The invention discloses lead-free high-
voltage capacitor dielectric ceramic sintered at medium temperature and a preparation method thereof; the lead-free high-
voltage capacitor dielectric ceramic is prepared from, by weight, 100 parts of Sr0.78Ca0.20Ba0.02TiO3, 8-20 parts of Bi2O3.2TiO2, 0.05-0.35 part of MnCO3, 0.05-0.30 part of Co2O3, 0.01-0.08 part of MgTiO3, 0-0.20 part of Al2O3, 0-0.10 PART OF Nb2O5, 0-0.08 part of HfO2, and 1-2 parts of a
sintering aid, via the steps of ball milling,
drying,
grinding and screening. The
dielectric constant and insulating resistance of the
capacitor dielectric
ceramic are adjusted mainly by changing the content of Bi2O3.2TiO2, comprehensive performance of the dielectric ceramic is improved by selecting different
doping modifying elements, and the finally prepared dielectric ceramic has high dielectric constant, low loss, high insulating resistance and high
breakdown strength. The dielectric ceramic is sintered at medium temperature and free of lead, is suitable for the preparation of high-
voltage multilayer ceramic capacitors (MLCC), and has great practical value and market value.