The invention discloses a
dielectric film based on
dielectric graphene coating modification, and belongs to the technical field of films. The core is a
composite structure of a'
graphene core-double-layer
dielectric shell layer 'core-shell filler and a
polymer matrix, the
oxygen content of the
graphene core is 5-8 at%, the sheet
diameter is 50-200 nm, and the high polarization characteristic is reserved; the inner layer of the double-layer shell layer is a high-dielectric
oxide, the outer layer is a high-insulation
oxide, and the
total thickness is 3-10nm; a core-shell filler is prepared through a
sol-gel + ALD fine trimming process, and the core-shell filler is compounded with matrixes such as PVDF / PI and the like to form a film with the filling amount of 2-8 wt%; according to the design,
electron tunneling is blocked,
electric field distortion is corrected, and performance
synergy is achieved, wherein the dielectric constant is larger than or equal to 21.5, the
breakdown strength is larger than or equal to 402 kV / mm, the
dielectric loss is smaller than or equal to 0.017, the tensile strength is larger than or equal to 56.9 MPa, and the
energy density is 12-15 J / cm < 3 >. The contradiction between dielectric enhancement and loss and
breakdown strength of a traditional
composite material is solved, the method is suitable for high-density
energy storage devices, flexible electronic devices and the like, and the technology is compatible with large-scale production.