction and training module; a causal inference analysis module; and a causal perception multi-objective optimization algorithm module. By constructing a multi-task prediction network guided by physical information, the internal physical law of the laser cladding process is fused into a deep learning model, and the accuracy and reliability of predicting a plurality of key quality indexes of the laser cladding layer of the water turbine are remarkably improved. Compared with a traditional pure data driving model, the method can generate a prediction result more conforming to an actual cladding mechanism by means of guidance of physical constraints even under the condition of limited experimental data, and lays a solid data foundation for subsequent process optimization.

The invention relates to the technical field of gas monitoring, and discloses an air quality monitoring method based on an olfactory chip, which comprises the following steps: step 1, preparing a multi-modal sensor system which comprises an olfactory chip module, a surface enhanced Raman scattering module and a microfluidic time division multiplexing module, the sensor surface of the olfaction chip module is modified with a metal organic framework material, and the substrate of the surface enhanced Raman scattering module is made of a core-shell structure nano material; and 2, synchronously collecting resistance response data of the olfaction chip module, spectral data of the surface enhanced Raman scattering module and temperature, humidity and wind speed data of the environment sensor. According to the invention, a multi-modal sensor cooperative detection technical scheme is adopted, the high-sensitivity detection effect on low-concentration harmful gas in air is achieved, and compared with a technical scheme of a single sensor and a fixed fusion algorithm in the prior art, the defect that accurate recognition of trace gas cannot be realized under ppb-level concentration is overcome.

The invention relates to the field of composite materials, and discloses an unmanned aerial vehicle carbon fiber shell preparation method, which comprises: carbon fiber surface modification treatment: carrying out surface cleaning, activation, chemical plating and surface functional modification on carbon fibers; preparing a resin matrix: mixing epoxy resin with a flexible toughening agent, a nano filler and a curing agent, and carrying out vacuum defoaming; carbon fiber laying: laying the modified carbon fiber cloth according to a set angle and sequence; vacuum bag forming: performing vacuum sealing on the laid carbon fiber composite material; and hot-pressing and curing: curing the composite material in an autoclave under the process conditions of set temperature, pressure and time. Through collaborative design of interface modification, matrix enhancement and process optimization, the comprehensive performance of the composite material is improved, so that the requirements of the unmanned aerial vehicle shell for high strength, fatigue resistance and impact resistance are met.

The invention relates to the technical field of laser welding, and discloses a laser machining device and method for a nuclear reactor shell, and the method comprises the steps that a shell plate welding area to be welded is subjected to surface modification pretreatment; the laser processing device is used for carrying out initial welding on the pretreated shell plate, in the initial welding process, the temperature sensing assembly is used for monitoring temperature distribution of the welding area in real time, and temperature information of the welding area is obtained; the temperature information is input into a preset temperature-deformation prediction model for prediction of a variable trend and a stress distribution condition so as to obtain a first prediction result; based on the obtained first prediction result, the welding parameters of the laser processing device are dynamically adjusted for the first time; welding deformation and stress concentration are effectively coped with, the welding quality and structural strength of the nuclear reactor shell after laser welding are improved, and the reliability and safety of the nuclear reactor shell during use are effectively improved.

The invention relates to a preparation method of spherical silicon dioxide micropowder with ultralow dielectric loss. The preparation method comprises the following steps: preparing an organic silicon polymer; preparing slurry; performing solid-liquid separation on the synthetic slurry to obtain concentrated slurry, and drying the concentrated slurry to obtain spherical silica powder; carrying out low-temperature heat treatment on the obtained spherical silica powder at 1500-7000 DEG C for h to remove residual organic matters and free water in the powder; then, high-temperature densification is carried out at the temperature of 3000-28000 DEG C for h, and moisture is further removed; adding a modifier into the stirring equipment for surface modification; and after surface modification, drying at 55-300 DEG C for h, and removing modified micromolecular byproducts to obtain the spherical silicon dioxide micro powder with ultralow dielectric loss. The method is simple in production process, short in production period, low in production cost, high in yield and capable of effectively reducing the dielectric loss of the spherical silicon dioxide micro powder.

The invention discloses a carbon fiber composite material surface modification spraying system and a control method thereof. The system comprises a multi-axis robot, a plasma spray gun, a contact angle measuring probe, a 3D line laser scanner, a hyperspectral imager, an environment sensor and a controller. According to the method, the plasma power and the robot speed are adjusted in real time through contact angle measurement and plasma treatment feedback control, so that the CFRP surface can accurately reach a target value, and the coating adhesive force is improved; 3D line laser scanning and hyperspectral imaging are combined, and the posture, the distance, the wet film thickness and the component uniformity of the spray gun are monitored in real time; based on a prediction model fusing a physical model and a neural network, a self-adaptive fuzzy PID control algorithm is adopted, and the coating flow and the track posture of a spray gun are accurately regulated and controlled in real time. The problems of weak coating binding force, uneven thickness, orange peel, sagging and serious coating waste in traditional spraying are effectively solved, and self-adaptive, high-quality and green spraying of workpieces with complex curved surfaces is achieved.

The present invention relates to the technical field of molecular interaction analysis, and specifically provides a method for analyzing intermolecular interactions. The method comprises the following steps: using a rare earth material with a ligand molecule modified on its surface as an upconversion material, contacting the upconversion material with a target molecule in a solution system, irradiating the solution system with excitation light that matches the rare earth material, and continuously changing the intensity of the excitation light actually received by the upconversion material as the target molecule continuously binds and dissociates with the ligand molecule of the upconversion material in a dynamic process, thereby changing the intensity of the emitted light. By recording the curve of the emission light intensity changing with time, the molecular interaction kinetic constants, such as the binding rate constant (K on ), dissociation rate constant (K off ) and affinity (K D ), etc., which solves the technical problems of low accuracy of existing BLI technology and high cost of SPR technology. Based on the above principles, the present invention has also developed a series of experimental consumables, kits, sensors and analytical devices for molecular interaction analysis.

The invention belongs to the technical field of ceramics and slurry thereof, and particularly relates to fiber-reinforced ceramic photocuring slurry, a preparation method and a reinforced ceramic material. The slurry provided by the invention consists of ceramic powder, ceramic composite short fibers, light-cured resin, a photoinitiator, a dispersing agent, a plasticizer and the like, wherein the ceramic composite short fibers are zirconium oxide and silicon oxide composite fibers; the light-cured resin contains a photosensitive resin monomer and a prepolymer; and the photoinitiator is compounded by a short-wavelength initiator and a long-wavelength initiator. The preparation method comprises the following steps: modifying the ceramic composite short fibers with a silane coupling agent, mixing the modified ceramic composite short fibers with all the materials, and carrying out ball milling and defoaming. The obtained slurry is subjected to 3D printing photocuring molding and degreasing sintering, and a reinforced ceramic material can be prepared. The slurry can be used for manufacturing a high-performance ceramic material through composite short fiber synergistic enhancement, long and short wavelength initiator synergistic curing and fiber surface modification, and the curing depth, the three-point bending strength and the fracture toughness are remarkably improved.

The present invention relates to the technical field of composite materials. Provided are a glass fiber-reinforced epoxy resin composite material and a preparation method therefor. In the present invention, an epoxy silane coupling agent solution is used for performing surface modification on glass fibers. An epoxy silane coupling agent contains a hydrolyzable group and an epoxy group. Silicon hydroxyl generated when the hydrolyzable group is hydrolyzed can be connected to the glass fibers, so as to effectively modify the surfaces of the glass fibers. The epoxy group can react with an epoxy resin matrix, thereby improving the infiltration effect of the epoxy resin on the glass fibers and improving the bonding performance of the interface of the glass fiber-reinforced epoxy resin composite material, and thus improving the mechanical properties of the glass fiber-reinforced epoxy resin composite material. The epoxy resin is cured and modified by using a functional curing agent or nanoparticles, so as to improve the ductility or strength of the epoxy resin, thereby improving the mechanical properties of the prepared glass fiber-reinforced epoxy resin composite material.

The invention discloses basalt fiber reinforced anti-crack road concrete and a preparation method thereof, and belongs to the technical field of concrete preparation, and the preparation method specifically comprises the following steps: transferring a concrete precursor into a mold, transferring the mold to a vibration table, vibrating for 1-2 minutes, scraping the raised part of the surface by using a scraper, covering the surface of the material with a preservative film, and drying to obtain the basalt fiber reinforced anti-crack road concrete. Performing post-treatment to obtain the anti-crack concrete. The preparation method comprises the following steps: cleaning basalt fibers, activating, carrying out surface modification, curing to obtain composite basalt fibers, hydrolyzing a borosilicate monomer to prepare modified borosilane with a double-bond structure, converting the double-bond structure into an epoxy group through an epoxidation reaction to obtain a modified curing agent, and preparing the composite basalt fibers by using the modified curing agent and the modified borosilane as additives. And mixing with cement and other materials to obtain the wear-resistant, fracture-resistant and corrosion-resistant anti-crack concrete.

The invention discloses atomic layer etching adopting single process gas and rapidly adjusting chamber pressure. The process includes a step time designed for optimizing the surface modification and sputtering process, thereby minimizing undesirable effects. The customized waveform generator enables rapid and accurate control of the substrate bias, thereby shortening the ALE cycle time. Besides, by presetting set values for the MFC and the vacuum valve, rapid adjustment of the pressure of the cavity is achieved, traditional PID control is not needed, and therefore the efficiency and precision in semiconductor manufacturing are further improved.

The invention provides an electrochemical biosensor based on a nanoparticle modified multilayer porous membrane and application of the electrochemical biosensor. The nano particle modified multilayer porous membrane is composed of a plurality of modified nano particles among membranes with nano pore channels. The electrochemical biosensor constructed based on the nanoparticle modified multilayer porous membrane has the following advantages: (1) good conductivity and stability; and (2) multiple capture probes are modified on the surfaces of the nano pore channels of the multi-layer porous membrane, so that multiple different targets can be respectively detected, and multiple different targets can also be detected at the same time. And (3) enzyme-free double-target sensitive normal-temperature amplification-free detection can be carried out. (4) preparation steps are simple, consumed time is short, and operability is high; and (5) the sensitivity and the specificity are high.

The invention discloses a gas sensing material based on Ag / Pd-LaFeO3 and application of the gas sensing material in detection of hydrogen sulfide gas in municipal sewage, and relates to the technical field of gas sensing materials. The chemical formula of the gas sensing material based on Ag / Pd-LaFeO3 is X wt% of Ag-Y wt% of Pd-LaFeO3, wherein 0 lt; x < = 5, 0lt; y < = 5. According to the invention, on the basis of LaFeO3, the humidity interference resistance of the gas sensing material based on Ag / Pd-LaFeO3 can be improved through double noble metal surface modification of Ag and Pd. In addition, through double noble metal doping of Ag and Pd, the response sensitivity and selectivity of the prepared gas-sensitive material to H2S gas can be improved, and the working temperature of the gas-sensitive material is reduced. Specifically, at the working temperature of 110 DEG C, the response value of the prepared double noble metal modified LaFeO3 to 1ppm H2S gas is 46.16.

The present invention uses commercially available 3-aminopropylsilane coupling agent, diallylamino polyether acrylate, and an alkylating agent, or γ-propanesultone, or γ-butyrolactone as raw materials, and through an aza-Michael addition reaction and a quaternization reaction, a multifunctional silane coupling agent containing one or more quaternary ammonium cations, or sulfobetaine, or carboxybetaine in its molecular structure is prepared, which is used for the surface modification of bioactive glass, and the bioactivity, antibacterial and antifungal properties, and hydrophilicity enhancement effects after the surface modification of bioactive glass are obtained.

The invention discloses a high-performance composite solvent-resistant nanofiltration membrane with a rigid twisted non-planar structure polyamide layer and a preparation method of the high-performance composite solvent-resistant nanofiltration membrane. The preparation method comprises the steps of preparation of the rigid twisted non-planar structure polyamide layer and surface modification. A water phase solution containing adamantane diamine and m-phenylenediamine and an organic phase solution containing 1, 3, 5-trimesoyl chloride and acetone are subjected to interfacial polymerization reaction to prepare a polyamide layer with a rigid twisted non-planar structure, and then a polyphenol modifier is used for carrying out hydrophilic modification on the polyamide layer, so that the rigid twisted non-planar structure is obtained. The pure water permeability and retention rate of the solvent-resistant nanofiltration membrane are obviously improved; due to the introduction of adamantane diamine, the interfacial polymerization process and the formation of a polyamide layer are remarkably regulated and controlled, and the separation performance of the solvent-resistant membrane is greatly improved on the premise that the interception performance of the membrane is hardly reduced; the preparation process is simple, and the prepared membrane is excellent in performance and has a good application prospect in the aspect of organic solvent separation.

The invention relates to the technical field of high-performance structural ceramic materials and corrosion resistance optimization thereof, in particular to a preparation method of high-performance silicon nitride ceramic, which realizes performance improvement through dynamic optimization of a composite sintering aid, closed-loop regulation and control of air pressure sintering and multi-process data linkage. In the raw material pretreatment stage, a laser particle size analyzer is adopted for monitoring particle size distribution in real time, surface modification parameters are adjusted in a linkage mode, and a uniform monomolecular coating layer is formed; the proportion of rare earth oxide and aluminum oxide in the composite sintering aid is dynamically adjusted according to the fluctuation of the mixing torque, and agglomeration and segregation of the aid are inhibited. And in the air pressure sintering stage, the argon pressure and the heating rate are dynamically adjusted based on the slope of a shrinkage curve, and directional arrangement of beta-phase grains is promoted by combining low-temperature nitrogen protection and high-temperature argon densification. And multi-dimensional process control synergistically optimizes grain boundary components, structure and density, so that the corrosion resistance and the service life of the silicon nitride ceramic in a sulfur-containing environment are remarkably improved and the service life of the silicon nitride ceramic in the sulfur-containing environment is remarkably prolonged.

The invention discloses a curved circuit three-dimensional printing-oriented base material surface modification and adhesive force enhancement method, which comprises the following steps of: performing surface modification on the surface of an insulating curved surface base material, and integrally plating copper after modification, so that a layer of uniform conductive copper film is formed on the surface of the base material; anti-etching mask ink is selectively jet-printed on the base material, curing is carried out after jet printing is completed until the anti-etching mask ink is completely dried, and an anti-etching film with a conductive pattern is formed on the surface of the insulation curved surface base material; then, the conductive copper film is soaked in etching liquid for selective etching, and the conductive copper film which is not covered with the anti-etching film is gradually dissolved until the original insulating curved surface base material is exposed; and then soaking in an alkaline solution until the anti-etching film with the conductive pattern is completely dissolved and falls off to obtain the insulating curved-surface base material with a clean surface and a complete conductive pattern. According to the method disclosed by the invention, the adhesive force between the conductive material and the insulating curved surface base material is greatly enhanced, and high-precision and high-reliability preparation of the curved surface circuit is realized.

The invention belongs to the field of electrode paste preparation, and provides low-temperature curing silver-coated copper paste for a heterojunction solar cell and a preparation method of the low-temperature curing silver-coated copper paste. Ethyl cellulose is adopted as a matrix material, a stable matrix network is provided for slurry through good cohesiveness and dispersity of ethyl cellulose, and a network structure with a high crosslinking degree is formed by adding modified phenolic resin, organic silicon modified epoxy acrylate and other chemical modification materials into the slurry. The mechanical strength and adhesive force of the slurry are further enhanced, surface modification is carried out on inorganic filler such as silver-coated copper powder and bismuth oxide through a silane coupling agent and a titanate coupling agent, and the interface bonding force between the filler and an organic matrix is enhanced through silicon-oxygen bonds formed on the surface of the filler; by adding the carboxylated polyamide wax and the organic bentonite, the agglomeration tendency of the filler is reduced by utilizing the adsorption and electrostatic repulsion effects of the carboxylated polyamide wax and the organic bentonite on filler particles, and the obtained conductive slurry has the characteristics of excellent conductivity and low-temperature rapid curing.

The invention relates to the technical field of circuit substrate manufacturing, and particularly discloses a preparation method of a composite solder sheet and an AMB ceramic copper-clad plate. The composite solder sheet is composed of an active metal foil and a copper-containing layer modified on the surface of the active metal foil, and the preparation method of the copper-clad plate comprises the following steps: after the surface of the active metal foil is pretreated, the copper-containing layer is deposited to prepare the composite solder sheet, and the composite solder sheet is placed between a copper substrate and a ceramic sheet to be pressed and assembled. And performing vacuum brazing on the assembly to complete the preparation of the ceramic copper-clad plate. A composite solder sheet containing active metal is adopted, high-temperature element diffusion during vacuum brazing is utilized at the diffusion temperature to achieve alloying of a composite solder layer, and then heat preservation is conducted at the brazing temperature to achieve uniform melting of solder and wetting metallurgical reaction between the solder and copper and between the solder and a ceramic substrate. By means of the preparation method, low-cost and high-reliability preparation of the AMB ceramic copper-clad plate can be achieved, and the prepared AMB ceramic copper-clad plate also has high peel strength and lower weld porosity.

A method includes forming a dielectric layer over a source / drain region. An opening is formed in the dielectric layer. The opening exposes a portion of the source / drain region. A conductive liner is formed on sidewalls and a bottom of the opening. A surface modification process is performed on an exposed surface of the conductive liner. The surface modification process forms a surface coating layer over the conductive liner. The surface coating layer is removed to expose the conductive liner. The conductive liner is removed from the sidewalls of the opening. The opening is filled with a conductive material in a bottom-up manner. The conductive material is in physical contact with a remaining portion of the conductive liner and the dielectric layer.

The invention discloses a graphene nanometer heavy anti-corrosion coating and a preparation method thereof, and belongs to the technical field of anti-corrosion coatings. The coating is prepared from the following components in parts by mass: 50 to 70 parts of diallyl bisphenol A type epoxy resin, 8 to 15 parts of histidine modifier, 12 to 20 parts of graphene nano composite modified filler, 5 to 10 parts of curing agent, 0.5 to 2 parts of flatting agent and 0.3 to 1 part of defoaming agent. The preparation method of the histidine modifier comprises the following steps: carrying out a Schiff base reaction on 1-palmitoyl-2-oleoyl ethanolamine and N-formyl-L-histidine to generate an intermediate A; reacting with a spiro quaternization reagent to form a quaternary ammonium salt intermediate B; and then compounding with aminopropyltriethoxysilane and silicotungstic heteropoly acid salt to obtain the product. The graphene nano-composite modified filler is prepared by modifying the surface of a graphene oxide / bentonite mutual intercalation layer structure through allyl trimethoxy silane. The graphene nano heavy anti-corrosion coating prepared by the invention forms a high-density cross-linked network, and has excellent barrier property, strong adhesive force, impact resistance and long-acting anti-corrosion performance.

The invention belongs to the field of macromolecules, and particularly relates to a PBO fiber surface modification method for a synergistic copolymer coating through plasma treatment. According to the method, modification is designed by adopting a synergistic mechanism of plasma treatment and a functional coating: firstly, the PBO fiber is treated by oxygen plasma, a microstructure and an active group are formed on the surface of the PBO fiber, and the surface activity of the PBO fiber is rapidly improved; then coating a monomer solution containing a photoinitiator, exciting light to initiate free radical polymerization through ultraviolet irradiation, forming a random copolymer coating on the surface of the PBO fiber, and repairing the damage of oxygen plasmas to the PBO fiber structure while introducing active groups into the coating; and active groups formed by oxygen plasma treatment can enhance the adhesive force between the coating and the PBO fiber. Finally, the invention provides an environment-friendly and controllable PBO fiber surface synergistic modification technology, the intrinsic performance of the PBO fiber and the interface bonding strength are improved for a long time, and a support is provided for engineering application of the high-performance PBO fiber.

The invention discloses a synergistic compound light stabilizer for an automobile coating and a preparation method of the synergistic compound light stabilizer, and belongs to the technical field of coating additives. The light stabilizer comprises the following components in percentage by mass: 30-50% of a hindered amine light stabilizer, 20-40% of an ultraviolet light absorber, 5-15% of surface modified nano cerium dioxide, 5-10% of a hyperbranched polyester anti-migration aid and the balance of a solvent, wherein the ultraviolet light absorber is a mixture of benzotriazole and triazine in a mass ratio of (1: 1)-(1: 3); the particle size of the nano cerium dioxide is 10-50nm, and the surface of the nano cerium dioxide is coated with a silane coupling agent; the preparation method comprises the following steps: modifying the surface of nano cerium dioxide, shearing and dispersing multiple components at a high speed, and adjusting and filtering a solvent; the weather resistance of the automobile coating is remarkably improved and the service life of the automobile coating is remarkably prolonged through the synergistic effect of a plurality of light stabilizing components and the combination of the photocatalytic degradation capability of the nano cerium dioxide and the anti-migration characteristic of the hyperbranched polyester.

The invention discloses an electrochemical sensor constructed based on a composite material and a preparation method and application thereof.The electrochemical sensor comprises a screen-printed electrode, the surface of the reaction end of a working electrode of the screen-printed electrode is loaded with a zirconium-based metal organic framework composite material, the composite material comprises UiO-66, and the surface of the composite material is modified with a polydopamine coating. The preparation method comprises the following steps: preparing the zirconium-based metal organic framework composite material and fixing the composite material on the working electrode of the screen-printed electrode. According to the invention, the zirconium-based metal organic framework composite material with many adsorption sites, good dispersibility, good conductivity and good hydrophilicity is used as a functional material, so that the sensor has the advantages of simple operation, low cost, rapid response, strong anti-interference capability, wide detection linear range, high detection sensitivity, long service life and the like, and can be widely used for detecting Mn < 2 + >, Mn < 2 + >, Mn < 2 + >, Mn < 2 + > and Mn < 2 + > in a water body. The method can realize rapid and accurate detection of Mn < 2 + > in a water body, and is high in use value and good in application prospect.

The invention discloses a microporous diaphragm for a low-electrical-impedance lithium battery and a preparation method of the microporous diaphragm. The diaphragm comprises: a base film layer, wherein the base film layer is of a microporous structure formed by biaxially stretching polypropylene and / or polyethylene; the surface of the base film layer is coated with the functional coating, and the functional coating contains mixed slurry of inorganic nanoparticles and a binder; the surface modification layer is formed by introducing a hydrophilic electrolyte group on the surface of the functional coating through plasma treatment or chemical grafting. The base membrane layer forms a uniform micropore structure through a two-way stretching process, the functional coating is formed by compounding nano silicon dioxide or aluminum oxide and polyvinylidene fluoride according to a specific proportion, a porous layer with gradient pore diameter is formed, the pore size of the porous layer is smaller than that of the base membrane layer, and efficient permeation of electrolyte is ensured. Electrolyte-philic groups such as sulfonic groups are introduced into the surface modification layer, so that the wettability of the diaphragm to an electrolyte is remarkably improved. During preparation, the base membrane is formed through melt blending, two-way stretching and pore-forming agent extraction, and then the functional layer is constructed through slurry coating and a low-temperature plasma treatment or sulfonation process. The diaphragm combines gradient aperture design, inorganic filler enhancement and surface chemical modification, and realizes low impedance, high thermal stability and excellent mechanical strength.

The invention discloses a silane coupling agent grafted MXene composite material and a preparation method thereof, relates to the technical field of composite materials, and aims to provide a surface modification method to enable the MXene composite material to be in good contact with a PDMS (polydimethylsiloxane) material. The surface modification method comprises the following steps: S1, performing wet chemical etching on an MAX phase material in combination with mechanical stripping to obtain a few-layer MXene dispersion liquid; s2, strong base is added into the few-layer MXene dispersion liquid in the step S1, the PH value of the few-layer MXene dispersion liquid is adjusted, a reaction is conducted in the argon environment, and hydroxyl modified MXene dispersion liquid, namely h-MXene dispersion liquid is obtained; and S3, adding a silane coupling agent and a catalyst into the h-MXene dispersion liquid in the step S2, and reacting in an argon environment to obtain the silane coupling agent grafted MXene composite material.

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).

The invention relates to a surface-modified lithium-rich manganese oxide material as well as a preparation method and application thereof, and belongs to the technical field of lithium ion battery positive electrode materials. The material comprises a layered lithium-rich manganese oxide substrate and layered spinel heterostructures uniformly distributed on the surface of the lithium-rich manganese oxide substrate, the spinel heterojunction is one or two of LiMn2O4 and Li4Mn5O12, and the thickness of the spinel heterojunction is 5 nm to 10 nm; the surface of the modified lithium-rich manganese oxide material also contains an oxygen vacancy structure. Benefited from the existence of the heterostructure and the oxygen vacancy structure, the material disclosed by the invention has relatively high capacity and rate capability; in the electrochemical cycle process, release of oxygen, interface side reaction and irreversible phase change of a layered phase, a spinel phase and a rock salt phase are all inhibited. The lithium ion battery assembled by using the material as a positive electrode has high first-circle coulombic efficiency, and the problem of capacity fading in circulation is also relieved.