The invention relates to an all-
solid-state
battery cell with a three-dimensional staggered
lithium ion conduction network as well as a preparation method and application of the all-
solid-state
battery cell. The method comprises the following steps: uniformly and electrostatically spraying positive
electrode powder A, B and C with different particle sizes and compositions into a
grinding tool in sequence; spraying a layer of
sulfide electrolyte on the composite positive
electrode layer; then uniformly and electrostatically spraying composite negative
electrode powder D and E which are uniformly mixed and have different particle sizes and compositions on the surface of an
electrolyte layer in sequence; and finally, integrally pressing the
powder by adopting warm isostatic pressing to prepare an all-
solid-state
battery cell, and assembling the all-solid-state battery
cell into a solid-state battery. The invention provides a brand new battery structure design, a three-dimensional staggered
lithium ion conduction network is constructed by introducing a low-
viscosity thermoplastic and an electrostatic dry spraying technology, the
lithium ion migration efficiency is remarkably improved, and meanwhile, the interface stability between an electrode and a solid
electrolyte is enhanced; therefore, the
interface impedance of the
sulfide solid-state battery is reduced so as to realize better capacity
retention ratio, longer cycle life and better safety performance.