4172results about "Fixed capacitor dielectric" patented technology

The invention relates to the technical field of capacitor films, in particular to a high-temperature-resistant polypropylene capacitor film and a preparation method thereof.The high-temperature-resistant polypropylene capacitor film is prepared from, by weight, 94-98 parts of polypropylene resin, 1-3 parts of filler-doped modified balance adjusting agent, 0.5-2 parts of boron nitride-glass fiber combined agent, 0.05-0.4 part of nucleating agent, 0.2-0.4 part of antioxidant and 0.1-0.4 part of silane coupling agent; the high-temperature-resistant polypropylene capacitor film is obtained through the processes of melting extrusion molding, cooling shaping, preheating, two-way stretching, heat shaping, rolling and the like of the raw material composition. The polypropylene resin, the nucleating agent, the antioxidant and the silane coupling agent are blended, the filler-doped modified balance adjusting agent and the boron nitride-glass fiber coupling agent are added, and the raw materials are blended and coordinated, so that high feasibility of a two-way stretching process is guaranteed, breakdown resistance, mechanical strength and dielectric loss performance of the product are optimized, and the product has good mechanical properties. And meanwhile, the high-temperature-resistant and corrosion-resistant stability effects are remarkable.

To provide a multilayer electronic component having excellent reliability by preventing penetration of external moisture or plating solution.SOLUTION: According to one embodiment of the present invention, there is provided a multilayer electronic component which includes: a body including a dielectric layer and an internal electrode alternately disposed with the dielectric layer; an external electrode including a base electrode layer connected to the internal electrode; and an interface layer disposed between an end of the dielectric layer and the base electrode layer. The interface layer includes a first glass containing Ba, Zn, and Si, and the base electrode layer includes a second glass containing Ba and Si. When an average molar ratio (Ba / Si) of Ba to Si contained in the first glass is M1 and an average molar ratio (Ba / Si) of Ba to Si contained in the second glass is M2, M1 and M2 satisfy M1 / M2≥1.5.SELECTED DRAWING: Figure 5

The invention belongs to the field of dielectric materials and dielectric energy storage, and particularly relates to a fluorene polyester and polyaryletherurea blended dielectric energy storage polymer film and a preparation method thereof. The preparation method specifically comprises the following steps: adding fluorene polyester and polyaryletherurea into a solvent, fully dissolving to obtain a mixed solution, uniformly coating a substrate with the mixed solution, and then drying; and carrying out vacuum annealing on the dried film, and then carrying out curing treatment to strip the film from the substrate to obtain the fluorene polyester and polyaryletherurea blended dielectric energy storage polymer film, thereby improving the charge-discharge efficiency and high discharge energy density of the polymer under high temperature and high field, and solving the problems of high electric leakage loss and low cost of the existing polymer film. And the charging and discharging efficiency is low.

The invention belongs to the technical field of thin film capacitors, and particularly relates to a chemical grafting modified polypropylene capacitor film material and a preparation method and application thereof. According to the preparation method of the chemical grafting modified polypropylene capacitor film material, provided by the invention, diethylenetriamine ethyl acrylate with a plurality of specific groups such as amino groups and carboxyl groups and unsaturated double bonds is synthesized through esterification reaction, and the diethylenetriamine ethyl acrylate is introduced into a polypropylene material through chemical grafting to obtain chemical grafting modified polypropylene; the prepared polypropylene capacitor film material has the excellent properties of good compatibility, difficulty in film breakage, capability of adsorbing and removing residual moisture, difficulty in oxidation corrosion, excellent breakdown resistance and the like, and the preparation method is a preparation method of the high-performance polypropylene capacitor film material; therefore, the technical problem that a polypropylene capacitor film material prepared in the prior art is low in performance is solved.

The invention relates to the technical field of dielectric materials, and discloses polyimide, a polyimide film and a preparation method and application thereof, the polyimide is obtained by a polymerization reaction of a dianhydride monomer and a diamine monomer, the diamine monomer comprises a methylene bridging group and a phenyl group with a substituent group, and the methylene bridging group is a phenyl group with a substituent group. The substituent group at least comprises one methyl group. The molecular twisted conformation lock structure provided by the invention not only can improve the tolerance of polyimide, but also can doubly inhibit intrachain and inter-chain charge migration of the dielectric film, so that the dielectric film still has extremely high energy storage density and energy storage efficiency at a service temperature close to a glass-transition temperature.

A capacitor provides a plurality of selectable capacitance values, by selective connection of six capacitor sections of a capacitive element each having a capacitance value. The capacitor sections are provided in a plurality of wound cylindrical capacitive elements. Two vertically stacked wound cylindrical capacitance elements may each provide three capacitor sections. There may be six separately wound cylindrical capacitive elements each providing a capacitor section. The capacitor sections have a common element terminal.

The invention discloses a polypropylene film for a bidirectional asynchronous stretching high-temperature-resistant three-layer structure capacitor and a preparation method of the polypropylene film. The film comprises a first surface layer, a second surface layer and a middle layer clamped between the two surface layers, the middle layer is made of polypropylene, the first surface layer is made of a cycloolefin copolymer (COC), and the second surface layer is made of polypropylene; the mass of the middle layer accounts for 85wt%-88wt% of the total mass, the mass of the first surface layer accounts for 5wt%-7wt% of the total mass, and the mass of the second surface layer accounts for 7wt%-8wt% of the total mass. The temperature resistance can be effectively improved by utilizing the characteristics of the cycloolefin copolymer, the film-forming property is improved by controlling the proportion content of the cycloolefin copolymer, the temperature resistance of the film can be improved to 125 DEG C or above, and the temperature resistance of the film is greatly improved. When the COC content is controlled to be 5%-7%, the film-forming property and the temperature resistance can be both considered, and the temperature reaches 125 DEG C.

A multilayer electronic component according to an example embodiment of the present disclosure may include: a body including a plurality of capacitance formation portions including first dielectric layers and internal electrodes alternately arranged in a first direction. An intermediate layer disposed is between the adjacent capacitance formation portions and includes a second dielectric layer. An external electrode is disposed on the body and connected to the internal electrode. The first and second dielectric layers may include a plurality of grains and pores. An average grain size of the first dielectric layer may be smaller than an average grain size of the second dielectric layer. A porosity of the first dielectric layer may be lower than a porosity of the second dielectric layer.

The invention discloses a polypropylene film for a film capacitor, the polypropylene film is composed of polypropylene and a cyclic olefin polymer, a plurality of gaps are distributed in the film, the gaps are approximately annular on the cross section of the film, and the inner diameter of the approximately annular gaps is 20-120nm. The invention also provides a preparation method of the polypropylene film, which comprises the following specific steps: putting the polypropylene and the cyclic olefin polymer into an extruder, heating and melting; the melt is extruded through a T-shaped die head and attached to a piece casting roller through an air knife for piece casting, and the temperature of the piece casting roller is 85-95 DEG C; the method comprises the following steps: preheating a cast sheet, longitudinally stretching at the stretching rate of 4-7 times and at the temperature of 135-150 DEG C, preheating the longitudinally stretched sheet at the temperature of 145-160 DEG C, transversely stretching at the stretching rate of 7-10 times and at the stretching temperature of 165-180 DEG C, and then entering a shaping area at the temperature of 168 DEG C; and carrying out corona treatment, rolling, curing and slitting on the heat-set film to obtain the product. The polypropylene film has good high temperature resistance and high pressure resistance, and is suitable for the field of capacitors.

An internal electrode layer includes therein a plurality of inner ceramic particles within an observation range of a cross-section intersecting the internal electrode layer. The position of the inner ceramic particles in the internal electrode layer relative to the center position of the internal electrode layer in the thickness direction is correlated with the position from the center position to the edge position, and the corresponding positions are indicated by the numbers 0-100. Such an index is referred to as Dsp. Inside the internal electrode layer, within a region of Dsp of 40 or less, preferably 30 or less, the inner ceramic particles are present in an area of at least 50% of the total area of the inner ceramic particles present within the observation range.

The invention discloses a high-entropy relaxation type lead-free perovskite ceramic and a preparation method thereof. The high-entropy relaxation type lead-free perovskite ceramic is a solid solution of Na < 0.2 > Bi < 0.2 > Ba < 0.2 > Sr < 0.2 > Ca < 0.2 >) TiO3 and (K < 0.5 > Na < 0.5 >) NbO3; the content of the (K0. 5Na0. 5) NbO3 accounts for 5 to 15 mol percent of the high-entropy relaxation type lead-free perovskite ceramic. By introducing (K0. 5Na0. 5) NbO3, energy band regulation and relaxation behavior adjustment are effectively realized, the breakdown electric field intensity is remarkably improved, the energy storage performance is improved, good stability is kept under the conditions of temperature, frequency and a circulating electric field, and the actual requirements of a pulse power capacitor on a high-performance and long-life energy storage dielectric material are met.

The invention relates to the technical field of dielectric materials, and discloses a composite dielectric material and a preparation method and application thereof.The composite dielectric material comprises filler and a base material, the filler is modified barium titanate, and the base material is cyanoethyl cellulose; the modified barium titanate comprises a barium titanate core and a shell, the shell comprises a polymer containing an epoxy group, the core and the shell are connected through a covalent bond, and an infrared spectrum test shows that in an infrared spectrogram of the modified barium titanate, characteristic peaks of the epoxy group and carbonyl respectively exist at 910 + / -10 cm <-1 > and 1720 + / -10 cm <-1 >. Epoxy groups in the modified barium titanate filler can react with hydroxyl groups in a cyanoethyl cellulose matrix material to form covalent linkage, compatibility of the filler and a matrix is improved, meanwhile, a potential well is formed, migration of carriers can be limited, and the composite material has good dielectric performance and energy storage performance.

The multilayer electronic component includes a laminate in which internal electrodes and dielectric layers are alternately laminated, a base electrode, and an external electrode. The internal electrodes include a first internal electrode and a second internal electrode. The base electrode includes a first base electrode and a second base electrode. The external electrode includes a first external electrode and a second external electrode. Each of the first base electrode and the second base electrode contains a plurality of sintered bodies made of dielectric particles. At least a part of the plurality of sintered bodies is located at the interface between each base electrode and the laminate.

Liquefied natural gas brings energy overriding and environmental disruption. However, the liquefied natural gas is a liquid dielectric medium, can be easily liquefied by pressurizing at room temperature, can be expanded by more than 250 times in volume during gasification, and is relatively high in dielectric constant and relatively low in voltage resistance. As a capacitor, such a liquid dielectric is considered; the energy of the liquid dielectric capacitor is consumed inside the capacitor for an engine, welding or buoyancy gas generation, or is consumed outside the capacitor for use as an on-board capacitor for a vehicle. [Solution] A liquid dielectric capacitor is considered as a dielectric breakdown induced igniter that can replace a conventional spark plug. In order to utilize the principle of such an igniter as an energy source for an engine, a welding device or a buoyancy bag for lifting a subsea resource, an electrical charge is applied to the liquid dielectric thin layer, and then the thickness of the liquid dielectric thin layer is made close to zero to cause dielectric breakdown, or the thickness of the liquid dielectric thin layer is increased to cause breakdown of the liquid dielectric thin layer. A high voltage source is established for a vehicle-mounted capacitor of the vehicle. Therefore, a world without environmental damage is realized.

The embodiment of the invention provides a ceramic diaphragm automatic positioning system based on high-precision visual feedback and closed-loop control, and the system comprises a parameter reference setting module which is used for setting a theoretical reference point and a visual detection parameter; the real-time visual detection module is used for collecting an image of the to-be-stacked film and outputting an image coordinate of the mark point; the core operation module is used for converting the image coordinates of the mark points into actual coordinates based on the visual detection parameters, reading a theoretical reference point of the current to-be-stacked diaphragm and calculating a position error vector between the actual coordinates and the theoretical reference point, and the position error vector comprises a translation compensation amount and a rotation compensation amount; and the motion control and closed loop feedback module is used for receiving the position error vector and generating a control instruction to drive the workbench to move. According to the system, through parameterized reference setting, real-time visual detection, intelligent error calculation and real-time motion compensation, the technical limitation is effectively overcome, and the lamination alignment precision and efficiency are remarkably improved.

The invention relates to the technical field of dielectric materials, in particular to a diamine monomer crosslinking modified fluorine-containing ferroelectric polymer, a preparation method and a device. The diamine monomer cross-linked modified fluorine-containing ferroelectric polymer comprises the following components: a semi-crystalline thermoplastic fluorine-containing ferroelectric polymer and a diamine cross-linking agent, the semi-crystalline thermoplastic fluorine-containing ferroelectric polymer is polyvinylidene fluoride with ferroelectricity and a copolymer derivative thereof; the diamine cross-linking agent is short-chain diamine containing a rigid structure; the mass fraction of the diamine cross-linking agent is 0.25%-10% compared with the total mass fraction. The thin film prepared by the invention meets the application requirements of improvement of dielectric constant, reduction of dielectric loss, reduction of leakage current, improvement of breakdown field strength and the like in a high electric field.

The present invention belongs to the technical field of microwave dielectric ceramics, and discloses a reducing-resistant microwave dielectric ceramic temperature-frequency characteristic regulator. Among them, the application of a microwave dielectric ceramic material as a microwave dielectric ceramic temperature-frequency characteristic regulator, and the chemical formula of the microwave dielectric ceramic material satisfies (AO)3(BO)(XO2)2, where A = Ba x Sr y , B = Mn h Mg k , X = Si m Ti n ; x + y = 1, h + k = 1, m + n = 1, 0 ≤ x ≤ 1, 0.6 ≤ h ≤ 1, 0.8 ≤ m ≤ 1; and when h = 1 and m = 1, x ≠ 0; this microwave dielectric ceramic material can be adjusted by addition to regulate the overall temperature coefficient of resonance frequency of the ceramic system. By improving the composition of the material, the obtained microwave dielectric ceramic material has the characteristics of adjustable dielectric constant, low dielectric loss, and high positive temperature coefficient of resonance frequency, and can especially be used as a microwave dielectric ceramic temperature-frequency characteristic regulator with a strong regulation effect.

The invention relates to the technical field of capacitor films. The invention discloses a preparation process of a high-performance polypropylene capacitor film. The preparation process comprises the following steps: A1, preparing a polypropylene capacitor film; a2, carrying out surface cleaning and activation pretreatment on the polypropylene capacitance film; a3, evaporating a gradient modified layer on the surface of the pretreated polypropylene capacitance film; a4, carrying out laser plasma synergistic treatment and crystallinity regulation and control on the modified polypropylene capacitor film; and A5, coating the outer layer of the modified polypropylene capacitance film with a functional layer, and carrying out annealing post-treatment to prepare the high-performance polypropylene capacitance film. The mechanical strength and the electrical stability are improved through nano filler dispersion, two-way stretching and crystallinity regulation and control; through the collaborative design of surface cleaning and activation and a gradient functional layer, excellent interface bonding force and environmental adaptability are given; and by means of technologies such as multi-source evaporation and laser plasma co-processing, precise regulation and control and diversified expansion of the performance are achieved, the method is suitable for various scenes, and the process repeatability is good.

A ceramic capacitor with double L-shaped pins comprises two supports arranged oppositely, one or more ceramic chips arranged between the two supports and two first solder layers respectively arranged between the end portions of the one or more ceramic chips and the opposite supports, and each support comprises two frames arranged symmetrically and a second solder layer arranged between the two frames. According to the invention, the structure of the ceramic capacitor is limited, and the two symmetrically arranged frames are mutually welded through the welding flux to serve as the support, so that the welding area of the prepared support and the PCB is doubled, the welding strength of the prepared ceramic capacitor is improved, the bonding strength of the ceramic capacitor and the PCB is better, and the service life of the ceramic capacitor is prolonged. Compared with a single-frame ceramic capacitor, the ceramic capacitor can resist higher-strength vibration, improves the reliability of a product, and can be applied to high-reliability occasions such as space flight and aviation.

The invention provides BCZT-BNT-based lead-free composite energy storage ceramic with high breakdown strength and a preparation method of the BCZT-BNT-based lead-free composite energy storage ceramic, and belongs to the field of dielectric energy storage ceramic materials. The general formula of the chemical composition is (1-x) [0.25 (Bi < 0.5 > Na < 0.5 >) TiO < 3 >-0.75 Ba < 0.85 > Ca < 0.15 > Zr < 0.1 > Ti < 0.9 > O < 3 >]-xBaZrO < 3 >, and x is the mole number and ranges from 0.05 to 0.20. According to the preparation method disclosed by the invention, chemical component disorder is induced by doping modification on an atomic scale, and a high-dynamic-polarity nano micro-region (PNRs) is formed, so that the nano micro-region has an obvious dielectric relaxation behavior and a slender ferroelectric hysteresis loop (P-E ring), and the energy storage ceramic material with high energy storage density and energy storage efficiency, ultrahigh breakdown strength and excellent frequency stability is obtained.

The invention provides a Joule heat ultrafast sintering preparation method of barium titanate ceramic with ultrahigh dielectric constant and low loss, which comprises the following steps: ball-milling and mixing barium titanate powder and copper oxide powder, drying, pressing into a cake-shaped sample, carrying out cold isostatic pressing to obtain a sample piece, and carrying out vacuum treatment on Joule heat ultrafast sintering equipment to obtain the barium titanate ceramic with ultrahigh dielectric constant and low loss. Putting the sample preparation sheet between two layers of graphite felts, and starting Joule heat ultrafast sintering equipment to enable the graphite felts to generate Joule heat, so as to realize short-time sintering of the barium titanate ceramic. According to the invention, a Joule heat ultrafast sintering technology is adopted, and Joule heat is generated by directly applying voltage and current to the graphite felt, so that the sintering time is greatly shortened, and environmental pollution is avoided; meanwhile, the dielectric constant of the barium titanate ceramic is greatly improved by adding copper oxide, and the energy consumption is remarkably reduced.

Provided is a multi-layered ceramic capacitor in which a penetration-type electrode unit, which is manufactured in a cone shape, passes through a plurality of internal electrodes in a collective stack of the internal electrodes and the dielectric layers, so that the capacitor is miniaturized and the electrical reliability thereof is improved.

In a multilayer ceramic capacitor, a segregation amount of silicon and magnesium on an outer layer side of an outermost internal electrode layer is larger than a segregation amount of silicon and magnesium on an inner layer side of the outermost internal electrode layer, and when a region defined by an existence region of the outermost internal electrode layer and a segregation region of silicon and magnesium in contact with the outermost internal electrode layer is defined as a first region, a line edge roughness of an outer layer side of the first region is larger than a line edge roughness of an inner layer side of the first region.

The present invention relates to a composition comprising more than 80.0 to less than 100.0 wt.% based on the total weight of the polypropylene composition of a high isotactic homopolymer (A) of propylene, and more than 0.0 to less than 20.0 wt.-% based on the total weight of the polypropylene composition of a polycarbonate (B). The composition allows to achieve electrical conductivities which are desirable for high temperature capacitor film applications. Thus, the present invention is, furthermore, directed to a film comprising the polypropylene composition and a biaxially oriented film comprising the polypropylene composition. Additionally, a capacitor comprising the biaxially oriented film is provided.

A multilayer ceramic electronic component includes a first extension portion including a bent portion in a cross section. The multilayer body is divided into four regions by a straight line passing through a middle portion of the multilayer body in a lamination direction and a straight line passing through a middle portion of the multilayer body in a length direction, and a region adjacent to a first main surface and a first end surface among the divided four regions is defined as a first reference region, and a regression line derived based on values of x and y with respect to the bent portion in a reference region is defined as a virtual connection line, the virtual connection line intersects an effective layer portion.

A multilayer ceramic electronic device includes an element body including a dielectric layer and an electrode layer being laminated. The dielectric layer contains a main component represented by a formula ABO3. The dielectric layer contains 0.05 mol or more and 0.25 mol or less Mn oxide in terms of MnO; 1.00 mol or more and 2.50 mol or less Mg oxide in terms of MgO; 0.50 mol or more and 1.50 mol or less R oxide in terms of R2O3, where R includes at least one selected from the group consisting of Y, Dy, Ho, Yb, Lu, Gd, and Tb; and 0.05 mol or more and 0.45 mol or less Zr oxide in terms of ZrO2, with respect to 100 mol of the main component. The dielectric layer further contains V. The dielectric layer has a Zr / V ratio of 2.00 or more and 4.00 or less in atomic ratio.

The invention provides a high-dielectric low-loss X7P type dielectric ceramic material and a preparation method and application thereof, and relates to the technical field of functional ceramic materials, the dielectric ceramic material is composed of a perovskite type compound as a main component and an auxiliary component; wherein the perovskite type compound contains a Ba element and a Ti element, and the auxiliary components comprise a first auxiliary component containing an Mg element, a second auxiliary component containing SiO2, a third auxiliary component containing an Mn element and a fourth auxiliary component containing a rare earth element R. According to the invention, barium titanate is doped and modified, so that the excellent performance of combining different compounds is realized, the dielectric constant and temperature stability of the dielectric ceramic material are improved, and the dielectric loss is reduced.

The invention provides a high-voltage low-loss dielectric material and a preparation method thereof, and relates to the technical field of high-voltage ceramic capacitors, and the high-voltage low-loss dielectric material comprises the following raw materials in parts by mass: 35-38 parts of barium titanate, 20-29.5 parts of strontium titanate, 15-17.5 parts of titanium dioxide, 9-12 parts of bismuth oxide, 3-4 parts of zirconium oxide, 0.8-1.0 part of X, 1.2-1.4 parts of antimony oxide, 1-1.2 parts of calcium carbonate and the like. The preparation method of the dielectric material comprises the following steps: 1, preparing the dielectric material; melting calcium carbonate, magnesium oxide, zinc oxide and the like, performing water quenching, and performing ball-milling granulation to obtain zinc borosilicate glass powder; uniformly mixing the zinc borosilicate glass powder with barium titanate, strontium titanate, titanium dioxide and the like, and granulating to obtain oxide powder; and tabletting and sintering the oxide powder to obtain the high-pressure low-loss dielectric material. The high-voltage low-loss dielectric material is high in dielectric constant, small in dielectric loss, high in compression strength and good in high-temperature stability, and the preparation method is simple.

A dielectric composition, including: dielectric grains containing a main component represented by a composition formula [(CaxSr(1-x))O]m[(TiyHfzZr(1-y-z))O2] (m is more than 1.020); a grain boundary phase located between the dielectric grains; and segregation grains each containing at least Ca, Si, and O. A first segregation grain is defined as a segregation further containing Mn among the segregation grains each containing at least Ca, Si, and O, and a second segregation grain is defined as a segregation containing substantially no Mn among the segregation grains each containing at least Ca, Si, and O. N1 / (N1+N2) is more than 0.23 and 1.00 or less, in which N1 is a number density of first segregation grains in a cross-section of the dielectric composition, and N2 is a number density of second segregation grains in the cross-section of the dielectric composition.

A capacitor includes a first electrode, a second electrode, and a dielectric. The dielectric is disposed between the first electrode and the second electrode. The dielectric includes a compound having an inverted perovskite structure. The inverted perovskite structure of this compound has a portion in which a cation is present at each vertex of corner-sharing octahedra and an anion is present at a center of each of the corner-sharing octahedra.