The invention discloses a
memristor based on a
covalent organic framework and a preparation method and application thereof.The
memristor comprises a substrate, a
semiconductor electrode, a
covalent organic framework film and a
metal electrode which are sequentially arranged in a stacked mode, and the
covalent organic framework film is composed of 1, 3, 4, 5, 6, 7, 8, 8, 9, 10, 11, 12, 13, 14, 16, 17, 17, 17, 17, 17, 17, 17, 17, the catalyst is prepared by condensing 1, 3, 5-tri (4-aminophenyl)
benzene and terephthalaldehyde or terephthalaldehyde with an
alkyl or alkoxy
side chain. The covalent organic framework film has a highly ordered structure and an adjustable porous structure, the preparation process is simple, the film thickness is uniform, the flatness and the
crystallinity are high, and the
dielectric property is adjusted, so that the switching
voltage and the
cycling stability of the
memristor are adjusted, and the memristor has stable and repeatable switching performance; the COFs-based memristor has high on / off ratio, low device variability and high flexibility, can be used for preparing the COFs-based memristor, can provide
technical support for neuromorphic devices with high efficiency, adjustability, structure adjustability and rich functions, and can be applied to the field of intelligent sensing and autonomous
system control such as an auxiliary driving
system.