A method of improving the
breakdown strength of
polymer multi-layer (PML) capacitors is provided and of providing a window in
food packaging is provided. The method comprises patterning the
aluminum coating, either by selective removal of deposited aluminum or by preventing deposition of the aluminum on selected areas of the underlying
polymer film. Apparatus is also provided for patterning
metal deposition on
polymer films comprising masking for defining regions in which
metal is deposited. The apparatus comprises: (a) a
rotating drum; (b) a
monomer evaporator for depositing a
monomer film on the
rotating drum; (c) a
radiation curing element for curing the
monomer film to form a cross-linked polymer film; and (d) a resistive
evaporator for depositing a
metal film on the cross-linked polymer film. The foregoing elements are enclosed in a
vacuum chamber. The masking comprising one of the following: (e1) a web
mask provided with openings for depositing the metal film therethrough, the web
mask including a portion adapted for positioning between the resistive
evaporator for depositing the metal film on the cross-linked polymer film and the
rotating drum; or (e2) a rotating element for transferring liquid from a source to the rotating drum, the rotating element adapted to transfer the liquid to the rotating drum after the monomer evaporator for depositing the polymer film and before the resistive evaporator for depositing the metal film.