599 results about "Hindered phenol" patented technology

The invention discloses a core-shell structure flame retardant with a thermo-oxidative aging resistance function and application of the core-shell structure flame retardant in preparation of a flame-retardant material, and belongs to the technical field of flame retardance. The core-shell structure flame retardant with the thermo-oxidative aging resistant function is composed of the core and the shell structure, the core is the flame retardant, the shell structure is a polymer containing hindered phenol and low-valence phosphorus, on one hand, hydrophobicity of the flame retardant can be improved, on the other hand, compatibility and dispersity of the flame retardant in a polymeric material can be improved, and the flame retardant performance is improved. Further, the flame retardant property and the mechanical property of the polymer material are improved. Besides, hindered phenol and low-valence phosphorus in the shell polymer not only can capture RO.and ROO.free radicals and inhibit the thermo-oxidative aging process of the polymer, but also can play a role in capturing the free radicals in the combustion process, so that the flame retardant property of the polymer material is further improved. The flame retardant disclosed by the invention has excellent flame retardance and thermal aging resistance, and can be applied to the fields of buildings, traffic, chemical engineering, machinery, communication, energy sources and the like.

The invention discloses a photo-thermal aging resistant polyester composite material and a preparation method thereof, a modified monomer, a modified filler, benzophenone, terephthalic acid and neopentyl glycol are subjected to esterification condensation polymerization to prepare the composite material, and the modified monomer is added, so that the prepared polyester molecule is of a branched structure; the side chain of a polyester molecule and the surface of the modified filler both contain unsaturated double bonds which can react after being irradiated by ultraviolet light, so that the number of crosslinking points of the composite material is increased, the crosslinking density is further improved, and the anti-aging effect of the material is further improved; the modified filler can improve the high-temperature-resistant effect of the composite material, the modified filler is matched with the hindered phenol structure of the side chain to further improve the heat aging-resistant effect of the composite material, hydroxyl and ketone groups on the modified filler form intramolecular hydrogen bonds, light energy can be converted into heat energy to be released, and then the light aging-resistant effect of the composite material is improved.

The invention relates to the technical field of polypropylene plastics, in particular to a high-strength antibacterial polypropylene plastic and a preparation method thereof. The antibacterial polypropylene material comprises the following components in parts by weight: 60-80 parts of polypropylene resin, 5-15 parts of nano titanium dioxide and nano zinc oxide composite particles modified by a special organosilicon polymer, 3-8 parts of an antibacterial agent compounded by quaternary ammonium salt and bioactive peptide, 5-10 parts of a core-shell structure MBS toughening agent and 0.5-2 parts of a hindered phenol-thioether composite antioxidant. 1-3 parts of a calcium stearate processing aid; and 3-8 parts of dopamine modified chopped carbon fibers. The composite material is high in strength, tensile strength, bending strength and impact strength are remarkably improved, and larger external force can be borne; the antibacterial performance is excellent, and the antibacterial rate reaches 95%-99%; the preparation process is environment-friendly and efficient, and the product is good in stability and recoverable; product safety can be guaranteed, the service life is prolonged, and economic and social benefits are good.

The invention discloses a neodymium iron boron composite magnet and a production process thereof, and belongs to the technical field of magnetic materials. Carrying out sand blasting and phosphoric acid treatment on the neodymium-iron-boron magnet to obtain a pretreated neodymium-iron-boron magnet; and mixing 50-60 parts of epoxy resin, 30-40 parts of polyurethane and 10-20 parts of polysiloxane, then adding 10-20 parts of a solvent, 8-16 parts of filler, 3-5 parts of an auxiliary agent and 1-3 parts of dibenzoyl peroxide, stirring to obtain a protective coating, then spraying the protective coating on the surface of the pretreated neodymium-iron-boron magnet, and curing to obtain the neodymium-iron-boron composite magnet. The auxiliary agent contains a hindered phenol structure, a benzotriazole structure and fluorine atoms, and a hybrid cross-linked network structure is formed among the auxiliary agent, the epoxy resin and the filler, so that the auxiliary agent and the filler can be highly dispersed and stably exist in the protective coating and fully play roles, and the protective coating has the advantages that the protective coating is more stable in performance due to the combined action of the other raw materials in the protective coating; the neodymium-iron-boron composite magnet has excellent and stable water resistance, aging resistance, corrosion resistance and the like.

The invention belongs to the technical field of polyurethane materials, and provides a high-damping anti-fatigue and anti-aging polyurethane elastomer and a preparation method thereof. The high-temperature-resistant polyurethane elastomer is prepared from the following raw materials in parts by weight: 20 to 30 parts of poly (diethylene glycol adipate) glycol (PDA), 30 to 50 parts of polytetrahydrofuran ether glycol (PTMEG), 5 to 15 parts of chain extender, 0.1 to 0.3 part of A33, 0.1 to 0.2 part of organic tin catalyst, 2 to 5 parts of hindered phenol antioxidant, 1 to 3 parts of hindered amine light stabilizer, 3 to 8 parts of nano particles and 30 to 50 parts of isocyanate prepolymer. The isocyanate prepolymer is prepared from 1, 4-phenyl diisocyanate (PPDI) and branched chain-containing polytetrahydrofuran glycol PTXG according to a mass ratio of 1: (1.8 to 2.2). The polyurethane elastomer is excellent in damping performance and fatigue aging resistance, and meets the use requirements under complex working conditions.

The invention discloses a high-strength nano composite stiffening filling master batch and a preparation method thereof, and relates to the technical field of high polymer materials, the raw materials comprise a nano filler, a matrix material and a functional additive; the nano filler comprises nano diamond, nano silicon carbide and bio-based nano cellulose, the base material comprises polyimide, polyether-ether-ketone and bio-based polylactic acid, and the functional additive comprises a hindered phenol antioxidant, a nano aluminum hydroxide flame retardant, a nano silicon dioxide reinforcing agent, an ultraviolet light absorber, a carbon nano tube and nano silver particles. Nano-diamond, nano-silicon carbide and bio-based nano-cellulose are adopted as nano-fillers, polyimide, polyether-ether-ketone and bio-based polylactic acid are combined as base materials, and a plurality of functional additives are added, so that the preparation of the high-strength nano-composite stiffening filling master batch is realized; and the problems of poor dispersibility, mechanical property damage, insufficient hardness and poor interface bonding of the traditional filler master batch can be solved.

The invention discloses a high-temperature-resistant and corrosion-resistant coating and a preparation method thereof, and belongs to the technical field of coatings. The preparation method comprises the following steps: uniformly stirring 40-50 parts by weight of epoxy resin, 25-35 parts by weight of phenolic resin, 20-30 parts by weight of modified filler, 4-10 parts by weight of pigment and 50-65 parts by weight of solvent, then adding 5-10 parts by weight of curing agent and 0.5-1 part by weight of accelerant, and stirring to obtain the coating. The modified filler contains inorganic fillers such as titanium dioxide and glass flakes, a benzotriazole structure and a hindered phenol structure, and the modified filler has good compatibility with other raw materials and has chemical action with epoxy resin, so that the modified filler can stably exist in the coating, is not easy to migrate and fall off, and plays a role for a long time; under the combined action of other raw materials, the coating has excellent and stable high temperature resistance, corrosion resistance, aging resistance, flame retardance and the like, and the service life is greatly prolonged.

The invention discloses a flame-retardant semi-solid gel electrolyte and a preparation method thereof, and the flame-retardant semi-solid gel electrolyte comprises the following raw materials in parts by weight: 100-120 parts of PVDF resin, 25-30 parts of PPC resin, 5-10 parts of modified hollow ceramic fiber, 3-5 parts of modified nano aluminum hydroxide, 15-20 parts of an organic solvent, and 4-6 parts of a conductive agent. The modified hollow ceramic fiber is a Li0. 5La0. 5TiO3 hollow ceramic fiber subjected to surface grafting modification by 3-aminopropyltrimethoxysilane, the modified nano aluminum hydroxide is an antioxidant flame retardant grafted modified nano aluminum hydroxide, and the antioxidant flame retardant is a triazine derivative containing a hindered phenol structure and a DOPO (9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) structure. According to the flame-retardant semi-solid gel electrolyte disclosed by the invention, the gel strength of the flame-retardant semi-solid gel electrolyte is improved, meanwhile, the ionic conductivity of the flame-retardant semi-solid gel electrolyte is improved, and the flame-retardant property and the thermal stability of the flame-retardant semi-solid gel electrolyte are improved by adding the modified nano aluminum hydroxide.

The invention provides a flame-retardant polyolefin composition as well as a preparation method and application thereof, and the flame-retardant polyolefin composition comprises the following components in parts by weight: 13-22 parts of an ethylene-vinyl acetate copolymer, 1.5-8.5 parts of linear low density polyethylene, 8-17 parts of a polyolefin elastomer, 35-55 parts of a flame retardant and 0.5-2.5 parts of an antioxidant. The antioxidant comprises a main antioxidant and an auxiliary antioxidant; the main antioxidant comprises a hindered phenol antioxidant and an amine antioxidant; and the auxiliary antioxidant comprises a thioester antioxidant and / or a phosphite ester antioxidant. According to the flame-retardant polyolefin composition disclosed by the invention, the ethylene-vinyl acetate copolymer, the linear low-density polyethylene and the polyolefin elastomer are compounded according to a specific content, and meanwhile, the antioxidant with specific composition is matched, so that the flame-retardant polyolefin composition is good in heat resistance, aging resistance and precipitation resistance; meanwhile, the mechanical property is good.

The invention relates to the field of drain pipes, and discloses an antibacterial polypropylene noise-reduction drain pipe and a preparation method thereof, the antibacterial polypropylene noise-reduction drain pipe comprises polypropylene, modified glass fiber, an antibacterial additive, a compatilizer and a stabilizer; the modified glass fiber is prepared by performing formylation modification on glass fiber by using 3-aminopropyltriethoxysilane and glutaraldehyde, grafting triethylene tetramine and DOPO into a glass fiber structure, and then grafting a hindered phenol antioxidant; the antibacterial additive is prepared by compounding chitosan Schiff base and modified nano titanium dioxide, the chitosan Schiff base is prepared by utilizing a Schiff base reaction between chitosan and vanillin, and the modified nano titanium dioxide is prepared by utilizing isocyanate propyl triethoxy silane and ethyl glycolate to modify nano titanium dioxide. By adding the modified glass fiber and the antibacterial additive, the pipe is endowed with excellent heat resistance, aging resistance, flame retardance and antibacterial performance.

The invention discloses a self-adhesive polymer modified asphalt composite root-resistant waterproof coiled material and a preparation method thereof, and relates to the field of waterproof coiled materials, the self-adhesive polymer modified asphalt composite root-resistant waterproof coiled material comprises an isolating membrane layer, a polymer modified asphalt layer, a tire base layer, a polymer modified asphalt layer and an isolating membrane layer which are sequentially arranged from top to bottom; the physical root resistance effect of the base layer and the chemical root resistance effect of the polymer modified asphalt layer synergistically improve the root resistance performance of the waterproof coiled material. The polymer modified asphalt layer is prepared from petroleum asphalt, aromatic hydrocarbon oil, SBS, modified styrene butadiene rubber, polyisobutene, modified microcapsules and other raw materials; the modified microcapsule is obtained by grafting nano montmorillonite, hindered phenol, thioether group and the like into a wall material urea-formaldehyde resin of an epoxy resin microcapsule, and the modified styrene-butadiene rubber is obtained by grafting DOPO and sorbate group into styrene-butadiene rubber through epoxidized emulsion polymerized styrene-butadiene rubber participating in a reaction. The waterproof coiled material disclosed by the invention has excellent self-repairing capability, flame retardance and antibacterial property, and is worthy of popularization.

The invention discloses a graphene antistatic PC composite material and a preparation method thereof, and belongs to the technical field of composite materials. 150-160 parts of polycarbonate resin, 10-20 parts of modified graphene, 2-5 parts of light stabilizer, 2-5 parts of ultraviolet absorber, and 2-5 parts of lubricant are weighed by weight and added to a high-speed mixer, and sent into a twin-screw extruder after mixing evenly, and after melt extrusion, cooled and pelletized to obtain a graphene antistatic PC composite material. The modified graphene contains graphene, quaternary ammonium salt structure and hindered phenol structure, and the modified graphene contains lipophilic benzene ring and long carbon chain, so the modified graphene has good compatibility with the polycarbonate resin containing benzene ring and other raw materials, and the modified graphene can be evenly dispersed in the composite material, and is not easy to agglomerate, so that the modified graphene can fully play a role, giving the composite material excellent antistatic, antibacterial and anti-aging properties.

The invention provides an insulating material, a preparation method, application and a cable. The insulating material is prepared from the following raw materials: polyethylene, a reactive antioxidant, an initiator, a cross-linking agent and an assistant cross-linking agent. The reactive antioxidant comprises one or more of a hindered phenol group, an allyl group, an acrylic acid group, an acrylate group, a carboxylic acid group, an anhydride group and an anhydride derivative group; the number of impurity particles with the particle size of 50-70 microns contained in the polyethylene is less than 3. The reactive antioxidant can be grafted to a polyethylene molecular chain through melting, and the grafted reactive antioxidant is not easy to migrate in the use process and shows excellent long-term thermal oxidation stability and space charge inhibition capability, so that the electrical performance and thermo-oxidative aging resistance of the insulating material are improved.

The invention discloses a melt blending preparation process of a semiconductive shielding material for an ultrahigh-pressure crosslinked polyethylene cable, which comprises the following steps: S1, premixing low-density polyethylene and an ethylene-vinyl alcohol copolymer in proportion, the vinyl alcohol chain segment content of the ethylene-vinyl alcohol copolymer being 25%-45%; s2, performing plasma surface treatment on carbon black, and compounding the carbon black with carbon nanotubes to form a conductive filler system; s3, under the protection of inert gas, adding the matrix resin in the step S1 and the conductive filler in the step S2 into a double-screw extruder in stages, and synchronously adding a hindered phenol and phosphite compound antioxidant; and S4, carrying out segmented mixing under the temperature gradient of 160-210 DEG C. Through synergistic compounding of the plasma surface modified carbon black and the carbon nanotubes and in combination with a staged feeding process, directional dispersion of the conductive filler is realized, a three-dimensional interpenetrating conductive network is formed, and the local electric field homogenization capability of the ultrahigh-voltage cable is remarkably improved.

The invention discloses modified asphalt and a preparation process thereof, and belongs to the technical field of road materials. The modified asphalt is prepared from 80-90 parts of matrix asphalt, 4-8 parts of butadiene styrene rubber, 2-5 parts of nano montmorillonite, 1.5-3 parts of core-shell structure nanoparticles (the core is SiO2 grafted with-SO3H, the middle layer is thermo-sensitive PNIPAM containing a photoinitiator, and the shell is GO grafted with a hindered phenol antioxidant group and a photosensitive coumarin group), 1-3 parts of a compatilizer, 3-6 parts of a plasticizer and 0.3-0.8 part of an antioxidant. The preparation process comprises the following steps: pretreating the modifier master batch, performing melt blending, performing high-speed shearing, performing ultrasonic dispersion, cooling, discharging and the like. The light response crosslinking mechanism is utilized, crosslinking is achieved under illumination through the light response characteristic of the core-shell structure nanoparticles, the high-temperature stability, the anti-aging performance and the fatigue life of the modified asphalt are remarkably improved, and the modified asphalt is suitable for the fields of high-grade road construction and the like.

The invention discloses an antistatic EVA foam material and a preparation method thereof, and belongs to the technical field of polymer composite materials. The preparation method comprises the following steps: weighing 90-100 parts of EVA, 15-25 parts of an ethylene-octylene copolymer, 10-18 parts of modified graphene, 2-4 parts of a foaming agent, 0.5-1 part of a lubricant, 0.5-1 part of zinc oxide and 0.1-0.5 part of a cross-linking agent, mixing in an internal mixer, mixing in an open mill, pressing the materials into sheets, finally putting the sheets into a preheated plate vulcanizing machine mold cavity, and carrying out mold pressing foaming to obtain the antistatic EVA foaming material. The modified graphene contains a lipophilic long carbon chain and a benzene ring, so that the modified graphene has good compatibility with the remaining raw materials, and the modified graphene containing the graphene, the hindered phenol structure and the quaternary ammonium salt structure can be highly dispersed in the EVA foaming material and fully plays a role, so that the EVA foaming material disclosed by the invention has efficient and lasting antistatic performance, antibacterial performance and anti-aging performance.

The invention relates to the technical field of high polymer materials, and particularly discloses a fluoride-free halogen-free flame-retardant polycarbonate material and a preparation method and application thereof.The fluoride-free halogen-free flame-retardant polycarbonate material is prepared from, by weight, 70-90 parts of polycarbonate resin, 8-15 parts of phosphorus-nitrogen flame retardant and 3-8 parts of silicon flame-retardant synergist, the composite material is prepared from the following raw materials in parts by weight: 20-30 parts of polypropylene, 2-5 parts of nano reinforcing filler, 0.1-0.5 part of hindered phenol antioxidant, 0.1-0.5 part of phosphite ester antioxidant and 0.1-0.5 part of pentaerythritol stearate. Through the synergistic effect of the composite flame-retardant system and the nanofiller, high flame retardance (UL94 V-0 level, 1.5 mm thickness), high heat resistance (the heat distortion temperature is greater than or equal to 130 DEG C) and excellent mechanical property are realized, the control is easy, the processing is stable, good balance of flame retardance and mechanical property is achieved on the premise of environmental protection, and the composite flame-retardant material is suitable for the fields of high-end household appliances and consumer electronics.

The invention discloses a modified polylactic acid material applied to high-speed 3D printing and a preparation method of the modified polylactic acid material. The modified polylactic acid material comprises the following components in parts by weight: 50-80 parts of a polylactic acid material, 10-30 parts of inorganic powder, 1-10 parts of a toughening agent, 0.1-0.5 part of a coupling agent, 0.1-0.4 part of a hindered phenol antioxidant, 0.1-0.4 part of a phosphite antioxidant and 0.2-0.6 part of a plasticizer. The invention has the following beneficial effects: PLA with different flowability is compounded as a base material and is blended with inorganic powder, so that the printing speed of the material reaches 500mm / s, and excellent printability of high precision, no wiredrawing and layer grain covering is achieved; the coupling agent is introduced into a system of the PLA and the inorganic powder, so that the surface polarity of the inorganic powder is improved, the inorganic powder has good compatibility with a resin matrix, and the interlayer adhesive force and the mechanical property of the material are further improved.

The invention relates to the technical field of transfer films, in particular to a graphene-containing far-infrared warm-keeping polyurethane transfer film and a preparation method thereof. The far-infrared warm-keeping polyurethane transfer film containing graphene comprises a three-layer structure including a supporting layer, a polyurethane transfer layer and a bonding layer, the polyurethane transfer layer is located on one side of the supporting layer, and the bonding layer is located on the other side of the polyurethane transfer layer; the polyurethane transfer layer is prepared from polyurethane resin, an organic solvent, an organic pigment and a composite modifier, the composite modifier is prepared from alkenyl modified graphene oxide, chloropropenyl modified hindered phenol and 4-allyloxy-2-hydroxybenzophenone, and the composite modifier is added, so that the polyurethane transfer layer is formed. The polyurethane transfer film has far infrared thermal insulation performance and good oxidation resistance and hydrolysis resistance.

The invention belongs to the field of preparation of insulating materials, and particularly relates to a peroxide crosslinked polyethylene insulating material for a 500kV ultrahigh-voltage direct-current cable and a preparation method of the peroxide crosslinked polyethylene insulating material. The preparation method of the peroxide cross-linked polyethylene insulation material comprises the following preparation steps: adding a low-density polyethylene base material into a reciprocating mixer for preliminary melting, adding hindered phenol antioxidant modified silicon dioxide for uniform mixing, finally adding dicumyl peroxide, and carrying out heat preservation and absorption at 70-110 DEG C for 10-12 hours, so as to obtain the peroxide cross-linked polyethylene insulation material. The peroxide crosslinked polyethylene insulation material is obtained. The hindered phenol antioxidant modified silicon dioxide improves the direct current breakdown strength of the polyethylene insulating material, so that the peroxide crosslinked polyethylene insulating material has excellent performance.

The invention discloses an antistatic agent for polyolefin film material production and a preparation method thereof. According to the invention, through reasonable molecular structure design, raw material selection and synthesis process optimization, the antistatic agent has multiple functions of high-efficiency antistatic property, oxidation resistance, antibacterial property, mechanical property enhancement and the like. The polyolefin material added with the multifunctional antistatic agent has good antistatic performance under different environmental conditions, and the oxidation resistance, the antibacterial property and the mechanical property are also remarkably improved. The antistatic agent has good adaptability with processing of a polyolefin film material and has wide application prospects and market competitive advantages, and the comprehensive performance of the polyolefin film material is remarkably improved through multi-component collaborative design. The composite system of the polyolefin quaternary ammonium salt and the graphene quantum dots strengthens the long-term effect of the antistatic effect, and meanwhile, the synergistic effect of the hindered phenol and the phosphite strengthens the antioxidant stability of the material in the processing and using processes.

The invention relates to the technical field of polyvinyl chloride, and discloses a wear-resistant and aging-resistant PVC (polyvinyl chloride) material.The wear-resistant and aging-resistant PVC material is characterized in that glycidyl acrylate grafted ABS is used as a compatilizer, carboxyl-terminated nitrile rubber is used as a flexibilizer and a wear-resistant modifier, and polyvinyl chloride is subjected to filling modification; the modified polyvinyl chloride can react with terminal carboxyl groups of nitrile rubber, so that nitrile rubber and polyvinyl chloride have better compatibility, and the notch impact strength and wear resistance of the PVC material are improved. The hindered phenol-lanthanum complex stabilizer contains a hindered phenol structure which can capture free radicals generated in the oxidation process, inhibit free radical chain reaction and overcome decomposition of polyvinyl chloride; meanwhile, lanthanum ions in the complex can react with hydrogen chloride generated by thermal decomposition of polyvinyl chloride, so that the phenomenon that the polyvinyl chloride is degraded by the hydrogen chloride is reduced.

The invention discloses a graphene antistatic PC composite material and a preparation method thereof, and belongs to the technical field of composite materials. 150-160 parts of polycarbonate resin, 10-20 parts of modified graphene, 2-5 parts of light stabilizer, 2-5 parts of ultraviolet absorber, and 2-5 parts of lubricant are weighed by weight and added to a high-speed mixer, and sent into a twin-screw extruder after mixing evenly, and after melt extrusion, cooled and pelletized to obtain a graphene antistatic PC composite material. The modified graphene contains graphene, quaternary ammonium salt structure and hindered phenol structure, and the modified graphene contains lipophilic benzene ring and long carbon chain, so the modified graphene has good compatibility with the polycarbonate resin containing benzene ring and other raw materials, and the modified graphene can be evenly dispersed in the composite material, and is not easy to agglomerate, so that the modified graphene can give full play to the effect, giving the composite material excellent antistatic, antibacterial and anti-aging properties.

The invention discloses a preparation method and application of an efficient migration-resistant hindered phenol antioxidant. The preparation method comprises the following steps: dissolving a hindered phenolic compound and an epoxy compound in a solvent to carry out ring-opening reaction, and then further reacting the carboxyl-activated hindered phenolic compound with a ring-opened product to obtain the novel antioxidant with 4-6 hindered phenolic hydroxyl groups in the structure. According to the novel antioxidant disclosed by the invention, on the basis of fully utilizing the capability of capturing free radicals by hindered phenolic hydroxyl, the oxidation resistance of the antioxidant is improved by changing a para-substituent structure, the migration resistance of the antioxidant is improved by changing the molecular weight and the molecular structure, and the service life of the antioxidant in a high polymer material is prolonged. The novel antioxidant has the advantages of simple process preparation, high efficiency, migration resistance and the like.

The invention relates to the technical field of cables, in particular to a high-flexibility ethylene-propylene insulating rubber material for a charging pile cable and a preparation process. The composite material comprises an ethylene propylene diene monomer, a thermoplastic polyolefin elastomer, an ethylene-butylene copolymer, nanoscale magnesium hydroxide, a silane coupling agent, dicumyl peroxide, a hindered phenol antioxidant and a phosphite antioxidant. The ethylene propylene diene monomer and the ethylene-butylene copolymer form a flexible network skeleton, and the ethylene-butylene copolymer and the thermoplastic polyolefin elastomer are subjected to molecular-level blending, so that the elongation at break and the bending fatigue resistance are improved; silane coupling agent modified nano magnesium hydroxide is chemically bonded with a rubber matrix, so that the flame retardance and thermal aging resistance are enhanced, and the negative influence of filler agglomeration on flexibility is reduced; the compound antioxidant system effectively inhibits thermal oxidation degradation at high temperature, avoids insulation failure, realizes collaborative optimization of high flexibility and high heat resistance, and improves the reliability and applicability of the charging pile cable.

The invention provides a PVC (polyvinyl chloride) stabilizer for ultrathin-wall automobile wires and a preparation method of the PVC stabilizer. The PVC stabilizer for the ultrathin-wall automobile wire comprises the following components in parts by weight: 15-25 parts of calcium-zinc composite metal soap, 5-10 parts of hydrotalcite, 3-8 parts of a beta-diketone compound, 2-5 parts of a hindered phenol antioxidant, 1-3 parts of a phosphite ester antioxidant, 2-5 parts of a lubricant, 1-3 parts of an ultraviolet light absorber, 0.5-2 parts of a coupling agent, 4-5 parts of calcined clay and 5-15 parts of filler. According to the PVC stabilizer for the ultrathin-wall automobile wire and the preparation method of the PVC stabilizer, the calcium-zinc composite metal soap, the hydrotalcite, the beta-diketone compound and other stabilizers have a synergistic effect, so that the PVC stabilizer has excellent thermal stability; according to the present invention, the material can effectively inhibit the oxidative degradation of the PVC during the processing and using process, can prolong the service life of the wire, and can provide the good insulation stability through the minimum addition proportion of the calcined clay so as to ensure the thermal stability and the mechanical physical property of the material.

The invention relates to the technical field of adhesives, and discloses an anti-aging polyurethane sealant and a preparation method thereof.The polyurethane sealant is prepared by the steps that polyether polyol and binary isocyanate serve as raw materials and react under the action of a catalyst to form a polyurethane prepolymer, then a functional chain extender is used for conducting chain extension on the prepolymer to form polyurethane latex, and then the polyurethane latex is subjected to heat preservation to form the anti-aging polyurethane sealant. The structure of the functional chain extender contains a hindered phenol antioxidant group, and the hindered phenol antioxidant group is introduced into a polyurethane molecular chain by adopting a chemical grafting mode, so that the aging resistance of the polyurethane sealant can be effectively improved, the aging resistance durability of the polyurethane sealant is guaranteed, and the service life of the polyurethane sealant is prolonged. Therefore, the service life and the application value of the polyurethane sealant are effectively improved.

The invention relates to the field of waterproof materials, and discloses a polymer modified asphalt waterproof material and a preparation method thereof.The polymer modified asphalt waterproof material is prepared from 40%-50% of asphalt, 8%-12% of polymer modifier, 5%-8% of atactic polypropylene, 3%-5% of rubber powder, 0.5%-1% of antioxidant, 0.3%-0.5% of ultraviolet light absorber, 1%-2% of compatilizer and 15%-20% of filler, the polymer modifier is specifically a styrene-butadiene-styrene block copolymer, the antioxidant is specifically a hindered phenol antioxidant, the ultraviolet light absorber is specifically a benzotriazole ultraviolet light absorber, the filler is specifically a mixture of talcum powder and calcium carbonate, the talcum powder accounts for 60-70% of the total amount of the filler, and the calcium carbonate accounts for 10-30% of the total amount of the filler. And calcium carbonate accounts for 30%-40%. By adding the styrene-butadiene-styrene block copolymer modifier, the hindered phenol antioxidant and the benzotriazole ultraviolet light absorber, the service life is remarkably prolonged, the waterproof maintenance frequency and cost of a building are reduced, and a long-acting waterproof defense line is built for the building.

The invention relates to a composite resin material for 3D printing and a preparation method thereof. The material is prepared from the following raw materials in parts by weight: 60-90 parts of polylactic acid, 5-15 parts of a toughening agent, 5-15 parts of a flame retardant, 5-10 parts of modified carbon nanotubes, 0.3-1 part of an anti-hydrolysis agent and 0.3-0.5 part of a lubricant. The flame retardant is added, a phosphate structure, a benzene ring and a hindered phenol structure are introduced into 5, 5 '-dibromo-[2, 2'-bipyridyl]-3, 3 '-diamine, and efficient flame retardance is achieved and the anti-aging performance of the composite resin material is enhanced through multiple synergistic effects of hindered phenol-phosphorus heterocycle-bipyridyl. The modified carbon nanotube is added as a reinforcing agent, so that the mechanical property of the composite resin material is remarkably improved, and the composite resin material is endowed with antibacterial property.

The invention provides low-viscosity high-wear-resistance vehicle engine oil and a preparation method thereof, and belongs to the technical field of engine oil. According to the preparation method, an ionic liquid group is introduced through a reaction, a nano interlayer compound is constructed by combining surface modification of a metal-ionic liquid complex and silicon dioxide nanoparticles, and a microcapsule structure is formed through coating of a urea-formaldehyde prepolymer; the ionic liquid group provides a low friction coefficient and thermal stability, the silicon dioxide nanoparticles provide physical isolation and wear-resistant protection, and the microcapsules realize controlled release and dynamic repair of the lubricating components; a skeleton polymer is prepared through a reaction of polyamidoamine and epoxy chloropropane so as to provide abundant active sites, and oxidation resistance is improved through a synergistic effect of the skeleton polymer, hindered phenol and calixarene; by combining oleic acid modified nanoparticles, the dispersity and the wear resistance are enhanced, and meanwhile, dynamic protection is provided on a friction interface; the synergistic effect prolongs the service life of the engine oil and improves the high-temperature stability of the engine oil.